• 제목/요약/키워드: carbon-based materials

검색결과 1,351건 처리시간 0.035초

Synthesis of Graphene on Hexagonal Boron Nitride by Low Pressure Chemical Vapor

  • Han, Jae-Hyun;Yeo, Jong-Souk
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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    • pp.391-392
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    • 2012
  • Graphene is a perfectly two-dimensional (2D) atomic crystal which consists of sp2 bonded carbon atoms like a honeycomb lattice. With its unique structure, graphene provides outstanding electrical, mechanical, and optical properties, thus enabling wide variety of applications including a strong potential to extend the technology beyond the conventional Si based electronic materials. Currently, the widespread application for electrostatically switchable devices is limited by its characteristic of zero-energy gap and complex process in its synthesis. Several groups have investigated nanoribbon, strained, or nanomeshed graphenes to induce a band gap. Among various techniques to synthesize graphene, chemical vapor deposition (CVD) is suited to make relatively large scale growth of graphene layers. Direct growth of graphene on hexagonal boron nitride (h-BN) using CVD has gained much attention as the atomically smooth surface, relatively small lattice mismatch (~1.7%) of h-BN provides good quality graphene with high mobility. In addition, induced band gap of graphene on h-BN has been demonstrated to a meaningful value about ~0.5 eV.[1] In this paper, we report the synthesis of grpahene / h-BN bilayer in a chemical vapor deposition (CVD) process by controlling the gas flux ratio and deposition rate with temperature. The h-BN (99.99%) substrate, pure Ar as carrier gas, and $CH_4$ are used to grow graphene. The number of graphene layer grown on the h-BN tends to be proportional to growth time and $CH_4$ gas flow rate. Epitaxially grown graphene on h-BN are characterized by scanning electron microscopy, atomic force microscopy, and Raman spectroscopy.

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음향방출 에너지 기반 손상 위치표정 기법을 이용한 복합재 CNG 탱크의 충격 신호 위치표정 (Impact Source Location on Composite CNG Storage Tank Using Acoustic Emission Energy Based Signal Mapping Method)

  • 한병희;윤동진;박춘수;이영신
    • 비파괴검사학회지
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    • 제36권5호
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    • pp.391-398
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    • 2016
  • 음향방출기법은 구조물에 존재하는 손상 및 손상 메커니즘을 규명하는 가장 유효한 비파괴검사 수단으로 널리 이용되고 있다. 그러나 기존의 손상위치표정 기법은 탄성파 전파 속도에 크게 의존하는 기법의 한계에 의하여 복합재료 또는 이종의 재료로 구성된 구조물에서의 손상을 탐지하기 어려운 한계점을 가지고 있다. 최근 다양한 분야에서 사용되고 있는 압축천연가스(CNG) 저장용기는 무게와 강성의 효율을 위하여 복합재료를 사용하여 외부를 보강하는 새로운 형태의 구조를 사용하고 있다. 이러한 다층 복합소재의 사용으로 기존의 손상탐지기법으로는 저장용기의 외부에서 가해지는 충격 혹은 결함에 의한 저장탱크에 발생한 손상의 측정이 매우 어렵게 되었다. 이러한 한계를 극복하기 위하여 본 연구에서는 선행연구를 통하여 개발된 에너지 기반 contour D/B map 기법을 이용하여 4 가지 형식의 CNG 저장탱크에 발생한 외부 충격 신호의 손상 위치를 측정하였다. 각각의 형식의 저장탱크에서 측정된 손상 위치 결과를 비교 분석하여 새로운 기법의 측정 성능을 알아보았다.

THz 전자기파를 이용한 나노시멘트 광학물성 측정 (Measurement of Optical Properties of Nano-Cement Using THz Electromagnetic Waves)

  • 김헌영;강동훈;오승재;주철민
    • 비파괴검사학회지
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    • 제36권5호
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    • pp.363-369
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    • 2016
  • 탄소나노튜브와 그래핀 등으로 대표되는 탄소 동소체기반 나노재료의 우수한 기계적 특성을 이용해 콘크리트의 압축강도를 증가시키기 위한 연구가 활발히 진행되고 있다. 일반적으로, 나노재료 적용을 통한 강도 향상을 위해서는 콘크리트 내 나노재료의 분산성이 높아야 하며, 이를 검증하기 위해 외부에서 비파괴적으로 확인할 수 있는 검사 기술이 요구된다. 본 연구에서는, 적외선의 직진성과 마이크로파의 투과성을 동시에 갖고 있는 THz 전자기파를 이용하여 MWCNT 및 GO가 포함된 두 종류의 나노시멘트 모르타르 시편을 제작하여 굴절률 및 흡수율과 같은 기초 광학물성 측정 시험을 수행하였다. 시험을 통해 일반 시멘트 모르타르에 비해 나노재료가 포함된 시편에서 굴절률은 평균 1.0~2.5%, 흡수율은 평균 -14~28% 차이로 측정됨을 확인하였다. 이를 통해, 비파괴적으로 콘크리트 내부에 포함된 나노재료의 분포도를 영상화할 수 있는 기술의 실현 가능성을 확인하였다.

A nonlocal quasi-3D theory for bending and free flexural vibration behaviors of functionally graded nanobeams

  • Bouafia, Khadra;Kaci, Abdelhakim;Houari, Mohammed Sid Ahmed;Benzair, Abdelnour;Tounsi, Abdelouahed
    • Smart Structures and Systems
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    • 제19권2호
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    • pp.115-126
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    • 2017
  • In this paper, size dependent bending and free flexural vibration behaviors of functionally graded (FG) nanobeams are investigated using a nonlocal quasi-3D theory in which both shear deformation and thickness stretching effects are introduced. The nonlocal elastic behavior is described by the differential constitutive model of Eringen, which enables the present model to become effective in the analysis and design of nanostructures. The present theory incorporates the length scale parameter (nonlocal parameter) which can capture the small scale effect, and furthermore accounts for both shear deformation and thickness stretching effects by virtue of a hyperbolic variation of all displacements through the thickness without using shear correction factor. The material properties of FG nanobeams are assumed to vary through the thickness according to a power law. The neutral surface position for such FG nanobeams is determined and the present theory based on exact neutral surface position is employed here. The governing equations are derived using the principal of minimum total potential energy. The effects of nonlocal parameter, aspect ratio and various material compositions on the static and dynamic responses of the FG nanobeam are discussed in detail. A detailed numerical study is carried out to examine the effect of material gradient index, the nonlocal parameter, the beam aspect ratio on the global response of the FG nanobeam. These findings are important in mechanical design considerations of devices that use carbon nanotubes.

국내에서 유통되는 활성탄을 이용한 벤젠, 톨루엔, 아세톤 및 노말 헥산의 등온흡착용량 평가 연구 (Research on the Adsorption Capacity for Benzene, Toluene, Acetone and N-hexane of Activated Carbon Acquired fromthe Domestic Market)

  • 이나루;이광용;박두용
    • 한국산업보건학회지
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    • 제24권2호
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    • pp.193-200
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    • 2014
  • Objectives: To develop domestic charcoal tubes with good adsorption capacity, breakthrough experiments were performed on four types of activated charcoal. Materials: The adsorption capacity and the adsorption rate were determined using a modified Wheeler equation after the breakthrough experiment. For four types of charcoal (J, K, S and SKC Inc. 226-01), 100 mg were used in the breakthrough experiment. The test was done on benzene, toluene, n-hexane, and acetone in a dynamic chamber. Results: K charcoal had the greatest surface area and the highest micropore volume. J charcoal had a similar surface area and micropore volume to SKC charcoal. S charcoal had the lowest surface area and micropore volume. J charcoal had the highest adsorption capacity at 101, 252 and 609 ppm of benzene. The gap in benzene adsorption capacity among the types of charcoal was the least at 609 ppm and the greatest at 101 ppm. J charcoal showed the highest adsorption capacity at 54, 106, 228 and 508 ppm of toluene. J charcoal and SKC charcoal had a similar adsorption capacity for acetone. J charcoal had the highest adsorption capacity for n-hexane. In the experiment featuring 10% breakthrough volume, 10% breakthrough occurred at 18 liters at $2065.9mg/m^3$ for J charcoal and at 20 liters at $1771.2mg/m^3$ for K charcoal. It was difficult to judge adsorption capacity by surface area and micropore volume of charcoal. J charcoal, which was similar to SKC charcoal in surface area and micropore volume, showed good adsorption capacity at common workplace concentrations. Conclusions: The adsorption capacity of J and K charcoal was superior compared with SKC charcoal. J and K charcoal can be considered appropriate for use as sampling media based on this result.

격자-강화된 다기능 복합재 구조체의 방사차폐에 관한 연구 (A Study on Radiation Shielding for Grid-stiffened Multi-Functional Composite Structures)

  • 장태성;이주훈;서현석;현범석;김택영;서정기
    • 한국항공우주학회지
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    • 제42권8호
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    • pp.629-639
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    • 2014
  • 강성이 우수하고, 경량으로 제작이 가능한 격자강화 복합재 구조체를 다기능 구조체의 기층구조로 적용함으로써, 전기전자회로를 용이하게 내장할 수 있으며 방사차폐 특성을 갖춘 다기능 구조체에 대한 설계 및 제작을 수행하였다. 피치계열 탄소섬유 복합재료의 적용을 통해 열전달특성을 향상시키고, 전자회로의 하우징 구조물이 없어도 우주방사환경에 충분한 내구성을 갖도록 경량 국부 강화 방사차폐 방법을 제안하고, 양성자 조사시험을 통하여 선택적 방사차폐의 효과를 검증하였다.

다중가스센서를 이용한 화재의 조기검출에 대한 연구 (A Study on the Early Fire Detection by Using Multi-Gas Sensor)

  • 조시형;장향원;전진욱;최석임;김선규;강종위;최삼진;박찬원
    • 센서학회지
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    • 제23권5호
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    • pp.342-348
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    • 2014
  • This paper introduced a novel multi-gas sensor detector with simple signal processing algorithm. This device was evaluated by investigating the characteristics of combustible materials using fire-generated smell and smoke. Plural sensors including TGS821, TGS2442, and TGS260X were equipped to detect carbon monoxide, hydrogen gas, and gaseous air contaminants which exist in cigarette smoke, respectively. Signal processing algorithm based on the difference of response times in fire-generated gases was implemented with early and accurately fire detection from multiple gas sensing signals. All fire experiments were performed in a virtual fire chamber. The cigarette, cotton fiber, hair, polyester fiber, nylon fiber, paper, and bread were used as a combustible material. This analyzing software and sensor controlling algorithm were embedded into 8-bit micro-controller. Also the detected multiple gas sensor signals were simultaneously transferred to the personnel computer. The results showed that the air pollution detecting sensor could be used as an efficient sensor for a fire detector which showed high sensitivity in volatile organic compounds. The proposed detecting algorithm may give more information to us compared to the conventional method for determining a threshold value. A fire detecting device with a multi-sensor is likely to be a practical and commercial technology, which can be used for domestic and office environment as well as has a comparatively low cost and high efficiency compared to the conventional device.

Effect of Distribution System Materials and Water Quality on Heterotrophic Plate Counts and Biofilm Proliferation

  • 장영철;정권
    • Journal of Microbiology and Biotechnology
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    • 제14권6호
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    • pp.1114-1119
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    • 2004
  • The biofilms on pipe walls in water distribution systems are of interest since they can lead to chlorine demand, coliform growth, pipe corrosion, and water taste and odor problems. As such, the study described in this paper is part of an AWWARF and Tampa Bay Water tailored collaboration project to determine the effect of blending different source waters on the water quality in various distribution systems. The project was based on 18 independent pilot distribution systems (PDS), each being fed by a different water blend (7 finished waters blended in different proportions). The source waters compared were groundwater, surface water, and brackish water, which were treated in a variety of pilot distribution systems, including reverse osmosis (RO) (desalination), both membrane and chemical softening, and ozonation-biological activated carbon (BAC), resulting in a total of 7 different finished waters. The observations from this study consistently demonstrated that unlined ductile iron was more heavily colonized by a biomass than galvanized steel, lined ductile iron, and PVC (in that order) and that the fixed biomass accumulation was more influenced by the nature of the supporting material than by the water quality (including the secondary residual levels). However, although the bulk liquid water cultivable bacterial counts (i.e. heterotrophic plate counts or HPCs) did not increase with a greater biofilm accumulation, the results also suggested that high HPCs corresponded to a low disinfectant residual more than a high biofilm inventory. Furthermore, temperature was found to affect the biofilms, plus the AOC was important when the residual was between 0.6 and 2.0 mg $Cl_2/l$. An additional aspect of the current study was that the potential of the exoproteolytic activity (PEPA) technique was used along with a traditional so-called destructive technique in which the biofilm was scrapped off the coupon surface, resuspended, and cultivated on an R2A agar. Both techniques indicated similar trends and relative comparisons among the PDSs, yet the culturable biofilm values for the traditional method were several orders of magnitude lower than the PEPA values.

Small scale computational vibration of double-walled CNTs: Estimation of nonlocal shell model

  • Asghar, Sehar;Khadimallah, Mohamed Amine;Naeem, Muhammad N.;Ghamkhar, Madiha;Khedher, Khaled Mohamed;Hussain, Muzamal;Bouzgarrou, Souhail Mohamed;Ali, Zainab;Iqbal, Zafar;Mahmoud, S.R.;Algarni, Ali;Taj, Muhammad;Tounsi, Abdelouahed
    • Advances in concrete construction
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    • 제10권4호
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    • pp.345-355
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    • 2020
  • In this paper, vibration characteristics of double-walled carbon nanotubes (CNTs) is studied based upon nonlocal elastic shell theory. The significance of small scale is being perceived by developing nonlocal Love shell model. The wave propagation approach has been utilized to frame the governing equations as eigen value system. The influence of nonlocal parameter subjected to diverse end supports has been overtly analyzed. An appropriate selection of material properties and nonlocal parameter has been considered. The influence of changing mechanical parameter Poisson's ratio has been investigated in detail. The dominance of boundary conditions via nonlocal parameter is shown graphically. The results generated furnish the evidence regarding applicability of nonlocal shell model and also verified by earlier published literature.

Wettability and cellular response of UV light irradiated anodized titanium surface

  • Park, Kyou-Hwa;Koak, Jai-Young;Kim, Seong-Kyun;Heo, Seong-Joo
    • The Journal of Advanced Prosthodontics
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    • 제3권2호
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    • pp.63-68
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    • 2011
  • PURPOSE. The object of this study was to investigate the effect of UV irradiation (by a general commercial UV sterilizer) on anodized titanium surface. Surface characteristics and cellular responses were compared between anodized titanium discs and UV irradiated anodized titanium discs. MATERIALS AND METHODS. Titanium discs were anodized and divided into the following groups: Group 1, anodized (control), and Goup 2, anodized and UV irradiated for 24 hours. The surface characteristics including contact angle, roughness, phase of oxide layer, and chemical elemental composition were inspected. The osteoblast-like human osteogenic sarcoma (HOS) cells were cultured on control and test group discs. Initial cellular attachment, MTS-based cell proliferation assay, and ALP synthesis level were compared between the two groups for the evaluation of cellular response. RESULTS. After UV irradiation, the contact angle decreased significantly (P<.001). The surface roughness and phase of oxide layer did not show definite changes, but carbon showed a considerable decrease after UV irradiation. Initial cell attachment was increased in test group (P=.004). Cells cultured on test group samples proliferated more actively (P=.009 at day 2, 5, and 7) and the ALP synthesis also increased in cells cultured on the test group (P=.016 at day 3, P=.009 at day 7 and 14). CONCLUSION. UV irradiation induced enhanced wettability, and increased initial cellular responses of HOS cells on anodized titanium surface.