• Title/Summary/Keyword: calorimeter

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An Experimental Study on Combustion Characteristics of Aluminum Composite Panels for Flame Retardant and General Materials (난연소재와 일반소재 알루미늄복합패널의 연소특성 비교에 관한 실험적 연구)

  • Min, Se-Hong;Yun, Jung-Eun;Kim, Mi-Suk
    • Fire Science and Engineering
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    • v.26 no.2
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    • pp.105-111
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    • 2012
  • In this research, aluminum composite panels of the general materials and fire retardant materials as building claddings make researches about fire performance comparison analysis. Test methods of the small and medium cone calorimeter experiments and SBI (Single Burning Item) experiments was applied to the determination. As a result, in the experiments peak heat release rate cone calorimeter the general aluminum composite panel $1,293kW/m^2$ ($75kW/m^2$), flame-retardant aluminum composite panel $70kW/m^2$ ($75kW/m^2$) was measured. In the SBI experiments fire growth rate the general fire aluminum composite panel is approximately 743 W/s and the flame-retardant aluminum composite panel is approximately 97 W/s of the value were measured. Thus, a standards enactment are urgently required in this case it is used as building claddings of the aluminum composite panel by fire risk assessment.

An Experimental Study on the Development of Fire-retardant Treated Wood for Construction (건축용 난연 목재 개발에 대한 실험 연구)

  • Seo, Hyun Jeong;Kim, Nam Kyun;Jo, Jeong Min;Lee, Min Chul
    • Journal of the Korean Society of Safety
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    • v.32 no.5
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    • pp.149-156
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    • 2017
  • This study investigates fire-retardant performances and combustion/thermal characteristics of fire-retardant treated wood by comparing them with those of fire-retardant untreated wood from the expreimental resutls of cone calorimeter and thermo-gravimetric(TG) analyzer. Hazardousness of combustion product gases for fire-retardant treated wood and untreasted wood were also observed from the results of internal finish material incombustibility test according to the Korea standard code of KS F 2271. In this study, we also tried to improve the fire retardant performance of wood by applying fire-retardant chemical composites, and to secure the fire safety performance in buildings. Red pine (Pinus densiflora) was selected as a test specimen because it is mostly used as a building material in Korea. Fire retardant chemical composites (FRCs) were prepared by mixing boron, phosphorous, and nitrogen species and treated by press-impregnation method. Water-based FRCs were composed of 3% boric acid($H_3BO_3$), 3% borax decahydrate($Na_2B_4O_7$), 8% ammonium carbonate($(NH_4)_2CO_3$), diammonium phosphate ($(NH_4)_2HPO_4$) varied from 10-30% and potassium carbonate($K_2CO_3$) varied from 10-30%. From the test results of cone calorimeter, TG analysis and gas hazard assessments, newly proposed were the optimal composition and production methods of FRCs which can sufficiently meet fire-retardant level 3 based on Korea law of construction. Thus, the FRCs, developed in this study, are anticipated to contribute to the improvement of fire safety and widespread of usage in wood as building materials.

Fire Characteristics of Plastic Insulating Materials from Cone Calorimeter Test (콘칼로리미터를 이용한 플라스틱 단열재의 화재특성)

  • 이근원;김관응
    • Fire Science and Engineering
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    • v.17 no.1
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    • pp.76-84
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    • 2003
  • This study was designed to investigate fire characteristics of the plastics insulating materials such as a polystyrene foam, polyurethane foam, and polyethylene foam, which is used an insulating materials i3t workplace. The fire characteristics of plastic insulating materials were carried out from the Cone Calorimeter test according to ISO 5660. The experimental materials used were commercial plastic insulating materials by products and their composition is not disclosed by the manufacturer. As the results of this study; the heat release rate of plastic insulating materials was increased with increasing density and heat flux. The peak heat release rate and the average heat release rate for the polyethylene foam in insulating materials were showed the highest, and the peak heat release rate for the polyethylene foam was the highest. The standard of heat release rate with a kind of products and heat flux of irradiance to prevent fire by plastic insulating materials was suggested.

A Study on Ignitability and Heat Release Rate Characteristics of Rigid Polyurethane Foam (경질 폴리우레탄폼의 착화성 및 열방출특성 연구)

  • 공영건;이두형
    • Fire Science and Engineering
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    • v.17 no.4
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    • pp.117-123
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    • 2003
  • In this study; the ignition and heat release rate characteristics of rigid polyurethane foam were investigated in accordance with setchkin ignition tester and cone calorimeter which is using oxygen consumption principle. In the ignition temperature study; flash-ignition temperature was $383^{\circ}C$-$390^{\circ}C$, self-ignition temperature was$ 493^{\circ}C$∼495$^{\circ}C$. The self-ignition temperature of rigid polyurethane foam was about $100^{\circ}C$ higher than the flash-ignition temperature. In the cone calorimeter study, the time to ignition of rigid polyurethane foam was faster as the external heat flux increase. In the same heat flux level, the time to ignition was faster as the density of rigid polyurethane foam decrease. Also the heat release rate was the largest value at the heat flux of /$50 ㎾\m^2$ and had a tendency of increase as the heat flux level and density increase. In the standpoint of time to ignition and heat release rate, the fire performance of rigid polyurethane foam was influenced by the applied heat flux level and density and the flashover propensity classified by Petrella's proposal was high.

Experimental Study on the Effect of Flow around Solid Combustibles and Thermal Thickness on Heat Release Rate Characteristics (고체 가연물 주위의 유동과 열적 두께의 변화가 열방출률 특성에 미치는 영향에 관한 실험적 연구)

  • Hong, Ter-Ki;Seo, Dong-Pyo;Park, Seul-Hyun
    • Fire Science and Engineering
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    • v.34 no.3
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    • pp.28-34
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    • 2020
  • In this study, an ISO 5660-1 cone calorimeter experiment was conducted to examine the effects of changes in flow and thermal thickness around solid combustibles on heat release rate characteristics. Polymethyl methacrylate (PMMA) is a solid combustible material that does not generate char during the combustion reaction. Hence, it was selected for the experiment, and the thermal penetration depth was calculated to distinguish the thermal thickness of PMMA. Furthermore, the thermal decomposition characteristics were analyzed by measuring the heat release rate measured during the combustion of PMMA. This was performed after generating the forced flow around the combustibles by setting the duct flow of the cone calorimeter to 12, 24, and 40 L/s. The results confirmed that the thermal release rate of the thermally thin combustible material was not significantly affected by the change in the surrounding flow. Hence, the thermally thick combustible material was significantly affected by the change in the flow rate.

Combustion Characteristics Analysis of a Non-class 1E Cable for Nuclear Power Plants according to Aging Period (경년열화 기간에 따른 원자력발전소용 비안전등급 케이블의 연소특성 분석)

  • Kim, Min Ho;Lee, Seok Hui;Lee, Min Chul;Lee, Sang Kyu;Lee, Ju Eun
    • Journal of the Korean Society of Safety
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    • v.35 no.5
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    • pp.22-29
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    • 2020
  • In this study, combustion and smoke release characteristics of a non-class 1E cable for nuclear power plants were investigated according to aging period. The aging was reproduced through an accelerated aging method for interval of 10 years :10, 20, 30 and 40 year, which was applied the Arrhenius equation. The cable was subjected to accelerated aging. In order to understand combustion and smoke release characteristics, the cone calorimeter test was performed according to the standard code of KS F ISO 5660-1. Heat release rate, mass loss rate, average rate of heat emission and smoke production rate were examined through cone calorimeter test. Fire performance index, fire growth index and smoke factor were derived from test results for the comparison of quantitative fire risk. When comparing the fire performance index and the fire growth index, the early fire risk tends to decrease as aging progresses, which might be attributed from the fact that the volatile substances of cables were evaporated. However, when comparing the heat release rate, average rate of heat emission and mass loss rate, which represent the mid and late periods of the fire risk, the values of accelerated aging cables were much higher than those of non-aged cable, which signifies the unstable formation of the char layer resulted in the change in the performance of flame retardants. In addition, the results from the smoke characteristics show that the accelerated aging cables were lager than the non-aged cables in terms of overall fire risk. These results can be used as baseline data when assessing fire risk of cables and establishing fire safety code for nuclear power plants.

Flame Retardancy and Foaming Properties of the NBR/Ground Tire Rubber Foams Containing Expandable Graphite (팽창 흑연을 포함한 NBR/GTR 발포체의 난연 및 발포특성)

  • Moon Sung-Chul;Choi Jae-Kon;Jo Byung-Wook
    • Polymer(Korea)
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    • v.28 no.5
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    • pp.412-425
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    • 2004
  • The influence of expandable graphite (EG) on flame retardancy and foaming properties of the NBR/GTR foams was studied. The foaming properties were similar to those of NBR/GTR foams without EG when the EG contents were 10$\~$30 phr. The LOI values were increased with the EG content. For cone-calorimeter test, the data showed the trend similar to that from experiment. When the composition ratios of the compounds of NBR/GTR were 100$\~$0/80$\~$20 (w/w), and the EG contents were 10$\~$30 phr, we obtained high flame retardancy foams with low heat release rate (HRR), total heat release (THR), effective heat of combustion (EHC) and carbon monoxide yield (COY). The smoke density is similar to CO yield values obtained by the cone-calorimeter test. TGA analysis also showed the results approximately similar to those from the LOI and cone-calorimeter experiments.

Flammable Evaluation of Plastics for Living by Cone Calorimeter Test (콘칼로리미터 시험법에 의한 생활용 플라스틱의 가연성 평가)

  • You, Jisun;Chung, Yeong-Jin
    • Fire Science and Engineering
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    • v.32 no.3
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    • pp.8-13
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    • 2018
  • It was conceived from the realization that there was a lack of studies on the fire risk compared to utility and importance of plastic which is widely used. In this study, the fire hazard of five types of plastic products was measured by Cone Calorimeter (ISO 5660-1). As a result, the time to ignition (TTI) of polyvinyl Chloride (PVC) plate delayed TTI (196 s), and polystyrene (PS) plate had the shortest TTI of 19 s. The total heat release (THR) of PS plate was measured at 213.07 % higher than the lowest measured PVC plate. Also, the PS plate will have 1.45 to 4.21 times higher $CO_2$ than other plastics, resulting in the highest incomplete combustion and the greatest possible damage of life. Thus, assessing the risk of fire revealed that PS plate is the most dangerous and PVC is the safest.

Study on the Long-term Thermal Stability by DSC & ARC and its ISCO behaviors with different AP Quality (DSC, ARC, ISCO를 활용한 다양한 순도를 가진 AP의 장기 열적안정성 연구)

  • Kim, Seunghee;Kwon, Kuktae;Lee, So Jung
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.2
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    • pp.59-65
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    • 2018
  • We conducted an isothermal slow cook-off(ISCO) test for an aluminized explosive containing AP. The sample bulged before the run-away reaction, and therefore we were unable to obtain the ISCO data. However, these phenomena did not occur for a certain AP grade, which means that the quality of the AP exerted a significant effect on the thermal stability of the explosive formulation. In this study, we investigated the thermal stability difference between a good and bad AP grade. First, we characterized the thermal properties of all APs by Differential Scanning Calorimeter(DSC) and correlated them to the ISCO phenomena. In addition to the DSC study and ISCO test, we also investigated and calculated the SADT and self-heating rate by the ARC of the different AP qualities to interpret the thermal stability of the explosive formulation. Moreover, we investigated the impurity of the AP and a preparation method to remove the included impurity and crystallization. Finally, we implemented qualification methods to identify the quality of AP by DSC using a high-pressure crucible.

A Study on the Heat Release Rate of EPS Sandwich Panel Core (EPS 샌드위치 패널 심재의 열방출율에 관한 연구)

  • Park, Hyung-Ju;Cho, Myung-Ho
    • Fire Science and Engineering
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    • v.22 no.5
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    • pp.72-78
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    • 2008
  • The mass loss rate and heat release rate of EPS sandwich panel cores were analysed using variable external irradiation level. The experimental materials were exposed to incident heat fluxes form 20 to 50 kW/$m^2$. For the measurement of mass loss rate and heat release rate, the size of specimen was $100mm{\times}100mm{\times}50mm$ and the samples were 3 different kinds. The combustion heat were carried out from the Oxygen bomb calorimeter and the mass loss rate and heat release rate were carried out from the Mass loss calorimeter according to ISO 5660-1. As the results of this study, the mass loss rate of Type A, B, and C were 2.7 g/$m^2s$, 2.8 g/$m^2s$, and 2.3 g/$m^2s$ and the heat release rate of Type A, B, and C were 58.23 kW/$m^2$, 47.19 kW/$m^2$, and 50.06 kW/$m^2$ respectively at the heat flux of 50 kW/$m^2$. In conclusion, when the heat release characteristics applied to a classification system of Canada, Type A and C can be classified grade C-3, and Type C can be classified grade C-2 from all data of this study.