• 제목/요약/키워드: carbon nanowires

검색결과 55건 처리시간 0.308초

One-dimensional Nanomaterials for Field Effect Transistor (FET) Type Biosensor Applications

  • Lee, Min-Gun;Lucero, Antonio;Kim, Ji-Young
    • Transactions on Electrical and Electronic Materials
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    • 제13권4호
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    • pp.165-170
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    • 2012
  • One-dimensional, nanomaterial field effect transistors (FET) are promising sensors for bio-molecule detection applications. In this paper, we review fabrication and characteristics of 1-D nanomaterial FET type biosensors. Materials such as single wall carbon nanotubes, Si nanowires, metal oxide nanowires and nanotubes, and conducting polymer nanowires have been widely investigated for biosensors, because of their high sensitivity to bio-substances, with some capable of detecting a single biomolecule. In particular, we focus on three important aspects of biosensors: alignment of nanomaterials for biosensors, surface modification of the nanostructures, and electrical detection mechanism of the 1-D nanomaterial sensors.

SnO2-CoO/carbon-coated CoO core/shell 나노선 복합체의 합성 및 구조분석 (Synthesis and Characterization of SnO2-CoO/carbon-coated CoO Core/shell Nanowire Composites)

  • 이유진;구본율;안효진
    • 한국분말재료학회지
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    • 제21권5호
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    • pp.360-365
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    • 2014
  • $SnO_2-CoO$/carbon-coated CoO core/shell nanowire composites were synthesized by using electrospinning and hydrothermal methods. In order to obtain $SnO_2-CoO$/carbon-coated CoO core/shell nanowire composites, $SnO_2-Co_3O_4$ nanowire composites and $SnO_2-Co_3O_4$/polygonal $Co_3O_4$ core/shell nanowire composites are also synthesized. To demonstrate their structural, chemical bonding, and morphological properties, field-emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy were carried out. These results indicated that the morphologies and structures of the samples were changed from $SnO_2-Co_3O_4$ nanowires having cylindrical structures to $SnO_2-Co_3O_4/Co_3O_4$ core/shell nanowires having polygonal structures after a hydrothermal process. At last, $SnO_2-CoO$/carbon-coated CoO core/shell nanowire composites having irregular and high surface area are formed after carbon coating using a polypyrrole (PPy). Also, there occur phases transformation of cobalt phases from $Co_3O_4$ to CoO during carbon coating using a PPy under a argon atmosphere.

Caffeine as a source for nitrogen doped graphene, and its functionalization with silver nanowires in-situ

  • Ramirez-Gonzalez, Daniel;Cruz-Rivera, Jose de J.;Tiznado, Hugo;Rodriguez, Angel G.;Guillen-Escamilla, Ivan;Zamudio-Ojeda, Adalberto
    • Advances in nano research
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    • 제9권1호
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    • pp.25-32
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    • 2020
  • In this work, we report the use of caffeine as an alternative source of nitrogen to successfully dope graphene (quaternary 400.6 eV and pyridinic at 398 eV according XPS), as well as the growth of silver nanowires (in-situ) in the surface of nitrogen doped graphene (NG) sheets. We used the improved graphene oxide method (IGO), chemical reduction of graphene oxide (GOx), and impregnation with caffeine as source of nitrogen for doping and subsequently, silver nanowires (NW) grow in the surface by the reduction of silver salts in the presence of NG, achieving a numerous of growth of NW in the graphene sheets. As supporting experimental evidence, the samples were analyzed using conventional characterization techniques: SEM-EDX, XRD, FT-IR, micro RAMAN, TEM, and XPS.

Semiconductor Nanowires;Their Emission Stability and Energy Distribution

  • Yu, Se-Gi;Yi, Whi-Kun;Lee, Sang-Hyun;Heo, Jung-Na;Jeong, Tae-Won;Lee, Jeong-Hee;Lee, Soo-Chang;Kim, J.M.;Lee, Cheol-Jin;Lyu, Seung-Chul;Han, Jae-Hee;Yoo, Ji-Beom
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.1028-1031
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    • 2002
  • Ga-based semiconductor nanowires (GaN, GaP) were synthesized by the reaction of Ga metal and GaN/GaP powder with a $NH_3/Ar$ gas using thermal chemical vapor deposition. The field emission and emission stability under oxygen and argon environments were investigated. Field emission energy distributions of electrons from these nanowires revealed that field emission mechanism of the semiconductor nanowires were different from carbon nanotubes.

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반도체 나노와이어에서 전자방출 안정성 (Emission Stability of Semiconductor Nanowires)

  • 유세기;정태원;이상현;허정나;이정희;이철진;김진영;이형숙;국윤필;김종민
    • 한국진공학회지
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    • 제15권5호
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    • pp.499-505
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    • 2006
  • 열 화학기상법으로 만든 GaN와 GaP 나노와이어에서 전계 방출과, 산소와 아르곤 분위기에서 안정성에 대해 조사하였다. GaN 나노와이어의 경우 산소 분위기에서 전계 방출이 급격하게 줄었으나, GaP에서는 그렇지 않았다. 두 나노와이어 모두 아르곤 분위기에서는 큰 변화가 없었다. GaP 나노와이어의 외부에 존재하는 산화물 층이 전자 방출 안정성에 크게 기여한 것으로 생각된다. 나노와이어에서 방출된 전자의 에너지 분포를 통해 반도체 나노와이어는 탄소 나노튜브와 그 전계 방출 메카니즘이 다름을 유추할 수 있었다.

무정제 단일벽 탄소나노튜브와 은나노와이어가 적층으로 코팅된 투명전도성 고분자 필름의 전기 전도성, 광학 투과도 및 산화안정성 (Electrical Conductivity, Optical Transmittance, and Oxidation Stability of Transparent Conductive Polymer Film Coated With Layered Pristine Single-walled Carbon Nanotube and Silver Nanowire)

  • 이영실
    • Korean Chemical Engineering Research
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    • 제61권3호
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    • pp.456-462
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    • 2023
  • 탄소나토튜브를 투명 전극에 활용하기 위한 필수요소인 정제과정없이 무정제 단일벽 탄소나노튜브(single-walled carbon nanotube, SWCNT)와 은나노와이어(silver nanowire) 분산액을 제조하여 폴리에틸렌 테레프탈레이트(polyethylene terephthalate, PET) 필름에 바 코팅을 이용하여 전기전도성 투명전극을 제조하였다. PET 기판 위에 SWCNT 및 은 나노와이어를 각각 포함하는 코팅층을 상호 교차시켜 적층함으로서 은나노와이어의 전기 전도도와 투과도를 극대화시키고 헤이즈 (haze)가 증가되는 단점을 극복하기 위해 SWCNT를 도입하였고, 무정제 SWCNT내에 존재하는 금속 촉매의 산화에 의해서 항온항습 테스트 후 저항이 급격하게 증가하는 문제를 은 나노와이어가 전기적 네트워크 형성에 기여하여 산화에 대한 안정성을 확보할 수 있었다. SWCNT함량이 0.025 wt% 인 분산액을 PET 기판에 먼저 코팅하고 그 위에 은 나노와이어의 함량이 0.05 wt%인 분산액을 코팅한 투명전극의 시트 저항은 47 Ω/□, 투과도는 96.72%, 헤이즈는 1.93% 로 전기적 광학적 특성이 우수하게 나왔고, 산화 안정성 평가를 위한 항온 항습 실험 후 시트 저항의 변화율이 6.4% 로 적게 나타나서 장기적 사용에 적합하다는 것을 알 수 있었다. 무정제 SWCNT 사용함으로 저비용, 친환경 하이브리드 투명전극을 상업적으로 활용 가능한 수준의 제품이 개발되었다.

유기금속 화학기상증착법을 이용한 TiO2 나노선 제조 (Synthesis of TiO2 Nanowires by Metallorganic Chemical Vapor Deposition)

  • 허훈회;웬티깅화;임재균;김길무;김의태
    • 한국재료학회지
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    • 제20권12호
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    • pp.686-690
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    • 2010
  • $TiO_2$ nanowires were self-catalytically synthesized on bare Si(100) substrates using metallorganic chemical vapor deposition. The nanowire formation was critically affected by growth temperature. The $TiO_2$ nanowires were grown at a high density on Si(100) at $510^{\circ}C$, which is near the complete decomposition temperature ($527^{\circ}C$) of the Ti precursor $(Ti(O-iPr)_2(dpm)_2)$. At $470^{\circ}C$, only very thin (< $0.1{\mu}m$) $TiO_2$ film was formed because the Ti precursor was not completely decomposed. When growth temperature was increased to $550^{\circ}C$ and $670^{\circ}C$, the nanowire formation was also significantly suppressed. A vaporsolid (V-S) growth mechanism excluding a liquid phase appeared to control the nanowire formation. The $TiO_2$ nanowire growth seemed to be activated by carbon, which was supplied by decomposition of the Ti precursor. The $TiO_2$ nanowire density was increased with increased growth pressure in the range of 1.2 to 10 torr. In addition, the nanowire formation was enhanced by using Au and Pt catalysts, which seem to act as catalysts for oxidation. The nanowires consisted of well-aligned ~20-30 nm size rutile and anatase nanocrystallines. This MOCVD synthesis technique is unique and efficient to self-catalytically grow $TiO_2$ nanowires, which hold significant promise for various photocatalysis and solar cell applications.

대기 분위기에서 열증발법에 의해 성장된 여러 가지 형상의 일차원 MgO 나노구조 (One-Dimensional MgO Nanostructures with Various Morphologies Grown by Thermal Evaporation Method under Atmospheric Environment)

  • 김남우;김진수;이근형
    • 한국재료학회지
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    • 제33권7호
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    • pp.279-284
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    • 2023
  • One-dimensional MgO nanostructures with various morphologies were synthesized by a thermal evaporation method. The synthesis process was carried out in air at atmospheric pressure, which made the process very simple. A mixed powder of magnesium and active carbon was used as the source powder. The morphologies of the MgO nanostructures were changed by varying the growth temperature. When the growth temperature was 700 ℃, untapered nanowires with smooth surfaces were grown. As the temperature increased to 850 ℃, 1,000 ℃ and 1,100 ℃, tapered nanobelts, tapered nanowires and then knotted nanowires were sequentially observed. X-ray diffraction analysis revealed that the MgO nanostructures had a cubic crystallographic structure. Energy dispersive X-ray analysis showed that the nanostructures were composed of Mg and O elements, indicating high purity MgO nanostructures. Fourier transform infrared spectra peaks showed the characteristic absorption of MgO. No catalyst particles were observed at the tips of the one-dimensional nanostructures, which suggested that the one-dimensional nanostructures were grown in a vapor-solid growth mechanism.