• 제목/요약/키워드: carbon oxides

검색결과 316건 처리시간 0.028초

Investigation of Charge Transfer between Graphene and Oxide Substrates

  • Min, Kyung-Ah;Hong, Suklyun
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.186.1-186.1
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    • 2014
  • Graphene, which is a 2-dimensional carbon material, has been attracting much interest due to its unique properties and potential applications. So far, many interesting experimental and theoretical works have been done concerning the electronic properties of graphene on various substrates. Especially, there are many experimental reports about doping in graphene which is caused by interaction between graphene and its supporting substrates. Here, we report the study of charge transfer between graphene and oxide substrates using density functional theory (DFT) calculations. In this study, we have investigated the charge transfer related with graphene considering various oxide substrates such as SiO2(0001) and MgO(111). Details in charge transfer between graphene and oxides are analyzed in terms of charge density difference, band structure and work function.

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퇴적물 내 비소의 지구미생물학적 거동 연구

  • 이종운;이상우;박지민;김경웅;전효택;정명채
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2006년도 총회 및 춘계학술발표회
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    • pp.111-114
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    • 2006
  • The effects of indigenous bacteria on geochemical behavior of As in As-contaminated sediments (Hwachon mine and Myoungbong mine) after biostimulation with a variety of carbon sources were investigated under anaerobic condition. In Hwachon sediment, As was dramatically extracted from nonsterile sediment with time, reaching the highest concentration of $500{\mu}g/L$. The As leaching was likely caused by microbial dissolution of Fe oxides/oxyhydroxides with which As had been coprecipitated. However, in the case of Myoungbong sediment supplied with glucose, dissolved As decreased with time likely due to production of As sulfide(s) and subsequent precipitation, which resulted from bacterial reduction of $SO_4^{2-}$. The results implied that bacterial in-situ stabilization of As In subsurface has a potential to be practically applied.

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플라즈마를 이용한 도시 쓰레기 소각재 용융처리 기술 (Slagging treatment of MSW incineration ash by plasma system)

  • 박현서;지규일;장준섭;전석구;배희주;김형진;이시창;주성준;신범수
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 1999년도 추계학술발표회
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    • pp.65-68
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    • 1999
  • A plasma melting system to vitrify ny ash from MSW(Municipal Solid Waste) incinerator has been operated in SHI(Samsung Heavy Industries) since 1996. Waste feeding rate was 200kg/hr. with maximum working power of 500㎾. Because of high melting temperature of fly ash, bottom ash was used as an additive to decrease melting temperature. Data analysis for discharged slag shows volume reduction up to 30% and no leaching of heavy metals such as Pb, Cd, Cr which were an obstacle for landfill and recycle. Atmospheric pollution gas like nitrogen oxides, carbon monoxide, and PCDD/PCDF were restrained below the regulatory limit.

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Synthesis of Titanium Diboride and Composites by Carbothermic Reduction of Titanium Oxide and Boric Oxide

  • Yoon, Su-Jong;Jha, Animesh
    • The Korean Journal of Ceramics
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    • 제4권4호
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    • pp.387-393
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    • 1998
  • The formation of titanium diboride ($TiB_2$ ) via the reduction of $TiO_2$ with boric oxide and carbon was studied in a partially reducing atmosphere of argon mixed with 4 vol.%H2. The effect of reaction time, temperature, partial pressure of nitrogen and $TiO_2/B_2_O3$ stoichiometric ratio on the reducibility of oxides has been studied. The phases formed were analysed by using X-ray rowder diffraction and scanning sosctron microscopic techniques. In this paper, we also investigated the presence of $CaC_2$ as a reducing agent on the reducibility of oxide mixtures and on the Ti-B-C-Ca-O phase equilibria. The morphology of $TiB_2$ formed in the presence of $CaC_2$ is compared with the microstructure of $TiB_2$ formed as a consequence of carbothermic reduction. The observed variation in $TiB_2$ crystals formed is also explained.

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Reduction Behaviors of Nitric Oxides on Copper-decorated Mesoporous Molecular Sieves

  • Cho, Ki-Sook;Kim, Byung-Joo;Kim, Seok;Kim, Sung-Hyun;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • 제31권1호
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    • pp.100-103
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    • 2010
  • In this study, NO reduction behaviors of copper-loaded mesoporous molecular sieves (Cu/MCM-41) have been investigated. The Cu loading on MCM-41 surfaces was accomplished by a chemical reduction method with different Cu contents (5, 10, 20, and 40%). $N_2/77$ K adsorption isotherm characteristics, including the specific surface area and pore volume, were studied by BET's equation. NO reduction behaviors were confirmed by a gas chromatography. From the experimental results, the Cu loading amount on MCM-41 led to the increase of NO reduction efficiency in spite of decreasing the specific surface area of catalysts. This result indicates that highly ordered porous structure in the MCM-41 and the presence of active metal particles lead the synergistical NO reduction reactions due to the increase in adsorption energy of MCM-41 surfaces by the Cu particles.

매연저감을 위한 천연가스 Dual-Fuel 엔진의 시내버스 적용평가 (The Evaluation on Smoke Reduction by Natural Gas Dual Fuel Engine for City Bus)

  • 엄명도;조강래;오용석;한영출
    • 한국대기환경학회지
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    • 제13권3호
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    • pp.215-220
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    • 1997
  • CNG dual fuel engine for heavy duty diesel engine developed by AFS International in Canada has been equipped to a Korean city bus engine and tested to compare the engine performance and the emission characteristics with the existing diesel fueled engine. Also the dual-fuel engine was applied to the city bus for road test. The results are summarized as follows. Performance optimization has been carried out to have engine power equivalent to or better than the diesel fueled engine. Smoke is decreased by 85% by Korean smoke 3 mode test. By 13 mode test CO is increased by 453% and THC is increased by 2, 086%. NOx is decreased by 7% in laboratory. D-13 test mode was changed in 1996 Korean regulation. Even though THC is increased very much, it's not too serious problem since CO and HC emission of diesel engine is very little compared to gasoline engine and more than 75% of THC is CH$_4$. But the reduction technologies of CO and HC has to be considered.

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수분무 STS 316L 분말사출성형체의 탈지 및 소결공정에 따른 인장 특성 (Effect of Debinding and Sintering Conditions on the Tensile Properties of Water-atomized STS 316 L Parts by Powder Injection Molding)

  • 윤태식;성환진;안상호;이종수
    • 한국분말재료학회지
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    • 제9권4호
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    • pp.218-226
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    • 2002
  • The purpose of the present study is to investigate the influence of thermal debinding and sintering conditions on the sintering behavior and mechanical properties of PIMed 316L stainless steel. The water atomized powders were mixed with multi-component wax-base binder system, injection molded into flat tensile specimens. Binder was removed by solvent immersion method followed by thermal debinding, which was carried out in air and hydrogen atmospheres. Sintering was done in hydrogen for 1 hour at temperatures ranging from 1000℃ to 1350℃ The weight loss, residual carbon and oxygen contents were monitored at each stage of debinding and sintering processes. Tensile properties of the sintered specimen varied depending on the densification and the characteristics of the grain boundaries, which includes the pore morphology and residual oxides at the boundaries. The sinter density, tensile strength (UTS), and elongation to fracture of the optimized specimen were 95%, 540 MPa, and 53%, respectively.

주상변압기 절연유의 경년열화반응 속도론에 관한 연구 (A Study on the Age Degradation Kinetics of Pole Transformer Oil)

  • 남영우
    • 한국조명전기설비학회지:조명전기설비
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    • 제11권1호
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    • pp.99-105
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    • 1997
  • 본 논문에서는 주상변압기 절연유의 가속열화반응을 수행하였다. 유중가스를 air bubbling 법으로 추출하여 가스크로마토크라프로 성분을 분석하였으며 가스농도는 각 가스의 추출율을 감안하여 보정하였다. 절연재료의 열화는 열분해반응과산화반응에의하여 진행되었으며 두 종류의 반응은 모두 0차반응의 특성을 보였고 탄화수소류, CO+{{{{ { CO}_{2 } }}}} 및 수소가스의 생성속도식을 얻었다. 유중가스 분석과 UV-Visible 분광광도법에 의하여 변압기내의 철심과 동코일이 열화과정에서 촉매역활을 함을 확인하였다.

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전기집진기술의 현황과 장래전망(I)

  • 고명삼;이달우
    • 한국조명전기설비학회지:조명전기설비
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    • 제11권1호
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    • pp.24-33
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    • 1997
  • 본 논문에서는 주상변압기 절연유의 가속열화반응을 수행하였다. 유중가스를 air bubbling법으로 추출하여 가스크로마토그라프로 성분을 분석하였으며 가스농도는 각 가스의 추출율을 감안하여 보정하였다. 절연재료의 열화는 열분해반응과 산화반응에 의하여 진행되었으며 두종류의 반응은 모두 0차반응의 특성을 보였고 탄화수소류, $CO+CO_2$ 및 수소가스의 생성속도식을 얻었다. 유중가스 분석과 UV-Visible 분광광도법에 의하여 변압기내의 철심과 동코일이 열화과정에서 촉매역활을 함에 확인하였다.

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SI 엔진에서 바이오에탄올 연료(E100)의 연소 및 배기특성 (Combustion and Exhaust Emission Characteristics of Bio-Ethanol Fuel(E100) in SI Engine)

  • 하성용;이창식
    • 대한기계학회논문집B
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    • 제32권8호
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    • pp.582-588
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    • 2008
  • An experimental investigation was conducted to investigate the effect of Bio-ethanol fuel on the engine performance and exhaust emission characteristics under various engine operating conditions. To investigate the effect of bio-ethanol fuel, the commercial 1.6L SI engine equipped with 4 cylinder was tested on EC dynamometer. The engine performance including brake torque, brake specific fuel consumption, and barke specific energy consumption of bio-ethanol fuel was compared to those obtained by pure gasoline. Furthermore, the exhaust emissions were analyzed in terms of regulated exhaust emissions such as unburned hydrocarbon, oxides of nitrogen, and carbon monoxide.Result of this work shows that the effect of blending of ethanol to gasoline caused drastic decrease of emissions under various operating conditions. Also, improved engine performance such as brake torque and brake power were indicated for bio-ethanol fuel.