• Title/Summary/Keyword: calcium resistance

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A Durability Assessment on Complex Deterioration of Concrete with Ground Granulated Blast-Furnace Slag Replacement (복합열화 환경하에서의 고로슬래그미분말 사용 콘크리트의 내구성능 평가)

  • Lee, Seung-Hoon;Kim, Hyung-Doo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.2
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    • pp.171-175
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    • 2010
  • This paper presents the experimental results of frost durability characteristics including freezing-thawing and de-icing salt scaling of the concrete for gutter of the road and marine structure. Mixtures were proportioned with the three level of water-binder ratio(W/B) and three binder compositions corresponding to Type I cement with 0%, 30% and 50% GGBS(Ground granulated blast furnace slag) replacement. Also, two different solutions of calcium chloride were used to evaluate their effect on the frost durability resistance. Specially, in case of complex of freezing and thawing with salt and carbonation, the deterioration of concrete surface is evaluated. Test results showed that the BFS30 and BFS50 mixture exhibited higher durability and lower mass loss values than those made with OPC mix and the use of GGBS can be used effectively in terms of economy and frost durability of the concrete to be in complex deterioration. Therefore, the resistance to complex deterioration with freezing-thawing was strongly influenced by the strength and the type of cement.

Experimental study of graphene oxide on wollastonite induced cement mortar

  • Sairam, V.;Shanmugapriya, T.;Jain, Chetan;Agrahari, Himanshu Kumar;Malpani, Tanmay
    • Advances in concrete construction
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    • v.12 no.6
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    • pp.479-490
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    • 2021
  • Present research is mainly focused on, microstructural and durability analysis of Graphene Oxide (GO) in Wollastonite (WO) induced cement mortar with silica fume. The study was conducted by evaluating the mechanical properties (compressive and flexural strength), durability properties (water absorption, sorptivity and sulphate resistance) and microstructural analysis by SEM. Cement mortar mix prepared by replacing 10% ordinary portland cement with SF was considered as the control mix. Wollastonite replacement level varied from 0 to 20% by weight of cement. The optimum replacement of wollastonite was found to be 15% and this was followed by four sets of mortar specimens with varying substitution levels of cementitious material with GO at dosage rates of 0.1%, 0.2%, 0.3% and 0.4% by weight. The results indicated that the addition of up to 15%WO and 0.3% GO improves the hydration process and increase the compressive strength and flexural strength of the mortar due to the pore volume reduction, thereby strengthening the mortar mix. The resistance to water penetration and sulphate attack of mortar mixes were generally improved with the dosage of GO in presence of 15% Wollastonite and 10% silica fume content in the mortar mix. Furthermore, FE-SEM test results showed that the WO influences the lattice framework of the cement hydration products increasing the bonding between silica fume particles and cement. The optimum mix containing 0.3% GO with 15% WO replacement exhibited extensive C-S-H formation along with a uniform densified structure indicating that calcium meta-silicate has filled the pores.

Effect of Combined Exercise on Lung Function, Blood Vitamin D, Calcium and Bone Metabolism Hormones in Elderly Women (복합운동이 여성노인의 폐기능, 혈중 비타민 D, 칼슘 및 골대사호르몬에 미치는 영향)

  • Ki, Min-Jae;Ha, Soo-Min;Kim, Jung-Sook;Koh, Su-Han;Kim, Ji-Sun;Kim, Do-Yeon
    • Journal of the Korean Applied Science and Technology
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    • v.37 no.4
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    • pp.699-710
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    • 2020
  • The purpose of this study was to investigate the effect of combined exercise on lung function, blood vitamin D, calcium and bone metabolism hormones in elderly women who are over 65 years by dividing them into a combined exercise group(n=13), control group(n=17). The combined exercise program included 60-minutes sessions 3times each week. Aerobic exercise intensity was 40-50%HRR(RPE 12-13) for 1-4 week, 50-60%HRR(RPE 13-14) for 5-8 week, and 60-70%HRR(RPE 14-15) for 9-12 week and resistance exercise intensity was set at OMNI-RES 3-4 for 1-4 week, OMNI-RES 5-6 for 5-8 week, OMNI-RES 7-8 for 9-12 week. As a result, lung function indicated that FEV1 showed an interaction effect between group and time and FVC/FEV1 levels significantly increased in combined exercise group. Blood vitamin D showed an interaction effect between group and time, also, significantly increased in combined exercise group and control group. Calcium showed an interaction effect between group and time, and significantly decreased in control group. Bone metabolism hormones indicated that both calcitonin and osteocalcin showed an interaction effect between group and time, osteocalcin significantly decreased in control group. For the following this conclusion, elderly women can be improved their lung function through 12 weeks combined exercise and also mitigate the blood vitamin D but there was no meaningful results of calcium and bone metabolism hormones.

Corrosion Evaluation of Epoxy-Coated Bars in Chloride Contaminated Concrete Using Linear Polarization Tests

  • Choi, Oan-Chul;Jung, Si-Young;Park, Young-Soo
    • International Journal of Concrete Structures and Materials
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    • v.18 no.1E
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    • pp.3-9
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    • 2006
  • Five slab specimens with predefined cracks are examined to evaluate the corrosion behavior of epoxy-coated bars in chloride contaminated concrete, using linear polarization method. The test specimens were subjected to alternating weekly cycles of ponding in a salt solution and drying for 48 weeks. Test results show that the current density of the specimen of normal steel bars becomes 0.715 ${\mu}A/cm^2$ indicating that the steel bars are in moderate or high corrosion condition. However, the corrosion rates of the specimens with damaged epoxy-coated bars are significantly below 0.1 ${\mu}A/cm^2$ and the bars appears to be in passive condition. The damaged epoxy-coated bars with a corrosion inhibitor of calcium nitrite showed a corrosion rate of 0.110 ${\mu}m/year$ or 56 percents of the corrosion rate of damaged epoxy-coated specimen without such an inhibitor, 0.195 ${\mu}m/year$. However, the corrosion rates of specimens containing the other two corrosion inhibitors, a combination of amines and esters or mixtures of organic alkenyl dicarboxyl acid salts are quite equivalent to the control specimen. The research technique of linear polarization resistance method has proven itself to be useful in measuring corrosion rates of reinforcement in concrete.

Low Temperature PECVD for SiOx Thin Film Encapsulation

  • Ahn, Hyung June;Yong, Sang Heon;Kim, Sun Jung;Lee, Changmin;Chae, Heeyeop
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.198.1-198.1
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    • 2016
  • Organic light-emitting diode (OLED) displays have promising potential to replace liquid crystal displays (LCDs) due to their advantages of low power consumption, fast response time, broad viewing angle and flexibility. Organic light emitting materials are vulnerable to moisture and oxygen, so inorganic thin films are required for barrier substrates and encapsulations.[1-2]. In this work, the silicon-based inorganic thin films are deposited on plastic substrates by plasma-enhanced chemical vapor deposition (PECVD) at low temperature. It is necessary to deposit thin film at low temperature. Because the heat gives damage to flexible plastic substrates. As one of the transparent diffusion barrier materials, silicon oxides have been investigated. $SiO_x$ have less toxic, so it is one of the more widely examined materials as a diffusion barrier in addition to the dielectric materials in solid-state electronics [3-4]. The $SiO_x$ thin films are deposited by a PECVD process in low temperature below $100^{\circ}C$. Water vapor transmission rate (WVTR) was determined by a calcium resistance test, and the rate less than $10.^{-2}g/m^2{\cdot}day$ was achieved. And then, flexibility of the film was also evaluated.

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Fabrication of Porous Ceramic Materials for Biomedical and Environmental Applications

  • Lee, Byong-Taek
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.18.2-18.2
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    • 2009
  • Ceramics have some properties that are unmatched by other kind of materials like metals or polymers. The ability of high thermal and chemical resistance and in case of being superior in specific mechanical properties makes the ceramic materials suitable for arange of applications. The microstructure and morphology of a material arguably permit the use of many advanced application otherwise difficult to achieve.Porous structures have some important applications in biomedical and environmental field. For human hard tissue reconstruction and augmentation procedure suitable biomaterials are used with a desirable porosity. A range of porous bioceramics were fabricated with tailored design to meet the demand of specific applications. Channeled and interconnected porosity was introduced in alumina, zirconia, and hydroxyapatite or tri calcium phosphate ceramics by different methods like multi-pass extrusion process, bubble formation in viscous slurry,slurry dripping in immiscible liquid, sponge replica method etc. The detailed microstructural and morphological investigations were carried out to establish the unique features of each method and the developed systems. For environmental filters the porous structures were also very important. We investigated a range of channeled and randomly porous silicon based ceramic composites to enhance the material stability and filtration efficiency by taking advantage of the material chemistry of the element. Detailed microstructural and mechanical characterizations were carried out for the fabricated porous filtration systems.

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Acid-proof Test of PCM using the Ultre Rapid Hardening Cement (초속경성 PCM의 내산성)

  • 소양섭;박홍신;조영국
    • Magazine of the Korea Concrete Institute
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    • v.2 no.4
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    • pp.83-90
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    • 1990
  • Ultra Rapid Hardening Cement (LJRHC) makes immediate response, cracks and finally collapses in the 5 % acid solution. Such physical and chemical reaction is assumed to occur beCaUSE) it contains calcium aluminate( 11 Cao . 7AI,O, . CaF,) and the hydrate. This experimental study aims to improve URHC by making up for its weakness, which appears when its pro¬perties are compared with other cements properties, in the Polymer Cement Mortar(PCM) The result are : PCM using URHC proved to be inferior to PCM using other cements in the resistance to the acid in that the former cracked and collapsed after 10 days, and 22 days, in P/C=O%, and 5% respectively. And in P/C=15% and 20 % the PCM using URHC proved to be more resistant to the acid.

A Study on the Synthesis of Starch-Acrylic Polymer by Emulsion Polymerization (유화중합에 의한 전분-아크릴 고분자의 합성에 관한 연구)

  • Lee, Mi-Suk;Ryu, Hoon;Cho, Ur-Ryong
    • Polymer(Korea)
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    • v.34 no.1
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    • pp.58-62
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    • 2010
  • The acrylic monomers were graft-polymerized to starch as matrix polymer by emulsion polymerization. Viscosity and particle size of the emulsion were increased with starch contents due to interaction with water and particle swelling toward the water phase by hydroxy group of starch. Chemical stability of the emulsion was also increased with enhancement of starch, but water and alkali resistance were reduced with increasing starch contents because of the increasement of hyrophilicity. Opacity of the starch-acrylic emulsion compound containing calcium carbonate was decreased with contents of starch by its intrinsic color. The film of starch-acrylic polymer showed more clear appearance with increasing starch contents owing to enhancement of amorphous state.

Selectivity of cations in electrodialysis and its desalination efficiency on brackish water (전기투석 막여과의 이온제거 특성 및 지하염수의 담수화효율)

  • Choi, Su Young;Kweon, Ji Hyang
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.4
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    • pp.445-456
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    • 2013
  • In this study, desalination by electrodialysis with ion exchange membranes was applied to synthetic waters with various ion concentrations and also for ground waters from coastal areas in Korea. Electrodialysis performance on the synthetic solutions showed the similar tendency in operation time and current curves, i.e., shorter operation time and higher maximum current with increasing applied voltages. The ED results of synthetic waters with different ion compositions, i.e., $Na_2SO_4$, $MgSO_4$, $CaSO_4$, at the similar conductivity condition, i.e., $1,250{\mu}s/cm$ revealed that effects of mono- and divalent ions on water quality and performance in electrodialysis were different. The divalent ions had less efficiency in the ED compared to monovalent sodium ions and also divalent calcium ions showed better performance than Mg ions. The electrodialysis on the ground waters produced high quality of drinking water. The groundwater from SungRoe however showed a buildup of membrane resistance. Organic matter concentrations and great portions of divalent ions in the groundwater were possible causes of the deteriorated performance.

Self Cleaning and Durability of Silicate Impregnant of Concrete (콘크리트 침투성 표면보호재의 자기세정 및 내구특성)

  • Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.433-436
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    • 2008
  • Deterioration in the concrete structure are due to carbonation, chloride ion attack and frost attack. Therefore, concrete structure is needed to surface protection for increase durability using silicate impregnants. Thus, this study is concerned with self-cleaning and durability of silicate hydrophilic impregnants of concrete structure using lithium and potassium silicates. From the experimental test results, lithium and potassium silicates have a good properties as a carbonation resistance. Lithium and potassium silicates make good use of hydrophilic impregnants of concrete structures.

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