• Fibers and Polymers
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• 제5권3호
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• pp.198-203
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• 2004

Composite films were prepared by casting the solution of polyacrylonitrile (PAN) and single wall nanotube (SWNT) in DMF subsequent to sonication. The SWNTs in the films are well dispersed as ropes with 20-30 nm thickness. Moreover, AFM surface image of the composite film displays an interwoven fibrous structure of nanotubes which may give rise to conductive passways and lead to high conductivity. The polarized Raman spectroscopy is an ideal characterization technique for identification and the orientation study of SWNT. The well-defined G-peak intensity at 1580 $cm^{-1}$shows a dependency on the draw ratio under cross-Nicol. The degree of nanotube orientation in the drawn film was measurable from the sine curve obtained by rotating the drawn film on the plane of cross-Nicol of polarized Raman microscope. The threshold loading of SWNT for electrical conductivity in PAN is found to be lower than 1 wt% in the composite film. The electrical conductivity of the SWNT/PAN composite film decreased with increasing of draw ratio due to the collapse of the interwoven fibrous network of the nanotubes with uniaxial orientation.

• 한국결정성장학회지
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• 제6권2호
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• pp.203-212
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• 1996

본 연구에서는 탄소/탄소 복합체의 내산화성을 증진시키기 위하여 CVD법에 의한 SiC 코팅과 PCS 함침법을 응용하여 실험을 행하였다. 전자현미경으로 시편의 미세구조를 관찰 한 결과 CVD법에 의해서는 표면에 SiC가 고르게 증착되었으며, 함침법에 의해서는 각 탄소 섬유의 표면에 PCS가 wetting된 후 SiC로의 전이가 잘 일어났음을 확인하였고, 이로 인하여 각 섬유들의 결합력을 증대시키고 기계적물성에 증진을 가져왔음을 확인하였다. PCS 함침된 탄소/탄소 복합체 시편은 함침되지 않은 시편에 비해 밀도는 25 %, 곡강도 값은 3.5배, 내산화성은 2.8배가 증가하는 현격한 기계적 물성이 증가함을 보였다. 이러한 증가는 CVD법에 의해 코팅된 탄소/탄소 복합체 사편보다도 우수한 기계적 성질을 나타내였다.

• Advanced Composite Materials
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• 제16권4호
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• pp.361-376
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• 2007

Disposing of conventional fiber-reinforced polymers (FRPs) poses an environmentally challenging problem. Disposal of FRPs by combustion discharges carbon dioxide in the air because the resin of FRPs is made of fossil fuel. When they are disposed of in the ground, FRPs remain semipermanently without decomposing. In response to these problems, green composites are now being developed and are extensively studied as a material that produces a lower environmental burden. In this paper, green composites using kenaf fiber yarn bundles and PLA (poly(lactic acid)) are fabricated and their tensile properties are evaluated in the experiment. The tensile Young's modulus of all of the laminations is larger than that of PLA alone and the tensile strength of some laminations is larger than that of PLA alone. In particular, the value of UD composite of $0^{\circ$ shows double the tensile strength of PLA alone. Furthermore, the molding conditions for fabricating with a hot press are investigated and the heat resistant tensile properties of green composites are also reported.

• Bulletin of the Korean Chemical Society
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• 제32권7호
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• pp.2193-2198
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• 2011

We prepared polycatenar 1H-imidazole amphiphiles having a structure in which a 1H-imidazole head was connected through a benzene ring to a pheny group having two or three oligo(ethylene glycol) chains and studied their supramolecular assembly by fluorescence spectroscopy, transmission electron microscopy (TEM) and atomic force microscopy (AFM). When the aqueous solutions of the amphiphiles ($5{\times}10^{-5}M{\sim}10^{-3}M$) were deposited onto a carbon-coated copper grid and dried, twisted structures with diameters of ~200-300 nm were imaged by TEM and AFM. We presume that the structures comprised a chain of the amphiphile dimers formed via successive hydrogen bonding between the 1H of the imidazole group and 3N of the neighboring one. In a solution of pH 4, entangled fibers with diameters of several nanometers were observed by TEM. In a pH 10 solution, film-like aggregates formed exclusively. The 1H-imidazole amphiphiles hydrolyzed tetraethoxysilane to induce gelation to form fibrous and spherical silica structures at neutral pH in aqueous solutions. No silica was formed when imidazole was used instead of the amphiphiles, suggesting that the selfassembled aggregates of the amphiphiles were responsible for the gelation.

• 대한조선학회논문집
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• 제54권5호
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• pp.415-420
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• 2017

Insulation systems in Liquefied Natural Gas Carriers (LNGC) are vulnerable to sloshing impact and fatigue loads because of waves. If gas leaks into the primary barrier, the Flexible Secondary Barrier (FSB) prevents the leakage of gas in this system. Fatigue strength of the FSB largely depends on the behavior of composite materials. In this study, a new system is applied to the FSB using aramid fiber to improve the fatigue strength of the secondary barrier, with the intention of replacing conventional E-glass fibers. The manufacturing method involved varying the ratio of the aramid fiber to the E-glass fiber for optimum design of the FSB. The fatigue tests results of the secondary barrier using aramid fiber were superior to that using E-glass fiber. The statistical analysis is performed to obtain the fatigue test results and estimate the probability of failure as well as the design guideline of LNGC secondary barriers.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2009년도 하계학술발표대회 논문집
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• pp.899-903
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• 2009

Recently, research and development of the linear compressor are being active. The reason is that the one has not only higher efficiency than reciprocating type, but also lower noise. But because the dicharge valve of linear compressor is operated in high pressure and temperature circumstance, it is important to prevent leakeage. In this paper three other plastic reinforced composite materials were used. Those are TPI, PEEK and PEK which were containing other volume and kind of carbon fibers. First, for assessing mechanical properties, we measured the hardness and the heating property of the trst sepecimen by the microvickers hardness tester and the differential scanning calorimeter respectively. Finally, through FALEX tester, we could know the characteristics of the wear proving the results of before-conducted experiments.

• 한국소음진동공학회논문집
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• 제22권7호
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• pp.626-633
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• 2012

In this paper, sound pressure sensitivity of the fiber optic acoustic sensor according to sensor direction and mandrel material were investigated experimentally. Three different directions were selected as stand, lay, and hole. Hollow cylinder type mandrel dimension is 30 mm in outer diameter, 45 mm in length, and 2 mm in thickness, and about 50 m optical fibers were wounded on the surface of the mandrel. Non-directional sound speaker was used as a sound source. Sagnac interferometer and single mode fiber, a laser with 1,550 nm in wavelength, $2{\times}2$ coupler were used. Based on the experimental results, lay direction's sensitivity is the highest in the frequency range of 2 kHz~4 kHz. 'PTFE+carbon' material is more sensitive than PTFE in the frequency range of 5 kHz~20 kHz. Sound pressure detection sensitivity depends on the mandrel direction and material under certain frequency.

• 한국기계가공학회지
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• 제16권1호
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• pp.134-140
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• 2017

CFRP has many industrial applications due to its low weight and high strength properties. CFRP is a composite material composed of carbon fibers embedded in a polymer matrix; it provides excellent resistance to fatigue wear, corrosion, and breakage due to fatigue. It is increasingly demanded in aircraft, automotive, and medical industries due to its superior properties to aluminum alloys, which were once considered the most suitable for specific applications. The basic machining methods of CFRP are drilling and route milling. However, in the case of drilling, the delamination of each layer, uncut fiber, resin burning, spalling, and exit burrs are barriers to successful application. This paper investigates the occurrence of exit burrs when drilling holes with ultrasonic vibration. Depending on design parameters such as the point angle, the characteristics of hole drilling were identified and appropriate machining conditions were considered.

• 한국기계가공학회지
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• 제16권4호
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• pp.97-103
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• 2017

The objective of this study is to develop and commercialize an on-board fuel storage system for CNG vehicles. A type 4 vessel is made of resin-impregnated continuous filament windings on a polyamide (PA6) liner. In particular, this study localized the PA6 liner's fabrication and development. To analyze the filament winding, a specimen test was performed, and the results were verified values obtained using finite element analysis. In this study, the filament winding and fibers were optimized for a 207 bar composite cylinder in a compressed natural gas vehicle.

• Fisheries and Aquatic Sciences
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• 제11권3호
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• pp.149-158
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• 2008

Labyrinthulids are unicellular heterotrophic marine microalgae. Two labyrinthulid strains, L4 and L75, which produce generous amounts of polyunsaturated fatty acids(PUFAs), were isolated from leaves floating in the coastal areas of Quang Ninh province, Vietnam, and Fukuoka Prefecture, Japan, respectively. Both strains had spindle-shaped cells surrounded by ectoplasmic networks. Numerous oil bodies were observed in each cell, mostly in the vicinity of cell membranes. When soybean oil or soybean lecithin was used as a carbon source with peptone as a nitrogen source, the proportion of PUFAs reached 25-30% and 50-56% for L4 and L75, respectively. After 14 days of growth at $25^{\circ}C$, L4 produced 0.3 mg PUFAs/g-agar in PYA-SBO medium and 0.6 mg PUFAs/g-agar in PYA-SBL medium. In comparison, L75 produced 0.2 mg PUFAs/g-agar in both types of media. The differences between the two strains included changes in cellular morphology and the capacity for attaching tightly to fibers when cultured in liquid PYA medium containing 2% SBL. In addition, when the strains were grown under the same conditions, L4 had a higher growth rate and produced more PUFAs than L75.