• Title/Summary/Keyword: carbon dioxide method

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Augmentation of Radiative Heat Transfer in an Infinite Cylindrical Pipe Enclosing a Participating Gas (참여기체를 가진 무한 원형관 계의 복사 열전달 증진)

  • 변기홍
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.10
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    • pp.1955-1962
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    • 1992
  • The purpose of this study is to identify the radiative heat transfer augmentation by a coaxial cylinder introduced in the infinite cylindrical pipe enclosing a participating gas. The gas is either a mixture of water vapor and carbon dioxide or gray. The gas is assumed to be homogeneous at a constant temperature, and has a refractive index of unity. All of the surfaces are opaque and gray, diffusely emitting and reflecting at a constant temperature, The effect of system diameter, diameter ratio, wall emittances, gas and surface temperatures, mixture component on heat transfer augmentation are studied by using the zone method with participating gas radiative properties evaluated from the weighted sum of gray gases model. From the radiative equilibrium condition, the installed wall temperature is formulated and calculated by the iteration method. If the medium is a gray gas, the augmentation observed are negligible. For the range of values studied for a real gas, if the system diameter is larger than about 0.1m the augmentation parameter increases up to about 1.2 as the system diameter increases. The augmentation parameter have a maximum value at a certain diameter ratio. The augmentation parameters decreases as the emittance of the installed wall decreases. If the gas temperature is higher than about 1273 k, the augmentation parameter decreases as the gas temperature increases.

Measuring Interfacial Tension between Brine and Carbon Dioxide in Geological CO2 Sequestration Conditions using Pendant Bubble Methods (수적(垂滴)법을 이용한 이산화탄소 지중저장 조건에서의 염수-이산화탄소 간 계면장력 측정)

  • Park, Gyuryeong;An, Hyejin;Kim, Seon-ok;Wang, Sookyun
    • Journal of Soil and Groundwater Environment
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    • v.21 no.6
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    • pp.46-55
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    • 2016
  • This experimental study was aimed to estimate interfacial tension of brine-$CO_2$ by using a pendant bubble method and image analysis. Measurements were performed for wide ranges of temperatures, pressures, and salinities covering reservoir conditions in Pohang basin, a possible candidate for $CO_2$ storage operation in Korea. The profiles of $CO_2$ bubbles in brine obtained from image analysis with the densities of brine and $CO_2$ from previous studies were applied to Laplace-Young equation for calculating interfacial twnsion in brine-$CO_2$ system. The experimental results reveals that the interfacial tension is significantly affected by reservoir conditions such as pressure, temperature and water salinity. For conditions of constant temperature and water salinity, the interfacial tension decreases as pressure increases for low pressures (P < $P_c$), and approaches to a constant value for high pressures. For conditions of constant pressure and water salinity, the interfacial tension increases as temperature increases for T < $T_c$, with an asymptotic trend towards a constant value for high temperatures. For conditions of constant pressure and temperature, the interfacial tension increases with increasing water salinity. The trends in changes of interfacial tension can be explained by the effects of the reservoir conditions on the density difference of brine and $CO_2$, and the solubility of $CO_2$ in brine. The information on interfacial tensions obtained from this research can be applied in predicting the migration and distribution of injecting and residual fluids in brine-$CO_2$-rock systems in deep geological environments during geological $CO_2$ sequestrations.

Mode II fracture toughness determination of rocks using short beam compression test (짧은 보 압축 시험법을 이용한 암석의 모드 II 파괴 인성 측정)

  • Ko, Tae Young;Kemeny, J.
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.15 no.6
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    • pp.547-557
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    • 2013
  • The mode II fracture toughness and strength due to shear stress are important parameters in the stability of caprock and injection zone with application to geological sequestration of carbon dioxide. In this research, a short beam compression test has been used to determine the shear strength and the mode II fracture toughness for Coconino sandstone. The average value of the shear strength and mode II fracture toughness are estimated to be 23.53 MPa and 1.58 MPa${\surd}$m respectively. The stress intensity factor is suggested by finite element analysis using the displacement extrapolation method. The effect of biaxial stress and water saturation on the fracture toughness has also been investigated. The fracture toughness increases with confining stresses, but decreases by 11.4% in fully saturated condition.

The Extraction of Metal Contaminants using Supercritical CO2 (초임계이산화탄소를 이용한 방사성 금속이온 추출)

  • Ju, Minsu;Kim, Jung-Hoon;Kang, Se-Sik
    • The Journal of the Korea Contents Association
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    • v.16 no.5
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    • pp.660-667
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    • 2016
  • Conventional decontamination methods utilize water-based systems, which generate high amounts of secondary wastes. Herein, we describe an environmentally benign decontamination method using liquid and supercritical $CO_2$. The use of $CO_2$ as a solvent affords effective waste reduction by its ability to be recycled, thereby leaving be hind only the contaminants upon its evaporation. In this study, a $CO_2$ solution process was assessed using t-salen(t-butylsalen), DC18C6 (dicyclohexano-18Crown6), 8-HQN(8-hydroxyquinoline), NEt4PFOSA(perfluoro-1-octanesulfonic acid tetra-ethyl ammonium salt), and NEt4PFOA(pentadecafluorooctanoic acid ammonium salt) to extract spiked radioactive contaminants(Nb,Zr,Co,Sr) from an inert sample matrix, namely filter paper. With the static extraction method, Sr was extracted with a maximum extraction rate of 97%, and Nb was extracted with a maximum extraction rate of 75%. Additionally, we were also able to extract Co and Zr with maximum extract ion ratesof 73% and 64%, respectively.

Development of an Anaesthesia Ventilator by Volume Control Method and a Gas Monitoring System (가스 모니터 및 볼륨 제어 방식의 마취기용 인공 호흡기 개발)

  • Lee, Jong-Su;Seong, Jong-Hun;Kim, Yeong-Gil
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.37 no.4
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    • pp.42-48
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    • 2000
  • Generally an operator would take notice at putting a patient under anesthesia. If the operation is executed in mistake, the patient is exposed to danger. The object of this Paper is that a system is developed for an accuracy of system and a convenience of user interface to prevent an operation of several elements of risk by mistake. The part of electrical system particularly is made for convenience of a manipulation using electrical switch and encoder. A real-time monitoring system is developed for an airway pressure and a gas concentration of carbon dioxide of patient using graphic LCD(liquid crystal display). Moreover, this flow control system could be developed control with accuracy by feedback control method. This is implemented using flow control valve and flow sensor. The implemented system gives convenience and precision of a manipulation of variable value using developed technique. This system shows guaranteed stabilization and confidence of anesthesia ventilator by notifying us that patient's state and information in case of being out of alarm range of variable value.

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Production Technology of Low-cholesterol Egg Prodecuts and Recycling of By-Products (저콜레스테롤 계란제품의 생산기술과 부산물의 재활용)

  • 유익종
    • Proceedings of the Korea Society of Poultry Science Conference
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    • 2000.04a
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    • pp.23-36
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    • 2000
  • Hurdle technique was used to remove cholesterol efficiently from liquid egg yolk. The quality of the low cholesterol egg products from the process were evaluated. From the 75 % cholesterol reduced egg yolk through $\beta$-cyclodextrin treatment. 2 times weight of soy bean oil was added to the egg yolk and homogenized followed by centrifuged to be maximized to remove cholesterol. When the pH of the yolk was adjusted to 9, 92 % of cholesterol was removed while 95.4 % of cholesterol was removed when 3 times weight of soy bean oil was added to the egg yolk. As the results of application of supercritical carbon dioxide extraction to the 75 % cholesterol reduced egg yolk through ${\beta}$-cyclodextrin treatment, 92.5 % of the cholesterol was removed from the egg yolk at $35^{\circ}C$, 4,500 psi, for 4 hours under co-solvent. The quality characteristics of the produced low cholesterol egg products were analysed. The cholesterol reduced egg yolk produced from ${\beta}$-cyclodextrin and soy bean oil treatment showed the lower emulsion capacity compared with control. The fatty acid composition of the cholesterol reduced egg yolk produced from ${\bet}a$-cyclodextrin and soy bean oil treatment showed increased C18:2 and C18:3 compared with control while decreased C16:1 and C18: 1 compared with control. The saponification method with extracting solvent of hexane showed that cholesterol concentration was 28.1 %. The quantity of hydrolysis solution(95 % ethanol : 33 % KOH = 94 : 6) was varied from 40 to 80 times of sample weights and the cholesterol concentration of 35.7 % was the highest result in the 60 times(v/w) hydrolysis solution. Cholesterol concentration of 35.7 % was recovered at the first trial with saponification method. but it could be improved up to 95.7 % after 4 times repetitive purification.

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An Analysis of Uncertainties in Energy Category: Estimation by using Tier 1 Method (에너지분야 온실가스 인벤토리의 불확도에 관한 연구: Tier 1 에러전파방법을 이용한 추정)

  • Hwang, In Chang;Jin, Sang Hyeon
    • Environmental and Resource Economics Review
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    • v.23 no.2
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    • pp.249-280
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    • 2014
  • IPCC requires the national uncertainties which show how credible the emission of greenhouse gases is. But the Korean government did not submit the total uncertainties, only the detailed uncertainties by items. Also it uses the default values of IPCC including some missing values. This paper tries to estimate the total uncertainties of energy by categories, which accounts for 85.3% in national emission of greenhouse gases. Concretely, it uses Tier 1 method suggested by IPCC. As a result of the analysis, the uncertainties in energy category are 3.4% similar to Finland's. But there was a big difference among greenhouse gases; carbon dioxide 2.7%, methane 116% and nitrous oxide 473%. So this paper suggests Korean government need to improve not only the activity but also the emission factor of data in order to reduce the national uncertainties in energy category.

Voice Features Extraction of Lung Diseases Based on the Analysis of Speech Rates and Intensity (발화속도 및 강도 분석에 기반한 폐질환의 음성적 특징 추출)

  • Kim, Bong-Hyun;Cho, Dong-Uk
    • The KIPS Transactions:PartB
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    • v.16B no.6
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    • pp.471-478
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    • 2009
  • The lung diseases classifying as one of the six incurable diseases in modern days are caused mostly by smoking and air pollution. Such causes the lung function damages, and results in malfunction of the exchange of carbon dioxide and oxygen in an alveolus, which the interest is augment with risk diseases of life prolongation. With this in the paper, we proposed a diagnosis method of lung diseases by applying parameters of voice analysis aiming at the getting the voice feature extraction. Firstly, we sampled the voice data from patients and normal persons in the same age and sex, and made two sample groups from them. Also, we conducted an analysis by applying the various parameters of voice analysis through the collected voice data. The relational significance between the patient and normal groups can be evaluated in terms of speech rates and intensity as a part of analized parameters. In conclusion, the patient group has shown slower speech rates and bigger intensity than the normal group. With this, we propose the method of voice feature extraction for lung diseases.

Catalytic Nitrate Reduction in Water over Nanosized TiO2 Supported Pd-Cu Catalysts (나노 크기의 타이타니아 담체를 활용한 Pd-Cu 촉매의 수중 질산성 질소 저감 반응에의 적용)

  • Kim, Min-Sung;Lee, Jiyeon;Lee, Kwan-Young
    • Clean Technology
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    • v.20 no.1
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    • pp.28-34
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    • 2014
  • In this study, we synthesized $TiO_2$ supports with nanosized crystalline structure by solvothermal method and prepared $TiO_2$ supported Pd-Cu catalysts. It was shown that the crystalline size of $TiO_2$ support in the catalyst influenced on the catalytic activity of nitrate reduction in water. The catalyst with the smaller crystalline size of $TiO_2$ support presented faster nitrate reduction rate, but had low nitrogen selectivity due to high pH environment of reaction medium during the reaction. Through injection of carbon dioxide as a pH buffer, the nitrogen selectivity increased by about 60%. Furthermore, we investigated that the relationships between the catalytic performance and the physicochemical properties of the prepared catalysts characterized by $N_2$ adsoprtion-desorption, X-ray diffraction (XRD), $H_2$-temperature programmed reduction (TPR), X-ray photoelectron spectroscopy (XPS).

Predicting Carbonation Progress of Carbonation Repaired RC Structures Repair (탄산화가 진행된 기존 RC구조물의 보수 공법 적용 후 탄산화 진행 예측)

  • Lee, Hyung-Min;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.3
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    • pp.235-243
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    • 2017
  • Carbonation of concrete is being occurred due to interaction of atmospheric carbon dioxide with hydroxides. Reinforce concrete (RC) structure is getting collapse or accident due to corrosion of embedded steel rebar. The maintenance of reinforced concrete structure recently has the attention of researchers regarding durability of structure and its importance day by day is increasing. In order to study the carbonation progress of pre-repaired concrete, present study was carried out to measure the carbonation velocity for different repair materials up to 100% of carbonation. The obtained results have predicted the carbonation progress of repair materials in service condition. These results have been verified by FEM and FDM analysis. As a result, the carbonation depth can be predicted by using the carbonation prediction formula after the repair, and the analytical and the experimental values are almost similar when the initial $Ca(OH)_2$ concentration is assumed to be 40%.