• Journal of the Korean Society of Tobacco Science
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• v.10 no.1
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• pp.75-82
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• 1988

Cigarettes were made using a triple filter with several porous materials in its cavity. The removal effect of the adsorbents on carbon monoxide and hydrogen cyanide in cigarette smoke was investigated with the variation of their surface area and pore volume distributions. Several attempts were made to activated coconut shell based char under the fixed steam purging rate. 1. The specific surface area increased in number of micropore. It was found for transitional pore to have a little effect on the total surface area. 2. A Small amount of the particulate matter adsorbed on the adsorbents with transitional pores, Zeolite showed a little effect on the carbon monoxide adsorption though its small pore volume, but there was no significant difference in the adsorption capacity zeolite and the others. 3. In the adsorption for hydrogen cyanide as a vapor phase in cigarette smoke, the adsorption effect of the adsorbents increased remarkably with increasing their surface area and number of micropore. It was considered that the adsorbents with small pore volume like molecular seive 4A, in which the capillary diffusion of adsorbates could not be able, would not be effective for the adsorption of hydrogen cyanide.

• Structural Engineering and Mechanics
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• v.64 no.4
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• pp.515-526
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• 2017

Dynamic response of functionally graded Carbon nanotubes (FG-CNT) reinforced pipes conveying viscous fluid under accelerated moving load is presented. The mixture rule is used for obtaining the material properties of nano-composite pipe. The radial force induced by viscous fluid is calculated by Navier-Stokes equation. The material properties of pipe are considered temperature-dependent. The structure is simulated by Reddy higher-order shear deformation shell theory and the corresponding motion equations are derived by Hamilton's principal. Differential quadrature (DQ) method and the Integral Quadrature (IQ) are applied for analogizing the motion equations and then the Newmark time integration scheme is used for obtaining the dynamic response of structure. The effects of different parameters such as boundary conditions, geometrical parameters, velocity and acceleration of moving load, CNT volume percent and distribution type are shown on the dynamic response of pipe. Results indicate that increasing CNTs leads to decrease in transient deflection of structure. In accelerated motion of the moving load, the maximum displacement is occurred later with respect to decelerated motion of moving load.

• Computers and Concrete
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• v.32 no.4
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• pp.393-398
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• 2023

This paper provides the free vibrations of chiral carbon nanotubes. The governing equations of Flügge theory is considered for vibration frequencies of chiral single walled carbon nanotubes. The solution of frequency equation is obtained from a novel model for better representation of stubby and short vibration characteristics of chiral tubes with clamped-clamped and clamped-simply supported end conditions. For the harmonic response of this tube, the model displacement function is adopted. The variational approach Rayleigh-Ritz method with kinetic and strain energies are used. The Lagragian function is differentiated with respect to unknown functions. The frequency equation is written in compact form to solve with MATLAB software. The frequencies of chiral SWCNTs for first ten aspect ratios as small level are investigated. The results shown as for decreasing the aspect rations, the frequencies are increases. The presented results of this model are verified with experimental and numerical results, which found as an excellent agreement.

• Clean Technology
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• v.21 no.1
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• pp.68-75
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• 2015

In this study, we investigated the structure and properties of a highly heat conductive metal-ceramic core-shell CoAl₂O₄@Al micro-composite for heterogeneous catalysts support. The CoAl₂O₄@Al was prepared by hydrothermal surface oxidation of Al metal powder, which resulted in the structure with a high heat conductive Al metal core encapsulated by a high surface area CoAl₂O₄ shell. For comparison, CoAl₂O₄ was also prepared by co-precipitation method and also utilized for a catalyst support. Rh catalysts supported on CoAl₂O₄@Al and CoAl₂O₄ were prepared by incipient wetness impregnation and characterized by N₂ adsorption, X-ray diffraction (XRD), scanning electron microscopy (SEM), CO chemisorption, and temperature-programmed reduction (TPR). The properties of catalysts were investigated for glycerol steam reforming reaction for hydrogen production at 550 ℃. Rh/CoAl₂O₄@Al exhibited about 2.8 times higher glycerol conversion turnover frequency (TOF) than Rh/CoAl₂O₄ due to facilitated heat transport through the core-shell structure. The CoAl₂O₄@Al and CoAl₂O₄ also showed some catalytic activities due to a partial reduction of Co on the support, and a higher catalytic activity was also found on the CoAl₂O₄@Al core-shell than CoAl₂O₄. These catalysts, however, displayed deactivation on the reaction stream due to carbon deposition on the catalysts surface.

• Korean Chemical Engineering Research
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• v.50 no.4
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• pp.729-732
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• 2012

Herein we report the in-situ synthesis and direct decoration of chalcogenide naoparticles (NPs) onto multiwalled carbon nanotubes (MWCNTs) through an ionic liquid-assisted sonochemical method (ILASM). The as-obtained MWCNT/$BMimBF_4$/CdTe, MWCNT/$BMimBF_4$/ZnTe and MWCNT/$BMimBF_4$/ZnSe nanocomposites were characterized by TEM images and EDS spectra. In particular, the morphologies of nanocomposites such as bump-like, rough, and smooth core-shell structures were strongly influenced by the type of precursors and the interactions with MWCNT. This synthetic strategy opens a new way to directly synthesize and deposit semiconducting NPs (s-NPs) onto CNTs, which consist of binary components obtained from two precursors with different reaction rates.

• Steel and Composite Structures
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• v.26 no.4
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• pp.513-531
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• 2018

In this article, static, buckling and free vibration analyses of a sinusoidal micro composite beam reinforced by single-walled carbon nanotubes (SWCNTs) with considering temperature-dependent material properties embedded in an elastic medium in the presence of magnetic field under transverse uniform load are presented. This system is used at micro or sub micro scales to enhance the stiffness of micro composite structures such as bar, beam, plate and shell. In the present work, the size dependent effects based on surface stress effect and modified strain gradient theory (MSGT) are considered. The generalized rule of mixture is employed to predict temperature-dependent mechanical and thermal properties of micro composite beam. Then, the governing equations of motions are derived using Hamilton's principle and energy method. Numerical results are presented to investigate the influences of material length scale parameters, elastic foundation, composite fiber angle, magnetic intensity, temperature changes and carbon nanotubes volume fraction on the bending, buckling and free vibration behaviors of micro composite beam. There is a good agreement between the obtained results by this research and the literature results. The obtained results of this study demonstrate that the magnetic intensity, temperature changes, and two parameters elastic foundations have important effects on micro composite stiffness, while the magnetic field has greater effects on the bending, buckling and free vibration responses of micro composite beams. Moreover, it is shown that the effects of surface layers are important, and observed that the changes of carbon nanotubes volume fraction, beam length-to-thickness ratio and material length scale parameter have noticeable effects on the maximum deflection, critical buckling load and natural frequencies of micro composite beams.

• Journal of the Korean Society for Railway
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• v.13 no.3
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• pp.271-277
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• 2010

In this paper, a numerical model for a Kevlar/Epoxy and Carbon-Kevlar/Epoxy tube used as an energy absorbing component has been developed and then results have been verified through experiment. The 2D shell element and Chang-Chang failure criterion of LS-DYNA that is commercial explicit FE code was used. Mechanical material properties for the model were obtained by material testing in advance. The numerical results were compared with quasi-static test results under axial compressive loading at 10mm/min. From the results, in the case of the Kevlar/Epoxy tube, load-crushed displacement curves were very close to the experiments and SEA (specific energy absorption) shows a good agreement with experimental one within less than 6%. However, the Carbon-Kevlar/Epoxy tube shows some differences with the experimental results.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.289-289
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• 2013

While there are plenty of studies on synthesizing semiconducting germanium nanowires (Ge NWs) by vapor-liquid-solid (VLS) process, it is difficult to inject dopants into them with uniform dopants distribution due to vapor-solid (VS) deposition. In particular, as precursors and dopants such as germane ($GeH_4$), phosphine ($PH_3$) or diborane ($B_2H_6$) incorporate through sidewall of nanowire, it is hard to obtain the structural and electrical uniformity of Ge NWs. Moreover, the drastic tapered structure of Ge NWs is observed when it is synthesized at high temperature over $400^{\circ}C$ because of excessive VS deposition. In 2006, Emanuel Tutuc et al. demonstrated Ge NW pn junction using p-type shell as depleted layer. However, it could not be prevented from undesirable VS deposition and it still kept the tapered structures of Ge NWs as a result. Herein, we adopt $C_2H_2$ gas in order to passivate Ge NWs with carbon sheath, which makes the entire Ge NWs uniform at even higher temperature over $450^{\circ}C$. We can also synthesize non-tapered and uniformly doped Ge NWs, restricting incorporation of excess germanium on the surface. The Ge NWs with carbon sheath are grown via VLS process on a $Si/SiO_2$ substrate coated 2 nm Au film. Thin Au film is thermally evaporated on a $Si/SiO_2$ substrate. The NW is grown flowing $GeH_4$, HCl, $C_2H_2$ and PH3 for n-type, $B_2H_6$ for p-type at a total pressure of 15 Torr and temperatures of $480{\sim}500^{\circ}C$. Scanning electron microscopy (SEM) reveals clear surface of the Ge NWs synthesized at $500^{\circ}C$. Raman spectroscopy peaked at about ~300 $cm^{-1}$ indicates it is comprised of single crystalline germanium in the core of Ge NWs and it is proved to be covered by thin amorphous carbon by two peaks of 1330 $cm^{-1}$ (D-band) and 1590 $cm^{-1}$ (G-band). Furthermore, the electrical performances of Ge NWs doped with boron and phosphorus are measured by field effect transistor (FET) and they shows typical curves of p-type and n-type FET. It is expected to have general potentials for development of logic devices and solar cells using p-type and n-type Ge NWs with carbon sheath.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.10a
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• pp.3.1-3.1
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• 2011

Nanoengineered materials with advanced architectures are critical building blocks to modulate conventional material properties or amplify interface behavior for enhanced device performance. While several techniques exist for creating one dimensional heterostructures, electrospinning has emerged as a versatile, scalable, and cost-effective method to synthesize ultra-long nanofibers with controlled diameter (a few nanometres to several micrometres) and composition. In addition, different morphologies (e.g., nano-webs, beaded or smooth cylindrical fibers, and nanoribbons) and structures (e.g., core-.shell, hollow, branched, helical and porous structures) can be readily obtained by controlling different processing parameters. Although various nanofibers including polymers, carbon, ceramics and metals have been synthesized using direct electrospinning or through post-spinning processes, limited works were reported on the compound semiconducting nanofibers because of incompatibility of precursors. In this work, we combined electrospinning and galvanic displacement reaction to demonstrate cost-effective high throughput fabrication of ultra-long hollow semiconducting chalcogen and chalcogenide nanofibers. This procedure exploits electrospinning to fabricate ultra-long sacrificial nanofibers with controlled dimensions, morphology, and crystal structures, providing a large material database to tune electrode potentials, thereby imparting control over the composition and shape of the nanostructures that evolved during galvanic displacement reaction.

• Bulletin of the Korean Chemical Society
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• v.32 no.9
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• pp.3274-3280
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• 2011

Monodispersed porous NiO and $Co_3O_4$ microcapsules with a hollow core were synthesized using SBA-16 silica sol and PS as a hard template. The porous hollow microcapsules were characterized by XRD, TEM and $N_2$ adsorption/desorption analysis. After $H_2$ reduction of metal oxide microspheres, they were conducted as an active catalyst in the reduction of chiral butylronitrile and cyanobenzene. The mesoporous metals having a hollow structure showed a higher activity than a nonporous metal powder and an impregnated metal on the carbon support.