• Title/Summary/Keyword: carbon number distribution

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Kerogen Facies of the Cretaceous Black Shales from the Angola Basin (DSDP Site 530), South Atlantic (앙골라분지 백악기 흑색셰일의 유기물상)

  • 박영수
    • 한국해양학회지
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    • v.22 no.2
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    • pp.87-104
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    • 1987
  • The middle Cretaceous stratigraphec section of Deep Sea Drilling Project (DSDP) Site 530 in the Angola Basin is characterized by cyclic interbeds of organic-carbon-rich black shales and organic-carbon-poor red and green claystones, namely the black shale sequence. A number of samples from the black shale sequence were analyzed for the typesand distribution of insoluble sedimentary organic matter(kerogen) in order to give more information on the depositional conditions of the black shales in the Angola Basin. The dominant type of kerogen in the black shale sequence at Site 530 is amorphous organic matter mainly of marine planktonic algal origin. It probably consists of remains of some unfossiliqed dinoflagellates. The cyclic preservation of organic-carbon-rich black shales in the Angola Basin during the mid-Cretaceous could be explained by the low dissolved-oxygen concentration in the warm, saline deep and bottom waters combined with the sluggish circulation within the highly restricted basin, and the periodic high productivity in the surface waters.

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NEAR-INFRARED PAH FEATURES IN GALACTIC PLANETARY NEBULAE

  • Ohsawa, R.;Onaka, O.;Sakon, I.;Mori, T. I.;Kaneda, H.;Matsuura, M.
    • Publications of The Korean Astronomical Society
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    • v.32 no.1
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    • pp.87-91
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    • 2017
  • Polycyclic aromatic hydrocarbons (PAHs) are considered to be carriers of the unidentified infrared bands, which are ubiquitously observed in the Universe. PAHs are mainly formed around evolved carbon-rich stars and injected into interstellar space. Planetary nebulae (PNe), a late stage of low- and intermediate stellar mass evolution, are suitable objects to investigate the formation and evolution of PAHs. The shortest PAH feature is located in $3.3{\mu}m$, which is important to examine the excitation and size distribution of PAHs. While the number of samples had been limited before, the high sensitivity of AKARI /IRC has drastically increased the number of samples. We obtained the $2-5{\mu}m$ spectra of Galactic PNe with AKARI /IRC and compiled a near-infrared spectral catalog, containing 73 PNe. We investigate the detection rate and the evolution of the PAH features. The characteristics of the catalog are illustrated and the origin of the evolution of the PAH features is discussed.

The Influence of Chlorine Application on Corrosion and Bacterial Growth in Home Plumbing Systems (급수관내 염소 주입이 미생물의 증식과 부식에 미치는 영향)

  • Kim, Tae-Hyun;Lee, Yoon-Jin;Lim, Seung-Joo
    • Journal of Environmental Health Sciences
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    • v.32 no.5 s.92
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    • pp.431-439
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    • 2006
  • This research was conducted using a model home plumbing system composed of copper, stainless steel, galvanized iron, carbon steel, and PVC (polyvinyl chloride) pipe. The number of bacteria present in stainless steel pipe and PVC was higher than other pipes. High turbidity and zinc release were found in galvanized iron pipe material and detected during the first 6 months. Conversely, there was a decrease in turbidity and zinc release after 6 months resulting in levels similar to other pipes. Copper concentration decreased as operation times increased. In this experiment, the number of bacteria detected in biofilm for a copper pipe continued to increase. Pipe material influenced bacterial numbers in biofilm and water. This showed that elevated chlorine could not control bacterial growth in biofilm for galvanized iron and stainless steel systems. It also suggested that the dosing of chlorine might not be available for all kinds of pipes. Therefore, another complementary method should be introduced to manage biofilm effectively in water distribution systems.

Comparison of the habitat distribution characteristics of Aquatic Oligochaeta according to the construction of weirs in four major rivers in South Korea (4대강 보 건설에 따른 실지렁이류(Aquatic Oligochaeta) 서식분포 특성 비교)

  • Wang, Ju Hyoun;Park, Hyung Joon;Park, Jung Ho;Song, Haeng Seop;Kim, Ho Joon;Park, Yeon Jeong;Choi, Jun Kil;Lee, Hwang Goo
    • Korean Journal of Environmental Biology
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    • v.37 no.4
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    • pp.607-617
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    • 2019
  • This study examined the habitat distribution characteristics of Aquatic Oligochaeta according to the construction of weirs in the four major rivers in South Korea. The area was investigated 10 times from March to October in 2018 and a total of 18 species and 35,390 ind. m-2 were sampled. The dominant species by number was Limnodrilus hoffmeisteri(77.1%) and the subdominant species was Branchiura sowerbyi(9.5%). A total of 32.418 g m-2 dry weight was analyzed. The correlation analysis showed that the number of Aquatic Oligochaeta individuals correlated with the sediment depth, clay ratio, silt ratio, sand ratio, cobble ratio, pebble ratio, pH and TOC mg L-1. Specifically, the clay ratio and sediment depth were associated with increases in the number of individuals. The total organic carbon(TOC) increased from March to October and, conversely, the number of individuals tended to decrease.

Thermochemical Sulfate Reduction Simulation Experiments on the Formation and Distribution of Organic Sulfur Compounds in the Tuha Crude Oil

  • Yue, Changtao;Li, Shuyuan;Song, He
    • Bulletin of the Korean Chemical Society
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    • v.35 no.7
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    • pp.2057-2064
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    • 2014
  • Thermochemical sulfate reduction (TSR) was conducted in autoclave on the system of crude oil and $MgSO_4$ at different temperatures. Gas chromatography pulsed flame photometric detector (GC-PFPD) was used to detected the composition of organic sulfur compounds in oil phase products. The results of the analysis indicate that with increased temperature, the contents of organic sulfur compounds with high molecular weight and thermal stability, such as benzothiophenes and dibenzothiophenes, gradually became dominated. In order to gain greater insight into the formation and distribution of organic sulphur compounds from TSR, positive ion electrospray Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) was used in detecting the detailed elemental composition and distribution of them. The mass spectra showed that the mass range of sulfur compounds was 200-550 Da. Four sulfur class species, $S_1$, $N_1S_1$, $O_1S_1$ and $O_2S_1$, were assigned in the positive-ion spectrum. Among the identified sulfur compounds, the $S_1$ class species was dominant. The most abundant $S_1$ class species increase associated with the DBE value and carbon number increasing which also indicates the evolution of organic sulfur compounds in TSR is from the labile series to the stable one. In pure blank pyrolysis experiments with crude oil cracking without TSR, different composition and distribution of organic sulfur compounds in oil phase products were seen from mass spectra in order to evaluate their pyrolysis behaviors without $MgSO_4$. FT-IR and XRD were used in analyzing the products of solid phases. Two distinct crystallographic phases MgO and $MgSO_4$ are found to coexist in the products which demonstrated the transformation of inorganic sulfur compounds into organosulfur compounds exist in TSR.

Quantitative Analysis of Fuel in Engine Oil (엔진오일 내 연료성분 정량분석)

  • Lim, Young-Kwan;Kim, Jiyeon;Na, Yong-Gyu;Kim, Jong-Ryeol
    • Applied Chemistry for Engineering
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    • v.28 no.6
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    • pp.714-719
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    • 2017
  • The contaminated engine oil by fuel can intimidate driver safety due to vehicle problems such as engine abrasion, fire and sudden unintended acceleration. In this study, we investigate various functional properties of the engine oil contaminated with fuel. The test results indicated that the engine oil contaminated with fuel had relatively low values of the flash point, pour point, density, kinematic viscosity and cold cranking simulator. Furthermore, a four ball test suggested that the contaminated engine oil increased wear scar due to the poor lubricity. Moreover, SIMDIST (simulated distillation) using ASTM D2887 was applied to analyze fuel characteristics in an engine oil. The SIMDIST analysis result showed a lower carbon number, and the fuel was detected at an earlier retention time than that of using engine oil in chromatogram. Also, it is possible to quantitatively analyze for fuel contents in the engine oil. The SIMDIST method for the diagnosis of oil conditions can be used whether the fuel was involved or not, instead of analyzing other physical properties that require various analytical instruments, large volumes of oil samples, and long analysis time.

Separation of Aromatics in Light Cycle Oil by Solvent Extraction - Re-extraction of Aromatics in Extract Phase - (용매 추출법에 의한 분해경유중의 방향족 분리 -추출상중의 방향족의 역수출-)

  • Kim, Su Jin;Kim, Duk-Hyun
    • Applied Chemistry for Engineering
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    • v.8 no.6
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    • pp.967-972
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    • 1997
  • Recovery of aromatics in extract phase which was obtained by batch equilibrium extraction between light cycle oil(LCO) and dimethylsulfoxide(DMSO) solution as solvent was investigated by re-extraction. To select the most suitable re-extraction solvent for recovery of aromatics in extract phase, distribution equilibrium was measured between extract phase and solvents. The solvents used were benzene(B), toluene(T), m-Xylene(mX), n-hexane(Hx) and n-hexane(Hx) and n-Octane(Ot). From the distribution coefficients and yields of aromatics, Hx seemed to be the most suitable. Furthermore, effects of operation parameters for re-extraction of aromatics in the extract phase were studied by batch equilibrium re-extracion with Hx as solvent. Yields of aromatics were found to increase with increasing solvent/feed (extract phase) mass ratio(S/F), while distribution coefficients of aromatics were fixed irrespective of S/F used. Operating temperature did not affect distribution coefficients and yields of aromatics. Distibution coefficients and yields of naphthalene group(carbon numer : 10~12) increased with increasing cabon number. Mass transfer rates of aromatics were also measured with a batch stirred vessel.

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Fungal Clusters and Their Uniqueness in Geographically Segregated Wetlands: A Step Forward to Marsh Conservation for a Wealth of Future Fungal Resources

  • Park, Jong Myong;Hong, Ji Won;Lee, Woong;Lee, Byoung-Hee;You, Young-Hyun
    • Mycobiology
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    • v.48 no.5
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    • pp.351-363
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    • 2020
  • Here, we investigated fungal microbiota in the understory root layer of representative well-conserved geographically segregated natural wetlands in the Korean Peninsula. We obtained 574,143 quality fungal sequences in total from soil samples in three wetlands, which were classified into 563 operational taxonomic units (OTU), 5 phyla, 84 genera. Soil texture, total nitrogen, organic carbon, pH, and electrical conductivity of soil were variable between geographical sites. We found significant differences in fungal phyla distribution and ratio, as well as genera variation and richness between the wetlands. Diversity was greater in the Jangdo islands wetland than in the other sites (Chao richness/Shannon/Simpson's for wetland of the Jangdo islands: 283/6.45/0.97 > wetland of the Mt. Gariwang primeval forest: 169/1.17/0.22 > wetland of the Hanbando geology: 145/4.85/0.91), and this variance corresponded to the confirmed number of fungal genera or OTUs (wetlands of Jangdo islands: 42/283> of Mt. Gariwang primeval forest: 32/169> of the Hanbando geology: 25/145). To assess the uniqueness of the understory root layer fungus taxa, we analyzed fungal genera distribution. We found that the percentage of fungal genera common to two or three wetland sites was relatively low at 32.3%, while fungal genera unique to each wetland site was 67.7% of the total number of identified fungal species. The Jangdo island wetland had higher fungal diversity than did the other sites and showed the highest level of uniqueness among fungal genera (Is. Jangdo wetland: 34.5% > wetland of Mt. Gariwang primeval forest: 28.6% > wetland of the Hanbando geology: 16.7%).

Evaluation and Modification of Tensile Properties of Carbon Fiber Reinforced Polymer(CFRP) as Brittle Material with Probability Distribution (확률분포를 이용한 취성재료 특성의 탄소섬유보강폴리머 인장물성평가 및 보정)

  • Kim, Yun-Gon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.3
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    • pp.17-24
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    • 2019
  • Carbon Fiber Reinforced Polymers(CFRP) has widely utilized as a material for rehabilitation because of its light-weight, deformability and workability. Because CFRP is brittle material whereas steel is ductile, it is inappropriate to apply conventional design approach for steel reinforcement. For ductile material, the behavior of combined elements is on average of that of unit element due to the stress redistribution between elements after yielding. Therefore, the mean value of the stress of combined elements is equal to that of unit element and the standard variation is smaller. Therefore, although the design value can increase, it is used as constant value because it is conservative and practical approach. However, for brittle material, the behavior of combined elements is governed by the weaker element because no stress redistribution is expected. Therefore, both the mean value and standard variation of the stress of combined elements decreases. For this reason, the design value would decrease as the number of element increases although it is eventually converged. In this paper, in brittle material, it is verified that the combination of unit element with normal distribution results in combined element with weibull distribution, so the modifying equation of mechanical properties is proposed with respect to the area load applied.

Change Analysis of Aboveground Forest Carbon Stocks According to the Land Cover Change Using Multi-Temporal Landsat TM Images and Machine Learning Algorithms (다시기 Landsat TM 영상과 기계학습을 이용한 토지피복변화에 따른 산림탄소저장량 변화 분석)

  • LEE, Jung-Hee;IM, Jung-Ho;KIM, Kyoung-Min;HEO, Joon
    • Journal of the Korean Association of Geographic Information Studies
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    • v.18 no.4
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    • pp.81-99
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    • 2015
  • The acceleration of global warming has required better understanding of carbon cycles over local and regional areas such as the Korean peninsula. Since forests serve as a carbon sink, which stores a large amount of terrestrial carbon, there has been a demand to accurately estimate such forest carbon sequestration. In Korea, the National Forest Inventory(NFI) has been used to estimate the forest carbon stocks based on the amount of growing stocks per hectare measured at sampled location. However, as such data are based on point(i.e., plot) measurements, it is difficult to identify spatial distribution of forest carbon stocks. This study focuses on urban areas, which have limited number of NFI samples and have shown rapid land cover change, to estimate grid-based forest carbon stocks based on UNFCCC Approach 3 and Tier 3. Land cover change and forest carbon stocks were estimated using Landsat 5 TM data acquired in 1991, 1992, 2010, and 2011, high resolution airborne images, and the 3rd, 5th~6th NFI data. Machine learning techniques(i.e., random forest and support vector machines/regression) were used for land cover change classification and forest carbon stock estimation. Forest carbon stocks were estimated using reflectance, band ratios, vegetation indices, and topographical indices. Results showed that 33.23tonC/ha of carbon was sequestrated on the unchanged forest areas between 1991 and 2010, while 36.83 tonC/ha of carbon was sequestrated on the areas changed from other land-use types to forests. A total of 7.35 tonC/ha of carbon was released on the areas changed from forests to other land-use types. This study was a good chance to understand the quantitative forest carbon stock change according to the land cover change. Moreover the result of this study can contribute to the effective forest management.