• Title/Summary/Keyword: carbon dioxide method

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A Study on the Optimal Method of Eco-Friendly Recycling through the Comparative Analysis of the Quantitative Calculation and Scope of Recycling

  • Seung-jun WOO;Eun-gyu LEE;Chul-hyun NAM;Kang-hyuk LEE;Woo-Taeg KWON;Hee-Sang YU
    • Journal of Wellbeing Management and Applied Psychology
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    • v.7 no.3
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    • pp.1-11
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    • 2024
  • Purpose: The purpose of this study is to present an efficient emission reduction ratio of plastic to reduce carbon dioxide, the main cause of greenhouse gases. Research design, data and methodology: This study calculated the absolute value of carbon dioxide by setting an equation through the emission coefficient using the US EPA's WARM model. Results: In the recycling ratio of 70%, it was found that the energy recovery ratio was 15.6%, which was the energy recovery ratio without generating carbon dioxide. When carbon dioxide is generated by changing plastic waste emissions, optimal efficiency is achieved by reducing emissions by 10% to 30% of energy recovery ratio, 20% to 50% of energy recovery ratio, and 30% to 80% or more of energy recovery ratio. Conclusions: The recycling rate should be set at a minimum of 70%, so that a carbon dioxide-free energy recovery rate could be obtained during the recycling process, supporting an eco-friendly basis for environmental policies aimed at this rate. In addition, it was possible to suggest that it is essential to reduce emissions by at least 30% for eco-friendly recycling measures that can achieve both economic and environmental feasibility in the energy recovery process through incineration during recycling in Korea.

Behavior Analysis of Discharged DIC Concentrated Seawater through Towed Pipe Injection from Ship

  • Kwon, Seong-Min;Kim, Kang-Min;Song, Hyeon-Woo;Lee, Joong-Woo
    • Journal of Navigation and Port Research
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    • v.43 no.2
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    • pp.79-85
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    • 2019
  • Climate change is a very vital issue that can be no longer avoided. Korea has been a top-level country Iin dealing with carbon dioxide emissions since 1960. Many studies have been conducted to suppress or eliminate carbon dioxide emissions, which account for a large portion of greenhouse gases. Carbon Capture and Storage (CCS), the most practical method of them, plays a significant role. However, these methods have the disadvantage of the limits of geographical distribution and high possibility of re-emission into the atmosphere. Recently, ocean storage has been studied using Accelerated Weathering of Limestone (AWL), a technique for storing carbon dioxide in the ocean as an alternative to CCS, an underground storage. AWL is a method of converting carbon dioxide into concentrated water in the form of bicarbonate ion and discharging it to the ocean to dilute and store it. It does not cause re-emission to the atmosphere, and the discharged concentrated water increases the alkalinity of the ocean to prevent marine acidification. The objective of this study was to understand the behavior of DIC (Dissolved Inorganic Carbon) including carbon dioxide during the ocean discharge of bicarbonate ion concentrated water in AWL method. This study area was set near Ulleung-do where sufficient water depth and operational efficiency were secured. CORMIX model was used to calculate the material diffusion by submerged discharge using ship.

Decomposition of Carbon Dioxide using $Zn_{x}Fe_{3-x}O_{4-{\delta}}$ (($Zn_{x}Fe_{3-x}O_{4-{\delta}}$를 이용한 이산화탄소의 분해)

  • Yang, Chun-Mo;Cho, Young-Koo;Rim, Byung-O
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.1
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    • pp.55-61
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    • 2000
  • $Zn_{x}Fe_{3-x}O_{4}(0.00.<X<0.08)$ was synthesized by air oxidation method for the decomposition of carbon dioxide. We investigated the characteristics of catalyst, the form of methane by gas chromatograph after decomposition of carbon dioxide and kinetic parameter. $Zn_{x}Fe_{3-x}O_{4}(0.00.<X<0.08)$ was spinel type structure. The surface areas of catalysts($Zn_{x{Fe_{3-x}O_{4}(0.00.<X<0.08)$) were $15{\sim}27$ $m^{2}/g$. The shape of $Zn_{0.003}Fe_{2.997}O_{4}$ was sphere. The optimum temperature for the decomposition of carbon dioxide into carbon was $350^{\circ}C$. $Zn_{0.003}Fe_{2.997}O_{4}$ showed the 85% decomposition rate of carbon dioxide and the degree of reduction by hydrogen(${\delta}$) of $Zn_{0.003}Fe_{2.997}O_{4}$ was 0.32. At $350^{\circ}C$, the reaction rate constant and activation energy of $Zn_{0.003}Fe_{2.997}O_{3.68}$ for the decomposition of carbon dioxide into carbon were 3.10 $psi^{1-{\alpha}}/min$ and 0.98 kcal/mole respectively. After the carbon dioxide was decomposed, the carbon which was absorbed on the catalyst surface was reacted with hydrogen and it became methane.

Adsorption Characteristics of Methane and Carbon Dioxide in Zeolite with Flexible Framework (유연한 구조체를 가지는 제올라이트에서 메탄과 이산화탄소의 흡착 특성)

  • Yang Gon Seo
    • Clean Technology
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    • v.30 no.3
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    • pp.248-257
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    • 2024
  • Carbon dioxide is an undesired component of biogas and landfill gas. As a result, it needs to be removed from these mixtures in order to increase their heating value and reduce corrosion during treatment. Zeolites are a class of microporous materials that can be used as adsorbents for the separation of carbon dioxide from gas mixtures. In this work, the pure gas adsorption isotherms of methane and carbon dioxide and the selectivity of their mixture onto LTA-4A, FAU-13X and FAU-NaY adsorbents at temperatures of 273, 298 and 323 K and pressures up to 30 bars were calculated by the Monte Carlo method. Also, the influence of a flexible framework in a set of zeolites on the separation of methane and carbon dioxide was studied. Carbon dioxide adsorption onto the zeolites used in this work was more favorable than methane adsorption. The FAU-13X adsorbent had the highest adsorption capacity among the studied adsorbents. However, the selectivity of carbon dioxide over methane for LTA-4A was the highest. The adsorption capacities of a rigid framework were higher than those of a flexible framework. The influence of the framework flexibility in FAU on adsorption capacity was small. In contrast, its influence on selectivity seemed to be much larger.

Coffee Deodorization with Supercritical Carbon Dioxide (초임계 이산화탄소를 이용한 커피의 탈취)

  • Lee, Joo-Hee;Kim, Hyung-Bae;Byun, Sang-Yo
    • KSBB Journal
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    • v.22 no.5
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    • pp.336-340
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    • 2007
  • Supercritical carbon dioxide was used to remove coffee odors. The odor removal efficiency was tested with coffee drink prepared by the espresso extraction method. Five typical odors in coffee were analyzed with GC and these odors in deodorized coffee were compared to those in control. Supercritical carbon dioxide extraction conditions were optimized as 350 bar and 70$^{\circ}C$ because the solvating power of supercritical fluid is depend on the density which is determined by temperature and pressure. A modified head space method was applied to collect coffee odors in coffee drink prepared by the espresso extraction method. Odors generated in coffee drink made with deodorized coffee powder were reduced by 73% in total mass of typical five coffee odors.

A Study on the Design Program Development of the Carbon Dioxide Fire Extinguishing System Using an Optimization (최적화 기법을 이용한 이산화탄소 소화설비의 설계프로그램 개발에 관한 연구)

  • Lee, Dong-Myung
    • Fire Science and Engineering
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    • v.28 no.3
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    • pp.1-9
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    • 2014
  • In this study, it was developed to the design program optimization the design factors of the carbon dioxide fire extinguishing system on the basis of design theory for the carbon dioxide fire extinguishing system, national emergency management agency (NEMA) notice No. 2012-11, KS B 6261 and steepest descent method of optimization. The design program was developed to C++ compiler based on established the logic and algorithms and was to operate on the Windows operating system. The optimization of design factors for the carbon dioxide fire extinguishing system are minimized subject to constraint on agent flow rate, emission time and design variables (pipe size etc.). It was verified to the design program performance for test system, and it was provided to the foundation for optimal design in fire fighting field. Also, it is considered to improve the efficiency of the fire extinguishing system and to maximize of fire suppression as the construction of the carbon dioxide extinguishing system based on the optimal design factors.

Facilitated Transport Separation of Carbon Dioxide Using Aminated Polyetherimide Membranes (아민화된 폴리이서이미드 막을 이용한 이산화탄소의 촉진수송분리)

  • Kwon, Se Hwan;Rhim, Ji Won
    • Membrane Journal
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    • v.25 no.3
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    • pp.248-255
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    • 2015
  • Aminated polyetherimide membrane synthesized in the laboratory according to amine ratio was used for measurement of gas permeability, diffusivity, and solubility about carbon dioxide, nitrogen, methane, oxygen, and sulfur dioxide with Time-lag method at room temperature. Generally, gas permeability is totally decreased because the more amination rate reacted to the main chain of amine groups, the more intermolecular space became narrow. However, gas permeability of sulfur dioxide was increased due to combination of sulfur dioxide and amine groups have acid and base properties respectively. Diffusivity and solubility of dry gas are totally decreased excluding sulfur dioxide as increasing amination rate. In case of sulfur dioxide, however, diffusivity as well as solubility was increased as increasing amination rate. Selectivity of carbon dioxide/nitrogen showed 60 when amination rate was 3. In case of humid gas, gas permeability of carbon dioxide was 70 barrer when relative humidity showed 100, and selectivity with nitrogen approximately showed 18.

Fundamental Study on the CO2 fixation method using the Cement-saturated solution (시멘트 수용액을 이용한 CO2 고정화 방안에 관한 기초적 연구)

  • Kwack, Jae-Seok;Kang, Chang-Soo;Ahn, Hee-Sung;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.41-42
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    • 2011
  • The purpose of this study is not only fixation of carbon dioxide using the cement-saturated solution by wet carbonating reaction but also evaluate the possibility of storage technology of Carbon dioxide. wet carbonation is reaction of CO2 injection by CO2 reactor. As a result of experiment, the carbon dioxide is fixed, and high-purity Calcium Carbonate is eluted.

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Analytic Expectation of Carbonation Depth of Indoor Concrete According to CO2 Concentration (건축물 실내 CO2 농도 분포에 따른 콘크리트 탄산화 깊이 산정에 관한 연구)

  • Park, Dong-Cheon;Park, Kun-Suok;Ahn, Jae-Cheol;Kang, Byung-Hee
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.231-233
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    • 2011
  • Carbon dioxide in atmosphere causes concrete carbonation which is the phenomenon, that is, the pH of concrete changes from 12-13 to 8.85-10. Even though the carbon dioxide concentration of indoor is higher than that of outdoor, the micro measurement has not carried out. The concentration of carbon dioxide was measured in three places. The data was used as boundary condition to FEM analysis for expectation of concrete carbonation depth. The affect of building finish materials to concrete carbonation was discussed.

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Fundamental Study on the CO2 gas Fixation Method using the Cement-Paste Solution's Calcium ion (시멘트 페이스트 수용액의 칼슘 이온을 이용한 CO2 가스 고정화에 관한 기초적 연구)

  • Kwack, Jae-Seok;Kang, Chang-Soo;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.05a
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    • pp.71-72
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    • 2012
  • The purpose of this study is not only fixation of carbon dioxide using the cement-Paste solution's calcium ion by wet carbonating reaction but also quantitatively evaluate the possibility of storage technology of Carbon dioxide. wet carbonation is reaction of CO2 injection by CO2 reactor. As a result of experiment, the carbon dioxide is fixed, and high-purity Calcium Carbonate is eluted.

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