• Title/Summary/Keyword: carbon dioxide method

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Serum Leakage Control using PP/PDMS Composite Membrane (PP/PDMS 복합막을 이용한 혈청누출 제어)

  • 김기범;이삼철;정순량;정경락
    • Membrane Journal
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    • v.10 no.1
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    • pp.47-53
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    • 2000
  • The artificial lung is a device used to replace the function of the lungs. The major function of the lung is to remove carbon dioxide from the venous blood and replace it with oxygen, or arterialize the blood. And the function of the artificial lung is to provide an adequate amount of oxygenated blood to all the tissues of body during the open heart surgery. Extracorporeal life support(ECLS or ECMO) is standard treatment for severe respiratory failure but poses many contributions to future lung transplantation. Artificial Lung or membrane oxygenators available today, based on microporous polypropylene fibers, are associated with two major problems. They require systemic anticoagulation of the patient and they allow serum leakage across the membrane from the blood side to the gas side during long-term use. We obtained newly fabricated polypropylene(PP)/polydimethylsiloxane(PDMS) membranes which combined PP membrane, a microporous support layer with PDMS, and we had investiaged a technique for minimizing serum lekage of polypropylene(PP) membrane. The gas permeability of each PP/PDMS membrane was almost constant before and after the whole blood test by Lee-White method, while that of PP membrane was significantly reduced. Therefore the PP/PDMS membrane could be prevented serum leakage of PP membrane. In addition, the gas permeability of $CO_2$ in PP/PDMS membrane was 11.5 times higher as compared with that of $O_2$.

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Evaluation of $CO_2$ Uptake Using $CO_2$ Philic Adsorbents in Mortar (친 이산화탄소 흡착제를 이용한 모르타르 내 이산화탄소 흡수능 평가)

  • Park, Hyojeong;Jang, Junwon;Lee, Jihyun;Park, Jaewoo
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.11
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    • pp.11-17
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    • 2012
  • This study focused on application of various $CO_2$ philic adsorbents with amine to improve $CO_2$ uptake in mortar. TGA, phenolphthalein method, FT-IR XRD, and FE-SEM analysis methods were used to evaluate $CO_2$ capture in mortar. When $CO_2$ philic adsorbents was used, $CO_2$absorption efficiency was improved maximum of 58.5%. Carbonation depth was increased 3 times compared with original mortar. Chemical reactions between bicarbonate ion, $CO_2$, $CO_2$ philic adsorbents aqueous solution, and $Ca^{2+}$ ions dissolved from cement formed $CaCO_3$ in the mortar. Therefore, impregnation of the $CO_2$ philic adsorbent on the surface of the mortar can increase the adsorbed $CO_2$.

Optimization of Sesame oil Extraction from Sesame cake using Supercritical Fluid $CO_{2}$ (초임계유체 $CO_{2}$를 이용한 참깨박 중 참기름 추출의 최적화)

  • Kim, Seong-Ju;Kim, Young-Jong;Chang, Kyu-Seob
    • Korean Journal of Food Science and Technology
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    • v.37 no.3
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    • pp.431-437
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    • 2005
  • Overall experiments were planned by central composite design, and results were analyzed by response surface methodology (RSM) to determine effects of three independent variables, temperature ($X_{1}$), extraction time ($X_{3}$), and pressure ($X_{3}$), on yield of sesame oil extract (Y). Regression equation model optimized by response surface analysis was: Y (sesame oil) = $-3.89+0.07X_{1}+0.03X_{2}+0.0006X_{3}-0.0007X_{1}^{2}-0.0002X_{2}X_{1}-0.00008X_{2}^{2}+0.000004X_{3}X_{1}+0.0000009X_{3}X_{2}-0.00000009X_{3}^{2}$. According to RSM analysis, optimum extracting conditions of temperature, time, and pressure were $45.89^{\circ}C$, 131.89 min, and 34228.41 kPa, respectively, and statistical maximum yield of sesame oil was 96.27%. Fatty acid composition of sesame oil showed sesame oil extracted by Supereritical Fluid $CO_{2}$ contained lower levels of palmitic, stcaric, and oleic acids and higher levels or palmitoleic and linoleic acids than commercial sesame oil. Commercial and extracted sesame oils were analyzed by electronic nose composed of 12 different metal oxide sensors. Obtained data were interpreted by statistical method of MANOVA. Sensitivities of sensors from electronic nose were analysed by principal component analysis. Proportion of first principal component was 99.92%. All sesame oils showed different odors (p < 0.05).

Control of dissolved Oxygen Concentration and Specific Growth Rate in Fed-batch Fermentation (유가식 생물반응기에서의 용존산소농도 및 비성장속도의 제어)

  • Kim, Chang-Gyeom;Lee, Tae-Ho;Lee, Seung-Cheol;Chang, Yong-Keun;Chang, Ho-Nam
    • Microbiology and Biotechnology Letters
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    • v.21 no.4
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    • pp.354-365
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    • 1993
  • A novel control method with automatic tuning of PID controller parameters has been developed for efficient regulation of dissolved oxygen concentration in fed-batch fermentations of Escherichia coli. Agitation speed and oxygen partial pressure in the inlet gas stream were chosen to be the manipulated variables. A heuristic reasoning allowed improved tuning decisions from the supervision of control performance indices and it coule obviate the needs for process assumptions or disturbance patterns. The control input consisted of feedback and feedforword parts. The feedback part was determined by PID control and the feedforward part is determined from the feed rate. The proportional gain was updated on-line by a set of heuristics rules based on the supervision of three performance indices. These indices were output error covariance, the average value of output error, and input covariance, which were calculated on-line using a moving window. The integral and derivative time constants were determined from the period of output response. The specific growth rate was maintained at a low level to avoid acetic acid accumulation and thus to achieve a high cell density. The specific growthe rate was estimated from the carbon dioxide evolution rate. In fed-batch fermentation, the simutaneous control of dissolved oxygen concentration (at 0.2; fraction of saturated value) and specific growth rate (at 0.25$hr^{-1}$) was satisfactory for the entire culture period in spite of the changes in the feed rate and the switching of control input.

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Characteristics of Biodegradation under Composting and Vermiculite Condition (폐 MDF 퇴비화 사용을 위한 생분해 환경 특성에 관한 연구 (I))

  • Choi, Chul;Yoo, Ji-Chang;Yang, Seong-min;Lee, Chang-goo;Lee, Seok-eon;Kang, Seog-goo
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.1
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    • pp.127-133
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    • 2016
  • This study is performed that furniture and interior materials of MDF's (Medium Density Fiberboard) biodegradation properties, and the goal of this study is investigation of possibility of waste-MDF's composting after landfilling. To investigate biodegradation, this study was performed according to KS M ISO 14855-1, and there were two different soil conditions including a compost condition and an activated vermiculite condition as artificial soil. This experiment was tested for 40 days. The measurement of carbon-dioxide generation was processed every 24 hour in 1-2 week, and every 48 hour after 3 week. In the same days, MDF showed 24.4% of biodegradation in compost condition, and 6.2% in activated vermiculite. Also, the reference material of TLC (thin-layer chromatography) grade cellulose showed 26.4%, 11.4% in compost and activated vermiculite respectively. The dilution plate method was performed for biological analysis in the study. This experiment was used for investigation of inoculum's (Bacillus licheniformis) activity. As the result of bioassay, compost has more other germs include inoculum than activated vermiculite in the first week. Especially in the 2nd week, the reference material under the compost condition showed the most germ's activity, and also the biodegradation was the highest. Consequentially, compost condition was able to reduce a performing period of biodegradation testing than activated vermiculite. However, activated vermiculite could be stabilizing errors between repetition.

Synthesis and Luminescence Properties of Tb3+-Doped K2BaW2O8 Phosphors (Tb3+ 이온이 첨가된 K2BaW2O8 형광체의 합성 및 형광특성)

  • Jang, Kyoung-Hyuk;Koo, Jae-Heung;Seo, Hyo-Jin
    • Korean Journal of Materials Research
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    • v.22 no.9
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    • pp.489-493
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    • 2012
  • Green phosphors $K_2BaW_2O_8:Tb^{3+}$(1.0 mol%) were synthesized by solid state reaction method. Differential thermal analysis was applied to trace the reaction processes. Three endothermic values of 95, 706, and $1055^{\circ}C$ correspond to the loss of absorbed water, the release of carbon dioxide, and the beginning of the melting point, respectively. The phase purity of the powders was examined using powder X-ray diffraction(XRD). Two strong excitation bands in the wavelength region of 200-310 nm were found to be due to the ${WO_4}^{2-}$ exciton transition and the 4f-5d transition of $Tb^{3+}$ in $K_2BaW_2O_8$. The excitation spectrum presents several lines in the range of 310-380 nm; these are assigned to the 4f-4f transitions of the $Tb^{3+}$ ion. The strong emission line at around 550 nm, due to the $^5D_4{\rightarrow}^7F_5$ transition, is observed together with weak lines of the $^5D_4{\rightarrow}^7F_J$(J = 3, 4, and 6) transitions. A broad emission band peaking at 530 nm is observed at 10 K, while it disappears at room temperature. The decay times of $Tb^{3+}$ $^5D_4{\rightarrow}^7F_5$ emission are estimated to be 4.8 and 1.4 ms, respectively, at 10 and 295 K; those of the ${WO_4}^{2-}$ exciton emissions are 22 and 0.92 ${\mu}s$ at 10 and 200 K, respectively.

Performance of an Intermittent Aerated Pilot-scale Reactor Vessel for Commercial Composting (상업용 퇴비화를 위한 간헐통기식 파이로트 규모 반응조의 성능)

  • Hong, Ji-Hyung
    • Journal of the Korea Organic Resources Recycling Association
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    • v.6 no.2
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    • pp.31-44
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    • 1998
  • Mixtures of hog manure slurry and sawdust were composted by an intermittent aeration method to verify the performance evaluation of pilot-scale reactor vessels during composting high rate (decomposition) process. Instrumentation was designed to measure temperatures in compost, oxygen and carbon dioxide concentration, air flow rates, and ammonia gas emitted. It was found that ammonia concentration during composting high rate decreased more quickly to the allowable range of 34-40 ppm after 14days at near the optimal levels (II) than in the case of lower levels (I). The influence of the optimal levels (II) such as moisture content (55-65%), C/N ratio (20-40), pH (7-8) and temperature in compost (<$60^{\circ}C$) on the reduction of ammonia gas was considerable for commercial composting.

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A Study on the Synthesis of $Mn_3O_4$ and the Decomposition and Adsorption of $CO_2$ ($Mn_3O_4$의 합성과 $CO_2$ 분해 및 흡착에 관한 연구)

  • Kim Seung-Ho;Park Young-Goo;Ko Jae-Churl
    • Journal of the Korean Institute of Gas
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    • v.4 no.2 s.10
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    • pp.27-32
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    • 2000
  • In this study, $Mn_3O_4$ was synthesized by the different equivalent ratios using solution of $MnCL_2 {\cdot} 4H_2O$ and NaOH. We have investigated the crystal structure and surface area by XRD, BET Method, studied on the decompositon and adsorption of carbon dioxide with synthesized $Mn_3O_4$. As the results, we surveyed that main peak was $Mn_3O_4$, some Peaks were $MnO_2$ and $Mn_5O_8$ The specific surface area was ranged from $13.92m^2/g$ to $32.33m^2/g$. The decomposition of $CO_2$ was observed by the differential equivalent ratios at $450^{\circ}C$. $CO_2$ was well decomposed at equivalent ratio of 0.75. The amount of chemisorption of $CO_2$ was ranged from 2.885 to 19.628cc/g. Optimal equivalent ratio was 1.00 for the chemisorption of $CO_2$.

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Flavor Components in the Filefish Processing (말쥐치 가공중 향기성분에 관하여)

  • LEE Jong-Ho;CHOI Byeong-Dae;LEE Kang-Ho;LEE Kun-Tae;KIM Tae-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.22 no.3
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    • pp.121-128
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    • 1989
  • Volatile compounds were collected by simultaneous distillation extraction and carbon dioxide method, and analyzed by GC and GC-MS. The neutral fraction obtained from the whole steam volatile concentrate 55 kinds of components, phenolic fraction had 4 kinds of components, basic fraction had 13 kinds of components and 10 kinds of components were in acidic fraction. Alcohols, propanols, butanols, octanols, dodecanols etc. and aldehydes, pentanals, hexanal, 2-methyl-1-propanal, heptenal etc. were highly increased after boiled and roasted. And these compounds were contributed to formation of filefish flavor. The molecular ion peak of phenolic fraction was generally appeared in the range 100 to about 160. From the basic fraction, 2-methylpyrazine, 2,5-dimethylpyrazine, 2-ethyl-3,5-di-methylpyrazine and 2-methylpyridine were identified. The contents of basic compounds and furans obtained from the neutral fraction were increased at the higher heating temperature. The flavor of acidic fraction was influenced by the low molecular as isovaleric and valeric acid.

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Numerical Simulation of Supercritical $CO_2$ Flow in a Geological Storage Reservoir of Ocean (해양 지중저장층내 초임계 $CO_2$ 유동에 대한 전산모사)

  • Choi, Hang-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.4
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    • pp.251-257
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    • 2011
  • In the present study, a 3-dimensional (3D) numerical model was developed to mimic the micro porous structure of a geological $CO_2$ storage reservoir. Especially, 3D modeling technique assigning random pore size to a 3D micro porous structure was devised. Numerical method using CFD (computational fluid dynamics) was applied for the 3D micro porous structure to calculate supercritical $CO_2$ flow field. The three different configurations of 3D micro porous model were designed and their flow fields were calculated. For the physical conditions of $CO_2$ flow, temperature and pressure were set up equivalent to geological underground condition where $CO_2$ fluid was stored. From the results, the characteristics of the supercritical $CO_2$ flow fields were scrutinized and the influence of the micro pore configuration on the flow field was investigated. In particular, the pressure difference and consequent $CO_2$ permeability were calculated and compared with increasing $CO_2$ flow rate.