• Title/Summary/Keyword: carbon waste

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High-temperature electrochemical corrosion behavior of SA106 Grade B carbon steel with corrosion inhibitors in HyBRID solution

  • Sung-Wook Kim;Sang-Yoon Park;Chang-Hyun Roh;Sun-Byeong Kim
    • Nuclear Engineering and Technology
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    • v.55 no.6
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    • pp.2256-2262
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    • 2023
  • The electrochemical corrosion behaviors of SA106 Grade B (SA106B) carbon steel in H2SO44-N2H4 and H2SO4-N2H4-CuSO4 solutions at 95 ℃ have been investigated with the addition of commercial corrosion inhibitors (CI#30 and No. 570S), to determine the stability of SA106B in the hydrazine-based reductive metal ion decontamination (HyBRID) process. The potentiodynamic polarization experiment revealed that the corrosion inhibitors were capable of lowering the corrosion rate of SA106B in H2SO4-N2H4 solution. It was found that the corrosion inhibitors induced formation of fixed surface layer on the carbon steel upon the corrosion. This corrosion inhibition performance was reduced in the presence of CuSO4 in the solution owing to the chemical reactions between organic compounds in the corrosion inhibitors and CuSO4. CI#30 showed a better corrosion inhibition effect in the H2SO4-N2H4-CuSO4 solution. Although the corrosion inhibitors can provide better stability to SA106B in the HyBRID solution, their application should be carefully considered because it may result in reduced decontamination performance and increased secondary waste generation.

Decontamination of simulated radioactive metal waste by modified electrolytic Process with neutral salt electrolytes (개선된 중성염 진해공정을 이용한 모의 방사성 금속폐기물의 제염)

  • Lee, Ji-Hoon;Yuk, Wan-Yi;Yang, Ho-Yeon;Ha, Jong-Hyun
    • Journal of Radiation Protection and Research
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    • v.27 no.2
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    • pp.95-100
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    • 2002
  • Conventional and modified electrolytic decontamination experiment were performed in the 1.7 M solution of sodium sulfate and sodium nitrate tot decontamination of carbon steel as the simulated metal wastes which have been produced in large amounts from nuclear power plants. Anode ant cathode were used as inconel and titanium respective. The reaction time and temperature were 1 hr and $25^{\circ}C$ The analyses were performed of the characteristics such as weight loss arid thickness change of metal waste. suspended solid in electrolyte and SEM observation. In modified electrolyte decontamination system with increased current density ranged from 0.1 to $0.6A/cm^2$, the metal waste showed thickness changes of $0.48{\pm}0.005$ to $67.7{\pm}0.02{\mu}m$ in 1.7 M sodium sulfate and those of $0.06{\pm}0.005$ to $17.7{\pm}0.05{\mu}m$ in sodium nitrate. Metal waste in modified electrolyte decontamination system showed the thickness change of $9.8{\pm}0.01{\mu}m$ while it reacted up to $3.7{\pm}0.03{\mu}m$ in conventional system with $0.3 A/cm^2$ of current density and 1.7 M sodium sulfate. Decontamination efficiencies of modified electrolytic process ate much hither than that of conventional electrolytic process when both are applied to metal waste.

Flame Retardancy and Foaming Properties of the Waste-Polyethylene(W-PE)/Waste-Ethylene vinyl acetate copolymer(W-EVA) Blend Foams (폐폴리에틸린/폐에틸렌 비닐아세테이트공중합체 블렌드 발포체의 난연 및 발포 특성에 관한 연구)

  • Moon, Sung-Chul;Jo, Byung-Wook;Choi, Jae-Kon
    • Elastomers and Composites
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    • v.38 no.4
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    • pp.316-325
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    • 2003
  • The blends of waste-polyethylene (W-PE)/waste-ethylene vinyl acetate copolymer (W-EVA) with inorganic and phosphorous flame retardants (i.e., aluminium hydroxide, magnesium hydroxide, and so on) were prepared by melt mixing techniques at different compositions and foamed. The flame retardancy and foaming properties of the blends, limiting oxygen index (LOI), heat release rate (HRR), carbon monoxide yield (COY), total heat release (THR), effective heat of combustion (EHC), expandability and cell structure were investigated using cone calorimeter, SEM, LOI tester and polarizing microscope. When the composition ratios of the W-PE/W-EVA blends were 50/50 (w/w), and the ranges of the flame retardants contents were $175{\sim}220 phr$, we could obtain foams with the uniform and closed cell, high expandability (1900 % or more), high LOI, and low HRR values. These results depend on crosslinking and loaming conditions, a char formation and smoke suppressing effect. Aluminium hydroxide had more effect in the increase of LOI than magnesium hydroxide, while magnesium hydroxide considerably affected the decrease of HRR and COY.

Biological Hydrogen Production from Mixed Waste of Food and Activated Sludge (음식물쓰레기와 폐활성슬러지의 혼합물로부터 혐기성 바이오 수소 생산)

  • Chung, Chong Min;Hong, Seok Won;Park, Chul Hee;Kim, Young O;Lee, Sang Hyup
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.5
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    • pp.571-580
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    • 2008
  • The influence of bacterial stress on anaerobic hydrogen-producing microorganisms was investigated in batch tests using serum bottles. Several physical and chemical stresses (i.e., heating, adding methane producing inhibitor and chemical acidification) were adapted as a pretreament of the seed sludge. In this experiment, the cultivation temperature were set at mesophilic ($35^{\circ}C$) and thermophilic conditions ($55^{\circ}C$) with adjusting pH at 5, 6, and 7 when using the mixture of food waste and activated sludge as a substrate. In conjunction with the pretreatment, hydrogen production was significantly enhanced as compared with that from untreated sludge. However, less biogas (hydrogen and methane) was produced without the pH control, resulted from the decrease of pH to below 4, mainly due to the formation of VFAs. Hydrogen and carbon dioxide gas were analyzed as main components of the biogas while methane not detected. With an application of chemical acidification, the highest hydrogen production value of 248 ml/l/day achieved at pH 7 and $35^{\circ}C$. In addition, more hydrogen gas produced when the ratio of butyric/acetic acid ratio increased. The optimum pH and temperature for hydrogen production were found to be 7 and $35^{\circ}C$, respectively.

Biogas Production and Utilization Technologies from Organic Waste (유기성폐기물을 이용한 바이오가스 생산 및 활용기술)

  • Heo, Nam-Hyo;Lee, Seung-Heon;Kim, Byeong-Ki
    • New & Renewable Energy
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    • v.4 no.2
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    • pp.21-30
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    • 2008
  • Anaerobic digestion (AD) is the most promising method of treating and recycling of different organic wastes, such as OFMSW, household wastes, animal manure, agro-industrial wastes, industrial organic wastes and sewage sludge. During AD, i.e. degradation in the absence of oxygen, organic material is decomposed by anaerobes forming degestates such as an excellent fertilizer and biogas, a mixture of carbon dioxide and methane. AD has been one of the leading technologies that can make a large contribution to producing renewable energy and to reducing $CO_2$ and other GHG emission, it is becoming a key method for both waste treatment and recovery of a renewable fuel and other valuable co-products. A classification of the basic AD technologies for the production of biogas can be made according to the dry matter of biowaste and digestion temperature, which divide the AD process in wet and dry, mesophilic and thermophilic. The biogas produced from AD plant can be utilized as an alternative energy source, for lighting and cooking in case of small-scale, for CHP and vehicle fuel or fuel in industrials in case of large-scale. This paper provides an overview of the status of biogas production and utilization technologies.

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Utilization of biofilter/photo-catalytic reactor system for the simultaneous treatment of hydrogen sulfide and toluene from waste-air

  • Lim, Kwang-Hee;Ping, Wang Zhi;Lim, Dong-Joon;Lee, Eun-Ju
    • 한국생물공학회:학술대회논문집
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    • 2005.04a
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    • pp.287-292
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    • 2005
  • Transient behavior of biofilter/photo-catalytic reactor system was observed to eliminate both hydrogen sulfide and toluene from waste air at its four sampling ports. The biofilter was packed with a equivolume mixture of granular activated carbon(GAC) and compost as packing media on which Thiobacillus sp. IW and Burkholderia cepacia G4 were inoculated and were fixed. The biofilter/photo-catalytic reactor system was run for eight stages of operation under various operating conditions. As a result the removal efficiencies of hydrogen sulfide and toluene began to decrease from 100% after the inlet loads of hydrogen sulfide and toluene surpassed ca. 100 $S-g/m^{3}/h$ and $161g/m^{3}/h$, respectively, and were rapidly decreased to 60% after the inlet loads of hydrogen sulfide and toluene were increased to 200 $S-g/m^{3}/h$ and $644g/m^{3}/h$, respectively.

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Chemical Treatment of Municipal Wastewater Using Alum Sludge

  • Shin, Dae-Yewn;Moon, Ok-Ran;Yoon, Mi-Ran;Ro, Chang-Wha;Kang, Gong-Unn;Moon, Deok-Hyn;Dermatas, Dimitris
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2005.12a
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    • pp.51-53
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    • 2005
  • Disposal of waterwork sludge is important problem in WTP(water treatment plant). Purpose of this study is treated municipal waste water chemically using sludge that is produced in waterwork plant by link to reutilize waterwork sludge. Municipal waste water that use in an experiment used is produced at C university, and is SS 220 mg/L, BOD 145 mg/L, COD 160 mg/L, T-N 52 mg/L and T-P 2.6 mg/L. Used Alum, polymer coagulant and coagulant aid (diatomite, powered activated carbon) as CaO, coagulant as alkaline aid by chemical treatment medicine. In case of does slow speed agitation and stations after pours waterwork sludge in sewage and alkaline aid and coagulant at rapidly mixing the colloidal creation speed is fast and fine colloids concentration was high but settling time is shortened a little and removal rate of pollutant improved by $60{\sim}99%$.

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Up-cycling Product Development for Daily Household Supplies Utilizing Used Jeans (폐기된 청바지를 활용한 생활용품 디자인 연구)

  • Ahn, In-Sook;Kim, Ho-Kyung
    • Journal of the Korean Society of Costume
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    • v.65 no.1
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    • pp.76-88
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    • 2015
  • Excessive spending and the ever-changing fashion trends lead to an increase in material production to meet consumers' needs, which also in turn, increase the amount of industrial waste and many harmful pollutants. To address this problem, this study aimed to utilize discarded jeans' parts, reconstructing them into edgy and functional designs for everyday products. Six pairs of discarded jeans were collected and were used to create six types of functional products -three types of baskets, a bag, a slipper, and a key-holder. The benefits of up-cycling outweigh recycling because it not only increases the recycling rate, but also decreases the amount of energy and cost, thereby increasing the efficiency in recreating new innovative products. These proposed up-cycling ideas will serve as a great alternative for consumers to actively participate in reducing carbon emission, water usage, and waste to landfill by utilizing used clothing. This will guide how consumers can extend the life of their used clothing, utilize recyclable items more thoroughly, and keep used clothing out of landfills.

Biogas Production and Utilization Technologies from Organic waste (유기성폐기물을 이용한 바이오가스 생산 및 활용기술)

  • Heo, Nam-Hyo;Lee, Seung-Heon;Kim, Byeong-Ki
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.202-205
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    • 2008
  • Anaerobic digestion(AD) is the most promising method of treating and recycling of different organic wastes, such as OFMSW, household wastes, animal manure, agro-industrial wastes, industrial organic wastes and sewage sludge. During AD, i.e. degradation in the absence of oxygen, organic material is decomposed by anaerobes forming degestates such as an excellent fertilizer and biogas, a mixture of carbon dioxide and methane. AD has been one of the leading technologies that can make a large contribution to producing renewable energy and to reducing $CO_2$ and other GHG emission, it is becoming a key method for both waste treatment and recovery of a renewable fuel and other valuable co-products. A classification of the basic AD technologies for the production of biogas can be made according to the dry matter of biowaste and digestion temperature, which divide the AD process in wet and dry, mesophilic and thermophilic. The biogas produced from AD plant can be utilized as an alternative energy source, for lighting and cooking in case of small-scale, for CHP and vehicle fuel or fuel in industrials in case of large-scale. This paper provides an overview of the status of biogas production and utilization technologies.

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Isolation and Characteris tics of Polyvinyl Alcohol Degrading Bacteria (폴리비닐 알콜 분해균주의 분리 및 특성)

  • 정선용;조윤래;김정목;조무환
    • Microbiology and Biotechnology Letters
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    • v.20 no.1
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    • pp.96-101
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    • 1992
  • Two strains of polyvinyl alcohol (PVA) utilizing bacteria were isolated from the waste water and soil. These strains, G5Y and PW, were able to utilize PVA symbiotically as a carbon source, but could not utilize PVA separately. In the mixed culture of these strains, 0.5 percent of PVA was almost completely degraded in 3 days. Effect of degree of PVA polymerization on the its utilization was examined, and there was no remarkable difference among three kind of PVA (PVA 500, 1500, a d 2000). These bacteria were able to utilize PV,4 in the desizing waste water of factory as well as enrichment PVA medium. These strains, C5Y and PW, were identified as Pseudomonas cepucia and Pseudomonus pseudomallei, respectively, based on morpholofical and biological characteristics.

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