• Corrosion Science and Technology
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• 제19권2호
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• pp.82-88
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• 2020

This work examined the corrosion protection performance of benzoate loaded hydrotalcite/graphene oxide (HT/GO-BZ) for carbon steel. HT/GO-BZ was fabricated by the co-precipitation method and characterized by infrared spectroscopy, X-ray diffraction, and scanning electronic microscopy. The corrosion inhibition action of HT/GO-BZ on carbon steel in 0.1 M NaCl solution was evaluated by electrochemical measurements. The benzoate content in HT/GO-BZ was determined by UV-Vis spectroscopy. Subsequently, the effect of HT/GO-BZ on the corrosion resistance of the water-based epoxy coating was investigated by the salt spray test. The obtained results demonstrated the intercalation of benzoate and GO in the hydrotalcite structure. The benzoate content in HT/GO-BZ was about 16%. The polarization curves of the carbon steel electrode revealed anodic corrosion inhibition activity of HT/GO-BZ and the inhibition efficiency was about 95.2% at a concentration of 3g/L. The GO present in HT/GO-BZ enhanced the inhibition effect of HT-BZ. The presence of HT/GO-BZ improved the corrosion resistance of the waterborne epoxy coating.

• Corrosion Science and Technology
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• 제19권2호
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• pp.75-81
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• 2020

To reduce structural weight, light metals, including aluminum and magnesium alloys, have been widely used in various industries such as aircraft, transportation and automobiles. Recently, composite materials such as Carbon Fiber Reinforced Plastics (CFRP) and Graphite Epoxy Composite Material (GECM) have also been applied. However, aluminum and its alloys suffer corrosion from various factors, which include aggressive ions, pH, solution temperature and galvanic contact by potential difference. Moreover, carbon fiber in CFRP and GECM is a very efficient cathode, and very noble in the galvanic series. Galvanic contact between carbon fiber composites and metals in electrolytes such as rain or seawater, is highly undesirable. Notwithstanding the potentially dangerous effects of chloride and temperature, there is little research on galvanic corrosion according to chloride concentration and temperature. This work focused on the effects of chloride concentration and solution temperature on AA7075T6. The increased galvanic corrosion between CRFP and AA7075T6 was evaluated by electrochemical experiments, and these effects were elucidated.

• Corrosion Science and Technology
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• 제7권6호
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• pp.328-331
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• 2008

Corrosion behaviour of water intake gate steel structures with different protective measures was investigated. Five material alternatives were taken for investigation, including: imported and recycled stainless steel, carbon steel with hot zinc spraying, painting and composite coatings. Results of corrosion rate for carbon steel, SUS 304, hot zinc spray coats in three water systems of Mekong river basin (saline, blackish and fresh) were also presented. Corrosion rate of carbon steel decreased with decreasing salinity in the investigated water environments. Meanwhile, these values for zinc coated steel, behaved by another way. Environmental data for these systems were filed and discussed in relation with corrosion characteristics. Method of Life Cycle Assessment (LCA) was applied in materials selection for water intake gate construction. From point of Life Cycle Cost (LCA) the following ranking was obtained: Zinc sprayed steel < Recycled stainless steel < Composite coated steel < Painting steel < SUS 304 From investigated results, hot zinc spray coating has been applied as protective measure for steel structures of water intake systems in Mekong river basin.

• 산업기술연구
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• 제17권
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• pp.291-295
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• 1997

The tests of stress corrosion cracking in structural carbon steel were carried out under the conditions of acid fog and general water. As the result of measurement SCC rupture time under acid fog was observed to be much shorter than that of general water at the same stress level. Therefore, acid fog drops the SCC strength in structural carbon steel due to strong corrosion. In the SCC process by acid fog, crack initiation was caused by pit corrosion and local stress concentration, and distinctive feature of crack growth shows branching since crack grows to the corrosion direction. Moreover, corrosion products were observed by clevage corrosion on the crack surfaces.

• 한국표면공학회지
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• 제36권3호
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• pp.229-233
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• 2003

Boron-Carbon-Nitrogen (B-C-N) system is an attractive ternary material since it has not only an extremely high hardness but also a number of other prominent characteristics such as chemical inertness, elevated melting point, and low thermal expansion. In this paper, the corrosion behavior of B-C-N thin films in aqueous solution was investigated B-C-N films with different composition were deposited on a platinum plate by magnetron sputtering in the thickness range of 150-280 nm. In order to understand effect of pH of solutions, $BC_{2.\;4}N$ samples were immerged in 1M HCl, 1M NaCl, and 1M NaOH solution at 298k, respectively. BCN samples with different carbon contents were exposed to 1M NaOH solutions to investigate effect of chemical composition on corrosion resistance. Corrosion rates of samples were measured by ellipsometry, From results, optical constant of $BC_{2,\;4}N$ films was found to be $N_2=2.110-0.295i$. The corrosion rates of $Bi_{1.\;0}C_{2.\;4}N_{1.\;0}$ films were NaOH>NaCl>HCl in orders. With increasing carbon content in B-C-N films, the corrosion resistance of B-C-N films was enhanced. The lowest corrosion rate was obtained for $B_{1.\;0}C_{4.\;4}N_{1.\;9}$ film.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2009년 추계학술발표대회
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• pp.82-82
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• 2009

강관은 물, 유류, 천연 가스 등을 운송하는 배관용 및 건물의 골조, 유압 및 공압 실린더, 가이드 레일 등 의 기계적 부품으로도 널리 사용되기도 한다. 이렇게 사용되는 강관의 70% 이상은 고주파 전기저항용접(High Frequency Electrical Resistance Welding,이하 ERW)으로 제조되고 있다. 아파트 등 실제 현장에서 ERW 강관에 흐르는 유체는 비드가 제거된 내면 부위에서 와류 (vortex)를 일으켜 기계적 침식(erosion)을 수반할 가능성이 있으며, 수격현상으로 인해 부식 부위에서 반복피로 하중을 받아 부식의 전파속도가 증가되어 최종적 으로 파손되는 경우도 예상할 수 있다. 이에 본 연구에서는 입열량을 달리하여 제조된 ERW 강관을 대상으로 강관 내부에서의 유속에 따라 홈부식 감수성에 미치는 영향을 확인하고자 하였다. 이를 위해 실제 사용 환경을 모사할 수 있는 장치를 제작하고 경계 조건을 선정하여 실험을 실시하였다. ERW 강관의 내부에서 유속이 빨라질 경우 부식속도는 증가를 하였고, 입열을 많이 받은 강관의 경우 부식속도가 감소하는 경향을 가졌다. 이러한 결과를 바탕으로 하여 ERW 강관에서 발생하고 있는 결함발생에 의한 피해를 극소화시킴으로서 안전하고 효율적인 관리에 기여하고자 한다.

• Corrosion Science and Technology
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• 제3권6호
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• pp.227-232
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• 2004

The carboxylates as a corrosion inhibitor has been studied by many researchers because of its environmental safety and low depletion rate. However, conventional test methods of inhibitor such as weight loss measurements, linear polarization resistance and corrosion potential monitoring etc., evaluate uniform corrosion of metals. These methods are unable to evaluate crevice-related corrosions, which are encountered in most of heat exchanging facilities. In order to choose the optimum corrosion inhibitor, the appropriate test methods are required to evaluate their performances in service environment. From this point of view, polarization technique was used to evaluate the characteristics of sodium heptanoate on corrosion behavior for carbon steel. Especially a thin film crevice sensor technique were applied to simulate the crevice corrosion in this study. From these experiments, we found that oxygen as an oxidizing agent was required to obtain stable passive film on the metal. Presence of oxygen, however, accelerated crevice corrosion. Potential shift by oxygen depletion and weakened inhibitive film inside the crevice were responsible for such accelerated feature. It is shown that film for corrosion inhibition is a mixture of sodium heptanoate and iron (II) heptanoate as reaction product of iron surface and sodium heptanoate. The iron (II) heptanoate which has been synthesized by reaction of heptanoic acid and ferrous chloride in methanol solution forms bidentate complex.

• Corrosion Science and Technology
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• 제19권2호
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• pp.66-74
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• 2020

In this paper, the author's team has carried out a comparative experimental study on the corrosion characteristics of Q235 steel commonly used in large-scale storage tanks under the specific bottom water environment found with Russian and Daqing crude oil. It was found that there is a certain degree of uniform or local corrosion on the tank floor depending on the kind of bottom water. The bottom water corrosion of Daqing crude oil is a uniform corrosion caused by carbon dioxide. While the Russian crude oil bottom water corrosion is clearly local corrosion caused by co-corrosion of carbon dioxide and hydrogen sulfide, here the corrosion rate is obviously higher than that caused by Daqing crude oil. There are two modes of storage tank inspection and maintenance that have been currently adopted by Chinese refining and chemical enterprises: a regular inspection mode and a API581-2016 risk-based detection mode. These modes have been effectively combined to form an intelligent tank inspection and maintenance mode, software tools to support this intelligent inspection and maintenance management have been developed.

• Corrosion Science and Technology
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• 제9권1호
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• pp.39-47
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• 2010

Galvanic coupling between GECM(graphite epoxy composite material) and metallic materials can facilitate corrosion of metals and alloys because GECM is noble and electrically conductive. Galvanic corrosion is affected by many factors including metallic materials, area ratio, surface condition, and corrosivity. This work aims to evaluate the effect of area ratio on galvanic corrosion between GECM and several metals. In the case of glavanic coupling of carbon steel and Al to GECM, corrosion rate increased with increasing area ratio. Corrosion rate of sensitized STS 316S stainless steel decreased a little at an area ratio 1:1 but increased at an area ratio 30:1. It is considered to be due to that area ratio affects galvanic corrosion more in less corrosion resistant alloys. However, in case of STS 316 and Ti, galvanic coupling reduces corrosion rate by the formation of passive film.

• 전기화학회지
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• 제10권3호
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• pp.179-183
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• 2007

The corrosion behavior of metal covered with mortar under a wet-dry cyclic condition were investigated to apply for the measurement of corrosion rates of reinforcing steel in concrete structure. The carbon steel in mortar having t=3 mm cover thickness was exposed to the alternate condition of 6 h immersion in chloride containing solution and 18 h drying at $25^{\circ}C$ and 50%RH. The electrochemical phenomena of a carbon steel and mortar interface was explained by an equivalent circuit consisting of a solution resistance, a charge transfer resistance and a CPE(Constant Phase Element). The corrosion rates were monitored continuously during exposure using an AC impedance technique. Simultaneously, the current distribution over the working electrode during impedance measurement was analyzed from the phase shift, $\theta$, in an intermediate frequency. The result showed that corrosion rate monitoring using an AC impedance method is suitable under the given exposure conditions even during the drying period when the metal is covered with the wetted mortar.