• 제목/요약/키워드: burning temperature

검색결과 421건 처리시간 0.026초

고체산화물 연료전지용 예혼합 연소시스템 개발 (Development of Combustion System for Solid Oxide Fuel Cell System)

  • 조순혜;이필형;차천륜;홍성원;황상순
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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    • pp.96.1-96.1
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    • 2011
  • Solid oxide fuel cells(SOFCs) can convert the chemical energy of fuel into electricity directly. With the rising fuel prices and stricter emission requirement, SOFCs have been widely recognized as a promising technology in the near future. In this study, lean premixed flame using the orifice swirl burner was analyzed numerically and experimentally. We used the program CHEMKIN and the GRI 3.0 chemical reaction mechanism for the calculation of burning velocity and adiabatic flame temperature to investigate the effects of equivalence ratio on the adiabatic flame temperature and burning velocity respectively. Burning velocity of hydrogen was calculated by CHEMKIN simulation was 325cm/s, which was faster than that of methane having 42 cm/s at the same equivalence ratio. Also Ansys Fluent was used so as to analysis the performance with alteration of swirl structure and orifice mixer structure. This experimental study focused on stability and emission characteristics and the influence of swirl and orifice mixer in Solid Oxide Fuel Cell Systme burner. The results show that the stable blue flame with different equivalence ratio. NOx was measured below 20 ppm from equivalence ratios 0.72 to 0.84 and CO which is a very important emission index in combustor was observed below 160 ppm under the same equivalence region.

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성층화 혼합기 연소 모델링을 위한 프로판 및 이소옥탄 연료의 층류 화염 속도 (Laminar Burning Velocities of Propane and Iso-Octane Fuels for Stratified Charged Combustion Modeling)

  • 배상수;김용태;임재만;민경덕
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2000년도 추계학술대회논문집B
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    • pp.704-709
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    • 2000
  • Laminar burning velocities of propane- and iso-octane-air mixtures have been numerically modelled over a wide range of equivalence ratio, pressure and temperature. These correlations are applicable to the modelling of stratified charged combustion like that of lean bum and GDI engine combustion. The numerical models are based on the results calculated by PREMIX code with Sloane's detailed chemical reaction mechanism for propane and FlameMaster code with Peters' for iso-octane. Laminar burning velocity for two fuels showed a pressure and temperature dependence in the following form, in the range of $0.1{\sim}4MPa$, and $300{\sim}1000K$, respectively. $S_L={\alpha}\;{\exp}[-\xi({\phi}-{\phi}_m)^2-{\exp}\{-{\xi}({\phi}-{\phi}_m)\}-{\xi}({\phi}-{\phi}_m)]$ where ${\phi}_m=1.07$, and both of ${\alpha}$ and ${\xi}$ are functions of pressure and temperature. Compared with the results of the existing models, those of the present one showed the good agreement of the recent experiment data, especially in the range of lean and rich sides. Judging from the calculated results of the stratified charged combustion by using STAR-CD, the above modelling prove to be more suitable than the other ones.

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Poly(glycidyl azide-co-glycidyl ferrocenyl ether)의 합성 (Synthesis of Poly(glycidyl azide-co-glycidyl ferrocenyl ether))

  • 정해지
    • 한국군사과학기술학회지
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    • 제22권1호
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    • pp.35-41
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    • 2019
  • Ferrocene and ferrocene derivatives have been widely used as a burning rate catalyst for composite solid propellants. However, its tendency to migrate through the propellant grain and to crystallize at the surface changes the composition of propellant which results in unpredictable burning rate. To overcome the weakness of ferrocene catalyst, we designed a polymer containing ferrocene, poly(glycidyl azide-co-glycidyl ferrocenyl ether) (GAFP). GAFPs were synthesized from poly(epichlorohydrin-co-glycidyl ferrocenyl ether) (PEGF) which has ferrocenyl ethers in its pendant groups. The structures of GAFPs were confirmed by FT-IR, $^1H$ and $^{13}C$ NMR spectral analyses. Thermal properties of the GAFPs were evaluated using differential scanning calorimeter (DSC). As the contents of ferrocene increased, the glass transition temperature ($T_g$) of the GAFPs shifted to a higher temperature, and the decomposition temperature ($T_d$) decreased because the ferrocene worked as a burning rate catalyst.

PCP/Nitramine/AP 기반 추진제의 연소 특성 연구 (Combustion Properties of PCP/Nitramine/AP Propellants)

  • 김성준
    • 한국추진공학회지
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    • 제25권4호
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    • pp.12-18
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    • 2021
  • 본 연구에서는 추력 제어용 추진제 조성 개발을 위해 고 압력지수 추진제를 만들고자 하였다. 프리폴리머로 PCP를 사용하며 니트라민 계열의 산화제인 HMX와 HNIW 기반 추진제를 제조하여 각각의 연소특성을 비교하였다. HMX에 비해 HNIW가 추진제의 연소속도, 비추력 그리고 화염온도에 큰 영향을 준다는 것을 알았다. 또한, AP를 조 산화제로 사용할 경우, 추진제의 연소속도, 비추력 및 화염온도는 미세 AP 함량, 총 고체 함량 그리고 가소제 양이 증가할수록 병행 상승하였으나, 압력지수는 오히려 낮게 나타났다. 그리고, 여러 압력 구간에서 온도에 따른 연소특성 변화를 알아보기 위해 150 psia부터 2,500 psia사이 구간에 대해 PCP/Nitramine/AP 추진제의 연소속도에 대한 온도 민감도를 측정하였다.

Al6061 합금의 정전압 아노다이징 피막의 형성거동 및 버닝에 대한 연구 (A Study on the Growth and Burning of Anodic Oxide Films on Al6061 Alloy During Anodizing at Constant Voltages)

  • 문상혁;문성모;송풍근
    • 한국표면공학회지
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    • 제53권1호
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    • pp.15-21
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    • 2020
  • In this study, growth and burning behavior of 6061 aluminum alloy was studied under constant anodic voltages at various temperatures and magnetic stirring rates in 20% sulfuric acid solution by analysing I-t curves, measuring thickness and hardness of aluminum anodic oxide (AAO) films, observations of surface and cross-sectional images of AAO films. AAO films were grown continuously at lower voltages than 18.5V but burning occurred when a voltage more than 19V was applied in 20% H2SO4 solution at 20±0.5℃ and 200 rpm of magnetic stirring. The burning was always related with an extremely large increase of anodic current density with anodizing time, suggesting that high heat generation during anodizing causes deteriorations of AAO films by chemical reaction with acidic solutions. The burning resulted in decreases of film thickness and hardness, surface color brightened and formation of porous defects in the AAO films. The burning voltage was found to decrease with increasing solution temperature and decreasing magnetic stirring rate. The decreased burning voltages seem to be closely related with increased chemical reactions between AAO films and hydrogen ions.

가솔린.메탄의 연소특성 비교 (Comparison of the Combustion Characteristics of Methane-Air and Gasoline-Air Mixtures)

  • 박명호
    • 한국분무공학회지
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    • 제7권3호
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    • pp.7-11
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    • 2002
  • Comparison of the combustion characteristics of methane-air and gasoline-air mixtures has been conducted experimentally by a spherical bomb technique. The results indicate 1) the burning velocity of gasoline is slightly higher than that of methane, but their basic behavior of combustion characteristics, positive dependence on temperature and negative one on pressure, are the same, and 2) 20 vol.% addition of hydrogen to methane enhances the burning velocity by about 30%, but does not come to reverse the tendency of pressure dependence to that of pure hydrogen.

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감압조형시 흑연첨가 및 주입온도가 피복상태에 미치는 영향 (The Effect of Graphite Addition and Pouring Temperature on the Coating State in Vaccum Process)

  • 조성준
    • 한국세라믹학회지
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    • 제34권5호
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    • pp.544-551
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    • 1997
  • We tried to improve the coating capability of the coating material using an additive(hexagonal cystalline graphite) of 2%, 3%, 4% and 6% under various pouring temperature for the easy isolation of sand and coating material from the final product. As a result in case of using a 2% and 3% additive generally no burning state has been occurred under the low pouring temperature, but it has been gradually increased with the pouring temperature. On the other hand in case of using a 4% and 6% additive there has been no burning state through out the whole pouring temperature. From this result we could see that the best state of the final product without sand and coating material could generally be obtained if 4% and/or 6% of the crystalline graphite and the pouring temperature of 140$0^{\circ}C$$\pm$5$^{\circ}C$ would be used.

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DOHC 가솔린기관의 연소실 벽표면순간온도 및 비정상 열유속 측정 및 해석(제3보 : 실린더 라이너에 관한 연구) (Measurement and Analysis of Instantaneous Surface Temperature and Unsteady Heat Flux at Combustion Chamber of DOHC Gasoline Engine ; Cylinder Linder)

  • 위신환;이종태
    • 한국자동차공학회논문집
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    • 제8권3호
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    • pp.1-11
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    • 2000
  • Instantaneous temperature probes were manufactured by pressing method. By using these probes, the instantaneous surface temperature and unsteady heat flux in the cylinder liner of DOHC engine were measured. The main results are as follows; ⅰ) the instantaneous surface temperature of cylinder liner are affected by the contact of piston ring as well as burning gas. ⅱ) the wall temperature of the siamese portion is much higher than other parts. ⅲ) it was shown that the rising trend of heat flux by burning gas are nearly limited to the 1/2-stroke distance from the top of cylinder liner.

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Combustion Characteristics of Heavy Fuel Oil-water Emulsion

  • Kim Houng-Soo
    • Journal of Advanced Marine Engineering and Technology
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    • 제30권1호
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    • pp.88-92
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    • 2006
  • This study is intended to check the flame temperature to raise in burning grade C heavy fuel oil and emulsion fuel oil in a boiler and to measure the concentration of Dry Shoot(DS) and Soluble Organic Fraction(SOF) after collecting the Particulate Matters (PM). The flames temperature in boiler was measured by burning grade C heavy oil and oil-water emulsion (C heavy oil $70\%\;and\;30\%$ of water) Combustion characteristics of two fuels was also compared by trapping particulate matters (PM) in exhaust gas and measuring the generated quantities of DS and SOF in fuel gas.