• 한국표면공학회지
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• 제48권1호
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• pp.1-6
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• 2015

Amino-carboxyl acid as a complexing agent in acid copper sulfate solution was utilized to improve the adhesion of immersion copper layer for steel wire. According to the tape test results, regardless of alloy composition of the wire, the adhesion of immersion copper layer was improved with the addition of amino-carboxyl acid. The incorporation of H and Fe in the plating layer was analyzed by TOF-SIMS. The H and Fe were detected at the entire coating layer without any addition of amino-carboxyl acid. However, with addition of amino-carboxyl acid, the H and Fe were scarcely detected at the coating layer.

• 약학회지
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• 제45권1호
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• pp.46-54
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• 2001

Protein carboxyl Ο-methylation is a kind of enzymatic reaction producing carboxyl methylester catalyzed by protein carboxyl Ο-methyltransferases at the carboxyl group of amino acid residues in polypeptide. Since the finding of carboxyl methylesterl many studies have been focused on the under-standing of biological functions in eukaryotes but still not clear except for roles in Ras attachment to membrane and protein repair. In this study, we investigated the protein carboxyl methylation in porcine liver and testis in respect of identification and characterization of carboxyl methylesters and natural proteinous substrates using pH stability of the esters and electrophoresis under acidic and basic conditions. We detected several kinds of methyl esters, 3 kinds each in cytosolic fractions from liver and testis. Under the treatment of strong acid and base, the ratio between base-stable substrates and unstable ones in liver (4 : 6) was different from the ratio obtained in testis (6 : 4). The methyl accepting capacities were affected by enzymatic proteolysis between the range of 55 to 65% in liver and of 35 to 45% in testis. Separation of the methylated proteins by acidic electrophoresis in the presence of urea and SDS revealed distinctively natural substrates of 26, 33 and 80 kD in the cytosol from liver and of 14, 25, 32 and 86 kD from testis. Most of the labelling, however were lost following electrophoresis under moderate alkaline condition, except for molecules of newly detected 7 and 17 kD in livers and 15, 29, 40 and 80 kD in testis. From these results, it was proposed that protein carboxyl Ο-methylation in each organs may be catalyzed by different classes of protein carboxyl Ο-methyltransferases. In addition, it is suggested that the protein carboxyl methylation in liver and testis may have different patterns in respect of natural substrates.

• Bulletin of the Korean Chemical Society
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• 제16권7호
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• pp.672-674
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• 1995

• 한국토양비료학회지
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• 제18권1호
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• pp.38-49
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• 1985

Sewage sludge를 시용하지 않은 토양(W), 6년간 시용한 토양($WS_6$), Swedge sludge와 토양의 혼합물을 1 주일동안 incubation한 토양( $WS_1$), 그리고 Sewage sludge (SS)로부터 각각 수용성 유기물을 추출, 정제하고 원소분석, 작용기분석을 함과 동시에 IR, UV-VIS, NMR spectroscopy에 의하여 구조적 특성을 조사하였다. SS는 W보다 H, N, P 함량이 많아서 높은 H/C비와 낮은 C/N비로 특징지워 졌으며 total acidity, carboxyl group, phenolic hydroxyl group 함량의 경우 일반적으로 SS가 가장 높았고 그 다음이 $WS_6$, $WS_1$, 그리고 W가 가장 낮았다. Aromatic character나 aromatic carboxyl group 함량은 W가 가장 크고 SS가 가장 적었으며, Aliphatic proton, aliphatic carboxyl group 함량은 SS가 가장 많고 W가 가장 적었다. 단백질 분해산물은 SS에서 풍부했고 W에서는 검출되지 않았다. NMR spectra는 SS의 수소가 W보다 다양한 functional group에 결합되어 있다는 것을 보여 주었으며 aromatic proton의 구조적 주변환경도 SS가 가장 복잡하고 그 다음이 $WS_1$, $WS_6$, 그리고 W가 비교적 단순함을 보여 주었다.

• 폴리머
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• 제31권4호
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• pp.335-342
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• 2007

장시간에 걸친 에이징이 carboxyl acid group을 포함한 수 백 나노 두께의 6FDA계 폴리이미드 박막에 미치는 영향을 박막의 가스투과도와 굴절률의 변화를 통하여 측정하였다. 에이징 시간에 따른 가스투과도의 변화는 carboxyl acid group을 포함한 박막이 이를 포함하지 않은 박막보다 빠른 투과도 감소와 선택도의 증가를 보였으며, 박막 특성의 정량적 분석을 위해 Lorent-Lorentz 이론을 통하여 volume relaxation을 정량화하였다. 박막의 밀도와 부분자유부피는 에이징 시간의 증가에 따라 지속적인 증가 혹은 감소의 경향을 보였으며, 에이징 시간에 따른 가스투과도와 부분자유부피간의 상관관계를 $P=Ae^{(-B/f)}$을 통하여 예측할 수 있었으며, 그 결과는 다른 고분자 분리막이 보인 경향과 일치하였다.

• 대한화학회지
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• 제39권3호
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• pp.213-217
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• 1995

수용액상에서 BUDDA(Butyldithiodiacetic acid), BMDDA(Benzmethyldithiodiac-etic acid), CHDDA(Cyclohexyldithiodiacetic acid)의 IR 스펙트라는 다양한 pH값에서 보고되어진다. 이온화된 carboxyl group과 비이온화된 carboxyl group의 비대칭 신축진동 흡수띠 차이를 이용하여 free-ligand의 구조를 추정한다. 또한 이들 연구의 접근은 리간드의 IR 스펙트라와 전위차 적정법을 이용하여 얻어진 $pk_a$값을 비교함으로서 설명된다.

• 한국세라믹학회지
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• 제48권6호
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• pp.510-515
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• 2011

In this study, as a material used to replace silica fumes for high strength concrete, nano-silica compound with organic functional group for dispersion and with inorganic silica group that can cause a pozzolan reaction is synthesized, These nano silica compound is divided into IC, which is nano size $SiO_2$ with irregularly combined hydroxyl group and carboxyl group, and RC, which is nano size $SiO_2$ with regularly combined hydroxyl group and carboxyl group. The effects of these nano silica compound on the hydration of cement are reviewed. As a result, all of synthesized nano-silica compounds have excellent dispersion on the cement flow, we think that dispersion property is the effect of air entraining by synthesized nano-silica compounds. The result of the microstructure observation showed that the particle size of the synthesized nano-silica is smaller than silica fume and spread evenly among the cement particles. In initial The phenomenon of strength decreasing occurred due to delayed hydration reaction by the synthesized nano-silica with carboxyl(-COOH) and hydroxyl(-OH) functional group.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
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• pp.265-270
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• 2006

This paper reports an improved headspace gas chromatographic method for the determination of carboxyl group content in wood fibers. Pretreatment of wood fibers was applied using dilute HCl to convert carboxyl groups to carboxylic acid groups and then using deionized water to wash fiber samples thoroughly. The samples were finally air dried. Sodium bicarbonate solution was used to react with carboxylic acid groups of the pretreated fibers in a closed testing vial to release carbon dioxide. The content of carboxyl groups in fibers was accurately quantified by determining the amount of carbon dioxide released by a headspace gas chromatograph equipped with a thermal conductivity detector. The modified process for fiber sample pretreatment increased the reliability and accuracy in measuring carboxylic acid groups. The present method is simple, accurate.

• Elastomers and Composites
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• 제48권3호
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• pp.225-231
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• 2013

본 연구에서는 carboxylated SBR latex와 zinc oxide가 SBS 복합재의 내마모성과 debris 특성 개선에 미치는 영향을 관찰하였다. 실리카를 첨가한 SBS 복합재는 실리카 입자간의 수소 결합에 의한 강한 filler-filler interaction으로 인한 낮은 분산성 때문에 기계적 강도, NBS 내마모성, debris 특성이 전체적으로 감소하는 것으로 나타났다. carboxylated SBR latex를 첨가한 SBS 복합재는 carboxyl group과 실리카의 silanol group간의 결합을 통하여 filler-filler interaction이 감소하고 실리카의 분산성이 증가하기 때문에 기계적 강도, NBS 내마모성, debris 특성이 향상되는 것을 확인 하였다. carboxylated SBR latex와 zinc oxide를 동시에 첨가한 경우, carboxyl group에 의한 실리카의 분산성 향상과 더불어 zinc ion과 carboxyl group간의 ion cluster 형성을 통하여 물성이 크게 증가하였다. Zinc ion과 carboxyl group간의 ion cluster 형성은 $1550{\sim}1650cm^{-1}$의 zinc carboxylate group stretch 피크의 FT-IR 분석 결과로 확인하였다. carboxylated SBR latex와 zinc oxide를 첨가한(SC-4) 복합재의 경우, 인장강도 $156kgf/cm^2$, 신장율 936%, 인열강도 59.4kgf/cm의 우수한 기계적 강도를 나타내었으며, NBS 내마모성은 338%로 가장 우수한 특성을 나타내었다. 또한, 표면 마찰 시에 debris 발생 역시 크게 감소하며, 표면 마찰 저항의 증가로 파도 형태의 마모 특성을 나타내었다.

• 한국염색가공학회지
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• 제15권4호
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• pp.17-23
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• 2003

Fourier transform infrared spectroscopy(FT-IR) was used to characterize the intermolecular ester crosslinkages in cotton cellulose. The FT-IR data show that the band of the ester carbonyl group can be separated from overlapping carboxyl/carbonyl band by converting carboxyl group to carboxylate. When esterification occurs between a polycarboxylic acid and cotton cellulose, the carbonyl groups retained in the cotton exist in three forms; ester, carboxyl, and carboxylate anion. The FT-IR data were also correlated to the durable press rating result obtained. The appearance of BTCA-finished durable press silk/cotton fabrics were improved.