• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2023년도 봄 학술논문 발표대회
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• pp.53-54
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• 2023

In recent decades, climate change has become an issue of global importance. The calcium sulfoaluminate (CSA) cement emits lower CO₂ than the Portland cements while manufacturing. However, ettringite, which is a main hydration product of CSA cement, starts dehydrating at a temperature above 100℃, hence it may limit the CSA cement for high temperature application. Recently, an early carbonation curing of cement-based material has been extensively studied in terms of carbon neutralization. The carbonation curing of CSA cement has a potential to transform the AFt and AFm phases into calcium carbonate, and the transformation of unstable hydrates to stable hydrates can increase the resistance to elevated temperature. This review study summarizes and discusses the carbonation curing effect of CSA cement and the thermal stability of CSA cement exposed to elevated temperatures.

• 시멘트 심포지엄
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• 32호
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• pp.107-115
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• 2005

• 한국건설순환자원학회논문집
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• 제11권3호
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• pp.202-209
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• 2023

In this study, microstructures and mechanical properties of repair materials using calcium sulfoaluminate (CSA) and/or amorphous calcium aluminate (ACA) cements were experimentally investigated. By XRD ansysis, the hydrates formed in repair materials were identified. In addition, the microstructures of repair materials were visually examined through SEM observation. Setting time of mortars made with repair materials were measured. The strength development and ultrasonic velocity of the mortars were also evaluated at the predetermined ages. As a result, it seems that ACA showed a benefit effect with respect to mechanical properties of mortars.

• Geomechanics and Engineering
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• 제33권1호
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• pp.41-51
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• 2023

Cementitious materials such as Ordinary Portland Cement (OPC), fly ash, lime, and bitumen have been employed for soil improvement over the years. However, due to the environmental concerns associated with the use of OPC, substituting OPC with calcium sulfoaluminate (CSA) cement offers good potential for ground improvement because it is more eco-friendly. Although earlier research has investigated the stabilizing effects of CSA cement-treated sand, no attempt has been made to examine soil behavior under high confining pressure. As a result, this study aimed to investigate the shear strength and mechanical behavior of CSA cement-treated sand using a consolidated drained (CD) triaxial test with high confining pressure. The microstructure of the examined sand samples was investigated using scanning electron microscopy. This study used sand with CSA cement contents of 3%, 5%, and 7% and confining pressures of 0.5, 1.0, and 1.5 MPa. It revealed that the confining pressures and CSA cement content significantly affected the stress-strain and volumetric change behavior of CSA cement-treated sand at high confining pressures.

• 자원리싸이클링
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• 제32권6호
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• pp.10-17
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• 2023

칼슘실리케이트 시멘트(Calcium silicate cement, CSC)는 친환경 저탄소 시멘트로써 최근에 많은 연구가 진행되고 있다. 하지만 이산화탄소 반응 활성화와 시료 handling을 위하여 사전경화 단계를 진행하여야하는 어려움이 있다. 본 연구에서는 CSC에 칼슘설포아루미네이트(Calcium sulfoaluminate, CSA) 속경시멘트를 혼합하여 초기강도 발현으로 사전경화 없이 사용할 수 있는 CSC의 확대적용 가능성을 살펴보고자 하였다. 이를 위하여 이산화탄소 분위기에서 CSC 와 CSA 속경성 시멘트 혼합비율 변화에 따른 압축강도와 Q-XRD 광물특성 함량 변화를 측정하였다. 압축강도 측정결과, CSC 50% 조건에서 3일과 7일 압축강도가 각 각 14.18MPa과 22.98MPa로 1종시멘트 KS규격을 만족하였다. 광물특성 분석을 통하여 이산화탄소 반응생성물인 calcite 광물이 증가하여 강도발현에 기여했음을 알 수 있었다. 7일 경과 후에도 수화광물인 dicalcium silicate 및 yeelimite광물뿐 아니라, 이산화탄소와 반응하지 않은 rankiniten 및 pseudowollastonite 광물이 다량 관찰되어 7일이후의 강도발현 가능성을 확인하였다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 가을 학술발표대회 논문집(III)
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• pp.888-893
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• 1998

Calcium sulfoaluminate, $C_4$A$_3$$\bar{S}$, was prepared for reutilizing industrial by-products, such as II-CaSO$_4$, Al(OH), CaF$_2$ and cement sludge wastes. Mixed powder was fired at 1,15$0^{\circ}C$. $C_4$A$_3$$\bar{S}$ clinkers fired at 1,15$0^{\circ}C$ were analyzed by SEM and XRD. Also were added in cement paste and mortar and characterized as setting time, flow values and compressive strength. $C_4$A$_3$$\bar{S}$ could be found in the X-ray diffraction pattern. The setting time of cement pastes added clinkers fired at 1,15$0^{\circ}C$ was shorter than that of ordinary portland cement. Also the compressive strengths of the cement mortar added clinkers was higher than those of ordinary portland cement.

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2000년도 춘계총회,특별강연,심포지움,연구발표회
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• pp.25.1-25.1
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• 2000

• International Journal of Concrete Structures and Materials
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• 제11권1호
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• pp.59-68
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• 2017

Mercury intrusion and nitrogen sorption porosimetry were employed to investigate the pore structure of calcium sulfoaluminate ($C{\bar{S}}A$) and portland cement pastes with cement-to-water ratio (w/c) of 0.40, 0.50, and 0.60. A unimodal distribution of pore size was drawn for $C{\bar{S}}A$ cement pastes, whereas a bimodal distribution was established for the portland cement pastes through analysis of mercury intrusion porosimetry. For the experimental results generated by nitrogen sorption porosimetry, the $C{\bar{S}}A$ cement pastes have a smaller and coarser pore volume than cement paste samples under the same w/c condition. The relative dynamic modulus and percentage weight loss were used for investigation of the concrete durability in freeze-thaw condition. When coarse aggregate with good freeze-thaw durability was mixed, air entrained portland cement concrete has the same durability in terms of relative dynamic modulus as $C{\bar{S}}A$ cement concrete in a freeze-thaw environment. The $C{\bar{S}}A$ cement concrete with poor performance of durability in a freeze-thaw environment demonstrates the improved durability by 300 % over portland cement concrete. The $C{\bar{S}}A$ concrete with good performance aggregate also exhibits less surface scaling in a freeze-thaw environment, losing 11 % less mass after 297 cycles.

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2000년도 추계총회,초청강연,특별강연,연구발표회
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• pp.60.1-60
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• 2000

• 한국자원리싸이클링학회:학술대회논문집
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• 한국자원리싸이클링학회 2005년도 추계정기총회 및 제26회 학술발표대회 고분자리싸이클링기술 특별심포지엄
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• pp.330-334
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• 2005

본 연구에서는 유해 중금속을 다량 함유하고 있는 산업폐기물의 고화 처리에 사용되는 칼슘설포알루미네이트(4CaO $3Al_2O_3\;SO_4$ 이후부터 CSA로 기입)의 제조를 위해 철강부산물인 압연 슬러지를 활용하여 그 특성에 대해 조사하였다. 본 연구에서는 철강 부산물인 압연슬러지 외에 석회석 미분물, 인산부산 석고를 혼합하여 칼슘알루미네이트 상을 합성하였다. 합성 결과 소성온도 $1250^{\circ}C$에서부터 CSA가 합성되었고, 이와 함께 칼슘실리케이트$(2CaO\;SiO_2)$와 칼슘알루미노페라이트($4CaO\;Al_2O_3\;Fe_2O_3$)도 함께 합성되었다. CSA 합성에 미치는 중금속 영향을 관찰한 결과 원료의 중금속이 CSA 합성 온도를 낮추는 효과가 있는 것으로 나타났다. CSA를 이용한 철강산업 폐기물의 중금속 고용 처리 연구에서도 본 실험에서 합성된 CSA가 폐기물의 중금속 고화 처리에 효과가 있는 것으로 나타났다.