• Asian Journal of Atmospheric Environment
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• v.4 no.2
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• pp.63-71
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• 2010

The removal characteristics for aromatic and aliphatic VOCs by electron beam (EB) were discussed in terms of several removal variables such as initial VOC concentration, absorbed dose, background gas, moisture content, reactor material and inlet temperature. It was reviewed that only reactor material was an independent variable among the potential control factors concerned. It was also suggested that main mechanism by EB should be radical reaction for the VOC removal rather than that by primary electrons. It was discussed that the removal efficiency of benzene was lower than that of hexane due to a closed benzene ring. In the case of aromatic VOCs, it was observed that the decomposition of the VOCs with more functional groups attached on the benzene ring was much easier than those with less ones. As for aliphatic VOCs, it was also implied that the longer carbon chain was, the higher the removal efficiency became. An EB-catalyst hybrid system was discussed as an alternative way to remove VOCs more effectively than EB-only system due to much less by-products. This hybrid included supporting materials such as cordierite, Y-zeolite, and $\gamma$-alumina.

• Journal of Environmental Policy
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• v.12 no.2
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• pp.33-57
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• 2013

This paper test the relationship among determinants of environmental investments, level of environmental investments, eco-efficiency (carbon productivity). The results show that profitability, leverage and R&D costs have a negative impact on environmental investments, and controlling ownership have a positive impact on environmental investments as well as environmental protection costs. The analysis also show that firms increasing environmental investments are able to gain superior environmental performance ($CO_2$ emission), but are negatively relationship with financial performance. Finally, the findings prove that differences exist in the relationship between determinants and effect of environmental investments when grouped by industry characteristics.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.2940-2945
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• 2008

The scale of 2.4 MW MCFC was taken to construct a high-efficiency and economical power generation system without CO2 emission into the atmosphere for utilizing its exhaust gas. The conventional steam turbine power generation system (STGS) was evaluated and the net generated power (NGP) was estimated to be only 133 kW and the STGS is not economically feasible. A CO2-caputuring repowering system was proposed, where low temperature steam (LTS) produced at HRSG by using exhaust gas from MCFC is utilized as a main working fluid of a gas turbine, and the temperature of LTS was raised by combusting fuel in a combustor by using pure oxygen, not the air. It has been shown that NGP of the proposed system is 264 kW, and CO2 reduction amount is 608 t-CO2/y, compared to 306 t-CO2/y of STGS. The CO2 reduction cost was estimated to be negligible small, even when the costs of oxygen production and CO2 liquefaction facilities etc. were taken into account.

• Environmental and Resource Economics Review
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• v.23 no.3
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• pp.453-472
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• 2014

Analyzing the effects of carbon emissions trading, which is scheduled to be introduced in Korea in 2015, requires an accurate assessment of $CO_2$ abatement costs by both industries and firms. Firms faced with regulatory constraints are unlikely to minimize their production costs due to rising production costs caused by allocative inefficiency of inputs. The use of a distance function would results in underestimation of $CO_2$ abatement costs, because it fails to capture the allocative distortion costs. Recognizing the disadvantage of the previous approach, first, this paper tests for allocative efficiency of input for the Korean steel industry over the period 1990-2010, then derives the marginal $CO_2$ abatement costs by applying a cost function approach. The hypothesis of allocative efficiency in inputs is rejected and the steel industry pays an annual average cost of 92,000 won in removing an additional ton of $CO_2$ over the sample period.

• Journal of Environmental Science International
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• v.21 no.11
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• pp.1321-1331
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• 2012

To date, carbon and nitrogen co-doped photocatalysts (CN-$TiO_2$) for environmental application focused mainly on the aqueous phase to investigate the decomposition of water pollutants. Accordingly, the present study explored the photocatalytic performance of CN-$TiO_2$ photocatalysts for the purification of indoor-level gas-phase aromatic species under different operational conditions. The characteristics of prepared photocatalysts were investigated using X-ray diffraction, scanning emission microscope, diffuse reflectance UV-VIS-NIR analysis, and Fourier transform infrared (FTIR) analysis. In most cases, the decomposition efficiency for the target compounds exhibited a decreasing trend as input concentration (IC) increased. Specifically, the average decomposition efficiencies for benzene, toluene, ethyl benzene, and xylene (BTEX) over a 3-h process decreased from 29% to close to zero, 80 to 5%, 95 to 19%, and 99 to 32%, respectively, as the IC increased from 0.1 to 2.0 ppm. The decomposition efficiencies obtained from the CN-$TiO_2$ photocatalytic system were higher than those of the $TiO_2$ system. As relative humidity (RH) increased from 20 to 95%, the decomposition efficiencies for BTEX decreased from 39 to 5%, 97 to 59%, 100 to 87%, and 100 to 92%, respectively. In addition, as the stream flow rates (SFRs) decreased from 3.0 to 1.0 L $min^{-1}$, the average efficiencies for BTEX increased from 0 to 58%, 63 to 100%, 69 to 100%, and 68 to 100%, respectively. Taken together, these findings suggest that three (IC, RH, and SFR) should be considered for better BTEX decomposition efficiencies when applying CN-$TiO_2$ photocatalytic technology to purification of indoor air BTEX.

• KIEAE Journal
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• v.13 no.4
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• pp.11-19
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• 2013

The purpose of this study is to establish the assessment baseline of $CO_2$ emissions from building operations in the view of GHG reduction policy in Korea. The assessment baseline of $CO_2$ emissions shall be used in GHG policy and Carbon Credits in building sectors, but the assessment baseline has not been studied enough or established yet. Also, $CO_2$ emissions from building operations will be variable according to the building occupancy. Therefore the baseline will be different and this study aimed at the establishment of the assessment baseline for residential apartments and office buildings firstly. After reviews of BEER and international standards for building $CO_2$ emissions such as ISO and UNEP-SBCI documents, the analysis of BEER certification data has been pursued for 292 residential apartment complexes and 65 office buildings in South Korea during 2004~2012. As analysis results, the assessment baseline was set to 23.03 $kg{\cdot}CO_2/m^2{\cdot}yr$ or 1.95 $t{\cdot}CO_2/unit{\cdot}yr$ for residential apartment complexes, and 95.91 $kg{\cdot}CO_2/m^2{\cdot}yr$ for office buildings according to the BEER certification basis. Additional assessment baselines were calculated according to year basis, region basis, public and private basis, and GHG policy basis. Finally, the established baseline for residential apartment complexes has been applied for the pilot project in M district, Seoul, and showed 24.97% reduction rate according to the BEER certification basis.

• Korean Chemical Engineering Research
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• v.55 no.4
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• pp.548-555
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• 2017

This study investigated the influence of air staging on combustion and NOx emission in a tangential-firing boiler at a 560 MWe capacity. For air staging, the stoichiometric ratio (SR) for the burner zone was varied from 0.995 to 0.94 while the overall value was fixed at 1.2. The temperature and heat flux in the burner zone and upper furnace corresponded to the distribution of SR, while the total boiler efficiency remained similar. The NOx emission at the furnace exit was reduced by up to 20% when the SR in the burner zone decreased to 0.94. However, the amount of unburned carbon and slagging propensity was not noticeably influenced by the changes in the SR of the burner zone. Therefore, it was favorable to lower the SR of the burner zone for reduction of NOx emission.

• Journal of Energy Engineering
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• v.24 no.4
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• pp.24-32
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• 2015

National and international regulations on the exhaust gases of diesel engines are being strengthened, and a study of the combutsion engine and the post-porcessing system are in progress as a variety of ways. There are many techniques for the removal of nitrogen oxide like HC-SCR, LNT, Urea-SCR. And the technical development on the Urea-SCR owing to high conversion efficiency and fuel economy characteristics has being processed. This study investigated the physical/chemical properties of urea according to the change of the urea content, and were analysed the characteristic of exhaust gas. According to the increase of urea content, the contests of biuret aldehyde, phosphate content was increased and the changes of emission quantity of carbon monoxide, hydrocarbons and particulate matter in the exhaust gas was very slight. The emission quantity of NOx was decreased in accordance with increasing the urea content and it was shown to be more than 80 % in the urea solution having more than 30 wt%.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.36 no.6B
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• pp.642-649
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• 2011

In this paper, we present the analysis of the characteristics of advanced mobile communication base station with multi-band about power loss, power efficiency and carbon reduction considering cable power loss. The advanced mobile base station system is installed on the outdoor for Antenna and RF part, and then the power loss is reduced because the fiber optic cable is used between RF part and baseband part. If the cable power loss is reduced by 5 dB replacing an entire the advanced base station systems, annual power consumption is reduced total 49,038 MWh in the CDMA 20W, WCDMA 30W, WiBro 10W systems. Furthermore the advanced base station system of annual $CO_2$ emission is 20,832 $tCO_2$ compare to 65,878 $tCO_2$. Therefore the advanced base system is confirmed considering green IT technology for the advanced mobile communication base station.

• Journal of Powder Materials
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• v.23 no.2
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• pp.95-101
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• 2016

Carbon nanofiber (CNF) composites coated with spindle-shaped $Fe_2O_3$ nanoparticles (NPs) are fabricated by a combination of an electrospinning method and a hydrothermal method, and their morphological, structural, and chemical properties are measured by field-emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. For comparison, CNFs and spindle-shaped $Fe_2O_3$ NPs are prepared by either an electrospinning method or a hydrothermal method, respectively. Dye-sensitized solar cells (DSSCs) fabricated with the composites exhibit enhanced open circuit voltage (0.70 V), short-circuit current density ($12.82mA/cm^2$), fill factor (61.30%), and power conversion efficiency (5.52%) compared to those of the CNFs (0.66 V, $11.61mA/cm^2$, 51.96%, and 3.97%) and spindle-shaped $Fe_2O_3$ NPs (0.67 V, $11.45mA/cm^2$, 50.17%, and 3.86%). This performance improvement can be attributed to a synergistic effect of a superb catalytic reaction of spindle-shaped $Fe_2O_3$ NPs and efficient charge transfer relative to the one-dimensional nanostructure of the CNFs. Therefore, spindle-shaped $Fe_2O_3$-NP-coated CNF composites may be proposed as a potential alternative material for low-cost counter electrodes in DSSCs.