• Title/Summary/Keyword: candidate materials

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Biomedical Materials for Regenerating Bone Tissue Utilizing Marine Invertebrate (해양무척추동물을 활용한 골 조직 재생용 바이오 메디컬 소재)

  • Oh, Gun-Woo;Jung, Won-Kyo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.48 no.1
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    • pp.1-15
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    • 2015
  • Tissue engineering is an emerging, innovative technology to improve or replace the biological functions of damaged tissues and organs. Scaffolds are important materials for tissue engineering as they support cell attachment, migration, and differentiation. Marine sponges naturally contain scaffolds formed by extracellular matrix proteins (collagen and sponging) and strengthened by a siliceous or calcium carbonate skeleton. Coral skeletons are also derived naturally formed by essential calcium carbonate in the form of aragonite, and are similar to human bone. In addition, collagen extracted from jellyfish is a biosafe alternative to bovine and porcine collagen and gained attention as a potential source for tissue engineering. Moreover, cuttlefish bone is an excellent calcium source and can be used to generate bio-synthetic calcium phosphate. It has become a natural candidate for biomimetic scaffolds. This review describes the use of natural products derived from marine invertebrates for applications in bone tissue engineering based on studies from 2008 to 2014.

Ferroelectricity of Bi-doped ZnO Films Probed by Scanning Probe Microscopy

  • Ben, Chu Van;Lee, Ju-Won;Kim, Jung-Hoon;Yang, Woo-Chul
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.323-323
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    • 2012
  • We present ferroelectricity of Bi-doped ZnO film probed by piezoresponse force microscopy (PFM), which is one of the Scanning Probe Microscopy techniques. Perovskite ferroelectrics are limited to integration of devices into semiconductor microcircuitry due to hard adjusting their lattice structure to the semiconductor materials. Transition metal doped ZnO film is one of the candidate materials for replacing the perovskite ferroelectrics. In this study, ferroelectric characteristics of the Bi-doped ZnO grown by pulsed laser deposition were probed by PFM. The polarization switching and patterning of the ZnO films were performed by applying DC bias voltage between the AFM tips and the films with varying voltages and polarity. The PFM contrast before and after patterning showed clearly polarization switching for a specific concentration of Bi atoms. In addition, the patterned regions with nanoscale show clearly the local piezoresponse hysteresis loop. The spontaneous polarization of the ZnO film is estimated from the local piezoresponse based on the comparison with LiNbO3 single crystals.

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Effect of Hydrogen on Mechanical S tability of Amorphous In-Sn-O thin films for flexible electronics (수소 첨가에 의한 비정질 ITO 박막의 기계적 특성 연구)

  • Kim, Seo-Han;Song, Pung-Geun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.56-56
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    • 2018
  • Transparent conductive oxides (TCOs) have attracted attention due to their high electrical conductivity and optical transparency in the visible region. Consequently, TCOs have been widely used as electrode materials in various electronic devices such as flat panel displays and solar cells. Previous studies on TCOs focused on their electrical and optical performances; there have been numerous attempts to improve these properties, such as chemical doping and crystallinity enhancement. Recently, due to rapidly increasing demand for flexible electronics, the academic interest in the mechanical stability of materials has come to the fore as a major issue. In particular, long-term stability under bending is a crucial requirement for flexible electrodes; however, research on this feature is still in the nascent stage. Hydrogen-incorporated amorphous In-Sn-O (a-ITO) thin films were fabricated by introducing hydrogen gas during deposition. The hydrogen concentration in the film was determined by secondary ion mass spectrometry and was found to vary from $4.7{\times}10^{20}$ to $8.1{\times}10^{20}cm^{-3}$ with increasing $H_2$ flow rate. The mechanical stability of the a-ITO thin films dramatically improved because of hydrogen incorporation, without any observable degradation in their electrical or optical properties. With increasing hydrogen concentration, the compressive residual stress gradually decreased and the subgap absorption at around 3.1 eV was suppressed. Considering that the residual stress and subgap absorption mainly originated from defects, hydrogen may be a promising candidate for defect passivation in flexible electronics.

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Pr2NiO4+δ for Cathode in Protonic Ceramic Fuel Cells

  • An, Hyegsoon;Shin, Dongwook;Ji, Ho-Il
    • Journal of the Korean Ceramic Society
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    • v.55 no.4
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    • pp.358-363
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    • 2018
  • To improve the polarization property of cathodes, which is the main factor limiting the performance of protonic ceramic fuel cells (PCFCs), $K_2NiF_4-type$ $Pr_2NiO_{4+{\delta}}$, which is expected to exhibit a triple conducting property (proton, oxygen ion, and hole conductions) was applied to PCFCs and its properties were investigated. Low-temperature microwave heat-treatment was used to achieve both sufficient interface adhesion between the electrolyte and the cathode layers and suppression of the secondary phase formation due to migration of elements such as barium and cerium. Through this fabrication method, a high performance of $0.82W{\cdot}cm^{-2}$ and low ohmic resistance of $0.06{\Omega}{\cdot}cm^2$ were obtained in an $Ni-BaCe_{0.55}Zr_{0.3}Y_{0.15}O_{3-{\delta}}$ | $BaCe_{0.55}Zr_{0.3}Y_{0.15}O_{3-{\delta}}$ | $Pr_2NiO_{4+{\delta}}$ single cell at $650^{\circ}C$. This result verifies that the $K_2NiF_{4+{\delta}}-type$ cathode shows good chemical compatibility which, in turn, will make it a potent candidate as a PCFC cathode.

Study on New Candidate Coating Materials to Challenge Rudder Cavitation Damage

  • Lee, H.I.;Han, M.S.;Baek, K.K.;Lee, C.H.;Shin, C.S.;Chung, M.K.
    • Corrosion Science and Technology
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    • v.7 no.5
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    • pp.274-282
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    • 2008
  • Ships' hull is typically protected by a combination of protective coating system and electrical cathodic protection system, which has been an economical and effective measure for ship's hull to date. However, ships' rudder and adjacent hull areas are known to be subjected to premature corrosion damages, which require more frequent coating repair than other hull areas. Conventional organic coating system for ship's hull has been known only to remain intact just for 2~3 months on the rudder and adjacent area, especially for the fast-going ships such as container carriers or naval vessels. In this study, special organic/inorganic coating materials, which are commercially available, were tested in terms of cavitation resistance as an alternative to existing rudder & hull protection system. Both standard ultrasonic tester and in-house developed ultra water jet test method were employed as a means to evaluate their performance against cavitation induced damages. Additionally, the overall cost evaluation and workability at actual shipyard were discussed.

Polymer semiconductor based transistors for flexible display

  • Lee, Ji-Yeol;Lee, Bang-Rin;Kim, Ju-Yeong;Jeong, Ji-Yeong;Park, Jeong-Il;Jeong, Jong-Won;Gu, Bon-Won;Jin, Yong-Wan
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.59.1-59.1
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    • 2012
  • Organic thin-film transistors (OTFTs) with printable semiconductors are promising candidate devices for flexible active-matrix (AM) display applications. Yet, stable operation of actual display panels driven by OTFTs has seldom been reported up to date. Here, we demonstrate a flexible reflective type polymer dispersed liquid crystal (PDLC) display, in which inkjet-printed OTFT arrays are used as driving elements with excellent areal uniformity in terms of device performance. As the active semiconductor, a novel, ambient processable conjugated copolymer was synthesized. The stability of the devices with respect to electrical bias stress was improved by applying a channel-passivation layer, which suppresses the environmental effects and hence reduces the density of trap states at the channel/dielectric interface. The combination of high performance and high stability OTFT devices enabled the successful realization of stable operating flexible color-displays by inkjet-printing.

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Study on the Hydrogen Delayed Fracture Property of TRIP Steel by Slow Strain Rate Testing Method (일정 변형률 시험에 의한 TRIP강의 수소 지연파괴 특성연구)

  • Cho, J.H.;Lee, J.K.
    • Corrosion Science and Technology
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    • v.10 no.4
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    • pp.131-135
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    • 2011
  • The demands of high-strength steel have been steadily increased to reduce the weight of vehicles. Although the TRIP steel has been the promising candidate material for the purpose, high strength hinders the application due to the susceptibility to hydrogen delayed fracture in the corrosive environment. Moreover, the testing method was not specified in the ISO standards. In this work, the test method to evaluate the susceptibility of hydrogen delayed fracture was studied by slow strain rate testing technique. The four test experimental parameters were studied : strain rate, hydrogen charging time, holding time after hydrogen charging, and holding time after cadmium plating. The steel was fractured by hydrogen in case the strain rate was in the range of $1{\times}10^{-4}{\sim}5{\times}10^{-7}/sec$. It was confirmed that the slow strain rate test is effective method to evaluate the susceptibility to hydrogen delayed fracture. The holding time over 24 hrs after hydrogen charging, nullified the hydrogen effect, that is, the specimen was no more susceptible to hydrogen after 24 hrs even though the specimen was fully hydrogen-charged. Moreover, cadmium electroplating could not prevent from diffusing out the hydrogen from the steel in the experiment. The effective experimental procedures were discussed.

Design of Control Algorithm for Mass Driving Anti-Rolling System Considering Control Input Constraint (제어 입력포화를 고려한 횡동요 저감장치용 제어알고리듬 설계)

  • Moon, Seok-Jun;Lim, Chae-Wook;Lee, Hae-Jong
    • Journal of the Society of Naval Architects of Korea
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    • v.42 no.6 s.144
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    • pp.566-574
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    • 2005
  • Reduction of a ship's rolling is the most important performance requirement for improving the safety of the crew on board and preventing damage to cargos as well as improving the comfort of the ride. A mass driving anti-rolling system (MO-ARS) might be one candidate of several systems against the ship's rolling. As the movable range of the mass on the ship is finite, the control system must include restriction on the mass position to protect the device and the ship. This restriction usually causes windup phenomenon and control performance is deteriorated seriously. Two control algorithms, anti-windup control and saturated sliding mode control, are studied in this paper. Control performance and robustness problem are checked out by numerical simulations.

An Experimental Study on Mass Driving Anti-Rolling System for Ships (가동질량을 이용한 선박용 횡동요 저감장치에 대한 실험적 연구)

  • Moon, Seok-Jun;Jeong, Jong-Ahn;Yoon, Hyeon-Kyu;Lee, Gyeong-Joong;Ann, Seong-Phil
    • Journal of the Society of Naval Architects of Korea
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    • v.42 no.6 s.144
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    • pp.666-672
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    • 2005
  • Reduction of a ship's rolling is the most important performance requirement for improving the safety of the crew on board and preventing damage to cargos as well as improving the comfort of the ride. A mass driving anti-rolling system (MO-ARS) might be one candidate of several systems against the ship's rolling. In this paper, three types of MD-ARS, two passive and one active devices, are developed for small ships. After they are installed on the cabin of the small leisure boat, respectively, a series of performance test is conducted before and after operating them. Through the test, it is confirmed that the roll responses of the ship are pretty well reduced by the MO-ARS.

Characteristics of Carbon Tetrafluoride Plasma Resistance of Various Glasses

  • Choi, Jae Ho;Han, Yoon Soo;Lee, Sung Min;Park, Hyung Bin;Choi, Sung Churl;Kim, Hyeong Jun
    • Journal of the Korean Ceramic Society
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    • v.53 no.6
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    • pp.700-706
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    • 2016
  • Etch rate, surface roughness and microstructure as plasma resistance were evaluated for six kinds of oxide glass with different compositions. Borosilicate glass (BS) was found to be etched at the highest etch rate and zinc aluminum phosphate glass (ZAP) showed a relatively lower etch rate than borosilicate. On the other hand, the etching rate of calcium aluminosilicate glass (CAS) was measured to be similar to that of sintered alumina while yttrium aluminosilicate glass (YAS) showed the lowest etch rate. Such different etch rates by mixture plasma as a function of glass compositions was dependent on whether or not fluoride compounds were formed on glass and sublimated in high vacuum. Especially, in view that $CaF_2$ and $YF_3$ with high sublimation points were formed on the surface of CAS and YAS glasses, both CAS and YAS glasses were considered to be a good candidate for protective coating materials on the damaged polycrystalline ceramics parts in semi-conductor and display processes.