• Journal of Electrochemical Science and Technology
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• v.3 no.3
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• pp.143-148
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• 2012

The unique effects of highly conductive conducting polymer/SWNT (single walled carbon nanotube) composite nanoparticles in electric double layer capacitors are studied for the enhancement of the adhesive properties, specific capacitance and power characteristics of the electrode. Because the conducting polymer/SWNT composite material, which is believed to act as a polymer binder, an active material for charge storage and a conducting agent, is well distributed on the activated carbon, greatly enhanced adhesion properties, cell capacitance and power characteristics were obtained.

• Transactions on Electrical and Electronic Materials
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• v.14 no.3
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• pp.125-129
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• 2013

Composites of platinum and multiwalled carbon nanotubes (MWNTs) were prepared in various reduction conditions and characterized using cyclic voltammetry. The MWNTs were functionalized with carboxylic acid and/or hydroxyl groups in acidic solutions prior to the formation of MWNT-Pt composites. Platinum nanoparticles were deposited onto the chemically-oxidized MWNTs in 1-propanol and 1,3-propanediol. The reduction of Pt precursors in other solutions could induce differences in their morphologies in composite thin films. The morphologies of MWNTs with Pt deposited were dependent on the reduction solutions, and the electrocatalytic activities on alcohols changed accordingly. The electrochemical activities of the as-prepared MWNT-Pt thin films on common alcohols such as methanol and ethanol were investigated.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.160-160
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• 2011

In this work, magnesium (Mg) nanoparticles were plated onto the surfaces of multi-walled carbon nanotubes (MWNTs) in order to investigate the effects of their presence on the high pressure hydrogen storage behaviors of the resultant Mg/MWNTs. The structure of Mg/MWNTs was characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The pore structure and total pore volumes of Mg/MWNTs were analyzed by $N_2$/77 K adsorption isotherms. The hydrogen storage behaviors of the Mg/MWNTs were investigated by BEL-HP at 298K and 100 bar. From the results, it was found that Mg particles were homogeneously distributed on the MWNT surfaces. The hydrogen storage capacity increased in proportion to the Mg content. It can be concluded that Mg paricles play an important role in hydrogen storage characteristics due to the hydrogen spillover effect.

• Bulletin of the Korean Chemical Society
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• v.31 no.1
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• pp.35-40
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• 2010

A comprehensive comparative investigation of small carbohydrates in laser desorption ionization was performed on supporting materials composed of sodiated 2,5-dihydroxybenzoic acid (DHB), carbon nanotubes, an ionic liquid matrix of DHB-pyridine, a binary matrix of DHB-aminopyrazine, zinc oxide nanoparticles, and gold nanoparticles. The abundance of $[M+Na]^+$ ions, where M is glucose or sucrose, was compared for each supporting material. The highest sensitivity for both glucose and sucrose, with a detection limit of 3 pmol, was observed with carbon nanotubes. Both carbon nanotubes and the ionic liquid matrix exhibited the highest reproducibility.

• Bulletin of the Korean Chemical Society
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• v.29 no.4
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• pp.777-781
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• 2008

In this work, silver nanoparticles-containing polyacrylonitrile (PAN) solutions in N,N-dimethylformamide (DMF) were electrospun to be webs consisting of nanofibers. The inputted voltage and PAN content in the solution were fixed at 15 kV and 10 wt.% in DMF with 10 cm of tip-to-collector distance (TCD). The PAN/Ag nanofiber webs were stabilized by oxidation at 250 ${^{\circ}C}$ for 2 h in air and carbonized at 1000 ${^{\circ}C}$ for 2 h in $N_2$. The resultant diameter distribution and morphologies of the nanofibers were evaluated by scanning electron microscope analysis. The electrochemical behaviors of the nanofiber webs were also observed by cyclic voltammetry tests. It was found that the presence of silver nanoparticles in carbon nanofiber webs led to the increase of specific capacitance and the decrease of fiber diameters.

• 한국정보디스플레이학회:학술대회논문집
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• 2007.08a
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• pp.772-774
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• 2007

The improvement in the field emission parameters, luminescent uniformity, degradation rate and half life has been observed for the thin-multi wall carbon nanotube (t-MWCNT) composite, after incorporating the Zn nanoparticles. The Zn nanoparticles $(diameter\;{\sim}\;100\;{\pm}15\;nm)$ has been incorporated to synthesize the Zn-t-MWCNT composite.

• Journal of Radiopharmaceuticals and Molecular Probes
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• v.4 no.2
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• pp.115-120
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• 2018

In recent years, many researchers have attempted to make use of 2D nanoparticles as molecular imaging probes since extensive investigations proved that 2D nanoparticles in the body tends to accumulate certain lesions by enhanced permeability and retention (EPR) effect. For example, graphene and carbon nitride which have high surface area and modifiable properties showed good biocompatibility and targetability when it used as imaging probes. However, poor dispersibility in physiological mediums and its uncontrolled size limited its usage in bio-application. Therefore, oxidation process and mechanical exfoliation have been developed for overcoming these problems. In this paper, we highlight the several major methods to synthesize biocompatible 2D nanomaterials like graphene and carbon nitride especially for molecular imaging study including positron emission tomography (PET).

• Steel and Composite Structures
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• v.38 no.2
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• pp.177-187
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• 2021

The effect of nanoparticle volume fraction on the elastic properties of a polymer-based nanocomposite was experimentally investigated and the obtained results were compared with various existing theoretical models. The nanocomposite was consisted of high density polyethylene (HDPE) as polymeric matrix and 0, 0.5, 1 and 1.5 wt.% multi walled carbon nanotubes (MWCNTs) prepared using twin screw extruder and injection molding technique. Nanocomposite samples were molded in injection apparatus according to ASTM-D638 standard. Therefore, in addition to morphological investigations of the samples, tensile tests at ambient temperature were performed on each sample and stress-strain plots, elastic moduli, Poisson's ratios, and strain energies of volume units were extracted from primary strain test results. Tensile test results demonstrated that 1 wt.% nanoparticles presented the best reinforcement behavior in HDPE-MWCNT nanocomposites. Due to the agglomeration of nanoparticles at above 1 wt.%, Young's modulus, yielding stress, fracture stress, and fracture energy were decreased and Poisson's ratio and failure strain were increased.

• Journal of Electrochemical Science and Technology
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• v.6 no.4
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• pp.121-130
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• 2015

The micro emulsion method has been successfully used for preparing perovskite LaCoO₃ with uniform, fine-shaped nanoparticles showing high activity as electro catalysts in oxygen reduction reactions (ORRs). They are, therefore, promising candidates for the air-cathode in metal-air rechargeable batteries. Since the activity of a catalyst is highly dependent on its specific surface area, nanoparticles of the perovskite catalyst are desirable for catalyzing both oxygen reduction and evolution reactions. Herein, LaCoO₃ powder was also prepared by sol-gel method for comparison, with a broad particle distribution and high agglomeration. The electro catalytic properties of LaCoO₃ and LaCoO₃-carbon Super P mixture layers toward the ORR were studied comparatively using the rotating disk electrode technique in 0.1 M KOH electrolyte to elucidate the effect of carbon Super P. Koutecky-Levich theory was applied to acquire the overall electron transfer number (n) during the ORR, calculated to be ~3.74 for the LaCoO₃-Super P mixture, quite close to the theoretical value (4.0), and ~2.7 for carbon-free LaCoO₃. A synergistic effect toward the ORR is observed when carbon is present in the LaCoO₃ layer. Carbon is assumed to be more than an additive, enhancing the electronic conductivity of the oxide catalyst. It is suggested that ORRs, catalyzed by the LaCoO₃-Super P mixture, are dominated by a 2+2-electron transfer pathway to form the final, hydroxyl ion product.

• Korean Chemical Engineering Research
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• v.48 no.6
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• pp.673-678
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• 2010

In the present study, mixed carbon-supported platinum(Pt) nanoparticles were prepared by a chemical reduction method of Pt precursor solution on two types of carbon materials such as activated carbons(ACs) and graphite nanofibers(GNFs). Average crystalline sizes and loading levels of Pt metal particles could be controlled by changing a content of GNFs. The highest electroactivity for methanol oxidation was obtained by preparing the carbon supports having 15 wt% GNFs. Furthermore, with an increase of GNFs content from 0% to 15%, an electrical conductivity was changed from $10^{-4}S/cm$ to $10^{-1}S/cm$. By an introduction of 10 wt% GNFs additive, the electroactivity of platinum particles was enhanced, but was saturated in the case of 15 wt% GNFs contents. This was related with the fact that the electroactivity change was dependent on the electrical conductivity of mixed carbon supports and Pt particle deposition content or deposition morphology.