• Title/Summary/Keyword: carbon content,

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Ductile-to-Brittle Transition Behavior of Two Austenitic Fe-18Cr-10Mn Alloys with the Combined Addition of Nitrogen and Carbon (질소와 탄소가 복합 첨가된 두 오스테나이트계 Fe-18Cr-10Mn 합금의 연성-취성 천이 거동)

  • Lee, S.Y.;Kim, B.Y.;Hwang, B.
    • Journal of the Korean Society for Heat Treatment
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    • v.28 no.1
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    • pp.1-6
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    • 2015
  • The ductile-to-brittle transition behavior of two austenitic Fe-18Cr-10Mn alloys with the combined addition of nitrogen and carbon was investigated in this study. The alloys exhibited a ductile-to-brittle transition behavior because of unusual brittle fracture at low temperatures unlike conventional austenitic alloys. The alloy with higher carbon content had higher yield and tensile strengths than that with lower carbon content due to the solid solution strengthening effect resulting from carbon addition. However, the increase in carbon content promoted the occurrence of intergranular fracture, and thus deteriorated the impact toughness. In order to develop successfully the austenitic Fe-18Cr-10Mn alloys with the excellent combination of strength and toughness in the future, therefore, more systematic studies are required to find the appropriate amount and ratio of nitrogen and carbon.

Synthetic Properties of Fe/MgO Catalyst on Characteristics of Carbon Nanotubes Prepared by Catalytic Chemical Vapor Deposition

  • Jung, Sung-Sil;Lee, Dae-Yeol;Chung, Won-Sub;Park, Ik-Min
    • Carbon letters
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    • v.5 no.3
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    • pp.133-141
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    • 2004
  • The synthetic behaviors of carbon nanotubes (CNTs) by Fe/MgO catalysts were investigated in 0~90 wt.% range of MgO mixture ratios by catalytic chemical vapor deposition (CCVD) process. The CNTs were synthesized with 40 minutes of synthetic time, and 923 K of synthetic temperature using 0.1 L/min of ethylene gas and 1.0 L/min of hydrogen gas as synthetic and carrier gas, respectively. As the increase of synthetic temperatures and times, the diameters of CNTs become thicker. The carbon yield showed in a parabolic curve as MgO content increased and the maximum carbon yield was obtained at 30 wt.% of MgO. There were no obvious changes in the diameters of CNTs respect to the change of MgO content. Fe/MgO CNTs showed good crystalinity by High Resolution Transmission Electron microscope (HR-TEM) analysis. The behaviors of Fe/MgO CNTs have a tendency of depending on synthetic time and temperature rather than MgO content.

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Formation and Dispersion Measurement in Semiconducting Materials Using the SEM and AFM (SEM과 AFM을 사용한 반도전 재료 내 카본블랙의 형태 및 분산성 측정)

  • Lee, Kyoung-Yong;Yang, Jong-Seok;Nam, Jong-Chul;Choi, Yong-Sung;Park, Dong-Ha;Park, Dae-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.236-237
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    • 2005
  • To measure surface roughness and smoothness of semiconducting materials in power cable, we have investigated the formation and growth process of carbon black showed by changing the content of carbon black. The specimens were primarily kneaded in material samples of pellet form for 5 minutes on rollers ranging between 70[$^{\circ}C$] and 100[$^{\circ}C$]. Then they were produced as sheets after pressing for 20 minutes at 180[$^{\circ}C$] with a pressure of 200[kg/cm]. The contents of conductive carbon black were the variable, and their contents were 20, 30 and 40[wt%], respectively. The surface roughness and smoothness of specimens were measured by SEM and AFM. From SEM experimental result, carbon black in specimens formed matrix as a particles. Also we showed growth process of carbon black according to an increment of the content of carbon black. From AFM experimental result, surface roughness of specimens decreased according to an increment of the content of carbon black.

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Quantitative Evaluation of Non-Carbon Content in the Single Wall Carbon Nanotube Soot using Thermogravimetric Analysis

  • Han, J.H.;An, K.H.;Lee, N.S.;Goak, J.C.;Jeong, M.S.;Choi, Y.C.;Oh, K.H.;Kim, K.K.;Lee, Y.H.
    • Carbon letters
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    • v.10 no.1
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    • pp.5-8
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    • 2009
  • We measured the non-carbon content of single-walled carbon nanotubes (SWCNTs) in SWCNT soot using thermogravimetric analysis. The weight increased percentage by the oxidation of metal in the raw soot is well obtained by TGA graph which was confirmed with ICP-AES, XRD, and XPS. This work will be very useful for the purity precise evaluation of SWCNT with UN-vis-NIR spectroscopy.

Analysis of Carbon Emissions from Combustion of Three Arbor in Youngdong Area (영동지역 교목 3수종 생엽의 연소에 따른 탄소배출량 분석)

  • Park, Young-Ju;Lee, Hae-Pyeong
    • Journal of the Korean Society of Safety
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    • v.25 no.6
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    • pp.210-215
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    • 2010
  • In this study, when the forest fire occurred, in order to estimate greenhouse gas emissions, tree glow in Gangwon Youndong area, Juglans mandshurica, Alnus japonica, Acer palmatum of carbon dioxide and carbon monoxide emissions were about. Water content were measured before the experiment, Juglans mandshurica 196.24%, Alnus japonica 169.17% Acer palmatum 210.10% moisture content showed a big difference, Living leaves of Acer palmatum were a lot of moisture. Also, 50g weight of carbon dioxide on the Juglans mandshurica 53.3644g, Alnus japonica 49.4256g, was released about Acer palmatum 51.3394g, Juglans mandshurica living leaves were the most carbon dioxide emissions. Carbon monoxide emissions result, About weight 50g Juglans mandshurica 1.5329g, Alnus japonica 1.7189g, 2.5002g about Acer palmatum was released, Acer palmatum living leaves were the most carbon monoxide emissions.

Blowout of Rubber Vulcanizates: Influences of Cure Systems, Content of Carbon Black, and Organic Addities

  • 최성신;김익식
    • Bulletin of the Korean Chemical Society
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    • v.19 no.2
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    • pp.174-178
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    • 1998
  • Blowout of NR and SBR vulcanizates was studied using a microwave oven. Rubber vulcanizates with different contents of carbon black (0, 30, 50, 70 phr) and various cure systems (conventional, semi-EV, and EV) were prepared. Unfilled rubber vulcanizates did not exploded by irradiation of microwave, while carbon black-filled ones exploded within 10 min. A blowout time of the carbon black-filled rubber vulcanizate decreases with an increase of the content of carbon black in the vulcanizate. A blowout temperature of the organic additive-extracted vulcanizate is higher than that of the not-extracted one, but the extracted vulcanizate blows out faster than the not-extracted one. A blowout temperature of the overcured vulcanizate is higher than that of the undercured one with the same cure system. Temperatures of unfilled SBR vulcanizates heated by the microwave irradiation are lower than those of unfilled NR ones. The carbon black-filled SBR vulcanizates blow out at higher temperatures than the carbon black-filled NR ones. Blowout times of the carbon black-filled SBR vulcanizates are longer than those of the carbon black-filled NR ones.

Effect of High Ash Coal on Unburned Carbon and NOx Emission (미연분 및 NOx배출 특성에 대한 고회분탄의 영향 연구)

  • Kim, Sangin;Lee, Byunghwa;Lim, Ho;An, Keju;Kim, Mancheol;Song, Juhun;Jeon, Chunghwan
    • 한국연소학회:학술대회논문집
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    • 2012.04a
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    • pp.341-342
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    • 2012
  • The effect of high ash coal which has relatively high ash content and low combustibility on unburned carbon and NOx emission was experimentally investigated at several excess air ratio and particle size conditions of four coals containing different ash content in a drop tube furnace. Flue gas was measured by Gas analyzer in order to figure out unburned carbon characteristics. The results show that the higher content of ash makes the higher unburned carbon rate, subsequent changes in NOx emission characteristics was investigated.

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Effect of Carbon Equivalent on the Fading Behavior of Hypoeutectic Ductile Cast Iron (아공정 구상흑연주철의 Fading 거동에 미치는 탄소당량의 영향)

  • Park, Hun-Berm;Park, Sang-Jun
    • Journal of Korea Foundry Society
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    • v.24 no.5
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    • pp.290-294
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    • 2004
  • The effect of carbon equivalent on the fading behavior of hypoeutectic ductile cast iron was investigated. The carbon content was slightly increased right after graphite spheroidization treatment and remained almost constant with holding at $1,490^{\circ}C$ after 4 minute. The residual magnesium content was decreased slowly with holding. The empirical equation expressing the relationship between this and holding time was proposed ; $C=C_o-P{\times}t$. The proportionality constant, P, was inversely proportional to carbon content.

Influence of Filler Composition Ratio on Properties of Both Silica and Carbon Black-Filled Styrene-Butadiene Rubber Compounds (실리카와 카본블랙으로 보강된 SBR 고무 배합물의 특성에 보강제 조성비가 미치는 영향)

  • Choi, Sung-Seen
    • Elastomers and Composites
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    • v.36 no.1
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    • pp.37-43
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    • 2001
  • Influence of the filler composition ratio on cure characteristics and bound rubber content of the compounds and on physical properties of the vulcanizates were studied using both silica and carbon black-filled styrene-butadiene rubber (SBR) compounds with the total filler content of 80.0 phr. The bound rubber content increased slightly with increase of the silica content ratio. The viscosity also increased with increasing the silica content ratio, especially increased steeply after the silica content of 60.0 phr. The cure times obtained with a rheometer, t2, t40, and t90, are increased by increasing the silica content ratio and the cure rate decreased. The delta torque increased with the increased silica content ratio. Variation or the modulus with the silica content ratio showed a decreased trend though the delta torque increased. The tan ${\delta}$ at $60^{\circ}C$ decreased with increased of the silica content ratio.

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The Relationship between the Estimated Water Content and Water Soluble Organic Carbon in PM10 at Seoul, Korea (서울시 PM10 내의 수용성 유기탄소와 수분함량과의 상관성 분석)

  • Lee, Seung Ha;Kim, Yong Pyo;Lee, Ji Yi;Lee, Seung Muk
    • Journal of Korean Society for Atmospheric Environment
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    • v.33 no.1
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    • pp.64-74
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    • 2017
  • In this study, we have analyzed relationship between the measured Water Soluble Organic Carbon (WSOC) concentrations and the estimated aerosol water content of $PM_{10}$ (particulate matter with an aerodynamic diameter of less than or equal to $10{\mu}m$) for the period between September 2006 and August 2007 at Seoul, Korea. Water content of $PM_{10}$ was estimated by using a gas/particle equilibrium model, Simulating composition of Atmospheric Particles at Equilibrium 2 (SCAPE2). The WSOC concentrations showed low correlation with Elemental Carbon (EC), but Water Insoluble Organic Carbon (WISOC) were highly correlated with EC. It seemed that hydrophilic groups were produced by secondary formation rather than primary formation. As with the previous studies, WSOC showed good correlation with secondary ions ($NO_3{^-}$, $SO_4{^{2-}}$, $NH_4{^+}$), especially WSOC was highly correlated with $NO_3{^-}$ that is a secondary ion formed by photochemical oxidation from more local sources than $SO_4{^{2-}}$. No apparent correlation between the measured WSOC and estimated water content was observed. However, WSOC showed good correlation with estimated water content when it was assumed that relative humidity was higher than the deliquescence relative humidity of the system. In conclusion, WSOC is correlated with water content by hygroscopic ions and it is expected that nitrate play an important role among the water content and WSOC.