• 제목/요약/키워드: carbon number distribution

검색결과 166건 처리시간 0.026초

Dynamic stability of FG-CNT-reinforced viscoelastic micro cylindrical shells resting on nonhomogeneous orthotropic viscoelastic medium subjected to harmonic temperature distribution and 2D magnetic field

  • Tohidi, H.;Hosseini-Hashemi, S.H.;Maghsoudpour, A.;Etemadi, S.
    • Wind and Structures
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    • 제25권2호
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    • pp.131-156
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    • 2017
  • This paper deals with the dynamic stability of embedded functionally graded (FG)-carbon nanotubes (CNTs)-reinforced micro cylindrical shells. The structure is subjected to harmonic non-uniform temperature distribution and 2D magnetic field. The CNT reinforcement is either uniformly distributed or FG along the thickness direction where the effective properties of nano-composite structure are estimated through Mixture low. The viscoelastic properties of structure are captured based on the Kelvin-Voigt theory. The surrounding viscoelastic medium is considered nonhomogeneous with the spring, orthotropic shear and damper constants. The material properties of cylindrical shell and the viscoelastic medium constants are assumed temperature-dependent. The first order shear deformation theory (FSDT) or Mindlin theory in conjunction with Hamilton's principle is utilized for deriving the motion equations where the size effects are considered based on Eringen's nonlocal theory. Based on differential quadrature (DQ) and Bolotin methods, the dynamic instability region (DIR) of structure is obtained for different boundary conditions. The effects of different parameters such as volume percent and distribution type of CNTs, mode number, viscoelastic medium type, temperature, boundary conditions, magnetic field, nonlocal parameter and structural damping constant are shown on the DIR of system. Numerical results indicate that the FGX distribution of CNTs is better than other considered cases. In addition, considering structural damping of system reduces the resonance frequency.

BTEX 혼합물질과 액상 간 분배성 추적자의 분배계수 예측 (Estimating Partition Coefficients of Partitioning Tracers between Water and BTEX Mixtures)

  • 이성수;조상연;오명학;박준범
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제12권2호
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    • pp.47-54
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    • 2007
  • 분배성 추적자 시험은 NAPLs(Nonaqueous Phase Liquids)로 오염된 대수층 및 토양 내 오염물질의 양을 예측하는 새로운 모니터링 방법으로 최근 많이 연구되고 있다. 분배성 추적자 시험은 액상과 NAPL 간에 분배되는 분배성 추적자의 분배계수를 정확히 구해야 높은 신뢰도를 가진 결과를 얻을 수 있다. 본 연구에서는 등가 알칸 탄소수(Equivalent Alkane Carbon Number; EACN) 접근법을 이용하여 액상과 벤젠, 톨루엔, 에틸벤젠, 자일렌 그리고 BTEX 혼합물질간에 분배되는 알코올 계열 추적자의 분배계수를 예측해보았다. 이 예측식을 이용한 예측값과 실험값은 BTEX 뿐만 아니라 BTEX 혼합물에서도 비교적 잘 일치하였으며, 이를 통해 추적자와 오염물질의 EACN 값을 알고 있을 경우 직접적인 분배계수 실험을 하지 않고도 간단하게 예측할 수 있음을 확인하였다.

동부 심해 울릉분지의 천연가스 하이드레이트 (Natural gas hydrates in the eastern deep-water Ulleung Basin)

  • 류병재;김지훈;정부흥;이영주
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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    • pp.610-612
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    • 2008
  • Piston cores retrieved from the eastern part of the deep-water Ulleung Basin were analyzed to access the potential of hydrocarbon gas generation and natural gas hydrate (NGH) formation. Seismic data acquired in the study area were also analyzed to determine the presence of hydrocarbon gas and/or NGH, and to map their distribution. Core analyses revealed high total organic carbon (TOC) contents which favor hydrocarbon generation. The cores recovered from the southern study area showed the sufficient residual hydrocarbon gas concentrations for the formation of significant NGH. These cores also showed the cracks developed parallel to the bedding that suggest significant gas content in situ. A number of seismic blanking zones were observed on seismic data. They are identified as vertical to sub-vertical chimneys caused by the upward migration of pore fluid or gas, and containing of free gas and/or NGH. Often, they are associated with velocity pull-up structures that are interpreted to be the result of high-velocity NGH. The seismic data also showed several bottom-simulating reflectors (BSRs) that are associated with overlying NGH and underlying free gas. The distribution of blanking zones and BSRs would be impacted by the lateral differences of upward methane fluxes.

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Polymerization of Methyl Methacrylate in Carbon Dioxide Using Glycidyl Methacrylate Linked Reactive Stabilizer: Effect of Pressure, Reaction Time, and Mixing

  • Han, Sang-Hun;Park, Kyung-Kyu;Lee, Sang-Ho
    • Macromolecular Research
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    • 제17권1호
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    • pp.51-57
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    • 2009
  • Using glycidyl methacrylate-linked poly(dimethylsiloxane), methyl methacrylate was polymerized in supercritical $CO_2$. The effects of $CO_2$ pressure, reaction time, and mixing on the yield, molecular weight, and molecular weight distribution (MWD) of the poly(methyl methacrylate) (PMMA) products were investigated. The shape, number average particle diameter, and particle size distribution (PSD) of the PMMA were characterized. Between 69 and 483 bar, the yield and molar mass of the PMMA products showed a trend of increasing with increasing $CO_2$ pressure. However, the yield leveled off at around 345 bar and the particle diameter of the PMMA increased until the pressure reached 345 bar and decreased thereafter. With increasing pressure, MWD became more uniform while PSD was unaffected. As the reaction time was extended at 207 bar, the particle diameter of PMMA decreased at $0.48{\pm}0.03%$ AIBN, but increased at 0.25% AIBN. Mixing the reactant mixture increased the PMMA yield by 18.6% and 9.3% at 138 and 207 bar, respectively.

GAC에 의한 고농도 계면활성제 폐수의 흡착처리 (Treatment of the Wastewater of High Surfactant Concentration by GAC GAC Adsorption)

  • 김학성;이진필;한훈석
    • 한국응용과학기술학회지
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    • 제16권1호
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    • pp.59-65
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    • 1999
  • For a cosmetic plant wastewater containing surfactants of high concentration, adsorption treatment by granular activated carbon(GAC) having different pore size distribution was studied. Three sorts GACs were used and regenerated afterwards with methanol. Experiments were composed of batch process and column test for both virgin and regenerated GACs. Following conclusions were drawn from the study: Methylene blue activating substance(MBAS) adsorption data from the batch tests for three GACs are described well by BET isotherm and Freundich isotherm. Simulation with the BET isotherm shows that maximum adsorption appears to be affected not only by specific surface area but also by pore size distribution. Maximum adsorption from the BET isotherm for MBAS appears to diminish as the number of reactivation increases. The diminishing ratio of maximum adsorption appears to decrease as the pore size decreases. Recovery ratio of the methanol by vacuum evaporation from the spent methanol ranges from 95% to 97%.

Metabolism of Very Long-Chain Fatty Acids: Genes and Pathophysiology

  • Sassa, Takayuki;Kihara, Akio
    • Biomolecules & Therapeutics
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    • 제22권2호
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    • pp.83-92
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    • 2014
  • Fatty acids (FAs) are highly diverse in terms of carbon (C) chain-length and number of double bonds. FAs with C>20 are called very long-chain fatty acids (VLCFAs). VLCFAs are found not only as constituents of cellular lipids such as sphingolipids and glycerophospholipids but also as precursors of lipid mediators. Our understanding on the function of VLCFAs is growing in parallel with the identification of enzymes involved in VLCFA synthesis or degradation. A variety of inherited diseases, such as ichthyosis, macular degeneration, myopathy, mental retardation, and demyelination, are caused by mutations in the genes encoding VLCFA metabolizing enzymes. In this review, we describe mammalian VLCFAs by highlighting their tissue distribution and metabolic pathways, and we discuss responsible genes and enzymes with reference to their roles in pathophysiology.

LDPE 반회분식 촉매열분해에서 조업조건이 반응 특성에 미치는 영향 (Effects of Reaction Conditions on the Performance of Catalytic Pyrolysis of LDPE in a Semi-Batch Reactor)

  • 나정걸;임철현;최휘경;정수현
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2006년도 추계학술대회
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    • pp.79-82
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    • 2006
  • Fueled by ballooning oil prices, waste plastics are now regarded as being cheap and abundant renewable sources, removing their stigma of dirty wastes Catalytic pryolysis of plastics in liquid phase allows recovery of light fuel oil as well as green treatment of polymerics wastes, and therefore significant efforts have been devoted to this research field. In this study, catalytic Pyrolysis of LDPE was carl ied out in semi-batch reactor which equipped a unit of separation and recirculation. The effect of react ion conditions were examined by analyzing liquid oil yield and carbon number distribution of products

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탄소섬유시트에 의한 콘크리트 보의 휨보강효과에 관한 실험연구 (An Experimental Study on Flexcural Performance of Repaired R/C Beams with CFS)

  • 이리형;이용택;김승훈;강윤구
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1997년도 봄 학술발표회 논문집
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    • pp.605-610
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    • 1997
  • An experimental investigation was conducted to examine the feasibility of Carbon Fiber Sheet(CFS), a kind of high strength fiber, for a repair and reinforcement method of concrete structures. The experimental program included tests of flexural beams different in wrapping method and amount of CFS. The beams were subjected to monotonic loading. Although the flexural strength for concrete members increases with wrapping methods of CFS., the reduction factor due to the distribution, amount bond of CFS should be completely examined. This study approached the effectiveness and application of CFS, along with reinforcement effects of CFS on reinforced concrete beams through tests. Test results indicated that the increase in the number of CFS layer caused the increase in strength of beams in strength.

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유동층 반응기 희박상 내 탄소나노튜브 응집체의 크기 및 형상 측정 (Measurement of Carbon Nanotube Agglomerates Size and Shape in Dilute Phase of a Fluidized Bed)

  • 김성원
    • Korean Chemical Engineering Research
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    • 제55권5호
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    • pp.646-651
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    • 2017
  • CNT 유동층 반응기(내경 0.15 m, 높이 2.6 m) 희박상 내 CNT 입자(평균입도 $291{\mu}m$, 벌크밀도 $72.9kg/m^3$)의 거동을 확인하기 위해 레이저 슬릿광 형상 측정법을 이용하여, CNT 응집체의 크기 및 형태를 측정하였다. 기포유동층 조건에서 CNT 반응기 내 축방향 고체체류량 분포는 하부 농후상과 상부 희박상을 갖는 S자 형태를 보였다. 기체 유속이 증가할수록 비산되는 CNT 응집체의 Heywood 직경과 Feret 직경이 증가하였고, 응집체 내 CNT 입자수가 증가하였다. 또한, 기체의 유속이 증가할수록 CNT 응집체의 종횡비는 증가하고, 원형도는 감소하였다. CNT 응집체의 원마도와 견고도는 기체의 유속이 증가할수록 감소하였다. 응집체의 형상 분석 정보에 기반한 희박상 내 응집체 형성 원인을 제안하였다.

Improving the Long-term Field Emission Stability of Carbon Nanotubes by Coating Co and Ni Oxide Layers

  • 최주성;이한성;이내성
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 추계학술발표대회
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    • pp.18.1-18.1
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    • 2011
  • Some applications of carbon nanotubes (CNTs) as field emitters, such as x-ray tubes and microwave amplifiers, require high current emission from a small emitter area. To emit the high current density, CNT emitters should be optimally fabricated in terms of material properties and morphological aspects including high crystallinity, aspect ratio, distribution density, height uniformity, adhesion on a substrate, low outgassing rate during electron emission in vacuum, etc. In particular, adhesion of emitters on the substrate is one of the most important parameters to be secured for high current field emission from CNTs. So, we attempted a novel approach to improve the adhesion of CNT emitters by incorporating metal oxide layers between CNT emitters. In our previous study, CNT emitters were fabricated on a metal mesh by filtrating the aqueous suspensions containing both highly crystalline thin multiwalled CNTs and thick entangled multiwalled CNTs. However, the adhesion of CNT film was not enough to produce a high emission current for an extended period of time even after adopting the metal mesh as a fixing substrate of the CNT film. While a high current was emitted, some part of the film was shown to delaminate. In order to strengthen the CNT networks, cobalt-nickel oxides were incorporated into the film. After coating the oxide layer, the CNT tips seemed to be more strongly adhered on the CNT bush. Without the oxide layer, the field emission voltage-current curve moved fast to a high voltage side as increasing the number of voltage sweeps. With the cobalt-nickel oxide incorporated, however, the curve does not move after the second voltage sweep. Such improvement of emission properties seemed to be attributed to stronger adhesion of the CNT film which was imparted by the cobalt-nickel oxide layer between CNT networks. Observed after field emission for an extended period of time, the CNT film with the oxide layer showed less damage on the surface caused by high current emission.

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