• Title/Summary/Keyword: carbon nanotubes (CNT)

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Enhanced Electron Emission from Carbon Nanotube Paste after Firing

  • Kang, Sung-Kee;Choi, Jong-Hyung;Han, Jae-Hee;Yoo, Ji-Beom;Park, Chong-Yun;Nam, Joong-Woo;Jung, J.E.;Kim, J.M.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.849-851
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    • 2003
  • After multi-walled carbon nanotubes (MWNT) powder was crushed with ball milling process, it was mixed with organic vehicles. And then CNT paste was printed on ITO coated glass substrate. The field emission characteristics of CNT pastes fired in air atmosphere was better than that of CNT paste fired in Ar ambient due to less organic residues after firing.

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Influence of the microstructure on effective mechanical properties of carbon nanotube composites

  • Drucker, Sven;Wilmers, Jana;Bargmann, Swantje
    • Coupled systems mechanics
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    • v.6 no.1
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    • pp.1-15
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    • 2017
  • Despite the exceptional mechanical properties of individual carbon nanotubes (CNTs), the effective properties of CNT-reinforced composites remain below expectations. The composite's microstructure has been identified as a key factor in explaining this discrepancy. In this contribution, a method for generating representative volume elements of aligned CNT sheets is presented. The model captures material characteristics such as random waviness and entanglement of individual nanotubes. Thus it allows studying microstructural effects on the composite's effective properties. Simulations investigating the strengthening effect of the application of a pre-stretch on the CNTs are carried out and found to be in very good agreement with experimental values. They highlight the importance of the nanotube's waviness and entanglement for the mechanical behavior of the composite. The presented representative volume elements are the first to accurately capture the waviness and entanglement of CNT sheets for realistically high volume fractions.

Recent advances in water and wastewater treatment using membranes with carbon nanotubes

  • Michal, Bodzek;Krystyna, Konieczny;Anna, Kwiecinska-Mydlak
    • Membrane and Water Treatment
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    • v.13 no.6
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    • pp.259-290
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    • 2022
  • Carbon nanotubes (CNTs), due to their excellent physical, chemical and mechanical properties and their ability to prepare new membranes with attractive properties, have found applications in water and wastewater technology. CNT functionalization, which involves the introduction of different types of functional groups into pure CNTs, improves the capabilities of CNT membranes for water and wastewater treatment. It turns out that CNT-based membranes have many advantages, including enhanced water permeability, high selectivity and anti-fouling properties. However, their full-scale application is still limited by their high cost. With their tremendous separation efficiency, low biofouling potential and ultra-high water flux, CNT membranes have the potential to be a leading technology in water treatment in the future, especially in desalination.

Effect of substrate pretreatment on the growth yield enhancement and growth temperature decrease of carbon nanotubes (탄소나노튜브의 합성수율 증대와 저온 합성에 미치는 기판 전처리의 영향)

  • Shin, Eui-Chul;Jo, Sung-Il;Jeong, Goo-Hwan
    • Journal of Industrial Technology
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    • v.39 no.1
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    • pp.7-14
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    • 2019
  • Carbon nanotubes (CNT) on metal substrates are definitely beneficial because they can maintain robust mechanical stability and high conductivity between CNT and metal interfaces. Here, we report direct growth of CNT on Ni-based superalloy, Inconel 600, using thermal chemical vapor deposition (CVD) with acetylene feedstock in the growth temperature range of $400-725^{\circ}C$. Furthermore, we studied the effect of substrate pretreatment on the growth yield enhancement and growth temperature decrease of CNT on Inconel 600. Activation energy (AE) for CNT growth was estimated from the CNT height change with respect to the growth temperature. The AE values significantly decreased from 205.03 to 24.35 kJ/mol by the pretreatment of thermal oxidation of Inconel substrate at $725^{\circ}C$ under ambient. Higher oxidation temperature tends to have lower activation energy. The results have shown the importance of pretreatment temperature on CNT growth yield and growth temperature decrease.

Selective Growth of Freestanding Carbon Nanotubes Using Plasma-Enhanced Chemical Vapor Deposition (플라즈마 기상 화학 증착법을 이용한 탄소나노튜브의 선택적 수직성장 기술)

  • Bang, Yun-Young;Chang, Won-Seok
    • Journal of the Korean Society for Precision Engineering
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    • v.24 no.6
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    • pp.113-120
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    • 2007
  • Chemical vapor deposition (CVD) is one of the various synthesis methods that have been employed for carbon nanotube (CNT) growth. In particular, Ren et al reported that large areas of vertically aligned multi-wall carbon nanotubes could be grown using a direct current (dc) PECVD system. The synthesis of CNT requires a metal catalyst layer, etchant gas, and a carbon source. In this work, the substrates consists of Si wafers with Ni-deposited film. Ammonia $NH_3$) and acetylene ($C_2H_2$) were used as the etchant gases and carbon source, respectively. Pretreated conditions had an influence on vertical growth and density of CNTs. And patterned growth of CNTs could be achieved by lithographical defining the Ni catalyst prior to growth. The length of single CNT was increased as niclel dot size increased, but the growth rate was reduced when nickel dot size was more than 200 nm due to the synthesis of several CNTs on single Ni dot. The morphology of the carbon nanotubes by TEM showed that vertical CNTs were multi-wall and tip-type growth mode structure in which a Ni cap was at the end of the CNT.

NO Gas Sensing Characteristics of Single-Walled Carbon Nanotubes and Heating Effect (단층 탄소나노튜브의 일산화질소 가스에 대한 감응특성과 열처리 효과)

  • Kim, Min-Ju;Yun, Kwang-Hyun;Huh, Jeung-Soo
    • Journal of Sensor Science and Technology
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    • v.13 no.4
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    • pp.292-297
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    • 2004
  • Carbon nanotubes (CNT) were synthesized by arc-discharge method. To fabricate CNT sensor, CNT powder was dispersed in ${\alpha}$-Terpinol($C_{10}H_{17}OH$) solution. The CNT tilms were fabricated by screen printing method on the interdigitated Pt/Pd alloy electrode. The microstructure of CNT film was observed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). In order to investigate the gas sensing characteristics of the film, the CNT film was experimented to measure NO response and recovery time. The CNT sensor with a heater was compared to that without a heater. And this sensor shows better reproductibility and faster recovery time than another CNT sensors. We suggest the possibility to utilize a CNT as new sensing materials for environmental monitoring.

NH3 Gas Sensing Characteristics of Single-Walled Carbon Nanotubes and Heating Effect (단층 탄소나노튜브의 암모니아 가스에 대한 감응특성과 열처리 효과)

  • Huh J. S;Lee S. T;Kim M. J;Yun K. H
    • Korean Journal of Materials Research
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    • v.14 no.4
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    • pp.276-280
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    • 2004
  • Carbon nanotubes(CNT) were synthesized by arc-discharge method. To fabricate CNT sensor, CNT powder was dispersed in $\alpha$-Terpinol($C_{10}$ $H_{17}$OH) solution. The CNT films were fabricated by screen printing on the interdigitated Pt/Pd alloy electrode. The microstructure of CNT film were observed by scanning electron microscopy (SEM). In order to investigate the gas sensing characteristics of the film, the CNT film was experimented to measure NH$_3$ response and recovery time. And this sensor shows better reproductibility and faster recovery time than another CNT sensors. We suggest the possibility to utilize a CNT as new sensing materials for environmental monitoring.

Drag Reduction Induced by Increased Kinematic Viscosity of Nanofluids Containing Carbon Nanotubes in A Horizontal Tube (카본나노튜브 나노유체의 동점성계수 증가로 인한 관내 유동에서의 항력 감소)

  • Yu, Jiwon;Jung, Se Kwon;Choi, Mansoo
    • Particle and aerosol research
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    • v.9 no.4
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    • pp.271-277
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    • 2013
  • This article reports the drag reduction phenomenon of aqueous suspensions containing carbon nanotubes (CNTs) flowing through horizontal tubes. Stable nanofluids were prepared by using a surfactant. It is found that the drag forces of CNT nanofluids were reduced at specific flow conditions compared to the base fluid. It is found that the friction factor of CNT nanofluids was reduced up to approximately 30 % by using CNT nanofluids. Increased kinematic viscosities of CNT nanofluids are suggested to the key factors that cause the drag reduction phenomenon. In addition, transition from laminar to turbulent flow is observed to be delayed when CNT nanofluids flow in a horizontal tube, meaning that drag reduction occurs at higher flow rates, that is, at higher Reynolds numbers.

Hydrogen Bonding-Driven Assembling of Thin Multiwalled Carbon Nanotubes (수소결합에 의한 얇은 다중벽 탄소나노튜브의 자기조립)

  • Han, Joong-Tark;Kim, Sun-Young;Woo, Jong-Seok;Lee, Gun-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.426-427
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    • 2007
  • Here we describe the formation of a self-assembled film of thin multiwalled carbon Nanotubes(t-MWNT) modified with hydroxy groups through hydrogen peroxide treatment. Morphologies of t-MWNT films could be controlled by the various coating method, such as filtering, drop casting, spraying method, etc. The results show that on densification of the CNT suspension during drying, multiple hydroxy group-modified MWNTs can be self-assembled through strong surface hydrogen bond interaction while MWNTs usually exist an entangled state in the film. The interaction between t-MWNT was illustrated from Raman spectrum of spray coated films.

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Generation of high field emission current from carbon nanotubes

  • Lim, Seong-Chu;Heong, Hee-Jin;Choi, Ha-Kyu;Song, Young-Il;Kim, Gil-Yong;Lee, Young-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1020-1022
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    • 2005
  • We have fabricated a high electron source from carbon nanotubes (CNTs) using hot-press method. Using hot-press method, we are able to control the tube density and the morphology of CNT films. We propose that the high emission current is due to the solid adhesion between the CNTs and substrates and uniform morphology of CNT film.

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