• Journal of the Korea institute for structural maintenance and inspection
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• v.12 no.3
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• pp.84-92
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• 2008

This study is to investigate the flexural performance of Near Surface Mounted (NSM) strengthening method using Fiber reinforced Polymer (FRP) materials to concrete structures. For this study, the inverse-shaped trapezoid CFRP composite material which has been registered as New Excellent Technology (NET) 351 was adopted to the concrete structure. In this study, two types of the CFRP types were considered; Type A ($15{\times}13{\times}6mm$) and Type B ($4{\times}3{\times}10mm$) with different strengthening ratio. In the result of the test, it was proved that NSM strengthened specimens had more flexural performance of 20-100% than that of the unstrengthened specimen. With this test result, the structural efficiency was investigated based on the coefficient of ductility and coefficient of crack resistance.

• Journal of the Korean Institute of Gas
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• v.27 no.3
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• pp.52-58
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• 2023

With the increasing awareness of the importance of carbon neutrality in response to global climate change, the utilization of hydrogen as a carbon-free fuel source is also growing. Hydrogen is commonly used in fuel cells (FC), but it can also be utilized in internal combustion engines (ICE) that are based on combustion. Particularly, ICEs that already have established infrastructure for production and supply can greatly contribute to the expansion of hydrogen energy utilization when it becomes difficult to rely solely on fuel cells or expand their infrastructure. However, a disadvantage of utilizing hydrogen through combustion is the potential generation of nitrogen oxides (NOx), which are harmful emissions formed when nitrogen in the air reacts with oxygen at high temperatures. In particular, for the EURO-7 exhaust regulation, which includes cold start operation, efforts to reduce exhaust emissions during the warm-up process are required. Therefore, in this study, the characteristics of nitrogen oxides and fuel consumption were investigated during the warm-up process of cooling water from room temperature to 88℃ using a 2-liter direct injection spark ignition (SI) engine fueled with hydrogen. One advantage of hydrogen, compared to conventional fuels like gasoline, natural gas, and liquefied petroleum gas (LPG), is its wide flammable range, which allows for sparser control of the excessive air ratio. In this study, the excessive air ratio was varied as 1.6/1.8/2.0 during the warm-up process, and the results were analyzed. The experimental results show that as the excessive air ratio becomes sparser during warm-up, the emission of nitrogen oxides per unit time decreases, and the thermal efficiency relatively increases. However, as the time required to reach the final temperature becomes longer, the cumulative emissions and fuel consumption may worsen.

• Economic and Environmental Geology
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• v.42 no.4
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• pp.315-333
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• 2009

In this study, the hydrochemical and the isotopic characteristics of major streams in the Daejeon area were investigated during rainy and dry seasons. The stream water shows the electrical conductivity of the range of $37{\sim}527{\mu}s$/cm, and pH $6.21{\sim}9.83$. The chemical composition of stream waters can be grouped as three types: the upper streams of Ca(Mg)-$HCO_3$ type, Ca(Mg)-$SO_4(Cl)$ type of middle streams flowing through urban area, and Na(Ca)-$HCO_3$(Cl, $SO_4$) type of the down streams. Based on in-situ investigation, the high pH of stream waters flowing through urban area is likely to be caused by the inflow of a synthetic detergent discharging from the apartment complex. The electrical conductivity of stream waters at a dry season is higher than those of at a rainy season. We suggest that the hydro-chemical composition of stream waters in the Daejeon area was affected by the discharging water from the sewage treatment facilities and anthropogenic contaminants as well as the interaction with soil and rocks. ${\delta}D$ and ${\delta}^{18}O$ values of the stream waters show the relationship of ${\delta}D=6.45{\delta}^{18}O-7.4$, which is plotted at a lower area than global meteoric water line(GMWL) of Craig(1961). It is likely that this isotopic range results from the evaporation effect of stram waters and the change of an air mass. The isotope value shows an increasing trend from upper stream to lower stream, that reflects the isotopic altitude effect. The relationship between ${\delta}^{13}C$ and $EpCO_2$ indicates that the carbon as bicarbonate in stream water is mainly originated from $CO_2$ in the air and organic materials. The increasing trend of ${\delta}^{13}C$ value from upper stream waters to lower stream waters can be attributed to the following reasons: (1) an increasing dissolution of $CO_2$ gas from a contaminated air in downtown area of the Daejeon, and (2) the increment of an inorganic carbon of groundwater inflowed into stream by base flow. Based on the relationship between ${\delta}^{34}S$ and $SO_4$ of stream waters, the stream waters can be divided into four groups. $SO_4$ content increases as a following order: upper and middle Gab stream${\delta}^{34}S$ value decreases as above order. ${\delta}^{34}S$ value indicates that sulfur of stream waters is mainly originated from atmosphere, and is additionally supplied by pyrite source according to the increase of sulfate content. The sulfur isotope analysis of a synthetic detergent and sewage water as a potential source of the sulfur in stream waters is furtherly needed.

• Resources Recycling
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• v.28 no.5
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• pp.60-67
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• 2019

A valuable metal recovery from waste resources such as spent rechargeable secondary batteries is of critical issues because of a sharp increase in the amount of waste resources. In this context, it is necessary to research not only recycling waste lithium-ion batteries (LIBs), but also reusing valuable metals (e.g., Li, Co, Ni, Mn etc.) recovered from waste LIBs. In particular, the lithium hydroxide ($LiOH{\cdot}xH_2O$), which is of precursors that can be prepared by the recovery of Li in waste LIBs, can be reused as a catalyst, a carbon dioxide absorbent, and again as a precursor for cathode materials of LIB. However, most studies of recycling the waste LIBs have been focused on the preparation of lithium carbonate with a recovery of Li. Herein, we show the preparation of high purity lithium hydroxide powder along with the precipitation process, and the systematic study to find an optimum condition is also carried out. The lithium carbonate, which is recovered from waste LIBs, was used as starting materials for synthesis of lithium hydroxide. The optimum precipitation conditions for the preparation of LiOH were found as follows: based on stirring, reaction temperature $90^{\circ}C$, reaction time 3 hr, precursor ratio 1:1. To synthesize uniform and high purity lithium hydroxide, 2-step precipitation process was additionally performed, and consequently, high purity $LiOH{\cdot}xH_2O$ powder was obtained.

• Resources Recycling
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• v.32 no.1
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• pp.50-59
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• 2023

The amount of dust generated during the dissolution of scrap in an electric arc furnace is approximately 1.5% of the scrap metal input, and it is primarily collected in a bag filter. Electric arc furnace dust primarily consists of zinc and ion. The processing of zinc starts with its conversion into pellet form by the addition of a carbon-based reducing agent(coke, anthracite) and limestone (C/S control). These pellets then undergo reduction, volatilization, and re-oxidation in rotary kiln or RHF reactor to recover crude zinc oxide (60%w/w). Next, iron is discharged from the electric arc furnace dust as a solid called Fe clinker (secondary by-product of the Fe-base). Several methods are then used to treat the Fe clinker, which vary depending on the country, including landfilling and recycling (e.g., subbase course material, aggregate for concrete, Fe-source for cement manufacturing). However, landfilling has several drawbacks, including environmental pollution due to leaching, high landfill costs, and wastage of iron resources. To improve Fe recovery in the clinker, we pulverized it into optimal -sized particles and employed specific gravity and magnetic force selection methods to isolate this metal. A carbon-based reducing agent and a binding material were added to the separated coarse powder (>10㎛) to prepare briquette clinker. A small amount (1-3%w/w) of the briquette clinker was charged with the scrap in an electric arc furnace to evaluate its feasibility as an additives (carbonaceous material, heat-generating material, and Fe source).

• Clean Technology
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• v.22 no.4
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• pp.258-268
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• 2016

In this work, carboxymethylcellulose-based composite superabsorbent hydrogels were prepared by electron beam radiation. The composition of carboxymethylcellulose (CMC) varied from 4 wt%, 5 wt%, and 6 wt% to 7 wt% based on the amount of distilled water in the syntheses of hydrogels. Graphite oxide, reduced graphene oxide, activated carbon, and bentonite were used as additives for the synthesis of composite superabsorbent. The effect of CMC composition and the type of additives on the gel properties of the prepared hydrogels was investigated. In order to verify the functional groups in the prepared materials, Fourier transform infrared spectroscopy was used. In addition, mechanical strength, gel fraction, swelling kinetics, and equilibrium swelling ratios were measured for the prepared hydrogels. Swelling experiments were carried out in distilled water, urea solution, and physiological saline water. Prepared hydrogels were reused for 5 times, and gel fraction and swelling ratio were measured at every 24 hours. Among the prepared hydrogels, $C_{5%}GO$ and $C_{5%}rGO$ exhibited excellent mechanical property and relatively high swelling ratios for urea solution and physiological saline water with promising applicability as slow-release fertilizers.

• Korean Chemical Engineering Research
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• v.48 no.2
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• pp.147-156
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• 2010

There are four key factors for gas-phase biofilters; biocatalysts(microorganisms), packing materials, design/operating techniques, and diagnosis/management techniques. Biofilter performance is significantly affected by microbial community structures as well as loading conditions. The microbial studies on biofilters are mostly performed on basis of culture-dependent methods. Recently, advanced methods have been proposed to characterize the microbial community structure in environmental samples. In this study, the physiological, biochemical and molecular methods for profiling microbial communities are reviewed, and their applicability to biofilters is discussed. Community-level physiological profile is based on the utilization capability of carbon substrate by heterotrophic community in environmental samples. Phospholipid fatty acid analysis method is based on the variability of fatty acids present in cell membranes of different microorganisms. Molecular methods using DNA directly extracted from environmental samples can be divided into "partial community DNA analysis" and "whole community DNA analysis" approaches. The former approaches consist in the analysis of PCR-amplified sequence, the genes of ribosomal operon are the most commonly used sequences. These methods include PCR fragment cloning and genetic fingerprinting such as denaturing gradient gel electrophoresis, terminal-restriction fragment length polymorphism, ribosomal intergenic spacer analysis, and random amplified polymorphic DNA. The whole community DNA analysis methods are total genomic cross-DNA hybridization, thermal denaturation and reassociation of whole extracted DNA and extracted whole DNA fractionation using density gradient.

• Journal of the Korean Wood Science and Technology
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• v.45 no.5
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• pp.588-598
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• 2017

Currently, bioethanol, a fuel additive for transportation, is produced mainly by using biomass (first generation) such as corn and sugar canes. First generation biomass can cause various problems in terms of increase in agricultural prices and ethical reasons. To address these problems, a nonedible lignocellulosic biomass can be utilized. Agricultural byproducts such as straw, bagasse, and forest byproducts from the wood processing industry. Therefore, production of wood based bioethanol can be an effective utilization route of second generation biomass, and its raw materials are more abundant than first generation resources. Furthermore, it is possible to secure cheap raw materials. One of the biggest advantages of using biofuels is that it contributes to the reduction of greenhouse gases by minimizing the environmental impact, unlike fossil fuels. In this study, we investigated the greenhouse gas reduction effects that can be achieved through the use of Lignocellulosic bioethanol and government policies on renewable energy currently being implemented in ASEAN countries (Indonesia, Malaysia, Thailand and the Philippines). In these four countries, policies and incentives related to biofuels have been developed. It is expected that the reduction ratio of carbon dioxide emission and the mixed biofuel will be gradually increased in the future.

• Journal of the Korean Society of Marine Environment & Safety
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• v.19 no.6
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• pp.674-680
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• 2013

As the range of marine leisure activity gradually expands to ocean-going, a habitable cruise boat has been getting the limelight. Advanced countries in the marine leisure industry in Europe and North America have already secured their competitiveness in designing and building cruise boats by elegant design, ergonomic structure and fuel efficiency through the adoption of light-weight hull materials. In contrast, mostly small power boats are developed and built in Korea, and GFRP take up the most of hull materials. This study inquired into the design and characteristics of a 50ft-class CFRP that ocean-going is possible. The hull-form of the CFRP cruise boast were analyzed to propose a hull form for the designed ship (MMU-C.B), and based on that, the design model of the MMU-C.B was built. Finally, the MMU-C.B's characteristics of the resistance performance and hull-planing were found by comparative reviews with the results of model tests of GFRP pleasure yachts.

• Korean Journal of Materials Research
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• v.9 no.9
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• pp.896-899
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• 1999

A carbon dioxide gas sensor was studied as a function of temperature and $CO_2$concentration in the Li$_2$ZrO$_3$ system. Lithium zirconate(Li$_2$ZrO$_3$) was synthesized by the heat-treatment of zirconia(ZrO$_2$)and Lithium carbonate(Li$_2$CO$_3$). The specimens were prepared both as bulk disk, 10mm in diameter and 1.0mm thickness, and thick films on an alumina substrate. Lithium zirconate readily responded to $CO_2$concentration from 0.1% to 100% in the range of 45$0^{\circ}C$ to $650^{\circ}C$. The sensitivity to $CO_2$ was dependent on the measuring temperature. Lithium zirconate(Li$_2$ZrO$_3$) decomposes into Li$_2$CO$_3$ and ZrO$_2$after the reaction with $CO_2$in the range of 45$0^{\circ}C$ to $650^{\circ}C$. Li$_2$CO$_3$ changes into Li$_2$O and $CO_2$ above $650^{\circ}C$. The material showed difficulty with reversibility and recovery. The optimum temperature for the highest sensitivity is around 55$0^{\circ}C$.