• Title/Summary/Keyword: carbon to nitrogen ratio

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Increased Microalgae Growth and Nutrient Removal Using Balanced N:P Ratio in Wastewater

  • Lee, Seung-Hoon;Ahn, Chi-Yong;Jo, Beom-Ho;Lee, Sang-Ah;Park, Ji-Yeon;An, Kwang-Guk;Oh, Hee-Mock
    • Journal of Microbiology and Biotechnology
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    • v.23 no.1
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    • pp.92-98
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    • 2013
  • Microalgal cultivation using wastewater is now regarded as essential for biodiesel production, as two goals can be achieved simultaneously; that is, nutrient removal efficiency and biomass production. Therefore, this study examined the effects of carbon sources, the N:P ratio, and the hydraulic retention time (HRT) to identify the optimal conditions for nutrient removal efficiency and biomass production. The effluent from a 2nd lagoon was used to cultivate microalgae. Whereas the algal species diversity and lipid content increased with a longer HRT, the algal biomass productivity decreased. Different carbon sources also affected the algal species composition. Diatoms were dominant with an increased pH when bicarbonate was supplied. However, 2% $CO_2$ gas led to a lower pH and the dominance of filamentous green algae with a much lower biomass productivity. Among the experiments, the highest chlorophyll-a concentration and lipid productivity were obtained with the addition of phosphate up to 0.5 mg/l P, since phosphorus was in short supply compared with nitrogen. The N and P removal efficiencies were also higher with a balanced N:P ratio, based on the addition of phosphate. Thus, optimizing the N:P ratio for the dominant algae could be critical in attaining higher algal growth, lipid productivity, and nutrient removal efficiency.

Effect of Mixing Ratio of n-heptane Fuel on the Combustion Characteristics of n-butanol Fuel (n-heptane 연료 혼합비에 따른 n-butanol 연료의 연소 특성)

  • Lim, Young Chan;Suh, Hyun Kyu
    • Journal of the Korean Society of Combustion
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    • v.20 no.3
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    • pp.21-26
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    • 2015
  • This study was performed to provide the information of the combustion characteristics of n-butanol fuel in accordance with the n-heptane fuel mixing ratio. The closed homogeneous reactor model was used for the analysis. The analysis conditions were set to 800 K of the initial temperature, 20 atm of initial pressure and 1.0 of equivalence ratio. The results of analysis were compared in terms of combustion temperature, combustion pressure, CO, Soot and $NO_X$ emissions. The results of combustion and exhaust emission characteristics showed that ignition delay was decreased and the combustion temperature was increased as the n-heptane mixing ratio was increased. Also, the carbon monoxide(CO) was slightly decreased however, the soot and nitrogen oxides($NO_X$) increased a little in accordance with the n-heptane fuel mixing ratio. In addition, the pressure difference was almost the same in any conditions.

One-step synthesis of dual-transition metal substitution on ionic liquid based N-doped mesoporous carbon for oxygen reduction reaction

  • Byambasuren, Ulziidelger;Jeon, Yukwon;Altansukh, Dorjgotov;Ji, Yunseong;Shul, Yong-Gun
    • Carbon letters
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    • v.17 no.1
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    • pp.53-64
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    • 2016
  • Nitrogen (N)-doped ordered mesoporous carbons (OMCs) with a dual transition metal system were synthesized as non-Pt catalysts for the ORR. The highly nitrogen doped OMCs were prepared by the precursor of ionic liquid (3-methyl-1-butylpyridine dicyanamide) for N/C species and a mesoporous silica template for the physical structure. Mostly, N-doped carbons are promoted by a single transition metal to improve catalytic activity for ORR in PEMFCs. In this study, our N-doped mesoporous carbons were promoted by the dual transition metals of iron and cobalt (Fe, Co), which were incorporated into the N-doped carbons lattice by subsequently heat treatments. All the prepared carbons were characterized by via transmission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). To evaluate the activities of synthesized doped carbons, linear sweep was recorded in an acidic solution to compare the ORR catalytic activities values for the use in the PEMFC system. The dual transition metal promotion improved the ORR activity compared with the single transition metal promotion, due to the increase in the quaternary nitrogen species from the structural change by the dual metals. The effect of different ratio of the dual metals into the N doped carbon were examined to evaluate the activities of the oxygen reduction reaction.

Optimal Culture Conditions for Mycelial Growth of Lignosus rhinocerus

  • Lai, W.H.;Murni, M.J. Siti;Fauzi, D.;Mazni, O. Abas;Saleh, N.M.
    • Mycobiology
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    • v.39 no.2
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    • pp.92-95
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    • 2011
  • Lignosus rhinocerus is a macrofungus that belongs to Polyporaceae and is native to tropical regions. This highly priced mushroom has been used as folk medicine to treat diseases by indigenous people. As a preliminary study to develop a culture method for edible mushrooms, the cultural characteristics of L. rhinocerus were investigated in a range of culture media under different environmental conditions. Mycelial growth of this mushroom was compared on culture media composed of various carbon and nitrogen sources in addition to C/N ratios. The optimal conditions for mycelial growth were $30^{\circ}C$ at pH 6 and 7. Rapid mycelial growth of L. rhinocerus was observed on glucose-peptone and yeast extract peptone dextrose media. Carbon and nitrogen sources promoting mycelial growth of L. rhinocerus were glucose and potassium nitrate, respectively. The optimum C/N ratio was approximately 10 : 1 using 2% glucose supplemented as a carbon source in the basal media.

Formaldehyde Adsorption Properties of Activated Carbon Fiber-Papers by Nitrogen Plasma Treatment (질소 플라즈마 처리에 따른 활성탄소섬유 페이퍼의 포름알데하이드 흡착 특성)

  • Min, Chung Gi;Lim, Chaehun;Myeong, Seongjae;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.33 no.6
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    • pp.624-629
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    • 2022
  • Formaldehyde is an indoor pollutant that is harmful to humans, such as causing respiratory and skin diseases. Nitrogen plasma treatment was performed to introduce nitrogen groups on the surface of the activated carbon fibers (ACFs), and the adsorption characteristics of formaldehyde for the surface-modified ACFs were considered. As the nitrogen gas flow rate increased, the content of nitrogen functional groups introduced to the surface of the ACFs increased by about 7%, and the ratio of nitrogen functional groups to each type present was similar. Ultramicropores increased on the ACFs surface due to the etching effect of plasma treatment. The adsorption efficiency of formaldehyde on the modified ACFs surface was also enhanced. However, under the nitrogen flow rate of 120 sccm or more, the surface of the ACFs was excessively etched, and the specific surface area and the formaldehyde adsorption capacity decreased. Therefore, the content of the nitrogen groups is the main factor in the adsorption of formaldehyde on the nitrogen plasma-treated ACFs, but it can be found that the adsorption efficiency of formaldehyde is improved when the ACFs have a suitable pore structure.

Analysis of Efficiency Enhancement of the Integrated Gasification Combined Cycle with Oxy-Combustion Carbon Capture by Changing the Oxygen Supply System (순산소연소 이산화탄소 포집을 적용한 석탄가스화 복합화력 발전시스템에서 산소공급방식 변경에 의한 효율향상 분석)

  • CHO, YEON WOO;AHN, JI HO;KIM, TONG SEOP
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.4
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    • pp.347-355
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    • 2019
  • As a solution to the growing concern on the global warming, researches are being actively carried out to apply carbon dioxide capture and storage technology to power generation systems. In this study, the integrated gasification combined cycle (IGCC) adopting oxy-combustion carbon capture was modeled and the effect of replacing the conventional air separation unit (ASU) with the ion transport membrane (ITM) on the net system efficiency was analyzed. The ITM-based system was predicted to consume less net auxiliary power owing to an additional nitrogen expander. Even with a regular pressure ratio which is 21, the ITM-based system would provide a higher net efficiency than the optimized ASU-based system which should be designed with a very high pressure ratio around 90. The optimal net efficiency of the ITM-based system is more than 3% higher than that of the ASU-based system. The influence of the operating pressure and temperature of the ITM on system efficiency was predicted to be marginal.

Evaluation of Organic Matter Sources of Phytoplankton in Paldang Reservoir using Stable Isotope Analysis (팔당호 내 식물플랑크톤 안정동위원소 분석을 통한 유기물 기원 평가)

  • Kim, Jongmin;Kim, Bokyong;Kim, Minseob;Shin, Kisik
    • Journal of Korean Society on Water Environment
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    • v.31 no.2
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    • pp.159-165
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    • 2015
  • The organic matter sources of phytoplankton and related environmental factors influencing algal bloom in Paldang reservoir were studied using nitrogen and carbon isotope ratio(${\delta}^{15}N$, ${\delta}^{13}C$). Phytoplankton samples for stable isotope analysis were collected from four points in reservoir using a plankton net. Physicochemical water quality, algal taxa and hydrological data were collected from published monitoring material. Phytoplankton samples were analyzed by IRMS. CN ratio of each sample was very similar to that of phytoplankton from literature cited. ${\delta}^{15}N$ of each sample was decreased during July. Mixing and dilution of nitrogen sources due to increment of influx by concentrated rainfall were considered as the main reason for the decline of ${\delta}^{15}N$. Based on analyzed ${\delta}^{15}N$ value of each sample, nitrogen source of Bughan river sample was presumed to come from soil. The nitrogen sources of Namhan river and Kyeongan stream samples seemed to be sewage or animal waste. Low ${\delta}^{15}N$ value in August (2012) seemed to be influenced by isotope fractionation due to the blooming of nitrogen-fixation blue-green algae (Anabaena spp.). Variation in ${\delta}^{15}N$ values particularly by blue-green algal bloom was considered the important factor for estimating the organic matter sources of phytoplankton.

A study on the denitrification and microbial community characteristics by the change of C/N ratio of molasses and nitrate nitrogen (당밀과 질산성 질소의 C/N ratio 변화에 따른 탈질 및 미생물 군집 특성에 관한 연구)

  • Eom, Hanki;Kim, Sungchul
    • Korean Journal of Microbiology
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    • v.54 no.2
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    • pp.105-112
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    • 2018
  • To compare the denitrification efficiency, this study used molasses and methanol were used as external carbon sources. Specific experimental conditions were classified according to C/N ratio conditions. The batch test showed that the denitrification efficiency increased as C/N ratios of molasses and methanol rose. The most suitable C/N ratio of molasses turned out 4:1 considering the concentration of the residue chemical oxygen demand (COD) and the denitrification efficiency, which was 91.4%. Specific denitrification rate (SDNR) drawn as a kinetic factor demonstrated that molasses and methanol showed similar SDNR values as C/N ratios of molasses and methanol increased. Under the condition of C/N ratio 4:1, 0.0292 g $NO_3{^-}-N$ removal/g mixed liquor volatile suspended solid (MLVSS)/day (molasses), 0.0299 g $NO_3{^-}-N$ removal/g MLVSS/day (methanol) were found. Sludge adapted to molasses showed that Bacterium Pseudomonas sp. and Bergeylla sp. dominated through an analysis of microbial community. In addition, some bacteria were high convergences than the variety of microbial community. Accordingly, it was assumed that molasses focus on growing microorganisms specialized in denitrification and applied as a replaceable external carbon source that can enhance denitrification performance.

Effects of Fermented Leachate of Food Waste (FLFW) and Temperature on Nutrient Removal in Sequencing Batch Reactor

  • Roh, Sung-Hee;Chun, Young-Nam;Lee, Sook-Young;Cheong, Hyeon-Sook;Lee, Jae-Wook;Kim, Sun-Il
    • Environmental Engineering Research
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    • v.13 no.3
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    • pp.155-161
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    • 2008
  • This study examined effects of the fermented leachate of food waste (FLFW) on nitrogen and phosphorous removal for domestic wastewater containing a low carbon-to-nitrogen (C/N) ratio in sequencing batch reactor (SBR). When the FLFW was not supplied in the process, release of phosphorus and excessive intake was not observed at both anaerobic and aerobic stages. On the other hand, when the FLFW was gradually added, active release of phosphorus and intake of phosphorus was noticed at an anaerobic stage and aerobic stage, respectively, resulting in improved phosphorus removal efficiency. The removal efficiency of nitrogen and phosphorus was increased from 75% and 37% (R-1, control test) to 97% and 80% (R-4, the highest substrate ratio test), respectively. In addition, although activity of the nitrogen oxidizing microorganisms was reduced when the reaction temperature was decreased to $10^{\circ}C$, the phosphorus removal efficiency was shown to increase with the addition of FLFW, indicating an independence from temperature. Overall, this study suggests that an efficient nutrients removal process can be successfully employed into a SBR when the FLFW is added to a wastewater which has a low C/N ratio.

A Study on the Operation Condition for Carbon-Nitrogen Removal in Wastewater and Sludge Reduction using PVA-gel Immobilized Microorganism (PVA-gel 미생물 고정화 담체를 이용한 고도하수처리 및 슬러지 감량화 운전조건 연구)

  • Lee, Jin-Sook;Park, Hyung-Whan;Nam, Duk-Hyun;Park, Chul-Hwi;Jung, In-Ho;Yoo, Young-Kwan
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.6
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    • pp.875-883
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    • 2006
  • The carbon and nitrogen removal process using PVA-gel (Polyvinyl Alcohol) immobilized microorganisms was studied. The process has been operated under diverse process conditions for 12 months. The process consists of denitrification with internal recycle of 300%, nitrification, aerobic digestion reactors and settling tank. Nitrificatoin and nitrogen removal efficiency according to gel packing ratio and temperature were studied. Yield for Heterotrophs ($Y_H$), decay coefficient for Heterotrophs($b_H$) in aerobic digestion reactor were determined to seize sludge reduction mechanism and compared with typical data of activated sludge process. Then SRT in aerobic digestion reactor was determined on an experimental basis and sludge reduction efficiency was calculated. The process was implemented successfully with sludge reduction efficiency of 92.0~98.5% on a basis of biomass.