• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2011.06a
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• pp.415-416
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• 2011

As the has been brought out in 1997, many ports pay attention to greenhouse gas emission reduction and try to develop the port as an Green Port. The purpose of this paper is to establish the activities priority for Green Port construction and analysis its efficiency for the port competition. First of all, the activities for Green Port is introduced and showed its characteristics. To analysis these effectiveness for Green Port, the questionnaire survey is done by considering the opinion of port specialists. And by using AHP analysis method, the priority between the port activities is obtained and its effect for Green Port is taken by considering port competitiveness.

• Korean Chemical Engineering Research
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• v.56 no.5
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• pp.752-760
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• 2018

The lowering of temperature for combustion of diesel particulate matters (or diesel soot) is one of the important tasks in automotive industry that is searching for a way to meet up "high-fuel efficiency, low-emission" standard. In this study, it was discussed how the use of ozone over platinum-based catalyst promotes a low-temperature soot oxidation occurred at $150^{\circ}C$. The use of platinum catalyst did not increase oxidation rate largely but was very effective in improving the selectivity of carbon dioxide. The pre-oxidation of NO into $NO_2$ using ozone was rather crucial in improving the oxidation rate of soot at $150^{\circ}C$.

• Journal of Climate Change Research
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• v.9 no.2
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• pp.197-207
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• 2018

The Korean government views coal-fired power plants as the key cause of the fine dust generation, and is developing an energy policy to replace and demolish old coal-fired power plants. According to the Eighth Power Supply Base Plan (2017-2031), the maximum power capacity in 2030 is expected to be 100.5GW, which is 17.9% higher than the current level (85.2GW). The plan aims to reduce the facility size and power generation ratio from nuclear and coal resources to even lower levels than today, and to rapidly expand power generation from new and renewable energy. Despite that, the proportion of coal power generation is still much higher than other resources, and it is expected that the reliance on goal will maintain for next several decades. Under such circumstances, the development, supply, and expansion of clean coal technology (CCT) that is eco-friendly and highly efficient, is crucial to minimize the emission of pollutants such as carbon dioxide and fine dust, as well as maximize the energy efficiency. The Korean government designated the Yong-Dong Thermoelectric Power Plant in Gangneung to develop clean coal power generation, and executed related projects for three years. The current study aims to suggest a plan to develop parts, technologies, testing, evaluation, certification, and commercialization efforts for coal-fired power generation, In addition, the study proposes a strategy to vitalize local economy and connect the development with creation of more jobs.

• Journal of Korea Trade
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• v.24 no.6
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• pp.37-60
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• 2020

Purpose - The purpose of this study is to investigate the direct and indirect impact of innovation space factors on the growth of semiconductor enterprises. Design/methodology - This empirical study uses the financial statements of 83 semiconductor listed companies in 23 provinces from 2004 to 2019 approved by CSRC (2019). A stepwise regression and backward regression are employed in order to examine the role of innovation space to expand technology investment in promoting business growth and uses South Korean Samsung's investment in China as a test case. Findings - Results indicate that innovation space, technology input, geographical area, owner's background, operating years and financing liabilities all contribute to a boost in business growth. Factors such as carbon emission, financial liberalization, government efficiency, technology input, and financing liabilities further influence management growth. Innovation space follows a nonlinear pattern, and this plays a positive role in magnifying the influence of technology on management growth. Additionally, operations of the state-owned companies and expansionary financing enterprises are influenced by the external economy. Regarding the spatial distribution, the Samsung investment in 24 companies in China shows that Samsung focuses on the acquisition of scarce resources for semiconductor production as a component of its investment and innovation strategy. Originality/value - Even though prior research has considered the concepts studied here, this study contributes to empirically evaluate the direct impact of innovation space on business growth, and the indirect impact of innovation space on business growth through technology investment. This study includes an in-depth discussion of the practical effects that innovation space has on China's economy, using a case of South Korean Samsung's investment in China as a test the empirical findings.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2021.11a
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• pp.201-202
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• 2021

Regulations on greenhouse gases emitted from ships in international shipping are being strengthened, and the greenhouse gas reduction target established by the International Maritime Organization is acting as a great challenge for shipping companies in terms of technical and operational aspects. The International Maritime Organization aims to reduce carbon intensity by 30% by 2030, 70% by 2050, and by 50% in terms of gross emissions compared to 2008. To realize this situation, the IMO adopted some short-term and mid-to-long-term measures and adopted technical measures such as the application of EEXI, an energy efficiency index, to existing ships from 2023, and the early application of EEDI phase 3 for some tpe of ships. In addition, reduction measures were introduced to reduce greenhouse gas in the operational aspect.

• Journal of Surface Science and Engineering
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• v.56 no.6
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• pp.437-442
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• 2023

This research aims to enhance the efficiency of Pt/C catalysts due to the limited availability and high cost of platinum in contemporary fuel cell catalysts. Nano-sized platinum particles were distributed onto a carbon-based support via the polyol process, utilizing the metal precursor H₂PtCl₆·6H₂O. Key parameters such as pH, temperature, and RPM were carefully regulated. The findings revealed variations in the particle size, distribution, and dispersion of nano-sized Pt particles, influenced by temperature and pH. Following sodium hydroxide treatment, heat treatment procedures were systematically executed at diverse temperatures, specifically 120, 140, and 160 ℃. Notably, the thermal treatment at 140 ℃ facilitated the production of Pt/C catalysts characterized by the smallest platinum particle size, measuring at 1.49 nm. Comparative evaluations between the commercially available Pt/C catalysts and those synthesized in this study were meticulously conducted through cyclic voltammetry, X-ray diffraction (XRD), and field-emission scanning electron microscopy-energy dispersive X-ray spectroscopy (FE-SEM EDS) methodologies. The catalyst synthesized at 160 ℃ demonstrated superior electrochemical performance; however, it is imperative to underscore the necessity for further optimization studies to refine its efficacy.

• Korean Chemical Engineering Research
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• v.61 no.3
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• pp.378-387
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• 2023

Petrochemical is an energy consuming industry that consumes about 30% of total industrial energy consumption and is a representative carbon dioxide (CO₂) emission source. Among them, the Naphtha Cracking Center (NCC), which produces ethylene, propylene, propane and mixed C4, consumes large amounts of energy and emits significant amounts of CO₂. For this reason, an integrated techno economic- environmental impact assessment aimed at reducing energy consumption and environmental impact factors is necessary to ensure efficiency in terms of economics and environment. This study aims to analyze the efficiency of the heat exchanger network used in the existing NCC base on the pinch analysis and select an improvement plan that can reduced energy consumption. In order to reduces the utility consumption in the process, an optimal heat exchanger network considering the high-temperature and low-temperature stream was derived, and the economic evaluation was conducted by considering the trade-off between the reduction in utility consumption and the increase in heat exchanger installation cost. In addition, an environmental impact assessment was conducted on the reduced CO₂ emission in consideration of the environmental aspect, and the economic environmental impact assessment used the payback period to recover the invested funds to come up with an energy saving plan that can be applied based on the actual process. As a result of considering the economic-environmental impact assessment, when the environmental impact assessment was not considered, it was 4.29 months, 3.21 months, and 3.39 months for each case, and when considering the environmental impact assessment, it was 4.24 months, 3.17 months, and 3.35 months for each case. These results appeared equally both when the environmental impact assessment was not include and when it was include. In addition, a sensitivity analysis was conducted for each case to determine how important factors affect the payback period. As a result of the sensitivity analysis, the cost of the heat exchanger was identified as a major factor influencing the overall cost.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.12
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• pp.840-846
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• 2012

Global climate changes caused by $CO_2$ emissions are currently debated around the world; green sources of energy are being sought as alternatives to replace fossil fuels. The sustainable use of biogas for energy production does not contribute to $CO_2$ emission and has therefore a high potential to reduce them. Catalytic steam reforming of a model biogas ($CH_4:CO_2$ = 60%:40%) is investigated to produce $H_2$-rich synthesis gas. The biogas utilized 3D-IR matrix burner in which the surface combustion is applied. The ruthenium catalyst was used inside a reformer. Parametric screening studies were achieved as Steam/Carbon ratio, biogas component ratio, Space velocity and Reformer temperature. When the condition of Steam/Carbon ratio, $CH_4/CO_2$ ratio, Space velocity and Refomer temperature were 3.25, 60% : 40%, $14.7L/g{\cdot}hr$ and $550^{\circ}C$ respectively, the hydrogen concentration and methane conversion rate were showed maximum values. Under the condition mentioned above, $H_2$ yield, $H_2$/CO ratio, CO selectivity and energy efficiency were 0.65, 2.14, 0.59, 51.29%.

• Asian-Australasian Journal of Animal Sciences
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• v.24 no.2
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• pp.285-294
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• 2011

The abatement of methane emission from ruminants is an important global issue due to its contribution to greenhouse gas with carbon dioxide. Methane is generated in the rumen by methanogens (archaea) that utilize metabolic hydrogen ($H_2$) to reduce carbon dioxide, and is a significant electron sink in the rumen ecosystem. Therefore, the competition for hydrogen used for methanogenesis with alternative reductions of rumen microbes should be an effective option to reduce rumen methanogenesis. Some methanogens parasitically survive on the surface of ciliate protozoa, so that defaunation or decrease in protozoa number might contribute to abate methanogenesis. The most important issue for mitigation of rumen methanogenesis with manipulators is to secure safety for animals and their products and the environment. In this respect, prophylactic effects of probiotics, prebiotics and miscellaneous compounds to mitigate rumen methanogenesis have been developed instead of antibiotics, ionophores such as monensin, and lasalocid in Japan. Nitrate suppresses rumen methanogenesis by its reducing reaction in the rumen. However, excess intake of nitrate causes intoxication due to nitrite accumulation, which induces methemoglobinemia. The nitrite accumulation is attributed to a relatively higher rate of nitrate reduction to nitrite than nitrite to ammonia via nitroxyl and hydroxylamine. The in vitro and in vivo trials have been conducted to clarify the prophylactic effects of L-cysteine, some strains of lactic acid bacteria and yeast and/or ${\beta}$1-4 galactooligosaccharide on nitrate-nitrite intoxication and methanogenesis. The administration of nitrate with ${\beta}$1-4 galacto-oligosaccharide, Candida kefyr, and Lactococcus lactis subsp. lactis were suggested to possibly control rumen methanogenesis and prevent nitrite formation in the rumen. For prebiotics, nisin which is a bacteriocin produced by Lactococcus lactis subsp. lactis has been demonstrated to abate rumen methanogenesis in the same manner as monensin. A protein resistant anti-microbe (PRA) has been isolated from Lactobacillus plantarum as a manipulator to mitigate rumen methanogenesis. Recently, hydrogen peroxide was identified as a part of the manipulating effect of PRA on rumen methanogenesis. The suppressing effects of secondary metabolites from plants such as saponin and tannin on rumen methanogenesis have been examined. Especially, yucca schidigera extract, sarsaponin (steroidal glycosides), can suppress rumen methanogenesis thereby improving protein utilization efficiency. The cashew nutshell liquid (CNSL), or cashew shell oil, which is a natural resin found in the honeycomb structure of the cashew nutshell has been found to mitigate rumen methanogenesis. In an attempt to seek manipulators in the section on methane belching from ruminants, the arrangement of an inventory of mitigation technologies available for the Clean Development Mechanism (CDM) and Joint Implementation (JI) in the Kyoto mechanism has been advancing to target ruminant livestock in Asian and Pacific regions.

• Clean Technology
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• v.20 no.2
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• pp.103-107
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• 2014

Acrylic acid is a commodity chemical which is applicable for various industries such as polymer and textile industry. Currently, it has been produced by chemical synthesis from petroleum. However, due to the high price of petroleum and global $CO_2$ emission, renewable materials such as sugar are interesting alternative carbon sources for the biological production of acrylic acid. For an economic production of acrylic acid from renewable carbon sources, a cost effective separation process for acrylic acid should be needed. In this study, reactive extraction by TOA (tri-n-octylamine) was used for the recovery of acrylic acid from its aqueous solutions. The effects of polarity of diluents and concentration of TOA on extraction equilibrium were investigated. The extraction efficiency was proportional to concentration of TOA and polarity of diluents and its value was more than 95% in the case of sufficient concentration of TOA. From IR spectroscopy, it was concluded that the ratio of (1,1) acid-amine complex was increased and the ratio of acid dimer was decreased with concentration of TOA. Equilibrium model based on IR spectroscopy was well fitted with experimental data.