• Title/Summary/Keyword: c/c composite

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Synthesis and Electrochemical Characterization of Porous Co3O4/RuO2 Composite (다공성 Co3O4/RuO2 복합체 합성 및 전기화학적 특성)

  • Lim, Hye-Min;Ryu, Kwang-Sun
    • Korean Journal of Materials Research
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    • v.22 no.3
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    • pp.118-122
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    • 2012
  • We synthesized porous $Co_3O_4/RuO_2$ composite using the soft template method. Cetyl trimethyl ammonium bromide (CTAB) was used to make micell as a cation surfactant. The precipitation of cobalt ion and ruthenium ion for making porosity in particles was induced by $OH^-$ ion. The porous $Co_3O_4/RuO_2$ composite was completely synthesiszed after anealing until $250^{\circ}C$ at $3^{\circ}C$/min. From the XRD ananysis, we were able to determine that the porous $Co_3O_4$/RuO2 composite was comprised of nanoparticles with low crystallinity. The shape or structure of the porous $Co_3O_4/RuO_2$ composite was studied by FE-SEM and FE-TEM. The size of the porous $Co_3O_4/RuO_2$ composite was 20~40 nm. From the FE-TEM, we were able to determine that porous cavities were formed in the composite particles. The electrochemical performance of the porous $Co_3O_4/RuO_2$ composite was measured by CV and charge-discharge methods. The specific capacitances, determined through cyclic voltammetry (CV) measurement, were ~51, ~47, ~42, and ~33 F/g at 5, 10, 20, and 50 mV/sec scan rates, respectively. The specific capacitance through charge-discharge measurement was ~63 F/g in the range of 0.0~1.0 V cutoff voltage and 50 mAh/g current density.

A Study on the Reduction Mechanism of Tungsten and Copper Oxide Composite Powders (W-Cu산화물 복합분말의 환원 기구에 관한 연구)

  • Lee, Seong;Hong, Moon-Hee;Kim, Eun-Pyo;Lee, Sung-Ho;Noh, Joon-Woong
    • Journal of Powder Materials
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    • v.10 no.6
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    • pp.422-429
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    • 2003
  • The reduction mechanism of the composite powders mixed with $WO_3$ and CuO has been studied by using thermogravimetry (TG), X-ray diffraction, and microstructure analyses. The composite powders were made by simple Turbula mixing, spray drying, and ball-milling in a stainless steel jar with the ball to powder ratio of 32 to 1 at 80 rpm for 1 h without process controlling agents. It is observed that all the oxide composite powders are converted to W-coated Cu composite powder after reducing treatment under hydrogen atmosphere. For the formation mechanism of W-coated Cu composite powder, the sequential reduction steps are proposed as follows: CuO contained in the ball-milled composite powder is initially reduced to Cu at the temperature range from 20$0^{\circ}C$ to 30$0^{\circ}C$. Then, $WO_3$ powder is reduced to W $O_2$ via W $O_{2.9}$ and W $O_{2.72}$ at higher temperature region. Finally, the gaseous phase of $WO_3(OH)_2$ formed by reaction of $WO_2$ with water vapour migrates to previously reduced Cu and deposits on it as W reduced by hydrogen. The proposed mechanism has been proved through the model experiment which was performed by using Cu plate and $WO_3$ powder.

A Study on Low Velocity Impact and Residual Compressive Strength for Carbon/Epoxy Composite Laminate (탄소섬유/에폭시 복합적층판의 저속 충격 및 잔류 압축강도에 관한 연구)

  • Lee, S.Y.;Park, B.J.;Kim, J.H.;Lee, Y.S.;Jeon, J.C.
    • Proceedings of the KSME Conference
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    • 2000.11a
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    • pp.250-255
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    • 2000
  • Damage induced by low velocity impact loading in aircraft composite laminates is the form of failure which is occurred frequently in aircraft. Low velocity impact can be caused either by maintenance accidents with tool drops or by in-flight impacts with debris. As the consequences of impact loading in composite laminates, matrix cracking, delamination and eventually fiber breakage for higher impact energies can be occurred. Even when no visible impact damage is observed, damage can exist inside of composite laminates and the carrying load of the composite laminates is considerably reduced. The reduction of strength and stiffness by impact loading occurs in compressive loading due to laminate buckling in the delaminated areas. The objective of this study is to determine inside damage of composite laminates by impact loading and to determine residual compressive strength and the damage growth mechanisms of impacted composite laminates. For this purpose a series of impact and compression after impact tests are carried out on composite laminates made of carbon fiber reinforced epoxy resin matrix with lay up pattern of $[({\pm}45)(0/90)_2]s$ and $[({\pm}45)(0)_3(90)(0)_3({\pm}45)]$. UT-C scan is used to determine impact damage characteristics and CAI(Compression After Impact) tests are carried out to evaluate quantitatively reduction of compressive strength by impact loading.

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Assessment of Lateral Behavior of Steel-concrete Composite Piles Using Full-scale Model Tests (실대형 모형 실험을 이용한 강관합성 말뚝의 수평 거동 특성 평가)

  • Kwon, Hyungmin;Lee, Juhyung;Park, Jaehyu;Chung, Moonkyung
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.5C
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    • pp.199-206
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    • 2009
  • This paper presents full scale model tests on the various types of model piles carried out to estimate the behavior of laterally loaded steel-concrete composite piles. Subgrade-reaction spring system was developed to simulate the reaction of ground in laboratory condition. In addition, lateral behavior of piles under working load condition was estimated using composite loading system, which is available for independent loading in vertical and horizontal direction. Steel-concrete composite piles showed higher efficiency in lateral resistance rather than drilled shaft made of reinforced concrete. The lateral resistance of composite pile was larger than the summation of steel pile and concrete pile due to the composite effect by steel casing. The effect of shear key or strength of concrete on the behavior of composite pile was examined. The substitution of reinforcing bar by steel casing was also investigated.

Developing of Sound Absorption Composite Boards Using Carbonized Medium Density Fiberboard (탄화 중밀도섬유판을 이용한 목재흡음판 개발)

  • Lee, Min;Park, Sang-Bum;Byeon, Hee-Seop;Kim, Jong-In
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.6
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    • pp.714-722
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    • 2014
  • In the previous study, a variety of wood-based panels was thermally decomposed to manufacture carbonized boards that had been proved to be high abilities of insect and fungi repellence, corrosion and fire resistant, electronic shielding, and formaldehyde adsorption as well as sound absorption performance. Based on the previous study, carbonized medium density fiberboard (c-MDF) was chosen to improve sound absorption performance by holing and sanding process. Three different types of holes (cross shape, square shape, and line) with three different sanding thickness (1, 2, and 3 mm) were applied on c-MDF and then determined sound absorption coefficient (SAC). The control c-MDF without holes had 14% of SAC, however, those c-MDFs with holes had 16.01% (square shape), 15.68% (cross shape), and 14.25% (line) of SAC. Therefore, making holes on the c-MDF did not significantly affect on the SAC. As the degree of sanding increased, the SAC of c-MDF increased approximately 65% on sanding treated c-MDFs (21.5, 21.83, and 19.37%, respectively) compared to the control c-MDF (13%). Based on these results, composite sound absorbing panel was developed with c-MDF and MDF (11 mm). The noise reduction coefficient of composite sound absorbing panel was 0.45 which was high enough to certify as sound absorbing material.