• Title/Summary/Keyword: calcium processing

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Processability Enhancement in Melt Processing of Poly(ethylene naphthalate) (폴리(에틸렌 나프탈레이트)의 가공 특성 향상 연구)

  • Kim Hyogap;Kang Ho-Jong
    • Polymer(Korea)
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    • v.29 no.5
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    • pp.475-480
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    • 2005
  • The lowering of melt viscosity has been investigated to achieve the processability enhancement in poly(ethylene naphthalate) (PEN) melt processing by the reactive melt blending with poly(ethylene terephthalate) (PET) and introducing lubricant as well. CaST lubricant resulted in the lowering of PEN melt viscosity but noticeable mechanical property drop was found in PEN with more than $2wt\%$ of lubricant due to the acceleration of thermal degradation by excess lubricant. PEN/PET (90/10) blend has less melt viscosity than PEN and transesterification between two polymers caused the additional viscosity depression. further viscosity lowering was found in PEN/PET blend with CaST since CaST is acting as the catalyst of transesterification as well as a lubricant in PEN/PET blend.

Development and Quality Characteristics Evaluation of Senior-friendly Seafood Products Using Softening Processes of the Pacific Saury Cololabis saira (꽁치(Cololabis saira)의 물성연화를 통한 고령친화형 수산식품의 개발 및 품질특성 평가)

  • Sun-Young Park;Mi-Soon Jang;Jae-Young Oh;Seok-Min Lee;Si-Hyeong Park;Yu-Ri Choe;Jin-Soo Kim;Sang-In Kang
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.56 no.6
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    • pp.773-780
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    • 2023
  • This study was conducted to prepare curry potato pancakes (CPP), curry fish balls (CFB) and steamed eggs (SE) using Pacific saury Cololabis saira as senior-friendly seafood and to determine the physical property stages and quality characteristics of the prepared food. Escherichia coli concentrations were undetected in all the products, which is considered an acceptable limit for senior-friendly foods. On applying the physical properties standards according to the Korean Industrial Standard, saury CPP, saury CFB, and saury SE were classified as the 1st, 2nd, and the 3rd stages as senior-friendly seafood, respectively. Regarding the nutritional properties per 100 g of the three types of senior-friendly seafood using saury according to the Korean food code, CPP had three types of nutrients (protein, riboflavin, and niacin), whereas CFB and SE had four (protein, riboflavin, niacin and calcium) and six (protein, vitamin D, vitamin C, riboflavin, niacin, and calcium) types of nutrients, respectively.

Effectiveness of biphasic calcium phosphate block bone substitutes processed using a modified extrusion method in rabbit calvarial defects

  • Lim, Hyun-Chang;Song, Kyung-Ho;You, Hoon;Lee, Jung-Seok;Jung, Ui-Won;Kim, Suk-Young;Choi, Seong-Ho
    • Journal of Periodontal and Implant Science
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    • v.45 no.2
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    • pp.46-55
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    • 2015
  • Purpose: This study evaluated the mechanical and structural properties of biphasic calcium phosphate (BCP) blocks processed using a modified extrusion method, and assessed their in vivo effectiveness using a rabbit calvarial defect model. Methods: BCP blocks with three distinct ratios of hydroxyapatite (HA):tricalcium phosphate (TCP) were produced using a modified extrusion method:HA8 (8%:92%), HA48 (48%:52%), and HA80 (80%:20%). The blocks were examined using scanning electron microscopy, X-ray diffractometry, and a universal test machine. Four circular defects 8 mm in diameter were made in 12 rabbits. One defect in each animal served as a control, and the other three defects received the BCP blocks. The rabbits were sacrificed at either two weeks (n=6) or eight weeks (n=6) postoperatively. Results: The pore size, porosity, and compressive strength of the three types of bone block were $140-170{\mu}m$, >70%, and 4-9 MPa, respectively. Histologic and histomorphometric observations revealed that the augmented space was well maintained, but limited bone formation was observed around the defect base and defect margins. No significant differences were found in the amount of new bone formation, graft material resorption, or bone infiltration among the three types of BCP block at either of the postoperative healing points. Conclusions: Block bone substitutes with three distinct compositions (i.e., HA:TCP ratios) processed by a modified extrusion method exhibited limited osteoconductive potency, but excellent space-maintaining capability. Further investigations are required to improve the processing method.

The Effect of Modified Atmosphere Packaging and Addition of Rosemary Extract, Sodium Acetate and Calcium Lactate Mixture on the Quality of Pre-cooked Hamburger Patties during Refrigerated Storage

  • Muhlisin, Muhlisin;Kang, Sun Moon;Choi, Won Hee;Lee, Keun Taik;Cheong, Sung Hee;Lee, Sung Ki
    • Asian-Australasian Journal of Animal Sciences
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    • v.26 no.1
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    • pp.134-142
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    • 2013
  • The effect of modified atmosphere packaging (MAP; 30% $CO_2$+70% $N_2$ or 100% $N_2$) and an additive mixture (500 ppm rosemary extract, 3,000 ppm sodium acetate and 1,500 ppm calcium lactate) on the quality of pre-cooked hamburger patties during storage at $5^{\circ}C$ for 14 d was evaluated. The addition of the additive mixture reduced aerobic and anaerobic bacteria counts in both 30% $CO_2$-MAP (30% $CO_2$+70% $N_2$) and 100% $N_2$-MAP (p<0.05). The 30% $CO_2$-MAP was more effective to suppress the microbial growth than 100% $N_2$-MAP, moreover the 30% $CO_2$-MAP combined with additive mixture resulted in the lowest bacterial counts. The hamburger patties with additive mixture showed lower CIE $L^*$ and CIE $a^*$, and higher CIE $b^*$ than those with no additive mixture. The 30% $CO_2$-MAP tended to decrease the TBARS during storage regardless of the addition of additives. The use of 30% $CO_2$-MAP in combination with additives mixture was effective for maintaining the quality and extending the shelf-life of pre-cooked hamburger patties.

Loss of Heterozygosity at the Calcium Regulation Gene Locus on Chromosome 10q in Human Pancreatic Cancer

  • Long, Jin;Zhang, Zhong-Bo;Liu, Zhe;Xu, Yuan-Hong;Ge, Chun-Lin
    • Asian Pacific Journal of Cancer Prevention
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    • v.16 no.6
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    • pp.2489-2493
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    • 2015
  • Background: Loss of heterozygosity (LOH) on chromosomal regions is crucial in tumor progression and this study aimed to identify genome-wide LOH in pancreatic cancer. Materials and Methods: Single-nucleotide polymorphism (SNP) profiling data GSE32682 of human pancreatic samples snap-frozen during surgery were downloaded from Gene Expression Omnibus database. Genotype console software was used to perform data processing. Candidate genes with LOH were screened based on the genotype calls, SNP loci of LOH and dbSNP database. Gene annotation was performed to identify the functions of candidate genes using NCBI (the National Center for Biotechnology Information) database, followed by Gene Ontology, INTERPRO, PFAM and SMART annotation and UCSC Genome Browser track to the unannotated genes using DAVID (the Database for Annotation, Visualization and Integration Discovery). Results: The candidate genes with LOH identified in this study were MCU, MICU1 and OIT3 on chromosome 10. MCU was found to encode a calcium transporter and MICU1 could encode an essential regulator of mitochondrial $Ca^{2+}$ uptake. OIT3 possibly correlated with calcium binding revealed by the annotation analyses and was regulated by a large number of transcription factors including STAT, SOX9, CREB, NF-kB, PPARG and p53. Conclusions: Global genomic analysis of SNPs identified MICU1, MCU and OIT3 with LOH on chromosome 10, implying involvement of these genes in progression of pancreatic cancer.

A Study on the Electrochemical Properties Fabrication Process of Mg-Ca Sacrificial Anode for the Corrosion Protection of Steel Structures (철 구조물의 부식방지를 위한 Mg-Ca 희생양극의 전기화학적 특성과 제조에 관한 연구)

  • Park, Kang-Geun;Kim, Hye-Sung
    • Journal of Korean Association for Spatial Structures
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    • v.6 no.4 s.22
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    • pp.73-80
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    • 2006
  • It is an object of the present paper to investigate a electrochemical properties of Mg-based sacrificial anodes and the effect of calcium added from calcium chloride into magnesium on the melt protection during the melting. Electrochemical data will be correlated with processing control variables, and the microstructural change by the addition of CaCl2. Small addition of calcium into magnesium from CaCl2 imparts beneficial effect in electrochemical properties of Mg alloys, primarily, through microstructural modifications. In addition, the protection effect of the melts surface of Ca with low melting point modification is obtained by adding Ca not more than 0.6%.

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Fabrication and Characterization of Biphasic Calcium Phosphate Scaffolds with an Unidirectional Macropore Structure Using Tertiary-Butyl Alcohol-Based Freeze-Gel Casting Method (동결-젤 주조 공정 기반 삼차부틸알코올을 이용한 단일방향 기공구조를 가지는 이상인산칼슘 세라믹 지지체의 제조 및 특성평가)

  • Kim, Kyeong-Lok;Ok, Kyung-Min;Kim, Dong-Hyun;Park, Hong-Chae;Yoon, Seog-Young
    • Journal of the Korean Ceramic Society
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    • v.50 no.4
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    • pp.263-268
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    • 2013
  • Porous biphasic calcium phosphate scaffolds were fabricated by a freeze-gel casting technique using a tertiary-butyl alcohol (TBA)-based slurry. After sintering, unidirectional macropore channels of scaffolds aligned regularly along the TBA ice growth direction were tailored simultaneously with micropores formed in the outer wall of the pore channels. The crystallinity, micro structure, pore configuration, bulk density, and compressive strength for the scaffolds were investigated with X-ray diffractometery, scanning electron microscopy analysis, a water immersion method, and a universal test machine. The results revealed that the sintered porosity and pore size generally resulted in a high solid loading which resulted in low porosity and small pore size, which relatively increased the higher compressive strength. After being sintered at $1100-1300^{\circ}C$, the scaffolds showed an average porosity and compressive strength in the range 35.1-74.9% and 65.1-3.0 MPa, respectively, according to the processing conditions.

Effect of the Calcium Nitrate Solution Treatment on the Tensile, Bending, and Shear Properties of Silk Fabric

  • Park, Su-Zin;Kang, Ji-Young;Seol, Da-Won;Yang, Hye-Min;Lee, Ji-Min;Ahn, Ye-Ji;Han, Seo-Young;Kim, Jong-Jun
    • Journal of Fashion Business
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    • v.14 no.6
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    • pp.39-52
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    • 2010
  • Interests in creating three-dimensionally designed fabric materials are growing rapidly in the sectors of the fashionable textiles with the creativity, new functions, and aesthetics. A number of finishing methods have been developed and proposed to add or create new functions and designs for silk fabrics. Due to the strong hydrogen bonds between the molecules of silk fibroins, the thermal treatment methods used in thermoplastic fiber processing, which can easily deform the synthetic filament fabrics to endow three-dimensional appearance to the fabrics, are not applicable to the silk fabric treatment. In order to modify the fine structure of silk fiber, neutral salt solution treatment methods have been suggested. In this study, the effect of the calcium nitrate solution on the physical and mechanical properties of silk fabrics was investigated by using the KES(Kawabata Evaluation System) equipment. Based on these findings, relationships between parameters, for example, the thickness and the compressional energy, the thickness and the compressional linearity, and the air permeability and the pore area statistical analysis were investigated. The relationships between the process parameters such as treatment temperature/time and the resulting fabric property parameters were also analyzed by using several SAS procedures.

Study on the Dispersion Stability of Precipitated Calcium Carbonate Suspensions (침강성 탄산칼슘 현탁액의 분산 안정성에 관한 연구)

  • Park, Myung-Jae;Ahn, Ji-Whan;Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.38 no.4
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    • pp.343-350
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    • 2001
  • 본 연구에서는 탄산화법으로 침강성 CaCO$_3$분말을 제조하고 제조된 CaCO$_3$현탁액의 분산안정성을 연구하였다. CaCO$_3$현탁액의 pH 변화와 고분자전해질 PMAA와 PAA의 첨가에 따른 입자크기, 유동학적 특성(점도), zeta potential 및 현탁액의 침강속도 등을 측정하였다. 탄산화법에 의해 약 0.1$\mu\textrm{m}$ 크기와 비표면적이 23.57$m^2$/g인 단분단 calcite형 CaCO$_3$분말을 제조하였다. pH가 11인 CaCO$_3$현탁액에 0.01 wt% PMAA가 첨가된 경우에 우수한 분산안정성을 나타내었는데 이는 CaCO$_3$입자표면에 PMAA의 흡착에 의한 electrosteric 안정화기구와 CaCO$_3$입자들 사이의 정전기적 반발력에 의한 것으로 판단된다. PMAA와 PAA 첨가량 변화에 따른 pH 6, 9, 11의 CaCO$_3$현탁액의 침전높이를 측정한 결과 PMAA와 PAA의 농도가 0.15 wt% 부근에서 분산안정성을 보였는데 이는 CaCO$_3$입자들 사이간의 분산제에 의한 뚜렷한 경계를 갖는 흡착층이 형성되었기 때문으로 생각되며 따라서 CaCO$_3$현탁액의 최적 분산안정성을 위해서는 적절한 pH 조절과 PMAA 및 PAA의 첨가가 필요함을 알 수 있다.

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Effects of Temperature on the Rheology of Lecithin/CaCl2 Organogels (Lecithin/CaCl2 유기젤의 온도 영향에 대한 유변학적 연구)

  • Jung, Yeon-Geon;Lee, Hee-Young
    • Applied Chemistry for Engineering
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    • v.29 no.2
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    • pp.244-247
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    • 2018
  • Lecithin, a zwitterionic phospholipid, forms spherical reverse micelles in organic solvents such as decane. The addition of multivalent ions like calcium chloride to lecithin organosols induces the transformation of organosols into organogels. A variety of applications of such organogels were found in gelation of fuels, food processing and drug delivery. Here, we investigated the effect of temperature on their rheological properties. In particular, the organogels showed a distinct melting temperature (${\sim}95^{\circ}C$) and their elastic properties decreased with increasing temperature. This is maybe due to the fact that the electrostatic interaction between lecithin and calcium chloride could be weaken with increasing temperature.