• Title/Summary/Keyword: carbon concentration mechanisms

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Carbon Stable Isotope Ratios of Phytoplankton and Benthic Diatoms in Lake Katanuma with Reference to Those of Other Lakes

  • Kikuchi, Eisuke;Takagi, Shigeto;Shikano, Shuichi;Hideyuki, Doi
    • Korean Journal of Ecology and Environment
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    • v.38 no.spc
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    • pp.8-11
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    • 2005
  • Carbon stable isotope ratios of producers varied in lake ecosystems. In tile present study, we tried to estimate the seasonal variations of carbon isotope ratios of phytoplankton and benthic diatoms in a strongly acidic lake ecosystem. Lake Katanuma is a volcanic, strongly acidic lake (average pH of 2.2), located in Miyagi, Japan. Only two algal species dominate in Lake Katanuma; Pinnularia acidojaponica as a benthic diatom, and Chlamydomonas acidophila as a green alga. Carbon isotope values of P. acidojaponica varied seasonally, while those of particulate organic matter, which were mainly composed of C. acidophila remained fairly stable. The differences suggested that $CO_2$ gas was more frequently limited for P. acidojaponica than C. acidophila, since high density patches of benthic diatoms were sometimes observed on the lake sediment. Generally, carbon concentration mechanisms (CCMs)of microalgae can fix bicarbonate in lakes, and affect the carbon isotope values of microalgae. While, in Lake Katanuma, CCMs of the microalgae may scarcely function because of high $CO_2$ gas concentration and low pH. This is the reason for low seasonal amplitude of carbon isotope values of phytoplankton relative to those in other lakes.

Investigation of field emission mechanism of undoped polycrystalline diamond films (도핑되지 않은 다결정 다이아몬드 박막의 전계방출기구 조사)

  • 심재엽;지응준;송기문;백홍구
    • Journal of the Korean Vacuum Society
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    • v.8 no.4A
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    • pp.417-424
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    • 1999
  • In order to investigate field emission mechanism of undoped polycrystalline diamond films, diamond films with different structural properties were deposited by varying positive substrate bias and/or $CH_4$ concentration. When increasing $CH_4$ concentration and positive substrate bias voltage, nondiamond carbon content in diamond films increased. Increase of nondiamond carbon content with increasing substrate voltage is ascribed to increase of substrate and excess generation of $CH_n$ radicals. Field emission properties of undoped polycrystalline diamond films ere significantly enhanced with increasing nondiamond carbon content. For diamond films with a small amount of nondiamond carbon, electrons are emitted through diamond surface while for the films with a large amount of nondiamond carbon, electron emission occurs through diamond bulk as well as surface. From this study, depending on nondiamond carbon content two field emission mechanisms were suggested.

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Influence of CO2 concentration on carbon concentrating mechanisms in cyanobacteria and green algae: a proteomic approach

  • Ramanan, Rishiram;Vinayagamoorthy, Nadimuthu;Sivanesan, Saravana Devi;Kannan, Krishnamurthi;Chakrabarti, Tapan
    • ALGAE
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    • v.27 no.4
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    • pp.295-301
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    • 2012
  • Carbon concentrating mechanisms play a vital role in photosynthesis in microalgae and cyanobacteria especially in the proper functioning of Rubisco and assimilation of carbon via the Calvin cycle. This study evaluates the role of carbon dioxide on carbon concentrating mechanism (CCM) in a cynaobacteria, Spirulina platensis and a microalga, Chlorella sp. 786. The study organisms were grown in both atmospheric (control sample, 0.035%) and high (exposed sample, 10%) $CO_2$ concentrations. Second dimension (2D) electrophoresis revealed a huge difference in the protein profiles of both organisms suggesting the induction of CCM related proteins in the sample maintained at atmospheric $CO_2$ concentration and the repression of CCM related proteins in the sample maintained at 10% $CO_2$. Liquid chromatography-mass spectroscopy analysis revealed the presence of two important $C_i$ transporter proteins in the control sample of S. platensis, namely ferredoxin-$NADP^+$ reductase and ATP binding cassette (ABC) transport system protein. These proteins were only expressed in the control sample and were downregulated or not expressed at all in the exposed sample. Consequently, this study conclusively proves that CCMs are only inducted at low $CO_2$ concentrations and are not functional at high $CO_2$ concentration.

Analysis of Sensing Mechanisms in a Gold-Decorated SWNT Network DNA Biosensor

  • Ahn, Jinhong;Kim, Seok Hyang;Lim, Jaeheung;Ko, Jung Woo;Park, Chan Hyeong;Park, Young June
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.14 no.2
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    • pp.153-162
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    • 2014
  • We show that carbon nanotube sensors with gold particles on the single-walled carbon nanotube (SWNT) network operate as Schottky barrier transistors, in which transistor action occurs primarily by varying the resistance of Au-SWNT junction rather than the channel conductance modulation. Transistor characteristics are calculated for the statistically simplified geometries, and the sensing mechanisms are analyzed by comparing the simulation results of the MOSFET model and Schottky junction model with the experimental data. We demonstrated that the semiconductor MOSFET effect cannot explain the experimental phenomena such as the very low limit of detection (LOD) and the logarithmic dependence of sensitivity to the DNA concentration. By building an asymmetric concentric-electrode model which consists of serially-connected segments of CNTFETs and Schottky diodes, we found that for a proper explanation of the experimental data, the work function shifts should be ~ 0.1 eV for 100 pM DNA concentration and ~ 0.4 eV for $100{\mu}M$.

Effects of Non-Woven Tissue on the Mechanical Behavior of Angle-Ply Laminates (부직포가 예각 적층판의 기계적 거동에 미치는 효과)

  • 정성균
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.10 no.6
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    • pp.109-115
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    • 2001
  • This paper investigates the mechanical characteristics of angle-ply laminates with non-woven carbon tissue. The lami- nates were made by inserting non-woven carbon tissue at the interface. Specimens were rounded near the tabs by grinding and polishing to reduce the stress concentration. Cyclic loads were applied to the specimens and the stress and fatigue life curves were obtained. The matrix crack density was also evaluated to check the effects of non-woven carbon tissue on the fracture resistance of composite laminates. C-Sean technique was used to evaluate the delamination, and SEM was used to understand the fracture mechanisms of the laminates. Experimental results show that the fatigue strength and life of composite laminates were increased by inserting non- woven carbon tissues. The results also show that the matrix crack density and delamination area were reduced by inserting non-woven carbon tissues.

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Selective Adsorption of Uranium Ionsin High Concentration of Chemical Salts

  • Jung, Chong-Hun;Won, Hui-Jun;Kim, Gye-Nam;Park, Wangkyu;Wonzin Oh
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.119-120
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    • 2004
  • A study on the selective adsorption of uranium(VI) from a high concentration of chemical salts has tern peformed to investigate the uranium removal mechanisms and the application conditions of the electrosorption technique using the activated carbon fiber(ACF) as a good conductive electrosorption adsorbent. Electrosorption test were carried out using an electrochemical cell.(omitted)

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Adsorption of p-Nitrophenol by Surface Modified Carbons from Aqueous Solution

  • Goyal, Meenakshi
    • Carbon letters
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    • v.5 no.2
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    • pp.55-61
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    • 2004
  • Adsorption isotherms of p-nitrophenol from its aqueous solutions on two samples of activated carbon fibres and two samples of granulated activated carbons have been determined in the concentration range 40~800 mg/L (ppm). The surface of these carbons was modified by oxidation with nitric acid and oxygen gas, and by degassing the carbon surface under vacuum at temperatures of $400^{\circ}C$, $650^{\circ}C$ and $950^{\circ}C$. The oxidation of carbon enhances the amount of carbon-oxygen surface groups, while degassing decreases the amount of these surface groups. The adsorption of p-nitrophenol does not depend upon the surface area alone but appears to be influenced by the presence of oxygen groups on the carbon surface. The adsorption decreases on oxidation while the degassing of the carbon surface enhances the adsorption. The decrease in adsorption depends upon the strength of the oxidative treatment being much larger in case of the oxidation with nitric acid, while the decrease in adsorption on degassing depends upon the temperature of degassing. The results show that while the presence of acidic surface groups which are evolved as $CO_2$ on degassing suppress the adsorption of p-nitrophenol, the presence of non acidic surface groups which are evolved as CO on degassing tend to enhance the adsorption. Suitable mechanisms compatible with the results have been presented.

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Numerical Simulation of Ozone Concentration using the Local Wind Model in Pusan Coastal Area, Korea (부산연안역에서 국지풍모델을 이용한 오존농도의 수치모의)

  • Jeon, Byung-Il;kim, Yoo-Keun;Lee, Hwa-Woon
    • Journal of Environmental Science International
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    • v.6 no.4
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    • pp.335-350
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    • 1997
  • Numerical simulations of photochemical air pollution (CBM: Carbon-Bond Mechanisms under a theoretical three-dimensional local wind system are carried to clarify the fundamental characteristics of the effects of local wind on photochemical air pollution. According to the AWS data of Pusan coastal area and KMA, the surface wind of Pusan during summertime showed a very remarkable land and sea breeze circulation. The ozone concentration distribution using local wind model showed that high ozone concentration zone near coastal area moved toward inland In the afternoon. This change implies a sea breeze Increases the ozone concentration, but a land breeze decreases it in Pusan coastal area.

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Adsorption of Phenols onto Chemically-Activated Carbons Developed from Wild Cherry Stones

  • Alaya, M.N.;Youssef, A.M.;Karman, M.;Abd El-Aal, H.E.
    • Carbon letters
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    • v.7 no.3
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    • pp.188-195
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    • 2006
  • Phosphoric acid-activated carbon WP's and zinc chloride-activated carbons WZ's were developed from wild cherry stones. The textural properties of the activated carbons were determined from nitrogen adsorption data at 77 K and the chemistry of the carbon surface, i.e. the surface carbon-oxygen groups (type and amount) was determined from the base and acid neutralization capacities (Boehm method). The adsorption of phenol, p-nitrophenol, p-chlorophenol, dinitrophenol and dichlorophenol was followed at 298 K. The activated carbons obtained were characterized by high surface area and large pore volumes as well as by high surface concentration of C-O groups. The investigated carbons exhibited high adsorption capacities towards phenols with these capacities increased with the increase of molecular weight and the decrease of the solubility of phenol in water. However, no general relationship could be observed between the adsorption capacities of carbons and any of their textural parameters or their surface chemistry. This may be attributed to the many factors controlling phenol adsorption and the different types and mechanisms of adsorption involved.

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Effects of Carbon Substrates on Exopolysaccharide Production by Enterobacter sp. (Enterobacter sp. 의 다당 생산에 미치는 탄소원 기질의 영향)

  • Lee Ju-Ha;Lee Shin-Young
    • KSBB Journal
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    • v.20 no.1 s.90
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    • pp.26-33
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    • 2005
  • The effects of carbon sources for exopolysaccharide production during batch cultivation of an Enterobacter sp. isolated from the composter were investigated. The highest amount of exopolysaccharide was obtained when lactose was used as carbon source. Lactose in medium was converted into glucose and galactose. Glucose was metabolized fast and was completely consumed, but about $20\%$ of lactose was accumulated as galactose. On the other hand, enzyme activity was about $350\~450$ unit with the increase of lactose concentration. Thus, it was considered that the exopolysaccharide might be produced in the course of that lactose was hydrolyzed into glucose and galactose by $\beta-galactosidase$ with respect to that enzyme activity on lactose hydrolysis was accorded to the exopolysaccharide production. When glucose and galactose were added to lactose medium, respectively, it could be considered that glucose was as a repressor and galactose was as a inducer for $\beta-galactosidase$ synthesis even though the mechanisms were not elucidated. The increase of lactose concentration was almost ineffective to the specific growth rate $(0.133\~0.151\;hr^[-1})$ but showed the difference in the biomass content. The higher carbon source concentration, the more residual sugar remained. It was assumed that the optimum lactose concentration for exopolysaccharide production was $30\~70g/L.$ On the other hand, it was considered that the nitrogen acted as growth limiting nutrients to the cell growth. In the cases of 30 and 70 g/L of the fixed carbon concentrations, the increase of the nitrogen sources concentration caused a remarkable increase within the range of $0.059\~0.225\;hr^{-1}$ and $0.141\~0.237hr^{-1}$ of the specific growth rate, respectively, while there was no significant difference in biomass.