• Title/Summary/Keyword: carbonation corrosion

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Corrosion of Steel Rebar in Concrete: A Review

  • Akib Jabed;Md Mahamud Hasan Tusher;Md. Shahidul Islam Shuvo;Alisan Imam
    • Corrosion Science and Technology
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    • v.22 no.4
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    • pp.273-286
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    • 2023
  • Rebar is embedded in concrete to create reinforced concrete (RC). Rebar carries most of the tensile stress and gives compressively loaded concrete fracture resistance. However, embedded steel corrosion is a significant cause of concern for RC composite structures worldwide. It is one of the biggest threats to concrete structures' longevity. Due to environmental factors, concrete decays and reinforced concrete buildings fail. The type and surface arrangement of the rebar, the cement used in the mortar, the dosing frequency of the concrete, its penetrability, gaps and cracks, humidity, and, most importantly, pollutants and aggressive species all affect rebar corrosion. Either carbonation or chlorides typically cause steel corrosion in concrete. Carbonation occurs when carbon dioxide in the atmosphere combines with calcium within the concrete. This indicates that the pH of the medium is falling, and the steel rebar is corroding. When chlorides pass through concrete to steel, corrosion rates skyrocket. Consideration must be given to concrete moisture. Owing to its excellent resistance, dry concrete has a low steel corrosion rate, whereas extremely wet concrete has a low rate owing to delayed O2 transfer to steel surfaces. This paper examines rebar corrosion causes and mechanisms and describes corrosion evaluation and mitigation methods.

Corrosion-Resisting Performance Evaluation of Concrete Mixed with Fly-Ash (플라이애시 혼합 콘크리트의 철근 부식 저항성능 평가)

  • Park, Sang-Soon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.1
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    • pp.117-125
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    • 2017
  • The role of fly ash in concrete become impotent with finding the characteristics of fly ash in which it is used as cement replacement material. In this paper, corrosion test results obtained by two test methods such as the long-term exposure corrosion test and the accelerated corrosion test method, were compared to investigated the corrosion resistance between fly ash concrete and normal concrete. Corrosion initiation time was measured in two types of concrete, i.e., one mixed with fly ash(FA) and the other without admixture(OPC). The accelerated corrosion test was carried out by four case, i.e., two samples is a cyclic drying-wetting method combined without carbonation(case 1) and combined with carbonation(case 2), and the other two samples is a artificial seawater ponding test method combined without carbonation(case 3) and combined with carbonation(case 4). Whether corrosion occurs, it was measures using half-cell potential method. The ponding test combined without carbonation was most effective in accelerating corrosion time of steel bars. The results indicated that the corrosion of rebar embedded in concrete occurred according to the order of OPC, FA. The delay relative ratio of corrosion obtained by corrosion initiation time between FA and OPC is 1.04 to 1.27. Consequently, fly ash concrete as the age increases its corrosion resistance was improved compared with OPC concrete.

The experimental study on the compressive strength for cementitious material using CO2 curing (CO2 양생을 이용한 시멘트계 재료의 압축강도 발현에 관한 실험적 연구)

  • Sung, Myung-Jin;Ryu, Hwa-Sung;Shin, Sang-Heon;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.05a
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    • pp.264-265
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    • 2014
  • Currently, CO2 existed in the air usually reacts concrete, and then CaCO3 can be appeared. As time goes by, pH of concrete is decreased and corrosion of steel can be happened. This phenomenon is called carbonation. For preventing carbonation of concrete, various methods like using corrosion inhibitor, high compressive strength concrete, and enough covering depth are adopted. But these method are usually passive methods focused on corrosion of steel and have limitation on economic. Thus, as basic study for active method of carbonation, cement pastes with CO2 reactive material (γ-C2S, MgO) and GBFS were in accelerated carbonation, and the compressive strengths were measured. On the result, the compressive strength was improved better than non-carbonation. Through measuring the weight change using TG-DTA, as specimens were carbonated, according to decreasing of Ca(OH)2 and Mg(OH)2, CaCO3 and MgCO3 were increased. Therefore it can be shown that carbonation curing can be realized.

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Practical applicable model for estimating the carbonation depth in fly-ash based concrete structures by utilizing adaptive neuro-fuzzy inference system

  • Aman Kumar;Harish Chandra Arora;Nishant Raj Kapoor;Denise-Penelope N. Kontoni;Krishna Kumar;Hashem Jahangir;Bharat Bhushan
    • Computers and Concrete
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    • v.32 no.2
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    • pp.119-138
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    • 2023
  • Concrete carbonation is a prevalent phenomenon that leads to steel reinforcement corrosion in reinforced concrete (RC) structures, thereby decreasing their service life as well as durability. The process of carbonation results in a lower pH level of concrete, resulting in an acidic environment with a pH value below 12. This acidic environment initiates and accelerates the corrosion of steel reinforcement in concrete, rendering it more susceptible to damage and ultimately weakening the overall structural integrity of the RC system. Lower pH values might cause damage to the protective coating of steel, also known as the passive film, thus speeding up the process of corrosion. It is essential to estimate the carbonation factor to reduce the deterioration in concrete structures. A lot of work has gone into developing a carbonation model that is precise and efficient that takes both internal and external factors into account. This study presents an ML-based adaptive-neuro fuzzy inference system (ANFIS) approach to predict the carbonation depth of fly ash (FA)-based concrete structures. Cement content, FA, water-cement ratio, relative humidity, duration, and CO2 level have been used as input parameters to develop the ANFIS model. Six performance indices have been used for finding the accuracy of the developed model and two analytical models. The outcome of the ANFIS model has also been compared with the other models used in this study. The prediction results show that the ANFIS model outperforms analytical models with R-value, MAE, RMSE, and Nash-Sutcliffe efficiency index values of 0.9951, 0.7255 mm, 1.2346 mm, and 0.9957, respectively. Surface plots and sensitivity analysis have also been performed to identify the repercussion of individual features on the carbonation depth of FA-based concrete structures. The developed ANFIS-based model is simple, easy to use, and cost-effective with good accuracy as compared to existing models.

Current Status on the Chloride Content and Carbonation of Train Structures in the East (동해안 39개 철도구조물의 염화물 함유량과 중성화에 대한 현황분석)

  • Lee, Young-Jae;Kim, Yong-Hee;Lee, Yoon-Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.7 no.1
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    • pp.259-266
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    • 2003
  • Recently, the premature corrosion for reinforced concrete structure exposed to chloride bring about a serious problem in concrete structures. Specially, the concrete structures of sea coast are exposed much to chloride which make rapid corrosion. Thus, construction activities and maintenances for marine facilities are more demanded than those for land structures. The results of this study have been analysed to identify the extent of chloride content and incidence of carbonation for construction age. After measuring chloride content in concrete, it was conclued that about 90% of all tests on concrete samples exceed the acceptable maximum limit to risk of chloride-induced carbonation. The carbonation rate coffnient by age of train structures in the east eatimated 6. 55, 4.76 grater than 3. 727. In the basis of this result, it is necessary to maintenance for the important train facilities with the regular tests of chloride and carbonation.

Predicting on Service Life of Concrete by Steel Corrosion (철근부식에 의한 육지 콘크리트의 수명예측)

  • 정우용;손영무;윤영수;이진용
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.04a
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    • pp.682-687
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    • 2000
  • In this research the remaining service life of the concrete due to the steel corrosion was predicted by three cases; causing carbonation, using sea sand, using deicing salts. In case of deterioration by carbonation, effective carbonation depth, effective coverage depth and relative humidity are considered for predicting method. In case of using sea sand, predicting method is made of rust growth equation from polarization resistance method. In case of using deicing salts, predicting method is made of transformation of Fick's law. Three methods are very useful in predicting service life of concrete.

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Applicability Study of the Rapid Carbonation Test Equipment for Concrete (콘크리트 급속 촉진 탄산화 장비의 적용성 연구)

  • Choi, Young-Jun;Lee, Kwang-Myong;Kim, Joo-Hyung;Jung, Sang-Hwa;Lee, Myung-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.601-604
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    • 2006
  • Reinforcement corrosion is the most important durability problem of reinforced concrete structures. One of the important factors affecting the steel corrosion is carbonation. However, existing carbonation test takes several months to obtain the results. Therefore, in this study, new rapid carbonation test equipment for concrete was developed and its applicability was investigated. The testing period can be reduced by increasing $CO_2$ concentration up to 100% in the equipment. It is found from the test results that the carbonation depth of concrete specimens tested for 2 weeks was $3{\sim}5$ times greater than that of specimens tested by existing test method. In conclusion, it would be possible to get the reliable test results enough to evaluate the durability of concrete structures in a short-period.

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Probabilistic service life of box culvert due to carbonation of concrete cover

  • Woo, Sang-Kyun;Chu, In-Yeop;Lee, Yun;Lee, Byung-Jae
    • Advances in concrete construction
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    • v.12 no.6
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    • pp.517-525
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    • 2021
  • More underground structures are increasingly being constructed such as box culverts for electric power transmission, and the life extension of these structures is very important. It is well known that the steel embedded in concrete is usually invulnerable to corrosion because the high alkalinity of the pore solution in concrete generates a thin protective oxide layer on the surface of the steel. Recent observations in the field and experimental evidence have shown that even steel in concrete can be corroded through the carbonation reaction of cover concrete. Carbonation-induced corrosion in concrete may often occur in a high carbon dioxide environment. In this study, the risk of carbonation of underground box culverts in Korea was evaluated by measuring the car¬bonation rate and concrete cover depth in the field. Then, the carbonation-free service life for the cover depth of the steel was calcu¬lated with in situ information and Monte Carlo simulation. Additionally, an accelerated carbonation test for a cracked beam specimen was performed, and the effect of a crack on the service life of a box culvert was numerically investigated with Monte Carlo simulation based on experimental results.

A Study on the Investigation of Remaining Life for the Domestic Reinforced-Concrete Apartment by the Corrosion Probability of Reinforcing-steel (철근부식확률에 의한 국내 철근콘크리트조 아파트구조물의 잔여수명 검토에 관한 연구)

  • 강석표;김규용;권영진;정성철;이덕찬;송병창;김무한
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10c
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    • pp.223-228
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    • 1998
  • This study is to investigate on the remaining life of reinforced concrete apartment by using the probability of a reinforcing-steel corrosion and the carbonation tendency of domestic reinforced concrete apartments by using the statistic method. The results are as follow. ·To compare with the carbonation velocity of Kishitani's formula (x=3.727{{{{ SQRT { t} }}) when water-cement ratio is w=0.6, R=1, it is founded out that the carbonation velocity is slow a little in all area investigated and inland area, and fast a bit in coastal area. ·In the influencing factors in regard to the probability of reinforcing-steel corrosion, It seems that the influence of elapsed time is more effective than that of region. Therefore, it is necessary that it makes sure of the cover depth under apartment construction in recent so far as the durability is considered.

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Corrosion Properties of Reinforced Concrete with Types of Surface Cover and Covering Depth under the Combined Deterioration Environments (복합열화 환경하에서 표면피복종류 및 피복두께에 따른 철근콘크리트의 부식특성)

  • Kim, Moo-Han;Kwon, Young-Jin;Kim, Young-Ro;Kim, Jae-Hwan;Jang, Jong-Ho;Cho, Bong-Suk
    • Journal of the Korea Institute of Building Construction
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    • v.4 no.1
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    • pp.119-126
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    • 2004
  • Generally, reinforced concrete is one of the most commonly used structural materials and it prevents corrosion of steel bar by high pH of interior, But, as time elapsed, reinforced concrete structure become deteriorated by many of combined deterioration factors and environmental conditions. And, there are large number of deteriorate mechanism of the reinforced concrete structure and it acts complexly. It is recognized that steel bar corrosion is the main distress behind the present concern regarding concrete durability. In this study, to institute combined deterioration environments, established acceleration condition and cycle for combined deterioration environments has a resemblance to environments which are real structures placed. After that to confirm corrosion properties of reinforced concrete due to permeability with covering depth and types of surface cover under combined deterioration environments, measured carbonation velocity coefficients, chloride ion diffusion coefficients, water absorption coefficients, air permeability coefficients and electric potential, corrosion area ratio, weight reduction, corrosion velocity of steel bar. The results showed that an increase in age also decrease carbonation velocity coefficients, increase Chloride ion diffusion coefficients and increases water absorption coefficients. As well, an increase in age also increases corrosion of steel bar. Data on the development of corrosion velocity of steel bar with types of surface cover made with none, organic B, organic A, inorganic B, and inorganic A is shown. As well, permeability and corrosion velocity of steel bar with covering depth is superior to 10mm than 20mm. And it is confirmed permeability and corrosion properties of steel bar are closely related.