• Title/Summary/Keyword: carbon Fibers

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Development of Alkali Stimulant-Based Reinforced Grouting Material from Blast Furnace Slag Powder (고로슬래그 미분말을 이용한 알칼리자극제 기반의 보강그라우트재 개발)

  • Seo, Hyeok;Jeong, Sugeun;Kim, Daehyeon
    • The Journal of Engineering Geology
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    • v.31 no.1
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    • pp.67-81
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    • 2021
  • Grouting is used for reinforcement and waterproofing of soft ground to increase its bearing capacity, reduce the impacts of rising or lowering groundwater levels, and reduce subsidence due to vibration and general causes. This study investigated the enhancement of grout strength and hardening time by the addition of reinforcing fibers, and the development of non-cement grouting materials from blast furnace slag. An experiment was performed to measure the increase in grout strength resulting from the addition of 0.5% increments of aramid and carbon reinforcing fibers. The results show that the uniaxial compressive strength of grout increases with increasing content of reinforcing fiber. Comparison of three admixtures of finely powdered blast furnace slag and 10%, 20%, and 30% calcium hydroxide stimulating agent showed that the uniaxial compressive strength of the mixture increases with increasing content of alkaline stimulant; however, the strength was lower than for 100% pure cement. The reaction of calcium hydroxide with blast furnace slag powder, which increases the strength of the grout, is more effective if injected as a solution rather than a powder.

Manufacture of Recycled PET E-Textile by Plasma Surface Modification and CNT Dip-Coating (플라즈마 표면 개질과 CNT 함침공정을 통한 고전도성의 재생PET사 전자섬유)

  • Jun-hyeok Jang;Sang-un Kim;Joo-Yong Kim
    • Science of Emotion and Sensibility
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    • v.26 no.1
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    • pp.79-86
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    • 2023
  • This study aims to create a highly conductive E-textile made by recycling PET with a Dip-coating process. PET fiber with hydrophobic properties is characterized by the difficulty in imparting great conductivity when both Virgin and Recycled are made of electronic fibers through a Dip-coating process. To advance the effectiveness of the Dip-coating process, a sample made of recycled PET was surface modified for 50 w 5 minutes and 10 minutes employing a Covance-2mprfq model from FEMTO SCIENCE. After that, the sample was immersed in an SWCNT dispersion (.1 wt%, Carbon Co., Ltd.) for 5 minutes, and then dip coating was conducted to allow the solution to permeate well into the sample through a padder (DAELIM lab). After the procedure was completed, the resistance measurement was measured with a multimeter at both ends and then accurately remeasured with a wider electrode. As a result of this contemplation, it was affirmed that great conductivity might be given through an impregnation process through the plasma surface modification. When the surface modification was performed for 10 minutes, the resistance was reduced by up to 2.880 times. Dependent on the results of this research, E-fibers employed in the smart wearable sector can also be made of recycled materials, improving smart wearable products that can save oil resources and reduce carbon emissions.

Single Carbon Fiber/Acid-Treated CNT-Epoxy Composites by Electro-Micromechanical Technique and Wettability Test for Dispersion and Self-Sensing (젖음성 시험과 전기-미세역학 시험법과 통한 단 카본섬유/산처리된 CNT-에폭시 나노복합재료의 분산과 자체-감지능)

  • Jang, Jung-Hoon;Wang, Zuo-Jia;GnidaKouong, Joel;Gu, Ga-Young;Park, Joung-Man;Lee, Woo-Il;Park, Jong-Kyoo
    • Journal of Adhesion and Interface
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    • v.10 no.2
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    • pp.90-97
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    • 2009
  • Dispersion and self-sensing evaluation for single-carbon fiber reinforced in three different acid-treated CNT-epoxy nanocomposites were investigated by electro-micromechanical techniques and wettability tests. Self-sensing based on contact resistivity exhibited more noise for single carbon fiber/acid-treated CNT-epoxy composites than it did for untreated CNT. However, the apparent modulus was higher the acid treated case than the untreated case which is attributed to better stress transfer. The interfacial shear strength (IFSS) between carbon fibers and the CNT-epoxy was lower than that between carbon fiber and neat epoxy due to the increased viscosity associated with the addition of the CNT. The CNT-epoxy nanocomposite exhibited more hydrophobicity than did neat epoxy. Change in the thermodynamic work of adhesion was consistent with changes in the IFSS but disproportional to that of the apparent modulus. The optimum condition of acid treatment on the need can be obtained instead of the maximum condition.

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Electrodeposition onto the Surface of Carbon Fiber and its Application to Composites(I) - Electrodeposition of MVEMA and EMA (탄소섬유 표면에의 고분자 전착과 복합재료 물성(I) - MVEMA와 EMA의 전착 -)

  • Kim, Minyoung;Kim, Jihong;Kim, Wonho;Kim, Booung;Hwang, Byungsun;Choi, Youngsun
    • Applied Chemistry for Engineering
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    • v.9 no.6
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    • pp.894-900
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    • 1998
  • An interphase between carbon fiber and epoxy matrix was introduced to increase impact strength of carbon fiber reinforced composites (CFRC) without sacrificing the interlaminar shear strength. Flexible polymers, I. e., MVEMA (poly(methyl vinyl ether-co-maleic anhydride)) and EMA(poly(ethylene-co-maleic anhydride)), which have reactive functional groups were considered as interphase materials. Weight hain of MVEMA and EMA onto the surface of carbon fibers was evaluated by changing the parameters of electrodeposition process. Electrodeposition mechanism of polymers which have anhydride functional group was identified by IR spectroscopy, that is, the generation of $RCOO^-$ functional group by the attack of hydroxide anion in the basic solution was observed. The weight gain was increased by increasing concentration of polymers, current density, and electrodeposition time. However the excess generation of oxygen gas decreased the weight gain by removing the deposited polymers. Washing in the running water easily removed the deposited polymers which are on the fiber surface without bonding, as a results, only 0.5 wt% of deposited polymers are remained.

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$CO_2$ Sensing Characteristics of Carbon-nanofibers Based on Effects of Porosity and Amine Functional Group (다공성 및 아민 작용기에 따른 탄소나노섬유의 $CO_2$ 감응특성)

  • Kim, Jong Gu;Kang, Seok Chang;Shin, Eunjeong;Kim, Da Young;Lee, Jin Hee;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.23 no.1
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    • pp.47-52
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    • 2012
  • Porous carbon nanofibers were prepared as a gas sensor electrode to study the $CO_2$ sensing property based on effects of porosity and introduced amine functional groups. Electrospun fibers were obtained by using electrospinning method with polyacrylonitrile precursor and they were treated by the thermal treatment and chemical activation. Amine functional groups were introduced by the liquid state treatment using diethylenetriamine. The specific surface area increased up to $2000m^2/g$ by the chemical activation. The Introduced amine functional group was identified using FT-IR spectroscopy. $CO_2$ gas sensing property was improved as four folds via introduced amine functional groups on the activated carbon nanofiber. In conclusion, the gas sensing property was improved based on the developed porosity by the chemical activation and the chemical attraction of $CO_2$ gas by introduced functional groups.

Reinforcement, Thermal and Fire Retardant Improvement of Phenolic Composites by Surface Treatment of CFRP Chip (CFRP Chip 표면처리에 따른 페놀복합재료의 강화, 내열성 및 난연성 향상)

  • Kwon, Dong-Jun;Wang, Zuo-Jia;Gu, Ga-Young;Park, Joung-Man
    • Journal of Adhesion and Interface
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    • v.13 no.2
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    • pp.58-63
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    • 2012
  • CFRP chip is the byproduct from carbon fiber reinforced plastic (CFRP) processing. CFRP chip is not simply a waste mainly composed of fine carbon fiber and epoxy resin. CFRP chip keeps matrix to maximize their reinforcing effect. To obtain a uniform length of carbon fiber in CFRP chip, chip was chopped ina mortar. CFRP chip should be purified to get better interface adhesion. Epoxy resin on the carbon fiber was removed by $H_2O_2$ surface etching treatment. Optimal dispersion and fabrication conditions of CFRP chip embedded in phenolic resin were determined by thermal stability for fire retardant applications. CFRP chip-phenolic composite exhibits better mechanical and thermal properties than neat phenolic resin. Surface condition of CFRP chip-phenolic composite was evaluated by static contact angle measurement. Contact angle of CFRP chip-phenolic composite was greater than neat phenolic due to heterogeneous condition of fine carbon fibers. From the evaluation for fire retardant (ASTM D635-06) test, thermal stability of CFRP chip-phenolic composite was found to be improved with higher concentration of CFRP chip.

The Effect of Heat Treatment Condition on the Mechanical Properties of oxi-PAN Based Carbon Fiber (Oxi-PAN 섬유를 기반으로 제조한 탄소섬유의 탄화 조건에 따른 구조 및 물성의 변화)

  • Choi, Kyeong Hun;Heo, So Jeong;Hwang, Sang-Ha;Bae, Soo Bin;Lee, Hyung Ik;Chae, Han Gi
    • Composites Research
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    • v.31 no.6
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    • pp.385-391
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    • 2018
  • In this study, carbon fibers were fabricated via carbonization of oxidized polyacrylonitrile (oxi-PAN) under different carbonization conditions. Carbonization of oxi-PAN fiber was performed under four different temperature (1300, 1400, 1500, $1600^{\circ}C$) with four different fiber tensions (14, 25, 35, 45 MPa). Effect of carbonization process on the structural development and mechanical properties of carbon fiber were characterized by single filament fiber tensile test and Raman spectroscopy. A clear correlation exists between the Raman spectrum and the tensile modulus of carbon fiber and effect of carbonization temperature on the tensile modulus showed increased tendency only at higher fiber tension (${\geq}25MPa$) while tensile strength showed decreased or random tendency. Therefore, it may be concluded that the optimization of carbonization temperature of oxi-PAN fiber also requires optimization of fiber tension.

$H_{2}S$ Removal and $CO_{2}/CH_{4}$ Separation of Ternary Mixtures Using Polyimide Hollow Fiber Membrane (폴리이미드 중공사막을 이용한 혼합기체로부터 $H_{2}S$ 제거 및 $CO_{2}/CH_{4}$ 분리에 관한 연구)

  • Park, Bo-Ryoung;Kim, Dae-Hoon;Jo, Hang-Dae;Seo, Yong-Seog;Hwang, Taek-Sung;Lee, Hyung-Keun
    • Korean Chemical Engineering Research
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    • v.49 no.2
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    • pp.250-255
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    • 2011
  • In this study, by using the polymeric membrane separation process, the $CO_{2}/CH_{4}$ separation and $H_{2}S$ removal from biogas were performed in order to $CH_{4}$ purification and enrichment for the fuel cell energy source application. Fibers were spun by dry/wet phase inversion method. The module was manufactured by fabricating fibers after surface coating with silicone elastomer. The scanning electron microscopy(SEM) studies showed that the produced fibers typically had an asymmetric structure; a dense top layer supported by a porous, sponge substructure. The permeance of $CO_{2}$ and $CO_{2}/CH_{4}$ selectivity increased with pressure and temperature. Mixture gas with increasing pressure and temperature, removal efficiency of the $CO_{2}$ and $H_{2}S$ were decreased while concentration of $CH_{4}$ was increased up to 100%. When retentate flow rate was increased with the decreasing of pressure and temperature the $CH_{4}$ recovery ratio in retentate side was increased while the $CH_{4}$ purity in retentate side was decreased.

Comparison of the Characteristics of Mix Design and the Performance of Shotcrete Used in Expressway Tunnel Construction Sites (고속도로 터널 숏크리트 현장배합 특성 및 성능 비교 연구)

  • Lee, Sangdon
    • Tunnel and Underground Space
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    • v.29 no.6
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    • pp.532-541
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    • 2019
  • Even though shotcrete is a main support for securing the stability of tunnel, the performance of shotcrete is not properly checked due to various difficulties arisen from the characteristics of materials themselves which constitute shotcrete, such as steel fibers and accelerators, and the on-site quality control. In this study, the actual conditions of shotcrete applied to expressway tunnel construction sites were tried to find out, and then some improvement was tried to derive. For this purpose, the characteristics of steel fibers and accelerators supplied to the expressway construction sites were investigated. Also, shotcrete specimens were prepared at the tunnel sites and performance tests were carried out. For steel fiber, domestic production states were investigated, and carbon content and tensile strength were measured using the steel fibers collected in the construction sites. For three types of accelerators such as aluminate, cement mineral and alkali-free, basic properties and total amount of alkali contents were analyzed. Shotcrete specimens were prepared using on-site shotcrete machine with regard to mix designs and types of accelerators. Using these specimens, uniaxial compression tests and flexural tests were performed. As the results, compressive strength, flexural strength, flexural toughness, and etc. were compared with types of acclerators and mix designs.

A Study on the Detoxification of Chrysotile and the use of High-density Extruded Cement Panel Reinforcement Fibers (백석면의 무해 섬유화 처리 방법과 고밀도 압출성형 패널 활용 연구)

  • Jang, Kyong-Pil;Kim, Tae-Hyoung;Song, Tae-Hyeob
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.2
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    • pp.223-228
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    • 2021
  • The final disposal method for asbestos building materials is to be landfilled at a designated waste landfill in accordance with the Waste Management Act. However, it is difficult to secure a domestic designated waste landfill site to landfill the entire amount of asbestos waste, which is expected to emit more than 400,000 ton/year by 2044. In this study, a detoxification treatment was performed on a ceiling tex with a density of 1.0 to 1.2g/cm3 containing 3 to 7% of chrysotile, and it was used as a reinforcing fiber for extruded panels. It was confirmed that asbestos components were detoxified through the reaction process using 30% oxalic acid and carbon dioxide, and it was recognized that these detoxifying properties were maintained even after extrusion molding. However, it was found that milling to a fiber size of less than 1mm for complete detoxification of asbestos resulted in a decrease in reinforcing performance. Therefore, in the case of using detoxified asbestos fibers in the extrusion molding process, it is considered desirable to add fibers with a length of 5mm or more to improve the reinforcing performance.