• Title/Summary/Keyword: capillary model

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Influence of Heating Conditions on the Formation of Acrylamide and Other Products in Asparagine-Glucose Model Reaction System (Model reaction system에서 가열조건이 acrylamide 및 기타 화합물들의 생성에 미치는 영향)

  • Lee Young-Guen
    • Journal of Life Science
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    • v.16 no.2 s.75
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    • pp.323-327
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    • 2006
  • The Formation of acrylamide was studied in Maillard model reaction systems based on asparagine-glucose. The mixture of asparagine and glucose in equal molar ratio, and then heated at 125, 150, 175 and $200^{\circ}C$ for 10, 20 and 30 minute, respectively. The reaction products were extracted with ethyl acetate and methanol, and then isolated and detected on FFAP capillary column and HP-5MS 5% phenyl methyl siloxane column by using GC/MS. Acrylamide was detected only from methanol extracts and on FFAP capillary column, at retention time 23.53 min., and the detection limit was 4.6 ng. Acrylamide content mainly increased with increasing temperature and processing time till $175^{\circ}C$, therefore, maximal acrylamide formation occurred at $175^{\circ}C$ for 10 minute ($116{\mu}g/g$), while, above $175^{\circ}C$, higher temperatures or prolonged processing times caused a decrease of acrylamide levels, finally disappeared at $200^{\circ}C$ for 30 minute. Three major compounds were identified as 1,3-dihydroxypropanone, 2,3-dihydro-3,5-dihydroxy-6-methyl-4H-pyrane-4-one and 5-hydroxymethylfurfural, and three minor compounds also as 5-methylfurfural, 2-acetylpyrrole and N,N-dimethylcyclohexamine, from ethyl acetate or methanol extracts on FFAP or HP-5MS capillary column.

Numerical Simulation of Immiscible Water-Gas Simultaneous Flow in the absence of Capillary Force in a Single Fracture (단일절리에서 모세관압을 고려하지 않은 불혼합성 물과 가스의 동시거동 해석)

  • 한일영;서일원
    • Journal of Soil and Groundwater Environment
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    • v.6 no.2
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    • pp.69-81
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    • 2001
  • The constitutive relation among capillary pressure, saturation and relative permeability should be predetermined in order to simulate immiscible water-gas flow in porous media. The relation between saturation and relative permeability becomes more important when the capillary force can be disregarded and viscous friction force governs the flow. In this study, a 2-dimensional finite difference numerical model was developed, in which the variation of viscosity with pressure and that of relative permeability with water saturation can be treated. Seven cases of parallel plate tests were performed in order to obtain the characteristic equation of relative permeability which would be used in. the developed numerical model. It was not possible, however, to match the curves of relative permeability from the plate tests with the existing emperical models. Consequently a logistic equation was proposed as a new emperical model. As this model was composed of the parameter involving aperture size, any aperture size of fracture can be applied to the model. For the purpose of verification, the characteristic equation of relative permeability was applied to the developed numerical model and the computed results were compared with those of plate test. As a result of application of numerical model, in order to check the field applicability, to single fracture surrounding an underground storage cavern, the simultaneous flow of water and propane gas was able to be simulated properly by the model.

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Air-conditioner cycle simulation using tube-by-tube method (관순법을 이용한 공조기 사이클 시뮬레이션)

  • Yoon, Baek;Park, Hyun-Yeon;Yoo, Guk-Chul;Kim, Yong-Chan
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.11 no.4
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    • pp.499-510
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    • 1999
  • A computer program was developed for simulating performance(capacity, power consumption and etc.) of air-conditioners using compressor, fin-tube heat exchanger and capillary tube. The program consists of five modules, condenser, evaporator, compressor, capillary tube simulation modules and properties modules of refrigerant and moist air, The present program is focused on R22 only, however can be easily extended for other refrigerants such as R407C and R410A just by adding property modules. The compressor simulation module utilizes performance maps supplied by manufacturers-map-based model. The condenser and evaporator simulation modules are modeled using tube-by-tube method. Simulation results(capacity and power consumption) were compared with calorimeter test results of actual air-conditioners of window and split types, where more than 82% of the data lied within ${\pm}5$% of the predicted results.

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One-Touch Type Immunosenging Lab-on-a-chip for Portable Point-of-care System (휴대용 POC 시스템을 위한 원터치형 면역 센싱 랩온어칩)

  • Park, Sin-Wook;Kang, Tae-Ho;Lee, Jun-Hwang;Yoon, Hyun-C.;Yang, Sang-Sik
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.8
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    • pp.1424-1429
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    • 2007
  • This paper presents a simple and reliable one-touch type multi-immunosensing lab-on-a-chip (LOC) detecting antibodies as multi-disease markers using electrochemical method suitable for a portable point-of-care system (POCS). The multi-stacked LOC consists of a PDMS space layer for liquids loading, a PDMS valve layer with 50 im in height for the membrane, a PDMS channel layer for the fluid paths, and a glass layer for multi electrodes. For the disposable immunoassay which needs sequential flow control of sample and buffer liquids according to the designed strategies, reliable and easy-controlled on-chip operation mechanisms without any electric power are necessary. The driving forces of sequential liquids transfer are the capillary attraction force and the pneumatic pressure generated by air bladder push. These passive fluid transport mechanisms are suitable for single-use LOC module. Prior to the application of detection of the antibody as a disease marker, the model experiments were performed with anti-DNP antibody and anti-biotin antibody as target analytes. The flow test results demonstrate that we can control the fluid flow easily by using the capillary stop valve and the PDMS check valves. By the model tests, we confirmed that the proposed LOC is easily applicable to the bioanalytic immunosensors using bioelectrocatalysis.

Study on the dynamics of capillary rise between elastic sheets (탄성박판간의 모세관 상승운동에 관한 연구)

  • Ahn, Won-Jin;Kim, Ho-Young
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2743-2746
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    • 2007
  • When a small tube is dipped into a liquid surface, surface tension forces cause the liquid in the tube to rise vertically against the gravity. When the tube is flexible, hydrostatic pressure difference caused by the capillary flow deforms the tube and the deformation which narrows the flow route changes the rising velocity. We study a simple model of this elastocapillary interaction in the context of the surface-tension-driven vertical rise of a liquid between two long flexible hydrophilic sheets that are held a small distance apart at one end. We provide an analytical theory for the rise rate of the liquid and show that our experiments are consistent with the theory.

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Development of a Gas Mixing System for Controlled Atmosphere(CA) Chambers

  • Yun, Hong-Sun;Lee, Hyun-Dong;Lee, Won-Ock;Chung, Hun;Cho, Kwang-Hwan
    • Agricultural and Biosystems Engineering
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    • v.2 no.1
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    • pp.31-36
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    • 2001
  • Based on the viscous flow characteristics of gas through capillary tube, a simple and cheap gas mixing system was developed for controlling gas compositions in CA chambers. The gas flow rate through capillary tube had a linear relationship with pressure, (length)$^{-1}$ and (radius)$^4$ of capillary tube, which agreed well with Hagen-Poiseuille’s law. The relationship between flow rate and combined parameters was described as Q=0.000209724($\pi$ r$^4$P/$\mu$L) and the coefficient of determination was 0.9984. The developed system could control gas concentrations in CA chambers within $\pm$0.3% deviation compared to the preset concentrations. It was possible to predict the required time and required gas flow rate for exchanging the gs in CA chamber to a certain concentration of gas by using the mathematical model developed in this study.

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An Experimental Study on the Application of Polypropylene Capillary Tube Cooling System (폴리프로필렌 모세유관 냉방시스템의 적용에 관한 실험적 연구)

  • Lee Young-Ju;Jin Wu-feng;Yeo Myoung-Souk;Kim Kwang-Woo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.9
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    • pp.873-881
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    • 2005
  • In this study, we made RFC, RCC and NCC according to the method by which polypropylene capillary tube was adopted, and evaluated cooling performance of each system through model experiments. We also investigated an applicability of the combined use of radiant cooling and dehumidification system. The results are as follows: In case of normal cooling load, RFC and RCC maintained set temperature without a condensation. But, in case of peak cooling load, RFC and RCC resulted in the lack of cooling performance and caused a condensation at the radiation surface. Consequently, the only use of polypropylene capillary tube is considered not to be enough for cooling in real application. Using the combination of a dehumidification and radiant cooling system maintained the set temperature without a condensation. NCC kept the set temperature at anytime without a condensation. It is more economic than packaged air-conditioner system due to the cooling effect of the floor surface.

Strength Estimation Model of Early-Age Concrete Considering Degree of Hydration and Porosity (수화도와 공극률을 고려한 초기재령 콘크리트의 강도 예측 모델)

  • 황수덕;이광명;김진근
    • Journal of the Korea Concrete Institute
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    • v.14 no.2
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    • pp.137-147
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    • 2002
  • Maturity models involving curing temperature and curing ages have been widely used to predict concrete strength, which can accurately estimate concrete strength. However, they may not consider physical quantities such as the characteristics of hydrates and the capillary porosity of microstructures associated with strength development. In order to find out the effects of both factors on a strength increment, the hydration model and the estimation method of the amount of capillary porosity were established, and the compressive strength test of concrete nth various water/cement ratios was carried out considering two test parameters, curing temperature and curing age. In this study, by analyzing the experimental results, a strength estimation model for early-age concrete that can consider the microstructural characteristics such as hydrates and capillary porosity was proposed. Measured compressive strengths were compared with estimated strengths and good agreements were obtained. Consequently, the proposed strength model can estimate compressive strength of concrete with curing age and curing temperature within an acceptable error.

Modeling of Capillary Filling Length in Silwet L-77 Added Poly(Dimethylsiloxane) (PDMS) Microchannels (Silwet L-77 이 포함된 Polydimethylsiloxane(PDMS) 마이크로 채널의 유동 길이 모델링)

  • Lee, Bom-Yee;Lee, Bong-Kee
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.8
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    • pp.823-829
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    • 2014
  • In the present study, simple models were proposed to predict the capillary-driven flow length in a surfactant-added poly(dimethylsiloxane) (PDMS) rectangular microchannel. Owing to the hydrophobic nature of PDMS, it is difficult to transport water in a conventional PDMS microchannel by means of the capillary force alone. To overcome this problem, microchannels with a hydrophilic surface were fabricated using surfactant-added PDMS. By measuring the contact angle change on the surfactant-added PDMS surface, the behavior was investigated to establish a simple model. In order to predict the filling length induced by the capillary force, the Washburn equation was modified in the present study. From the investigation, it was found that the initial rate-of-change of the contact angle affected the filling length. Simple models were developed for three representative cases, and these can be useful tools in designing microfluidic manufacturing techniques including MIcroMolding In Capillaries (MIMIC).

Surface energy assisted gecko-inspired dry adhesives

  • Rahmawan, Yudi;Kim, Tae-Il;Kim, Seong-Jin;Lee, Kwang-Ryeol;Moon, Myoung-Woon;Suh, Kahp-Yang
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.449-449
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    • 2011
  • We reported the direct effect of intrinsic surface energy of dry adhesive material to the Van der Waals and capillary forces contributions of the total adhesion force in an artificial gecko-inspired adhesion system. To mimic the gecko foot we fabricated tilted nanohairy structures using both lithography and ion beam treatment. The nanohairy structures were replicated from Si wafer mold using UV curable polymeric materials. The control of nanohairs slanting angles was based on the uniform linear argon ion irradiation to the nanohairy polymeric surface. The surface energy was studied utilizing subsequent conventional oxygen ion treatment on the nanohairy structures which resulted in gradient surface energy. Our shear adhesion test results were found in good agreement with the accepted Van der Waals and capillary forces theory in the gecko adhesion system. Surface energy would give a direct impact to the effective Hamaker constant in Van der Waals force and the filling angle (${\varphi}$) of water meniscus in capillary force contributions of gecko inspired adhesion system. With the increasing surface energy, the effective Hamaker constant also increased but the filling angle decreased, resulting in a competition between the two forces. Using a simple mathematical model, we compared our experimental results to show the quantitative contributions of Van der Waals and capillary forces in a single adhesion system on both hydrophobic and hydrophilic surfaces. We found that the Van der Waals force contributes about 82.75% and 89.97% to the total adhesion force on hydrophilic and hydrophobic test surfaces, respectively, while the remaining contribution was occupied by capillary force. We also showed that it is possible to design ultrahigh dry adhesive with adhesion strength of more than 10 times higher than apparent gecko adhesion force by controlling the surface energy and the slanting angle induced-contact line of dry adhesive the materials.

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