• Title/Summary/Keyword: carbon

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Densification of 4D Carbon Fiber Performs with Mesophase Pitch as Matrix-Precursor

  • Joo, Hyeok-Jong;Lee, Jae-Won
    • Carbon letters
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    • v.6 no.3
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    • pp.173-180
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    • 2005
  • In this study, AR (aromatic resin) pitch was employed as the matrix-precursor for carbon/carbon composite because it exhibits much higher coke yield than coal tar pitch. As a result, a fabrication process of carbon/carbon composites can be shortened. It has been known that the pitches may cause swolling problem during the carbonization process. In order to restrain the swelling occurrence, a small quantity of carbon black was added to the AR pitch. Due to addition of carbon black the swelling was decreased largely and the perform can be infiltrated with the AR pitch. The densification efficiency of the performs was compared with various matrix-precursors. The coke yield of matrixprecursors, the morphology and the degree of graphitization of carbon matrix were analyzed.

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The Vibration Characteristic of Carbon-Carbon Composite Material due to Tensile Loading (인장하중에 따른 Carbon/Carbon복합재의 진동특성)

  • Oh, Seung-Gyu;Kwac, Lee-Ku;Kim, Hong-Gun
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.20 no.6
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    • pp.740-744
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    • 2011
  • Carbon-carbon composite material is the reinforced carbon fiber. Because of its high strength, elasticity and the excellent heat-resisting property in high temperature, carbon-carbon composite material has been used in many fields such as aerospace and automotive industries, etc. Especially, aircraft brake discs used at aerospace can be cracked due to its fatigue and vibration under various loading condition. This research is focused on the influence of the vibration of carbon-carbon composite material by using accelerometer with impact hammer excitation. And the change of vibration mode will be known by applying tensile loading test.

Mechanical Properties and Oxidation Behaviors of Boron Oxide Implanted Carbon Fibers

  • Noh, Baek-Nam;Kim, Jung-Il;JooN, Hyeok-Jong
    • Carbon letters
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    • v.1 no.2
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    • pp.64-68
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    • 2000
  • This paper describes the mechanical properties and oxidation resistance of carbon fibers with and without additions of boron oxide additives, and describes the changes in the properties resulting from increased heat treatment temperature (HTT) of the fibers. Carbon fibers in this experiment were heat treated up to $2800^{\circ}C$ each with and without boron oxide treated on the surface of fibers. In the case of boron oxide added carbon fibers, they do not show the improvement of tensile strength and modulus compared to those of no treated carbon fibers below $2200^{\circ}C$ since they are doped substitutionally with boron above $2600^{\circ}C$, which accelerate the graphitization of carbon fibers. Boron oxide implanted carbon fibers showed high resistance to oxidation, however, when carbon fibers were heat treated below $2200^{\circ}C$, they showed almost the same trend of air oxidation.

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Formation of Isotropic Carbon Matrix in Carbon/Carbon Composites Derived from Pitch

  • Ahn, Chong-Jin;Park, In-Seo;Joo, Hyeok-Jong
    • Carbon letters
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    • v.11 no.4
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    • pp.304-310
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    • 2010
  • To manufacture a carbon/carbon composite the coal tar pitch was used as the matrix precursor and the PAN (polyacrylonitrile)-based carbon fiber was used as the reinforcing material to weave 3-directional preform. For pressure carbonization HIP equipment was used to produce a maximum temperature of $1000^{\circ}C$ and a maximum pressure of 100 MPa. The carbonization was induced by altering the dwell temperature between $250^{\circ}C$ and $420^{\circ}C$, which is an ideal temperature for the moderate growth of the mesophase nucleus that forms within the molten pitch during the pressure carbonization process. The application of high pressure during the carbonization process inhibits the mesophase growth and leads to the formation of spherical carbon particles that are approximately 30 nm in size. Most particles were spherical, but some particles were irregularly shaped. The spread of the carbon particles was larger on the surface of the carbon fiber than in the interior of the matrix pocket.

A Study on the Machining Charcterisitics of Milling of cylinderical Rod Materials for Passenger Car (승용차용 CYLINDER ROD 소재의 밀링 적삭 특성 연구)

  • 채왕석
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 1996.03a
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    • pp.143-148
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    • 1996
  • In this paper, we have studied internal quality including chemical compositions, microscopic structure and nonmetalic inclusion of test materials. We have analyzed dynamic characteristics of cutting force of milling including tensile strength value hardness etcs. Test materials are used the tempered carbon steel and the non-tempered carbon steel. The obtained results are as follows: 1.In analyzing internal quality, the tempered carbon steel have typical martensite structure and the non-tempered carbon steel have ferrite+pearlite structure. 2.Yield strength, tensile strength and hardness value are in the non-tempered carbon steel but elongation is maximum value in the tempered carbon steel. 3.Cutting force is smaller non-tempered carbon steel than tempered carbon steel when feed speed and depth of cut is constant. 4.Cutting force is smaller to the tempered carbon steel and smaller non-tempered carbon steel than tempered carbon steel when cutting conditions

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Research Status on the Carbon Nanotube Reinforced Nanocomposite (탄소나노튜브 강화 나노복합재료의 연구현황)

  • 차승일;김경태;이경호;모찬빈;홍순형
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.25-28
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    • 2003
  • Carbon nanotubes(CNTs), since their first discovery, have been considered as new promising materials in various fields of applications including field emission displays, memory devices, electrodes, NEMS constituents, hydrogen storages and reinforcements in composites due to their extra-ordinary properties. The carbon nanotube reinforced nanocomposites have attracted attention owing to their outstanding mechanical and electrical properties and are expected to overcome the limit of conventional materials. Various application areas are possible for carbon nanotube reinforced nanocomposites through the functionalization of carbon nanotubes. Carbon nanotube reinforced polymer matrix nanocomposites have been fabricated by liquid phase process including surface functionalization and dispersion of CNTs within organic solvent. In case of carbon nanotube reinforced polymer matrix nanocomposites, the mechanical strength and electrical conducting can be improved by more than an order of magnitude. The carbon nanotube reinforced polymer matrix nanocomposites can be applied to high strength polymers, conductive polymers, optical limiters and EMI materials. In spite of successful development of carbon nanotube reinforced polymer matrix nanocomposites, the researches on carbon nanotube reinforced inorganic matrix nanocomposites show limitations due to a difficulty in homogeneous distribution of carbon nanotubes within inorganic matrix. Therefore, the enhancement of carbon nanotube reinforced inorganic nanocomposites is under investigation to maximize the excellent properties of carbon nanotubes. To overcome the current limitations, novel processes, including intensive milling process, sol-gel process, in-situ process and spark plasma sintering of nanocomposite powders are being investigated. In this presentation, current research status on carbon nanotube reinforced nanocomposites with various matrices are reviewed.

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Carbon Material from Natural Sources as an Anode in Lithium Secondary Battery

  • Bhardwaj, Sunil;Sharon, Maheshwar;Ishihara, T.;Jayabhaye, Sandesh;Afre, Rakesh;Soga, T.;Sharon, Madhuri
    • Carbon letters
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    • v.8 no.4
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    • pp.285-291
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    • 2007
  • Carbon materials of various morphologies were synthesized by pyrolysis of Soap-nut seeds (Sapindus mukorossi), Jack Fruit seeds (Artocarpus heterophyllus), Date-seeds (Phoenix dactylifera), Neem seeds (Azadirachta indica), Tea leaves (Ehretia microphylla), Bamboo stem (Bambusa bambus) and Coconut fiber (Cocos nucifera), without using any catalyst. Carbon materials thus formed were characterized by SEM XRD and Raman. Carbon thus synthesized varied in size (in ${\mu}m$) but all showed highly porous morphology. These carbon materials were utilized as the anode in Lithium secondary battery. Amongst the various precursors, carbon fibers obtained from Soap-nut seeds (Sapindus mukorossi) and Bamboo stem (Bambusa bambus), even after $100^{th}$ cycles, showed the highest capacity of 130.29 mAh/g and 92.74 mAh/g respectively. Morphology, surface areas and porosity of carbon materials obtained from these precursors were analyzed to provide interpretation for their capacity to intercalate lithium. From the Raman studies it is concluded that graphitic nature of carbon materials assist in the intercalation of lithium. Size of cavity (or pore size of channels type structure) present in carbon materials were found to facilitate the intercalation of lithium.

Effect of Silicon Infiltration on the Mechanical Properties of 2D Cross-ply Carbon-Carbon Composites

  • Dhakate, S.R.;Aoki, T.;Ogasawara, T.
    • Carbon letters
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    • v.5 no.3
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    • pp.108-112
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    • 2004
  • Effect of silicon infiltration on the bend and tensile strength of 2D cross-ply carbon-carbon composites are studied. It is observed that bend strength higher than tensile strength in both types of composite is due to the different mode of fracture and loading direction. After silicon infiltrations bend and tensile strength suddenly decreases of carbon-carbon composites. This is due to the fact that, after silicon infiltration, silicon in the immediate vicinity of carbon forms the strong bond between carbon and silicon by formation silicon carbide and un-reacted silicon as free silicon. Therefore, these composites consist of three components carbon, silicon carbide and silicon. Due to mismatch between these three components secondary cracks developed and these cracks propagate from $90^{\circ}$ oriented plies to $0^{\circ}$ oriented plies by damaging the fibers (i.e., in-situ fiber damages). Hence, secondary cracks and in-situ fiber damages are responsible for degradation of mechanical properties of carbon-carbon composites after silicon infiltration which is revealed by microstructure investigation study by scanning electron microscope.

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Developing a Large-scale Carbon Offset Project Based on Forest Management - In Case of Jin-An Leading Forest Management Zone - (산림탄소상쇄 사업의 흡수량 증대를 위한 대규모 산림경영형 사업모델 개발에 관한 연구 - 진안군 선도 산림경영단지를 중심으로 -)

  • Kim, Young-hwan
    • Journal of Climate Change Research
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    • v.7 no.2
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    • pp.137-142
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    • 2016
  • To achieve large-scale carbon removals, a carbon offset project based on forest management was designed and its carbon stock change was estimated in this study. The project was designed for 874 hectares of forests in the Jin-An Leading Forest Management Zone. For estimating the carbon stock change of the project, the Korean Forest Carbon Standard and VCS (Verified Carbon Standard) methodologies were applied. Three types of management options were considered in the project : extension of rotation age, conversion to productive forests, and conversion to selective harvesting. The estimated carbon removals from the project designed in this study were $259,936tCO_2$ ($8,664tCO_2$ annually), which is 98% of estimated carbon removals from the entire 69 projects currently registered to the Forest Carbon Offset Registry in Korea. The results of this study showed that a large-scale carbon offset project based on forest management could have a huge potential to produce carbon offset credits.

Growth of nickel-catalyzed carbon nanofibers using MPCVD method and their electrical properties

  • Kim, Sung-Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.14 no.1
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    • pp.1-5
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    • 2004
  • Carbon nanofilaments were formed on silicon substrate via microwave plasma-enhanced chemical vapor deposition method. The structure of carbon nanofilaments was identified as the carbon nanofibers. The extent of carbon nanofibers growth and the diameters of carbon nanofibers increased with increasing the total pressure. The growth direction of carbon nanofibers was horizontal to the substrate. Laterally grown carbon nanofibers showed the semiconductor electrical characteristics.