• 한국세라믹학회지
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• 제48권5호
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• pp.335-341
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• 2011

Continuous SiC fiber-reinforced SiC-matrix composites ($SiC_f$/SiC) had been fabricated by electrophoretic infiltration combined with ultrasonication. Nano-sized ${\beta}$-SiC added with 12 wt% of $Al_2O_3-Y_2O_3$ additive and Tyranno$^{TM}$-SA3 fabric were used as a matrix phase and fiber reinforcement, respectively. After hot pressing at 5 different conditions, the density, microstructure and mechanical properties of $SiC_f$/SiC were characterized. Hot pressing at relatively severe conditions, such as $1750^{\circ}C$ for 1 and 2 h, resulted in a brittle fracture behavior due to the strong fiber-matrix interface in spite of their high flexural strength. On the other hand, toughened $SiC_f$/SiC composite could be achieved by hot pressing at milder condition because of the formation of weak interface in spite of the decreased flexural strength. These results proposed the importance of weak fiber-matrix interface in the fabrication of ductile $SiC_f$/SiC composite.

• Bulletin of the Korean Chemical Society
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• 제35권6호
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• pp.1794-1798
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• 2014

Graphitic g-$C_3N_4-WO_3$ composite was synthesized simply by decomposing melamine in the presence of $WO_3$ at $500^{\circ}C$. The obtained material was characterized by XRD, SEM, IR and XPS. The results showed that the as-prepared composite exhibits orthorhombic $WO_3$ phase coated by g-$C_3N_4$ and the g-$C_3N_4$ decomposed completely with N-doped $WO_3$ remaining at elevated calcination temperatures. The photocatalytic activity of the composite was evaluated by the photodegradation of methylene blue under visible light. An enhancement in photocatalytic activity for the graphitic g-$C_3N_4-WO_3$ composite compared to the conventional nitrogen-doped $WO_3$ was observed, which can be attributed to the presence of g-$C_3N_4$ in the material.

• 한국수소및신에너지학회논문집
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• 제20권5호
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• pp.361-370
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• 2009

Ni-PTFE composite plated on graphite (C/Ni-PTFE) and PTFE (PTFE/Ni-PTFE) particles were prepared uniformly by electroless composite plating. The conductivity of C/Ni-PTFE particles was 280 S/m higher than 95 S/m of PTFE/Ni-PTFE particles at same composite plating condition (Ni:35~36 wt%, PTFE:8 wt%). The C/Ni-PTFE particles were formed into the C/Ni-PTFE plate using heat treatment at $350^{\circ}C$ under 10~$1000\;kg/cm^2$. The C/Ni-PTFE plate showed 1) high conductivity of $5.7\;{\times}\;10^4\;S/m$ due to the existence of graphite as conducting aid and the formation of 3-dimensional Ni network 2) good gas diffusion caused by various pore volumes (0.01~$100\;{\mu}m$) in the plate. The plate could be useful for an electrode in an alkaline fuel cell (AFC). The current density of C/Ni-PTFE electrode indicated $84\;mA/cm^2$ at 0.3V and it was 3.0 times higher than that of PTFE/Ni-PTFE electrode.

• Composites Research
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• 제21권6호
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• pp.15-22
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• 2008

본 연구는 SiC입자를 20% 강화된 알루미늄기 복합재료를 이용해서 평면굽힘피로시험을 향했다. 표면미소피로균열의 발생 및 진전거동은 레프리카법으로 연속관찰을 했고 파괴원인과 파괴기구를 규명하기 위해서 주사전자현미경을 이용했다. da/dn-$K_{max}$ 관계에서 저응력 레벨에서는 여러 개의 균열이 진전하고, 합체 등이 일어나는 것으로부터 진전속도는 꽤 분산(흐트러짐)이 심하고, 고응력 레벨에서는 비교적 흐트러짐은 적게 나타나는 것을 알 수 있었다.

• 한국세라믹학회지
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• 제37권4호
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• pp.302-307
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• 2000

The objective of this study was to investigate the sintering behavior, crystallization characteristic of glass-ceramic and optimal sintering condition on the glass/ceramic composite for fabricating substrate of LTCC. Glass/ceramic composite was made from alumina powder and glass frit, which was composed of SiO2-TiO2-RO-PbO/(R: Ba, Sr, Ca), and was sintered for 0, 30, 60minutes in the temperature range from 700$^{\circ}C$ to 1000$^{\circ}C$. Properties of frit and glass/ceramic compsoite were analyzed by DTA, XRD, SEM and Network Analyzer and so on. Main sintering mechanism was densification occurred above 730$^{\circ}C$ by viscous flow and crystallization starting about 780$^{\circ}C$ affected sintering also. So viscous flow was affected by sintering temperature, duration time, and creation of crystallization phase etc. From this study, it was possible to fabricate glass/ceramic composite by changing sintering temperature and duration time.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2001년도 추계학술발표대회 논문집
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• pp.141-143
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• 2001

Ceramic fiber-reinforced composites have good mechanical properties in hardness and durability. In this study, we studied the formation of SiC/C composites from methyltrichlorosilane and hydrogen by the Pulse-chemical vapor infiltration(PCVI) to deposit silicon carbide around the changes of the amount of deposit. SiC/C composites formed at $950^{\circ}C$, 20torr, Pulse-times (5s/60s). SEM of the cross sectional area of semple showed deposited silicon carbide around fibers.

• 대한기계학회논문집A
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• 제31권4호
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• pp.425-431
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• 2007

[ $Al_2O_3/SiC$ ]composite ceramics were sintered to evaluate the bending strength and elastic wave characteristics. The three-point bending test was carried out under room temperature. The elastic wave was detected by fracture wave detector. The crack healing behavior was investigated from 1373 K to 1723 K. The bending strength of $Al_2O_3/SiC$ composite by nanocomposite is higher than that of $Al_2O_3$ monolithic. Crack-healing behavior depended on an amount of additive powder $Y_2O_3$. In $Al_2O_3/SiC$ composite ceramics with 3 wt. % $Y_2O_3$ for additive powder, the bending strength at 1573 K is about 100% increase than that of the smooth specimens. From the result of wavelet analysis of elastic wave signal, the smooth specimen and heat treated specimen of $Al_2O_3$ monolithic and $Al_2O_3/SiC$ composite ceramics showed characteristics of frequency about 58 kHz. The strength of $Al_2O_3/SiC$ composite ceramics was a little higher than those of $Al_2O_3$ monolithic. The dominant frequencies were high with increasing of $Y_2O_3$ for additive powder. The dominant frequencies had direct connection with the bending strength.

• 한국세라믹학회지
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• 제35권9호
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• pp.923-932
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• 1998

Al2O3/Al composites were produced by displacement reaction method which was carried out by imm-ersing the sintered silica preform which was prepared form fused silica powder in molten aluminu. an ac-tivation energy of 94kJ/mole was calculated from Al-SiO2 reaction data in 1000-130$0^{\circ}C$ temperature range With increase of reaction temperature the alumina particle in the Al2O3/Al composites produced with pur metal Al showed grain growth and the growth of alumina particle in Al2O3/Al composite produced by using of Mg contained Al alloy was inhibited. The flexural strength of Al2O3/Al composites produced at 100$0^{\circ}C$ showed the highest value as 393 MPa. Flexural strength of the composite fabricated at 85$0^{\circ}C$ showed higher deviation than that of the composite produced at above 100$0^{\circ}C$ Low flexural strength of the composite fa-bricated at 120$0^{\circ}C$ due to the growth of pore and alumina particle size. The hardness of composites de-pended on alumina content in Al2O3/Al composite decreased with increasing of aluminium content in case the same alumina content and increased with increasing of silicon content in composite.

• 한국주조공학회지
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• 제15권6호
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• pp.566-573
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• 1995

In this study, the microstructural characteristics such as primary silicon, eutectic silicon, $SiC_p$ dispersion behavior, compound amount and Si solubility in $Al/SiC_p$ composite fabricated by the squeeze casting under various conditions were investigated systematically. As applied pressure(MPa) increases, cooling rate and compound amount are increased. In gravity casting, the cooling rate of hypereutectic composite is slower than of hypoeutectic composite by exothermic reaction of primary Si crystallization. But the cooling rate of hypereutectic composite is faster than that of hypoeutectic composite fabricated by same applied pressure, because amount of primary Si crystallization in hypereutectic composite was decreased, on the contrary, primary ${\alpha}-Al$ in hypoeutetic composite was increased due to increase of Si solubility in matrix by applied pressure. The crystalized primary silicon in hypereutectic composite fabricated by squeeze casting become more fine than that in non-pressure casting This is because mush zone became narrow due to increase of Si content of eutectic composition by pressure and time for growth of primary silicon got shorter according to applied pressure. It is turned out that eutectic temperature and liquidus are decreased by the increasing of squeeze pressure in all the composite due to thermal unstability of matrix owing to increasing of Si solubility in matrix by the increasing of applied pressure, as indicated in thermal anaiysis(DSC) results.

• Composites Research
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• 제32권3호
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• pp.148-157
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• 2019

본 연구에서는 탄소섬유, 탄화규소섬유 그리고 하이브리드섬유를 강화재로 하여 TGCVI와 PIP 혼합 공정으로 $C_f/SiC$, $SiC_f/SiC$, $C_f-SiC_f/SiC$의 세라믹복합재를 제조하였다. 열충격싸이클시험, 3점 굴곡시험과 Oxy-Acetylene 토취 시험후에 그들의 기계적물성, 산화저항성과 내삭마성을 평가하였다. $C_f/SiC$복합재는 온도 증가에 따라서 기계적물성의 감소와 준 연성의 파단모드, 그리고 높은 삭마량을 보였다. $SiC_f/SiC$복합재는 $C_f/SiC$ 복합재에 비하여 강한 기계적물성, 낮은 삭마량을 그리고 취성의 파단모드를 나타냈다. 한편 하이브리드 복합재는 가장 우수한 기계적물성과 $SiC_f/SiC$보다는 연성의 파단모드 그리고 $C_f/SiC$ 보다 낮은 삭마량의 결과를 나타냈다. Oxy-Acetylene 토취 시험 중에 SiC매트릭스는 산화되어 $SiO_2$층을 형성하였으며, 특히 이 층은 $C_f-SiC_f/SiC$와 $SiC_f/SiC$ 복합재에서 섬유의 추가적인 삭마를 막는 역할을 하는 것으로 나타났다. 결론적으로 낮은 기공율을 갖는 하이브리드 복합재를 제조한다면, $C_f/SiC$의 산화로 인한 기계적물성의 감소와 $SiC_f/SiC$ 복합재의 취성 파단모드의 개선으로 고온 산화분위기에서 고온열구조재로의 적용이 높을 것으로 기대한다.