• Title/Summary/Keyword: carbon dioxide method

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Smelting and Refining of Silicon (실리콘의 제련과 정제)

  • Sohn, Ho-Sang
    • Resources Recycling
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    • v.31 no.1
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    • pp.3-11
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    • 2022
  • Silicon is the most abundant metal element in the Earth's crust. Metallurgical-grade silicon (MG-Si) is an important metal that has wide industrial applications, such as a deoxidizer in the steelmaking industry, alloying elements in the aluminum industry, the preparation of organosilanes, and the production of electronic-grade silicon, which is used in the electronics industry as well as solar cells. MG-Si is produced industrially by the reduction smelting of silicon dioxide with carbon in the form of coal, coke, or wood chips in electric arc furnaces. MG-Si is purified by chemical treatments, such as the Siemens process. Most single-crystal silicon is produced using the Czochralski method. These smelting and refining methods will be helpful for the development of new recycling processes using secondary silicon resources.

Development of a Simulation Model based on CAN Data for Small Electric Vehicle (소형 전기자동차 CAN 데이터 기반의 시뮬레이션 모델 개발)

  • Lee, Hongjin;Cha, Junepyo
    • Journal of ILASS-Korea
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    • v.27 no.3
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    • pp.155-160
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    • 2022
  • Recently, major developed countries have strengthened automobile fuel efficiency regulations and carbon dioxide emission allowance standards to curb climate change caused by global warming worldwide. Accordingly, research and manufacturing on electric vehicles that do not emit pollutants during actual driving on the road are being conducted. Several automobile companies are producing and testing electric vehicles to commercialize them, but it takes a lot of manpower and time to test and evaluate mass-produced electric vehicles with driving mileage of more than 300km on a per-charge. Therefore, in order to reduce this, a simulation model was developed in this study. This study used vehicle information and MCT speed profile of small electric vehicle as basic data. It was developed by applying Simulink, which models the system in a block diagram method using MATLAB software. Based on the vehicle dynamics, the simulation model consisted of major components of electric vehicles such as motor, battery, wheel/tire, brake, and acceleration. Through the development model, the amount of change in battery SOC and the mileage during driving were calculated. For verification, battery SOC data and vehicle speed data were compared and analyzed using CAN communication during the chassis dynamometer test. In addition, the reliability of the simulation model was confirmed through an analysis of the correlation between the result data and the data acquired through CAN communication.

Perspective: Analysis of Conditions for High-efficiency/Eco-friendly Energy Production Devices for Smart Cities (스마트시티용 고효율/친환경 에너지생산장치의 조건 분석)

  • Sang Wook Kang;Jeong Uk Kim
    • Membrane Journal
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    • v.33 no.1
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    • pp.46-51
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    • 2023
  • The purpose of this study is to analyze the utilization forms of hydrogen fuel cells, which are the core of building a smart city, and suggest ways to solve them. In the case of power plants to utilize hydrogen fuel cell, it was analyzed as the most promising form of use in the future due to the advantage of being free from intermittence problems. However, despite many advantages, local residents' opposition continues to emerge due to concerns about explosions and the problem of carbon dioxide generation in the case of certain hydrogen production methods, and it is analyzed that resolving them will be the main key to establishing the smart city. Finally, by analyzing the current hydrogen production method and identifying the problems facing it, the solution for the complete construction of the smart city was presented.

The Structure and Evolution of Renewable Energy Trade Networks in the RCEP Region: Application of SNA Method

  • Jinyan Tian;Qianli Wu;Congying Sun;Ziyang Liu
    • East Asian Economic Review
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    • v.28 no.1
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    • pp.3-35
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    • 2024
  • This paper utilizes social network analysis to examine the structural characteristics and trade dynamics of the renewable energy (hydropower, wind energy, and solar energy) trade network within the RCEP region from 2011 to 2020. The findings reveal: (1) The renewable energy trade network within the RCEP exhibits dynamism, heterogeneity, and an uneven development. The solar energy network is the most balanced and stable, while the wind energy network lags and shows marked fluctuations, with the hydropower network falling between these two. This demonstrates the diversity of energy trade within the region. (2) China, Singapore, and Japan are identified as the key exporting and importing countries, with Vietnam showing substantial growth potential. Individual analyses shed light on the stark disparities in trade status among nations, reflecting the diverse roles and future potential of member countries. (3) The QAP regression analysis reveals a significant influence of environmental pressure, particularly carbon dioxide emissions, on the renewable energy trade network. This study contributes to promoting environmental sustainability and energy security in the RCEP region and provides empirical evidence for global renewable energy trade strategies.

Effect of Supercritical Carbon Dioxide on Physicochemical Properties and Microbial Reduction of Freeze-Dried Bovine Liver (초임계 이산화탄소 처리가 동결 건조된 소간의 이화학적 특성 및 미생물 저감화에 미치는 영향)

  • Kim, Hye-Min;Woo, Sung-Woon;Kim, Ah-Na;Heo, Ho-Jin;Chun, Ji-Yeon;Choi, Sung-Gil
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.44 no.12
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    • pp.1847-1855
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    • 2015
  • Supercritical carbon dioxide ($SC-CO_2$) treatment has been becoming an important method for substituting the use of organic solvents for samples extraction prior to analysis due to its low toxicity, ease of handling, low cost of disposal etc. Freeze-dried bovine liver was treated with $SC-CO_2$ under different pressures (200, 300, and 450 bar) in order to investigate effects on physicochemical properties and reduction of microbial load. The yield of lipid extraction from bovine liver by $SC-CO_2$ treatment increased with increasing pressure, with values of 84, 86, and 90% in response to 200, 300, and 450 bar, respectively. Results of high performance liquid chromatography analysis showed that vitamin A and coenzyme $Q_{10}$ ($CoQ_{10}$), which is soluble in lipid, were almost removed from bovine liver by $SC-CO_2$ treatment. Saturated fatty acids ratio of bovine liver decreased with increasing pressure, whereas polyunsaturated fatty acids increased with increasing pressure. Total content of amino acids in bovine liver treated by $SC-CO_2$ was less than that of the control sample without treatment. The number of aerobic bacteria in bovine liver, which was stored at $5^{\circ}C$ for 5 days and freeze-dried, decreased from 6.2 to 4.2 log CFU/g by $SC-CO_2$ treatment at 100 bar for 3 h. Interestingly, coliform bacteria were not found in the bovine liver sample by $SC-CO_2$ at 100 bar for 3 h under all storage conditions. This indicates that $SC-CO_2$ treatment can effectively reduce coliform bacteria in the food matrix even at low moisture. In conclusion, freeze-dried bovine liver by proper $SC-CO_2$ treatment may be used as a potential high protein source, with increasing microbial safety and stability of lipid oxidation.

Effects of Carbon Dioxide Fertilization on the Quality and Storability of Strawberry 'Maehyang' (재배 시 탄산시비가 딸기 '매향' 의 품질과 저장성에 미치는 영향)

  • Choi, In-Lee;Yoon, Jae Su;Yoon, Hyuk Sung;Choi, Ki-Young;Kim, Il-Seop;Kang, Ho-Min
    • Journal of Bio-Environment Control
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    • v.26 no.2
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    • pp.140-145
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    • 2017
  • This study was conducted to find out the effects of $CO_2$ fertilization (1,000ppm) on the quality and storability of 'Maehyang' strawberry fruits. Qualities such as firmness, soluble solid, and acidity of strawberry fruits showed higher numbers in those treated with $CO_2$ fertilization compared to those after harvest. Strawberry fruits were stored at $8^{\circ}C$; MA condition using $20,000cc{\cdot}m^{-2}{\cdot}day^{-1}{\cdot}atm^{-1}$ OTR (oxygen transmission rate) films and conventional condition using unsealed PE box stored for 20 and 10 days, respectively. Fresh weight loss rate was less than 1.0% in MA storage regardless of $CO_2$ fertilization treatment. Concentrations of oxygen, carbon dioxide, and ethylene in OTR films did not show any significant difference between $CO_2$ fertilization treatment and control (nontreatment) during storage. $CO_2$ fertilization treatments maintained higher firmness after storage regardless of storage methods, but soluble solid, acidity, and surface color did not differ among the treatments. Visual quality and off-flavor based on sensory evaluation was the highest in $CO_2$ fertilization treated strawberry and stored at a MA condition, and was the lowest in $CO_2$ fertilization treated strawberry and those stored in a conventional condition, respectively. The fungal incidence rate of strawberry fruits showed less in $CO_2$ fertilization treatment than control during both MA and conventional storage. These results suggest that $CO_2$ fertilization can improve firmness, increase visual quality after harvest and storage at $8^{\circ}C$, and the MA storage method enhances the shelf-life of 'Maehyang' strawberry fruits.

Variations in Nutrients & CO2 Uptake Rates and Photosynthetic Characteristics of Saccharina japonica from the South Coast of Korea (다시마(Saccharina japonica)의 생장에 따른 영양염 및 CO2 흡수율과 광합성 특성 변화)

  • Hwang, Jae-Ran;Shim, Jeong-Hee;Kim, Jeong-Bae;Kim, Sook-Yang;Lee, Yong-Hwa
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.16 no.4
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    • pp.196-205
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    • 2011
  • To investigate the contribution of macroalgae to biogeochemical nutrients and carbon cycles, we measured the uptake rates of nutrients and $CO_2$ and characteristics of fluorescence of Saccharina japonica (Laminaria japonica Areschoug) using an incubation method in an acrylic chamber. From January to May 2011, S.japonica was sampled at Ilkwang, one of well-known macroalgae culture sites around Korea and ranged 46~288 cm long and 4.8~22.0 cm wide of whole thallus. The production rate of dissolved oxygen by S. japonica (n=25) was about $6.9{\pm}5.8{\mu}mol\;g^{-1}$ fresh weight(FW) $h^{-1}$. The uptake rate of total dissolved inorganic carbon ($TCO_2$), calculated by total alkalinity and pH, was $8.9{\pm}7.9{\mu}mol\;g^{-1}\;FW\;h^{-1}$. Mean nutrients uptake were $175.6{\pm}161.1\;nmol\;N\;g^{-1}\;FW\;h^{-1}$ and $12.7{\pm}10.1\;nmol\;P\;g^{-1}\;FW\;h^{-1}$. There were logarithmic relationships between thallus length and uptake rates of nutrients and $CO_2$, which suggested that younger specimens (<100-150 cm) were much more efficient at nutrients and $CO_2$ uptake than old specimens > 150 cm. There was a positive linear correlation ($r^2$=9.4) existed between the dissolved oxygen production rate and the $TCO_2$ uptake rate, suggesting that these two factors may serve as good indicators of S. japonica photosynthesis. There was also positive linear relationship between maximal quantum yield ($F_v/F_m$) and production/uptake rates of dissolved oxygen, $TCO_2$ and phosphate, suggested that $F_v/F_m$ could be used as a good indicator of photosynthetic ability and $TCO_2$ consumption of macroalgae. Maximum relative electron transport rate ($rETR_{max}$) of S. japonica increased as thallus grew and was high in distal part of thallus which may be resulted from the increase of photosynthetic cell density per area. The annual $TCO_2$ uptake by S. japonica in Gijang area was estimated about $1.0\sim1.7{\times}10^3C$ ton, which was about 0.02-0.03% of carbon dioxide emission in Busan City. Thus, more research should be focused on macroalgae-based biogeochemical cycles to evaluate the roles and contributions of macroalgae to the global carbon cycle.

Calibration of δ13C values of CO2 gas with different concentrations in the analysis with Laser Absorption Spectrometry (레이저흡광분석기(Laser Absorption Spectrometry)를 이용한 CO2가스의 탄소안정동위원소비 보정식 산출)

  • Jeong, Taeyang;Woo, Nam C.;Shin, Woo-Jin;Bong, Yeon-Sik;Choi, Seunghyun;Kim, Youn-Tae
    • Economic and Environmental Geology
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    • v.50 no.6
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    • pp.537-544
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    • 2017
  • Stable carbon isotope ratio of carbon dioxide (${\delta}^{13}C_{CO2}$) is used as an important indicator in the researches for global climate change and carbon capture and sequestration technology. The ${\delta}^{13}C$ value has been usually analyzed with Isotope Ratio Mass Spectrometer (IRMS). Recently, the use of Laser Absorption Spectrometry (LAS) is increasing because of the cost efficiency and field applicability. The purpose of this study was to suggest practical procedures to prepare laboratory reference gases for ${\delta}^{13}C_{CO2}$ analysis using LAS. $CO_2$ gas was adjusted to have the concentrations within the analytical range. Then, the concentration of $CO_2$ was assessed in a lab approved by the Korea Laboratory Accreditation Scheme and the ${\delta}^{13}C_{CO2}$ value was measured by IRMS. When the instrument ran over 12 hours, the ${\delta}^{13}C$ values were drifted up to ${\pm}10$‰ if the concentration of $CO_2$ was shifted up to 1.0% of relative standard deviation. Therefore, periodical investigation of analytical suitability and correction should be conducted. Because ${\delta}^{13}C_{CO2}$ showed the dependency on $CO_2$ concentration, we suggested the equation for calibrating the concentration effect. After calibration, ${\delta}^{13}C_{CO2}$ was well matched with the result of IRMS within ${\pm}0.52$‰.

A Study on Application and Performance Verification of Aged Reservoir Reinforcing Method using Ground Injection Material of Utilizing Circulation Resources. (순환자원 활용 지반차수재의 노후저수지 보강 적용사례 및 성능검증에 관한 연구)

  • Park, Seong-hun;Seo, Se-Gwan;Song, Sang-Hwon
    • Journal of the Korean Institute of Rural Architecture
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    • v.22 no.3
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    • pp.17-24
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    • 2020
  • Reservoirs, which make up most of South Korea's reservoirs, are located in rural areas. In the case of rural reservoirs, about 75% have been reported over 50 years old aged reservoirs constructed before the 1960s. Reservoirs are important facilities that store and supply water necessary for daily life. However, if it is destroyed, the reservoir can cause a lot of damage, so continuous management is necessary. As a method for strengthening old reservoirs, a method using cement has been widely applied. However, OPC is a product that uses a lot of carbon dioxide and natural resources. Therefore, the amount of cement should be reduced. Against this background, in this study, the ground injection material of utilizing circulation resources was applied to the site. Applied reservoirs have been around for 75 years and leaks have occurred in some sections. The application method was constructed in two rows, up to a depth of 12m. After reinforcement, the electrical resistivity test was conducted three times. As a result, similar resistance was shown at 1 month after construction. And after 6 months, the saturation area decreased. And the performance after reinforcing the aged reservoir was examined. As a result of the review, this study confirmed that the applicability was equivalent to that of OPC, and the excellent performance of reinforcing the aged reservoir was shown.

Estimation of Net Biome Production in a Barley-Rice Double Cropping Paddy Field of Gimje, Korea (김제 보리-벼 이모작지에서의 순 생물상생산량의 추정)

  • Shim, Kyo-Moon;Min, Sung-Hyun;Kim, Yong-Seok;Jung, Myung-Pyo;Choi, In-Tae
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.17 no.2
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    • pp.173-181
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    • 2015
  • Fluxes of carbon dioxide ($CO_2$) were measured above crop canopy using the Eddy Covariance (EC) method, and emission rate of methane ($CH_4$) was measured using Automatic Open/Close Chamber (AOCC) method during the 2012-2013 barley and rice growing season in a barley-rice double cropping field of Gimje, Korea. The net ecosystem exchange (NEE) of $CO_2$ in the paddy field was analyzed to be affected by crop growth (biomass, LAI, etc.) and environment (air temperature, solar radiation, etc.) factors. On the other hand, the emission rate of $CH_4$ was estimated to be affected by water management (soil condition). NEE of $CO_2$ in barley, rice and fallow period was -100.2, -374.1 and $+41.2g\;C\;m^{-2}$, respectively, and $CH_4$ emission in barley and rice period was 0.2 and $17.3g\;C\;m^{-2}$, respectively. When considering only $CO_2$, the barley-rice double cropping ecosystem was estimated as a carbon sink ($-433.0g\;C\;m^{-2}$). However, after considering the harvested crop biomass ($+600.3g\;C\;m^{-2}$) and $CH_4$ emission ($+17.5g\;C\;m^{-2}$), it turned into a carbon source ($+184.7g\;C\;m^{-2}$).