• Title/Summary/Keyword: carbon dioxide method

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Extraction of Active Compounds from Angelica gigas using Supercritical Carbon Dioxide and its Physiological Activity (초임계 이산화탄소를 이용한 참당귀 유효 성분의 추출 및 생리활성 효능)

  • Park, Su In;Heo, Soo Hyeon;Lee, Jinseo;Shin, Moon Sam
    • Journal of Convergence for Information Technology
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    • v.11 no.6
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    • pp.206-212
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    • 2021
  • This study aimed to maximize the efficacy of Angelica gigas by finding a more effective way to extract active compounds from Angelica gigas. After extracting Angelica gigas by hydrothermal, ethanol, and supercritical carbon dioxide extraction methods, analysis of decursin and decursinol angelate content, quantification of total polyphenol content, and evaluation of efficacy of antioxidant, whitening, and antibacterial were conducted. The content of decursin and decursinol angelate was very high at 38.65% of the supercritical carbon dioxide extract, and the total polyphenol content was high in the order of hydrothermal extract, ethanol extract and supercritical carbon dioxide extract, but the difference was relatively small. The antioxidant effects were consistent with the total polyphenol content, and the antibacterial effects were consistent with the decursin and decursinol angelate content. In other words, through this study, we found that the optimal method for extracting active compounds from Angelica gigas is the supercritical carbon dioxide extraction method.

PREPARATION OF CARBON DIOXIDE ABSORPTION MAP USING KOMPSAT-2 IMAGERY

  • Kim, So-Ra;Lee, Woo-Kyun
    • Proceedings of the KSRS Conference
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    • 2008.10a
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    • pp.200-203
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    • 2008
  • The objective of this study is to produce the $CO_2$ (carbon dioxide) absorption map using KOMPSAT-2 imagery. For estimating the amount of $CO_2$ absorption, the stand biomass of forest was estimated with the total weight, which was the sum of individual tree weight. Individual tree volumes could be estimated by the crown width extracted from KOMPSAT-2 imagery. In particular, the carbon conversion index and the ratio of the $CO_2$ molecular weight to the C atomic weight, reported in the IPCC (Intergovernmental Panel on Climate Change) guideline, was used to convert the stand biomass into the amount of $CO_2$ absorption. Thereafter, the KOMPSAT-2 imagery was classified with the SBC (segment based classification) method in order to quantify $CO_2$ absorption by tree species. As a result, the map of $CO_2$ absorption was produced and the amount of $CO_2$ absorption was estimated by tree species.

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The Optimum of $CO_2$ Decomposition using Spinel Phase Magnetite (스피넬상 마그네타이트를 이용한 $CO_2$ 분해의 최적조건)

  • Ryu, Dae-Sun;Hong, Phil-Sun;Lee, Poong-Hun;Kim, Soon-Tae
    • Journal of the Korean Ceramic Society
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    • v.38 no.10
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    • pp.901-907
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    • 2001
  • Magnetite was synthesized using $0.2M-FeSO_4{\cdot}7H_{2}O$ and 0.5 M-NaOH by air oxidation method for carbon dioxide decomposition to carbon. The carbon dioxide decomposition was successfully carried out after reduction of ${Fe_3}{O_4}$ for 2 hrs using hydrogen gas. The carbon dioxide decomposition at 325, 350, 375, 400, $425^{\circ}C$, 88% was the highest at $350^{\circ}C$ and the activation energy of ${Fe_3}{O_4}$ in carbon dioxide decomposition was 30.96 kJ/mol. After $CO_2$ decomposition, the carbon of surface of catalyst reacted with hydrogen produced methane.

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Applicability of DGCI (Dark Green Color Index) to Assess Potential Impacts of CO2 Leakage from the Geological Storage Site (이산화탄소 지중저장 시설의 잠재적 누출 판단을 위한 DGCI(Dark Green Color Index) 적용 가능성 평가)

  • Yoo, Sin Yee;Song, Yoon Jin;Oh, Hee Joo;Kim, You Jin;Yoo, Ga Young
    • Journal of Climate Change Research
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    • v.7 no.3
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    • pp.351-356
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    • 2016
  • The carbon capture and storage (CCS), which collects and stores carbon dioxide in a geological site, is a promising option to mitigate climate change. However, there is the possibility of carbon dioxide leakage from the soil in the steps of collecting, transporting, and storing. To ensure the feasibility of this technology, it is important to monitor the leakage of carbon dioxide and to assess the potential impacts. As plants are sensitive to the changes in carbon dioxide in the soil environment, we can utilize plant parameter to detect the carbon dioxide leakage. Currently, chlorophyll a content is a conventional index indicating the changes in plants, however, this method is labor intensive and it only utilizes a small portion of leaves. To overcome its limitations, a simple spectroscopic parameter, DGCI (dark green color index), was suggested as an easy and quick indicator. In this study, we compared the values of chlorophyll a contents with DGCI from the experiment investigating the impacts of high underground $CO_2$ on grape plants. Results suggest that DGCI had high correlation with chlorophyll a contents and it has high potential to be utilized as an easy indicator to monitor plants' responses to $CO_2$ treatment.

Characteristics of CO2 Conversion Using Cobalt Ferrite Powders (코발트계 페라이트 분말을 이용한 이산화탄소 전환특성)

  • Park, Sungyoul
    • Korean Chemical Engineering Research
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    • v.50 no.6
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    • pp.1008-1014
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    • 2012
  • The amount of domestic carbon dioxide emissions is more than 600 million tons/year. The emitted $CO_2$ should be captured and stored, however, suitable storage sites have not been found yet. A lot of researches on the conversion of captured carbon dioxide to useful carbon source have been conducted. The purpose of this study is to convert stable carbon dioxide to useful resources using less energy. For this purpose reducing gas and metallic oxide (activator) are required. Hydrogen was used as reducing gas and cobalt ferrite was used as activator. Considering that activator has different physical properties depending on synthesis methods, activator was prepared by hydrothermal synthesis and solid method. Decomposition characteristics of carbon dioxide were investigated using synthesized powders. Temperature programmed reduction/oxidation (TPR/TPO) and thermogravimetric analyzer (TGA) device were used to observe the decomposition characteristics of carbon dioxide. Activator prepared by solid method with 5 and 10 wt% CoO content showed an excellent performance. In TGA experiments with samples prepared by the solid method, reduction by hydrogen was 29.0 wt% and oxidation by $CO_2$ was highest in 27.5 wt%. 95% of adsorbed $CO_2$ was decomposed with excellent oxidation-reduction behaviors.

Effect of High-Molecular Weight Organic Compounds on Improvement of Pore Structure of Cement Materials

  • Lee, Woong-Geol;Jeon, Se-Hoon;Song, Myong-Shin;Kim, Jusung
    • Journal of the Korean Ceramic Society
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    • v.56 no.6
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    • pp.534-540
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    • 2019
  • Carbon dioxide emissions involved in global warming are one of the most important issues in the world, and carbon dioxide emissions from the cement industry are about 7% of total carbon dioxide emissions. Thus, reduction in the amount of utilized cement can contribute to a reduction of carbon dioxide emissions. The average life of concrete is 20 ~ 30 years, and if concrete life can be improved by ten years, cement use will be much lower. In this study, we examined the use and effect of fructan from microbes as a method for the densification of the pore structure of cement. The effect of fructan on the hydration reaction and pore distribution, as well as the water absorption of hardened cement mortar were studied. Pores distribution increased in mesopore OPC, and absorption rate was found to decrease with the use of fructan, which has a glue-like and swelling character.

Separation of Protein and Fatty Acids from Tuna Viscera Using Supercritical Carbon Dioxide

  • Kang Kil-Yoon;Ahn Dong-Hyun;Jung Sun-Mi;Kim Dong-Hun;Chun Byung-Soo
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.10 no.4
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    • pp.315-321
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    • 2005
  • Supercritical carbon dioxide extraction was investigated as a method for removing lipids and bad flavor from tuna viscera. To find the optimum conditions, different experimental variables, such as pressure, temperature, flow rate of solvent and sample size, were evaluated for the effective removal of lipids and the undesirable smell. Ethanol was used as the entrainer, with a $3\%$ by vol $CO_2$ flow rate. By increasing the pressure at constant temperature, the efficiency of the lipid removal was improved and the protein was concentrated without denaturalization. The main fatty acids extracted from the tuna viscera were palmitic acid (16:0), heptadecanoic acid (17:1), oleic acid (18:1) and docosahexaenoic acid (22:6). The major amino acids in the tuna viscera treated by supercritical carbon dioxide were glutamic acid, leucine and lysine, and the free amino acids were L-proline, taurine and L-$\alpha$-aminoadipic acid.

Lipase-catalyzed Esterification of (S)-Naproxen Ethyl Ester in Supercritical Carbon Dioxide

  • Kwon, Cheong-Hoon;Lee, Jong-Ho;Kim, Seung-Wook;Kang, Jeong-Won
    • Journal of Microbiology and Biotechnology
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    • v.19 no.12
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    • pp.1596-1602
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    • 2009
  • A lipase-catalyzed esterification reaction of (S)-naproxen ethyl ester by CALB (Candida antarctica lipase B) enzyme was performed in supercritical carbon dioxide. Experiments were performed in a high-pressure cell for 10 h at a stirring rate of 150 rpm over a temperature range of 313.15 to 333.15 K and a pressure range of 50 to 175 bar. The productivity of (S)-naproxen ethyl ester was compared with the result in ambient condition. The total reaction time and conversion yields of the catalyzed reaction in supercritical carbon dioxide were compared with those at ambient temperature and pressure. The experimental results show that the conversion and reaction rate were significantly improved at critical condition. The maximum conversion yield was 9.9% (216 h) at ambient condition and 68.9% (3 h) in supercritical state. The effects of varying amounts of enzyme and water were also examined and the optimum condition was found (7 g of enzyme and 2% water content).

A Study on the Characteristics of Evaporative Heat Transfer for Carbon Dioxide in a Horizontal Tube (수평원관 내 이산화탄소의 증발열전달 특성 연구)

  • Cho, E.S.;Yoon, S.H.;Kim, M.S.
    • Proceedings of the KSME Conference
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    • 2000.04b
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    • pp.104-107
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    • 2000
  • Evaporative heat transfer characteristics of carbon dioxide has been investigated. Experiment has been carried out for seamless stainless steel tube with outer diameter of 9.55 mm and inner diameter of 7.75 mm. Direct heating method is used for supplying heat to the refrigerant was uniformly heated by electric current which was applied to the tube wall. The saturation temperature of refrigerant is calculated from the measured saturation pressure by using an equation of state. Inner wall temperature was calculated from measured outer wall temperature, accounting for heat generation in the tube and heat conduction through the tube wall. Mass Quality of refrigerant was calculated by considering energy balance in the preheater and the test section. Heat fluxes were set at 12, 16, 20, 23, and $27kW/m^2$, mass fluxes were controlled at 212, 318, 424, and $530 kg/m^2s$, and saturation temperature of refrigerant were adjusted at 0, 3.4, 6.7 and $10.5^{\circ}C$. From this study, heat transfer coefficients of carbon dioxide have been provided with respect to quality for several mass fluxes, heat fluxes. Finally, the experimental results in this study are compared with the correaltion by Gungor and Winterton(1987).

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Change of End-tidal PCS During Cardiopulmonary Bypass (체외순환시 호기말 이산화탄소압의 변화)

  • 오중환
    • Journal of Chest Surgery
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    • v.25 no.12
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    • pp.1399-1403
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    • 1992
  • The evaluation of the effectivess of ongoing cardiopulmonary resucitation efforts is dependent on the commonly used methods, such as the presence of femoral or carotid artery pulsations, arterial blood gas determinations, peripheral arterial pressure and intracardiac pressure monitoring. But recent studies suggest that end-tidal carbon dioxide tension serves as a non-invasive measurement of pulmonary blood flow and therefore cardiac output under constant ventilation. A prospective clinical study was done to determine whether end-tidal carbon dioxide monitoring in open heart surgery under cardiopulmonary bypass could be used as a prognostic indicator of bypass weaning. We monitored end-tidal PCO2 values continuously during cardiopulmonary bypass in 30 patients. "Ohmeda 5210 CO-2 monitor" under infrared absorption method were incorperated into the ventilator circuit by means of a side point adaptor between endotracheal tube and ventilator tubing. 18 patients[Group I ] were res-ucitated from partial bypass followed by aorta cross clamp off and 12 patients[Group II ] from aorta cross clamp off followed by partial bypass. But there was no difference between two groups[p>0.05]. The value of end-tidal carbon dioxide tension during ventricular fibrillation or nearly arrest state was 6.6$\pm$2.9 mmHg, and at the time of spontaneous beating was 19.3$\pm$5.6 mmHg[Mean$\pm$Standard deviation], In conclusion end-tidal carbon dioxide tension monitoring provides clinically useful, continous, noninvasive and supplementary prognostic indicator during cardiopulmonary bypass weaning procedures.rocedures.

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