• Title/Summary/Keyword: carbon incorporation

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Synthesis and Lubricant Properties of Nitrogen doped Amorphous Carbon (a-C:N) Thin Films by Closed-field unbalanced Magnetron Sputtering Method (비대칭 마그네트론 스퍼터링법에 의한 비정질 질화탄소 박막의 합성 및 윤활 특성)

  • Park, Yong-Seob;Cho, Hyung-Jun;Choi, Won-Seok;Hong, Byung-You
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.8
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    • pp.701-705
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    • 2007
  • The incorporation of N in a-C film is able to improve the friction coefficient and the adhesion to various substrates. In this study, a-C:N films were deposited on Si and steel substrates by closed-field unbalanced magnetron (CFUBM) sputtering system in $Ar/N_2$ plasma. The lubricant characteristics was investigated for a-C:N deposited with total working pressure from 4 to 7 mTorr. We obtained high hardness up to 24GPa, friction coefficient lower than 0.1 and the smooth surface of having the extremely low roughness (0.16 nm). The physcial properties of a-C:N thin film are related to the increase of cross-linked $sp^2$ bonding clusters in the film. However, the decrease of hardness, elastic modulus and the increase of surface roughness, friction coefficient with the increase of $N_2$ partial pressrue might be due to the effect of energetic ions as a result of the increase of ion bombardment with the increase of ion density in the plasma.

Experimental Study on the Ductile Behavior of Reinforced Concrete Beams with Carbon Fiber Sheets (탄소섬유시트로 보강된 철근콘크리트 보의 연성거동에 관한 실험적 고찰)

  • Park, Hyun-Jung;Park, Sung-Soo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.5 no.3
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    • pp.181-189
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    • 2001
  • Recently, the need for strengthening reinforced concrete(R.C.) structure has been increased, particularly when there is an increase in load requirements, a change in use, a degradation problem, or design/construction defects. The use of composite materials for structural repair presents several advantages and has been investigated all over the world. It is well known that the incorporation of carbon fiber sheet(CFS) with concrete is one of the most effective ways to strengthen the R.C. structure. In this papers, experimentally investigated the ductile behavior of the R.C. beams strengthened with CFS, and provided the basic data for design of R.C. beams strengthened with CFS. Tests were carried out with 15 beams ($20cm{\times}30cm{\times}240cm$) reinforced with CFS, and with parameters including and the ratio of tensile reinforcement to that of balanced condition and number of CFS. The results show that strengthened and non-strengthened beams exhibit different ductile behovior. Non-strengthened beams showed increase of ductility as amount of the tensile reinforcement decreased. However, bearing capacity of the CFS-strengthened beams are dictated by the strength of the CFS layers that a very high ductility is indicated for the beams with large number of CFS.

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Recent advances of aromatic C-F bond borylation and its application to positron emission tomography

  • Song, Dalnim;Lee, Sanghee;Lee, Byung Chul;Kim, Sang Eun;Lee, Eunsung
    • Journal of Radiopharmaceuticals and Molecular Probes
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    • v.1 no.2
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    • pp.80-87
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    • 2015
  • Carbon-fluorine (C-F) bonds have been found ubiquitously in pharmaceuticals, radiopharmaceuticals, agrochemicals, and material science due to their unique properties such as thermal and oxidative stability and lipophilicity to improve bioavailability. For the past five years, there have been significant advances in F-18 fluorination of aromatic complex molecules combined with the development of late-stage fluorination reactions. More recently, direct incorporation of F-18 to fluorinated aromatic molecules via borylation of C-F bonds has been developed by Niwa and Hosoya. In this minireview, we will discuss the progress of C-F bondborylation of fluorinated arenes utilizing transition metal catalysts and the impact on the development of F-18 radiotracers for positron emission tomography (PET).

Energy Maestro and Development Status of the DNA-oriented Energy-ICT Technology for Carbon Neutrality (에너지 거장과 탄소 중립을 위한 DNA(데이터, 네트워크, 인공지능) 중심 에너지ICT 기술 개발 현황)

  • Park, W.K.;Ku, T.Y.;Lee, I.W.
    • Electronics and Telecommunications Trends
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    • v.36 no.1
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    • pp.109-119
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    • 2021
  • The Korean government recently announced a plan of the Carbon Neutral policy in addition to the Green New Deal of the Korean New Deal and the Renewable Energy 3020. The energy sector is entering the era of major transformation involving the expansion of decarbonization, decentralization, and digitalization. DNA-oriented ICT technology will be incorporated into the sector. Further, new energy industries and services are being realized via efficient and smart operation and by appropriately managing the energy-environment changes. Recently, ETRI presented a technology development map for 2035 comprising 12 new concepts in four major fields(personal, social, industrial and public) of national intelligence. This map includes the concept of "Energy Maestro" associated with the field of public intelligence for human sustainability. This paper briefly introduces this concept and ETRI's Energy-R&D status. Based on the domain knowledge and the experience acquired through the R&D, ETRI will lead to a new paradigm with respect to the creation of new energy services and industries via the incorporation of the new ICT technologies including AI and big-data into the energy sector.

Thermal buckling of rectangular sandwich plates with advanced hybrid SMA/CNT/graphite/epoxy composite face sheets

  • Saeed Kamarian;Jung-Il Song
    • Advances in nano research
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    • v.14 no.3
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    • pp.261-271
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    • 2023
  • The present study follows three main goals. First, an analytical solution with high accuracy is developed to assess the effects of embedding pre-strained shape memory alloy (SMA) wires on the critical buckling temperatures of rectangular sandwich plates made of soft core and graphite fiber/epoxy (GF/EP) face sheets based on piecewise low-order shear deformation theory (PLSDT) using Brinson's model. As the second goal, this study compares the effects of SMAs on the thermal buckling of sandwich plates with those of carbon nanotubes (CNTs). The glass transition temperature is considered as a limiting factor. For each material, the effective ranges of operating temperature and thickness ratio are determined for real situations. The results indicate that depending on the geometric parameters and thermal conditions, one of the SMAs and CNTs may outperform the other. The third purpose is to study the thermal buckling of sandwich plates with advanced hybrid SMA/CNT/GF/EP composite face sheets. It is shown that in some circumstances, the co-incorporation of SMAs and CNTs leads to an astonishing enhancement in the critical buckling temperatures of sandwich plates.

Suspension Polymerization with Hydrophobic Silica as a Stabilizer II. Preparation of Polystyrene Composite Particles Containing Carbon Black (소수성 실리카를 안정제로 하는 현탁중합 II. 카본블랙을 함유하는 폴리스티렌 복합체 입자의 합성)

  • Park, Moon-Soo
    • Polymer(Korea)
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    • v.30 no.6
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    • pp.505-511
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    • 2006
  • We tried to prepare polystyrene composite particles containing carbon black by suspension polymerization with water as a reaction medium. Hydrophobic silica was selected as a stabilizer and oil-soluble azobisisobutyronitrile (AIBN), as an initiator. All polymerization reactions were carried out at a fixed temperature of $75^{\circ}C$. Stabilizer concentration was varied from $0.17{\sim}3.33wt%$ compared to water, where particles with $7.96{\mu}m$ in average diameter were obtained at 1.57 wt% of stabilizer. Increase in divinylbenzene concentration, as a crosslinking agent, from $0.1{\sim}1.0 wt%$ compared to monomer exhibited a large increase in average particle diameter Incorporation of 1wt% of carbon black compared to monomer produced an increase in average diameter It is speculated that viscosity lower than that necessary to induce even dispersion of carbon black particles led to poor dispersion, and as a result, large particles. For a styrene mixture containing 3 wt% carton black compared to monomer, enhanced dispersion due to an increase in carbon black concentration reduced average particle diameters. For styrene mixtures containing 1 and 3 wt% carbon black compared to monomer, preparticles before polymerization and polymer composite particles after polymerization showed a similar tendency towards particle formation. When carbon black concentration compared to monomer was increased to 5 and 7 wt%, styrene mixtures exhibited a large increase in viscosity and thus better dispersion of carbon black particles, which led to a decrease in preparticle diameters. However, these particles experienced agglomeration in the polymerization process, and polystyrene composite particles increased in average diameter.

3-D Vibration analysis of FG-MWCNTs/Phenolic sandwich sectorial plates

  • Tahouneh, Vahid
    • Steel and Composite Structures
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    • v.26 no.5
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    • pp.649-662
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    • 2018
  • In this study, based on the three-dimensional theory of elasticity, free vibration characteristics of sandwich sectorial plates with multiwalled carbon nanotube-(MWCNT)-reinforced composite core are considered. Modified Halpin-Tsai equation is used to evaluate the Young's modulus of the MWCNT/epoxy composite samples by the incorporation of an orientation as well as an exponential shape factor in the equation. The exponential shape factor modifies the Halpin-Tsai equation from expressing a straight line to a nonlinear one in the MWCNTs wt% range considered. In this paper, free vibration of thick functionally graded sandwich annular sectorial plates with simply supported radial edges and different circular edge conditions including simply supported-clamped, clamped-clamped, and free-clamped is investigated. A semi-analytical approach composed of two-dimensional differential quadrature method and series solution are adopted to solve the equations of motion. The material properties change continuously through the core thickness of the plate, which can vary according to a power-law, exponentially, or any other formulations in this direction. This study serves as a benchmark for assessing the validity of numerical methods or two-dimensional theories used to analysis of laminated sectorial plates.

Modeling Fresh Produce Respiration and Designing Modified Atmosphere Package

  • Lee, Dong-Sun
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.13 no.3_4
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    • pp.113-120
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    • 2007
  • The method to characterize the fresh produce respiration was presented with possible application of modified atmosphere package design. Particularly the respiration model based on enzyme kinetics was introduced as function of oxygen and carbon dioxide concentrations. The method to estimate the equilibrated package atmosphere for any package conditions was presented by incorporation of $O_2$ and $CO_2$ permeabilities of the packaging film. Temperature dependences for fresh produce respiration and gas permeation were given by Arrhenius equation and then used to analyze the effect of temperature on the package atmosphere. An example analysis was presented for better understanding of the concept.

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Characteristics of Carbon and Aluminum Incorporation in AlGaAs by UHVCVD using Trimethylgallium, Trimethylalumnium, and Arsine (Trimethylgallium, Trimethylauminum과 Arsine을 사용하여 UHVCVD방법으로 성장된 AlGaAs의 탄소 및 알미늄의 유입 특성)

  • 노정래;심재기;하정숙;박성주;이일항
    • Journal of the Korean Vacuum Society
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    • v.2 no.1
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    • pp.34-40
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    • 1993
  • 새로운 단결정 박막 성장방법으로 최근에 많은 관심을 끌고 있는 초고진공 화학기상증착법(Ultra-High Vacuum Chemical Vapor Deposition)을 이용하여 AlGaAs에 에피탁시 박막을 성장시켰다. AlGaAs 에피탁시층의 성장은 2。 경사진 GaAs(100) 기판을 사용하였다. 반응 기체로는 Trimethylgallium(TMGa), Trimethylaluminum(TMAl)과 arsine을 사용하였고, 성장온도는 $580~700^{\circ}C$, 기체 압력은 10-5~10-4Torr를 유지하였다. 특히 본 연구에서는 arsine을 사전에 열분해 하는 통상의 Chemical Beam Epitaxy(CBE) 성장법과는 달리, arsine이 표면에서 분해되는 화학 반응만을 사용하여도 AlGaAs 에피탁시를 성장할 수 있음은 물론 박막내의 탄소 불순물의 농도가 크게 낮아짐을 관찰하였다. 또한 성장 온도의 변화에 따른 AlGaAs 에피탁시층의 Al 함유 과정에 대하여도 고찰하였다.

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Computational modelling for description of rubber-like materials with permanent deformation under cyclic loading

  • Guo, Z.Q.;Sluys, L.J.
    • Interaction and multiscale mechanics
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    • v.1 no.3
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    • pp.317-328
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    • 2008
  • When carbon-filled rubber specimens are subjected to cyclic loading, they do not return to their initial state after loading and subsequent unloading, but exhibit a residual strain or permanent deformation. We propose a specific form of the pseudo-elastic energy function to represent cyclic loading for incompressible, isotropic materials with stress softening and residual strain. The essence of the pseudo-elasticity theory is that material behaviour in the primary loading path is described by a common elastic strain energy function, and in unloading, reloading or secondary unloading paths by a different strain energy function. The switch between strain energy functions is controlled by the incorporation of a damage variable into the strain energy function. An extra term is added to describe the permanent deformation. The finite element implementation of the proposed model is presented in this paper. All parameters in the proposed model and elastic law can be easily estimated based on experimental data. The numerical analyses show that the results are in good agreement with experimental data.