• Membrane Journal
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• v.33 no.4
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• pp.211-221
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• 2023

This study presents a comprehensive study on the synthesis and characterization of PVI-PGMA/LiTFSI polymeric membrane electrolytes and CxNy-C flexible electrodes for energy storage applications. The dual-functional PVI-PGMA copolymer exhibited excellent ionic conductivity, with the PVI-PGMA73/LiTFSI200 membrane electrolyte achieving the highest conductivity of 1.0 × 10^-3 S cm^-1. The electrochemical performance of the CxNy-C electrodes was systematically investigated, with C3N2-C demonstrating superior performance, achieving the highest specific capacitance of 958 F g^-1 and lowest charge transfer resistance (R_ct) due to its highly interconnected hybrid structure comprising nanowires and polyhedrons, along with binary Co/Ni oxides, which provided abundant redox-active sites and facilitated ion diffusion. The presence of a graphitic carbon shell further contributed to the enhanced electrochemical stability during charge-discharge cycles. These results highlight the potential of PVI-PGMA/LiTFSI polymeric membrane electrolytes and CxNy-C electrodes for advanced energy storage devices, such as supercapacitors and lithium-ion batteries, paving the way for further advancements in sustainable and high-performance energy storage technologies.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.23 no.6
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• pp.449-469
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• 2011

This article reviews the papers published in the Korean Journal of Air-Conditioning and Refrigerating Engineering during 2010. It is intended to understand the status of current research in the areas of heating, cooling, ventilation, sanitation, and indoor environments of buildings and plant facilities. Conclusions are as follows. (1) Research trends of thermal and fluid engineering have been surveyed as groups of general thermal and fluid flow, fluid machinery, and new and renewable energy. Various topics were presented in the field of general thermal and fluid flow. Research issues mainly focused on the thermal reliability of axial fan and compressor in the field of fluid machinery. Studies on the design of ground source heat pump systems and solar chemical reactors were executed in the field of new and renewable energy. (2) Research works on heat transfer area have been reviewed in the categories of heat transfer characteristics and industrial heat exchangers. Researches on heat transfer characteristics included heat transfer in thermoelectric cooling/power generation systems, combined heat and power systems, carbon nano fluid with PVP, channel filled with metal foam and smoke ventilation in a rescue station of a railroad tunnel. Also the studies on flow boiling of R123/oil mixture in a plain tube bundle and R410A charge amount in an air cooled mini-channel condenser were reported. In the area of industrial heat exchangers, researches on plate heat exchanger, shell and tube heat exchanger, enthalpy exchanger, micro channel PCHE were performed. (2) Research works on heat transfer area have been reviewed in the categories of heat transfer characteristics and industrial heat exchangers. Researches on heat transfer characteristics included heat transfer in thermoelectric cooling/power generation systems, combined heat and power systems, carbon nano fluid with PVP, channel filled with metal foam and smoke ventilation in a rescue station of a railroad tunnel. Also the studies on flow boiling of R123/oil mixture in a plain tube bundle and R410A charge amount in an air cooled mini-channel condenser were reported. In the area of industrial heat exchangers, researches on plate heat exchanger, shell and tube heat exchanger, enthalpy exchanger, micro channel PCHE were performed. (3) Refrigeration systems with alternative refrigerants such as hydrocarbons, mixed refrigerants, and CO2 were studied. Performance improvement of refrigeration systems are tried applying various ideas of refrigerant subcooling, dual evaporator with hot gas bypass control and feedforward control. The hybrid solar systems combining the solar collection devices with absorption chillers or compression heat pumps are simulated and studied experimentally as well to improve the understanding and the feasibility for actual applications. (4) Research trend in the field of mechanical building facilities has been found to be mainly focused on field applications rather than performance improvements. Various studies on heating and cooling systems, HVAC facilities, indoor air environments and energy resources were carried to improve the maintenance and management of building service equipments. In the field of heating and cooling systems, papers on a transformer cooling system, a combined heat and power, a slab thermal storage and a heat pump were reported. In the field of HVAC facilities, papers on a cooling load, an ondol and a drying were presented. Also, studies on HVAC systems using unutilized indoor air environments and energy resources such as air curtains, bioviolence, cleanrooms, ventilation, district heating, landfill gas were studied. (5) In the field of architectural environment and energy, studies of various purposes were conducted such as indoor environment, building energy, renewable energy and green building. In particular, renewable energy and building energy-related researches have mainly been studied reflecting the global interest. In addition, many researches which related the domestic green building certification of school building were performed to improve the indoor environment of school.

• Korean Chemical Engineering Research
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• v.59 no.4
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• pp.548-556
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• 2021

This study was conducted to investigate the applicability of lignocellulosic fiber and coconut shell activated carbon (CSA) for the production of a particulate matter (PM)-reducing air-filter as raw materials to solve the environmental problems of non-woven fabrics. CSA had a good potential to use as a raw material of air-filter for reducing volatile organic compounds as well as noxious metals, and reduction capability of the CSA was 5 times higher than that of wood fiber. Natural adhesives formulated with proteinaceous wastes mostly were applied successfully to fabricate air-filters with the shape of fiberboard. The air-filter fabricated with the minimum target density of 200 kg/m³ and the maximum CSA-content of 40 wt% in fiberboard had a good manageable strength. However, the fiberboard filters was required to make vent-holes for improving an air-permeability of the filters. Size of the CSA particles was adjusted to greater than 2 mesh with the consideration of strength and formability of the fiberboard. Three-layers fiberboard that only wood fiber and the mixture of wood fiber and CSA were formed in the surface and middle layers, respectively, was determined to the optimal condition for the production of air-filters. In addition, traditional Korean paper handmade from mulberry trees (TKP) showed a good PM-reducing property as an air-filter. It is concluded that air-filtering set composed of fiberboard with vent-holes and TKP instead of conventional air-filters made with non-woven fabrics can be used as a filter for reducing the concentrations of PM, VOC and noxious metals existed in indoor and outdoor spaces.

• Korean Journal of Heritage: History & Science
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• v.55 no.4
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• pp.24-36
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• 2022

The Bonghwang-dong ruins in Gimhae, the central area of Geumgwan Gaya, is presumed to be the site of the royal palace, and excavations have been in progress at the Gaya National Cultural Heritage Research Institute. According to a research conducted by lowering the level to the base layer on the north side of the site, mostly shell layers composed of oysters were confirmed, and soil composed of different material was alternately filled in to form a site construction. In other words, it can be seen that there was work at the site of the Bonghwang-dong ruins that required large-scale labor, such as building ramparts and embankments. There is stratigraphic confusion such as showing different age values in the same shell layer through a chronological analysis of organic matter and charcoal in the sedimentary layer, and deriving a result value in the upper layer ahead of the lower layer. In addition, open-sea diatoms are observed not only in the sedimentary layers, but also the pits. Therefore, it is judged that the soil constituting the ruins was brought from the outside. The Bonghwang-dong ruins are located inside the commonly called Bonghwang earthen ramparts, where many excavation organizations conducted research within the estimated range of the earthen fortifications. As a result, it was found that it was similar to the sedimentary layers of the ruins of the Three Kingdoms Period, which were investigated along with the ruins of Bonghwang-dong. Through this, the surrounding ruins, including those of Bonghwang-dong, were located close to paleo-Gimhae Bay, so it is believed that the soil brought from the surroundings was used to reinforce the ground. As a result of the excavation research on the Bonghwang-dong ruins conducted so far, it was found by sedimentary layer analysis and soil experiments that the ruins were created on stable land. Relics excavated in the sediments of the ruins and carbon dating data show that Bonghwang-dong carried out large-scale civil construction work in the 4th century to build the site, which clearly shows the status of Geumgwan Gaya.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.46 no.1
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• pp.18-28
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• 2014

Renewable Portfolio Standards(RPS) is a regulation that requires a renewable energy generated from eco-friendly energy sources such as biomass, wind, solar, and geothermal. The RPS mechanism generally is an obligatory policy that places on electricity supply companies to produce a designated fraction of their electricity from renewable energies. The domestic companies to supply electricity largely rely on wood pellets in order to implement the RPS in spite of undesirable situation of lack of wood resources in Korea. This means that the electricity supply companies in Korea must explore new biomass as an alternative to wood. Palm kernel shell (PKS) and empty fruit bunch (EFB) as oil palm wastes can be used as raw materials used for making pellets after their thermochemical treatment like torrefaction. Torrefaction is a pretreatment process which serves to improve the properties including heating value and energy densification of these oil palm wastes through a mild pyrolysis at temperature typically ranging between 200 and $300^{\circ}C$ in the absence of oxygen under atmospheric pressure. Torrefaction of oil palms wastes at above $200^{\circ}C$ contributed to the increase of fixed carbon with the decrease of volatile matters, leading to the improvement of their calorific values over 20.9 MJ/kg (=5,000 kcal/kg) up to 25.1 MJ/kg (=6,000 kcal/kg). In particular, EFB sensitively responded to torrefaction because of its physical properties like fiber bundles, compared to PKS and hardwood chips. In conclusion, torrefaction treatment of PKS and EFB can greatly contribute to the implement of RPS of the electricity supply companies in Korea through the increased co-firing biomass with coal.

• The Korean Journal of Malacology
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• v.31 no.3
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• pp.203-212
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• 2015

This study was performed to describe the influence of temperature on the clearance rate and ingestion rate of the blue mussel, Mytilus galloprovincialis with three food organisms and habitat location (shell size) of mussel. Food organisms used in this experiments were Isochrysis galbana, Chaetoceros didymus and Prorocentrum dentatum. The size of mussels inhabiting higher midlittoral zone was smaller than those of lower midlittoral zone. Regardless of the kind of food organisms, filtration rates and ingestion rates of higher midlittoral mussels were higher than those of lower midlittoral mussels in experiment temperature conditions. The variation of filtration rate and ingestion rate showed same tendency with temperature. Filtration rates and ingestion rates increased with temperature, and recorded maximum values at $20-25^{\circ}C$ of temperature, and thereafter decreased gradually. Theoretical optimum temperatures showing maximum filtration rates and ingestion rates estimated from polynomial regression curves were also in the range of $20-25^{\circ}C$. Blue mussels showed different variation of filtration rate and ingestion rate with the kind of food organisms. Filtration rates and ingestion rate based on cell number were similar regardless of habitat location(tidal elevation) and food organisms. Ingestion rates based on carbon content showed very high values in case of P. dentatum beside I. galbana and C. didymus as food organism.

• Journal of the Korean earth science society
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• v.24 no.5
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• pp.477-490
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• 2003

Bottom sediments from Youngil Bay, East Coast of Korea, were analyzed for grain composition as well as elemental compositions and total organic carbon (TOC) content in order to investigate the spatial variability and content of metal elements. Grain size distribution of the sediments seems to be controlled by anticlockwise current pattern with bottom topography of the study area. Spatial variability of TOC and all elemental contents reflects those of grain size, but an exception was found in the harbor area (Old-Port): their contents are high in the central part of the bay with the muddy sediment and decrease toward the sand-dominated coastal zone. However, contents of Ca, Sr, K are high in the sand-dominated coastal zone and contents of some heavy metals (Cd, Cu, Zn) are high in the Old-Port area and the mouth of Hyeongsan River. The correlation matrix and R-mode factor analyses reveal that four important factors controlling the distribution of metals in the bay are sediment grain size (or quartz dilution effect), the formation of sulfide minerals associated with decomposition of organic matters under anoxic geochemical environment, calcium carbonate (mainly shell fragments) and coarse-grained feldspar mineral. According to the metal content of labile fraction an CER (concentration enrichment ratio) value, high accumulation of some heavy metals in the harbor area seems to result not formed by early diagenetic processes under anoxic environment.

• Journal of Conservation Science
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• v.27 no.3
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• pp.313-322
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• 2011

The floral wall of Lee Sang-beom's House and Atelier, which is No. 171 of the Registrated Cultural Heritage was conserved. In addition, materials characteristics and manufacturing technique have revealed through the scientific analysis. As a result of the analysis, samples were divided into three sections; the support layer that is made from block bricks, the paint layer and the cement mortar layer on the paint layer for the reinforcement of the construction. The higher layer lies, the finer grains it has. Furthermore, a little it was generated a small quantity of pores and calcium carbonates ($CaCO_3$) generated due to aeration of cement mortar. The patterns of letters, animals and plants pattern were expressed in the paint layer by relief and openwork. The results of qualitative analysis of the pigments of the paint layer were detected components of carbon black (C), Fe oxide ($Fe_2O_3$) and oyster shell white ($CaCO_3$, or quicklime). On the other hands, as the conservation of the floral wall, stainless frames were set up for the structural stability, the cement mortar were removed from the surface and the partly damaged and cracked areas were filled with KSE Filler A, B.

• Journal of Energy Engineering
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• v.17 no.4
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• pp.241-246
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• 2008

Increase of $CO_2$ by using fossil fuels makes mainly global warming and the international efforts to reduce the $CO_2$ emission is being promoted. Absorption process using aqueous alkanolamine solution to remove acid components in the mixed gases has been used commercially. This method was used to remove $CO_2$ in the flue gas in recent years. $CO_2$ Absorption characteristics of several aqueous alkanolamine solutions such as MEA, DEA and AMP was studied by measuring vapor-liquid-equilibrium(VLE) and absorption velocity in this study. VLE measuring equipment, shell and reactor type, was used to acquire VLE data, equilibrium $CO_2$ pressure(${P_{CO_2}}^*$) and time at each pulse gas input. We also acquired the $CO_2$ absorption velocity by measuring the time to arrive the VLE at $40{\sim}80^{\circ}C$ and first gas input. The $CO_2$ absorption capacity of MEA 10wt% solution was higher than two alkanolamine solutions at $40^{\circ}C$ and the equilibrium $CO_2$ loading was 0.5. Absorption capacity was excellent as follows; AMP>DEA>MEA. But absorption velocity was fast as follows; MEA>AMP>DEA. Though good absorbent was considered by many variables, absorption velocity and capacity was more important factor.

• Korean Journal of Soil Science and Fertilizer
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• v.48 no.6
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• pp.744-750
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• 2015

The objectives of this study were to investigate soil chemical characteristics for forest rehabilitation and suggest management in abandoned coal mine areas in Boryeong City, Chungcheongnam-do. Total study sites were seven sites, and soil properties analyzed were soil pH, total organic carbon (TOC), total-N, C/N ratio, and available $P_2O_5$ (A.v. P). Average soil pH (range) was 5.9 (4.5~7.0). Three study sites (Samgwang, Shinsung1, and Shimwon1) showed lower soil pH than standard (pH 5.6~7.3) of Korea Industrial Standards (KS) for abandoned coal mine forest rehabilitation. Average contents of TOC, and total-N were 1.5% (0.1~4.7%), and 0.10% (0.03~0.23%), respectively. Five study sites where the collapsed time was less than 10 years (Wangjashingang, Wonpoong, Samgwang, Shinsung1, and Shinsung2) showed lower TOC level than standard of KS (more than 1.2%). Wangjashingang, Wonpoong, Samgwang, and Shinsung1 showed lower level of total-N than standard of KS (more than 0.09%). C/N ratio of six study sites except Shimwon1 was out of proper range (15:1~30:1). Average A.v. P (range) was $20.7mgkg^{-1}$ (4.8~63.1), less than other abandoned coal mine fores rehabilitation areas in Mungyong City, and Hwasun-gun. TOC, total N and A.v. P increased with elapsed time from forest rehabilitation, while other soil properties did not show distinct pattern. Betula platyphylla was planted in Samkwang and Sinsung where soil pH was less than KS standard. Because the growth of Betula platyphylla can be limited in acid soil, it is necessary to neutralize soil pH to proper level with some soil amendment such as lime or shell of oyster. Furthermore, TOC, total-N and A.v. P in early stage of forest rehabilitation showed lower level than proper to vegetation growth. Therefore it needs continuous monitoring of soil characteristics and fertilization for vegetation growth and influx from surrounding forest in early stage of rehabilitation.