• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
• /
• pp.107-109
• /
• 2014

Through the economic development, people enjoying the camping and demand of camping goods are increasing since they have free time. So they use portable butane gas range outdoor. In addition to that, many restaurants that offer hotpot or meat in Korea use portable butane gas ranges for their convenience. But 19% of gas accidents are using portable butane gas range, 13.7% of them are using oversized cookware. Despite the high accident rate, there is no safety standards about portable butane gas range using oversized cookware. Therefore we conducted to measure temperature and pressure of portable butane gas ranges for reforming safety standards. As a result. we confirmed relation between bottom temperature of the portable butane gas barrel and pressure of the butane gas. Also we confirmed that portable butane gas ranges operate safely when bottom temperature of the portable butane gas barrel is bellow $50^{\circ}C$.

• 한국지하수토양환경학회지:지하수토양환경
• /
• 제8권1호
• /
• pp.27-34
• /
• 2003

본 논문에서는 순수균주인 ENV425와 유류오염토양에서 butane을 탄소원 및 에너지원으로 이용하여 분리한 혼합균주를 대상으로 MTBE와 기타 가솔린 산화제 분해특성을 조사했다. ENV425와 혼합균주의 butane monooxygenase (BMO)에 의해 butane 분해시 1-butanol이 주요 부산물로 축적되었다. 또한 monooxygenase의 방해자로 알려진 acetylene의 첨가시에는 butane의 분해 및 1-butane떠 축적이 일어나지 않아 butane monooxygenase에 의한 분해임을 알 수 있다. 본 연구결과에서, propane, pentane, butane을 포함한 alkane류는 MTBE 공대사에 우수한 성장기질이었고, BTEX 화합물 역시 MTBE 공대사에 가능성 있는 기질임이 관찰되었다. 또한 균주농도 역시 MTBE분해에 영향을 미치는 것으로 나타났는데, 균주 농도 증가에 따라 MTBE 분해량은 증가하나 transformation capacity는 상대적으로 감소하는 경향을 보였다. 그리고 대표적인 가솔린 산화제인 MTBE 외에 ETBE, TAME도 부탄분해균에 의해 효과적으로 분해가 이루어짐이 관찰되었다.

• 한국연소학회지
• /
• 제22권2호
• /
• pp.50-56
• /
• 2017

This study was conducted an experiment for the thermal flow mechanism of the surrounding butane gas can and pressure change in butane can with oversized cookware. And numerical analysis was performed to analyze the process of heat transfer around butane can. Effect of radiant heat from small size cookware is very small. Thus small size cookware does not have a significant impact on the butane gas range safety. But radiant heat of oversized cookware is larger than small size cookware. Therefore it gives an adverse effect on the butane can. And when internal pressure of butane can is greater than about 406.8~447.2 kPa, a safety device of portable butane gas range were working. The causes of safety device working is because of trivet height. Trivet height is lowered, the radiant heat is increased. This radiant heat is to raise pressure of inside butane can. Experimental and numerical analysis results, the lower thermal conductivity of the cookware is greater the effects of radiant heat.

• 한국결정성장학회지
• /
• 제7권1호
• /
• pp.174-184
• /
• 1997

야자각탄으로부터 수증법을 이용하여 활성탄을 제조하였다. 활성화 온도와 시간, 수증기의 농도와 양이 n-butane 흡착특성에 미치는 영향을 비표면적, 기공분석, n-butane 흡착량을 측정함으로서 분석하였다. 90$0^{\circ}C$ 이하에서 활성화한 경우 온도와 시간이 증가하거나 수증기의 농도와 양이 많을수록 n-butane 흡착량은 증가하였으나 95$0^{\circ}C$에 이르면 이러한 경향은 나타나지 않았다. $900^{\circ}C$, 185분간 활성화한 시료는 비표면적 978 $\textrm{m}^2$/g, 평균기공 크기 9.3 $\AA$, n-butane 흡착랑이 5.9 g/100 ml이었다.

• 한국가스학회지
• /
• 제15권3호
• /
• pp.39-46
• /
• 2011

본 연구에서는 DME와 n-Butane 연료를 사용하여 혼합연료 및 성층화효과가 HCCI 연소 특성에 미치는 영향을 화학반응수치계산을 통해서 알아보고자 한다. 우선, 기존에 완성된 DME와 n-Butane 반응스킴을 이용하여 새로운 화학 반응 모델을 만들고 기존의 DME 화학 반응 모델과 n-Butane 화학 반응 모델과 비교하여 유효성을 확보한다. 나아가, 자발화 특성이 다른 DME와 n-Butane 두 연료의 혼합비 변화에 따른 HCCI 연소 특성을 파악한다. 마지막으로, 혼합 연료를 각각 성층급기 했을 경우에 압력상승률 저감 효과를 파악 한다.

• 한국연소학회지
• /
• 제19권4호
• /
• pp.35-41
• /
• 2014

The experiment was conducted to measure temperature and pressure around operating portable butane gas ranges with oversized cookwares. In this experiment, portable butane gas range with different safety equipment and two kinds of oversized cookware, each of which is made of aluminum alloy and rock, was used. As a result, temperature of the bottom of the butane and the pressure of butane barrel tend to aligned with each other. Through this result, it is reasonable that a safety criteria can be decided based on the temperature of the bottom of butane. Especially, portable butane gas ranges are safely conducted under the condition of the temperature is under 50 degree and pressure is under 500 kPa, respectively, at the bottom of the butane barrel.

• 신재생에너지
• /
• 제2권4호
• /
• pp.70-77
• /
• 2006

The butane decomposition over the catalyst is an attractive method for the hydrogen production. The objective of the work was investigated the catalysis of carbon black in butane decomposition reaction. The Butane decomposition was performed over carbon black catalyst in a range of $500-1100^{\circ}C$. The butane conversion of thermal decomposition and catalytic decomposition were increased with increasing the reaction temperature The butane conversion of the thermal decomposition was higher than the butane conversion of the catalytic decomposition. Hydrogen and methane were mostly observed in the butane decomposition over $1000^{\circ}C$. Especially, the hydrogen yield was steadily increased with raising the reaction temperature, It could be known that the hydrogen yield of the catalytic decomposition was higher than one of the thermal cracking because the hydrogen productivity was improved by the catalyst. The deactivation of the catalyst was not observed in the reactivity test. The surface and crystalline of the fresh and used catalysts were characterized by TEM, BET surface area and XRD analysis, respectively. The fresh carbon black particles had mostly smoothly round-shaped surfaces. In the surface of the carbon black after the reaction, the deposited carbon was formed as the protrusion-shaped carbon and the cone-shaped. The proper peaks of carbon black appeared in XRD analysis.

• 대한화학회지
• /
• 제21권6호
• /
• pp.422-426
• /
• 1977

Zeolite Y를 합성하여 Co, Ni 및 Pd 이온으로 이온교환하고 수소기류중에서 환원함으로서 전이금속-Zeolite Y 촉매를 얻었다. 이들 Co-, Ni-, Pd-Y와 La-이온교환한 Y(LaY) 촉매에서의 1-butene 및 n-butane의 분해반응을 micro-catalytic pulse 방법으로 연구하였다. 1-Butene 분해반응에 있어서는 Ni-, Co-, Pd-Y 및 LaY 모두 높은 활성을 보여주었고 1-butene 분해반응에 대한 활성은 촉매상의 금속성분과는 큰 관계없이 산성 성분만이 주로 관련되고 있는것 같다. LaY에서는 $400^{\circ}C$에서 n-butane 분해반응에 대한 활성을 나타내지 않았으나 소량의 1-butene을 가함으로써 분해반응이 촉진되었다. Ni- 및 Pd-zeolite Y에서는 n-butane의 분해반응이 현저하게 일어났다. 분해반응에 대해서는 수소에 의한 환원온도가 높고 또 금속성분 함량이 많은 것이 활성이 높았다. n-butane 분해반응에 있어서는 금속성분에서의 butene으로의 탈수소반응이 첫 단계인 것으로 본다. Ni-Y에서는 1-butene과 수소 혼합반응물 및 n-butane의 분해생성물이 모두다 C_1$뿐이었다. n-butane은 Ni-Y에서는 butene으로 탈수소되고 이어서 C_1$으로 hydrocracking 되는 반응과정을 밟고 있다고 본다.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
• /
• pp.97-100
• /
• 2014

The combustion and emission characteristics of propane and n-butane which are the main components of LPG were compared with gasoline. The experiment was performed in a stratified DISI engine under lean combustion conditions. Mixtures of propane and n-butane wre more homogeneous because propane and n-butane have better evaporation characteristics. As a result, combustion speeds of n-butane and propane were slower, and emission levels of NOx and PM were lower. However, in spite of better evaporation, PM from propane was higher.

• 한국지하수토양환경학회:학술대회논문집
• /
• 한국지하수토양환경학회 2001년도 총회 및 춘계학술발표회
• /
• pp.136-139
• /
• 2001

In this study, we have examined potential degradation of MTBE (methy1 tert-butyl ether) by pure culture ENV425 and mixed culture isolated from gasoline contaminated soil using n-butane as the sources of carbon and energy. The results described in this study suggest that MTBE is degraded cometabolically by ENV425 and mixed culture grown n-butane, and the disappearance of TBA after complete degradation of MTBE suggest the further degradation of TBA. Butane and MTBE degradation was completely inhibited by acetylene, which indicated that both substrates were degraded by butane-utilizing bacteria. MTBE was degraded ENV425 and mixed culture grown n-butane, and TBA (tert-butyl alcohol) was produced as product of MTBE oxidation. TBA production was accounted 54.7% and 58.6% for MTBE oxidation by ENV425 and mixed culture, respectively. The observed maximal transformation yield (T$_{y}$) were 44.7 and 34.0 (nmol MTRE degraded/$\mu$mol n-butane Utilized) by ENV425 and mixed culture, respectively.y.