• Title/Summary/Keyword: bulk metallic glasses

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A Study on the Micro Vibration Forming of Al-based Superplastic Alloy and Zr-based Bulk Metallic Glass (Al계 초소성합금과 Zr계 비정질합금의 마이크로 진동성형에 관한 연구)

  • Son, Seon-Cheon;Park, Kyu-Yeol;Na, Young-Sang
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.16 no.6
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    • pp.193-200
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    • 2007
  • Micro forming is a suited technology to manufacture very small metallic parts(several $mm{\sim}{\mu}m$). Al5083 superplastic alloy with very small grains has a great advantage in achieving micro deformation under low stress due to its relatively low strength at a specific high temperature range. Micro forming of $Zr_{62}Cu_{17}Ni_{13}Al_8$ bulk Metallic glass(BMG) as a candidate material for this developing process are feasible at a relatively low stress in the supercooled liquid state without any crystallization during hot deformation. In this study, the micro formability of Al5083 superplastic alloy and bulk metallic glass, $Zr_{62}Cu_{17}Ni_{13}Al_8$, was investigated with the specially designed micro vibration forming system using pyramid-shape, V-shape and U-shape micro die pattern. With these dies, micro vibration forming was conducted by varying the applied load, time. Micro formability was estimated by comparing the hight of formed shape using non-contact surface profiler system. The vibration load effect to metal flow in the micro die and improve the micro formability of Al5083 superplastic alloy and $Zr_{62}Cu_{17}Ni_{13}Al_8$ bulk Metallic glass(BMG).

Soft Magnetic Properties of Ring-Shaped Fe-Co-B-Si-Nb Bulk Metallic Glasses

  • Ishikawa, Takayuki;Tsubota, Takahiro;Bitoh, Teruo
    • Journal of Magnetics
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    • v.16 no.4
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    • pp.431-434
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    • 2011
  • The reduction of the Nb content in the $(Fe_{0.75}B_{0.20}Si_{0.05})_{96}Nb_4$ bulk metallic glass (BMG) has been studied. The glass-forming ability (GFA) is reduced by decreasing the Nb content, but it can be enhanced by replacing partially Fe by Co. Furthermore, the saturation magnetization of the $(Fe_{0.8}Co_{0.2})_{76}B_{18}Si_3Nb_3$ BMG is 1.35 T, being with 13% larger than that of the base alloy $(Fe_{0.75}B_{0.20}Si_{0.05})_{96}Nb_4$. $(Fe_{0.8}Co_{0.2})_{76}B_{18}Si_3Nb_3$ BMG exhibits slightly larger $B_{800}$ (the magnetic flux density at 800 A/m) and smaller core losses (20%-30%) compared with the commercial Fe-6.5 mass% Si steel.

Microstructure and Tribological Properties along with Chemical Composition and Size of Initial Powder in Fe-based BMG Coating through APS (대기 플라즈마 용사공정을 이용한 Fe계 벌크 비정질 금속 코팅의 초기 분말의 화학조성과 크기에 대한 미세 조직 및 마모 특성)

  • Kim, Jung-Hwan;Yoon, Sang-Hoon;Na, Hyun-Taek;Lee, Chang-Hee
    • Journal of the Korean institute of surface engineering
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    • v.41 no.5
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    • pp.220-225
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    • 2008
  • In this study, two kinds of Fe-based bulk metallic glasses (BMG) powder were built-up through atmospheric plasma spray (APS) technique. The microstructure of two coatings was analyzed through X-ray diffraction, scanning electron microscopy and transmission electron microscopy. Crystallization and oxidation in coatings were affected by chemical composition and initial powder size. Then, both of them influenced the tribological property.

Effects of Impact Velocity on Crystallization and Activation Energy of Cu-based Bulk Metallic Glasses in Kinetic Spray Coating (저온 분사 코팅 공정에서 충돌속도에 따른 CuNiTiZr 벌크 비정질 소재의 활성화 에너지와 결정화 거동 분석)

  • Yoon, Sang-Hoon;Bae, Gyu-Yeol;Kim, Jung-Hwan;Lee, Chang-Hee
    • Journal of the Korean institute of surface engineering
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    • v.41 no.6
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    • pp.301-307
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    • 2008
  • In this paper, nanocrystallization of CuNiTiZr bulk metallic glass (BMG) subjecting to a kinetic spraying, dependent on impact velocity, was investigated by numerical and experimental approaches. The crystallization fraction and nucleation activation energy of initial feedstock and as-deposited coating were estimated by DSC and Kissinger method, respectively. The results of numerical modeling and experiment showed that the crystalline fraction and nucleation activation energy in BMG coatings were depended on kinetic energy of incident particle. Upon impact, the conversion of particle kinetic energy leads to not only decreasing free energy barrier but also increasing the driving force for an amorphous to crystalline phase transformation. The nanocrystallization of BMGs is associated with the strain energy delivered by a plastic deformation with a high strain rate.

Artificial Neural Network Supported Prediction of Magnetic Properties of Bulk Metallic Glasses (인공신경망을 이용한 벌크 비정질 합금 소재의 포화자속밀도 예측 성능평가)

  • Chunghee Nam
    • Korean Journal of Materials Research
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    • v.33 no.7
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    • pp.273-278
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    • 2023
  • In this study, based on the saturation magnetic flux density experimental values (Bs) of 622 Fe-based bulk metallic glasses (BMGs), regression models were applied to predict Bs using artificial neural networks (ANN), and prediction performance was evaluated. Model performance evaluation was investigated by using the F1 score together with the coefficient of determination (R2 score), which is mainly used in regression models. The coefficient of determination can be used as a performance indicator, since it shows the predicted results of the saturation magnetic flux density of full material datasets in a balanced way. However, the BMG alloy contains iron and requires a high saturation magnetic flux density to have excellent applicability as a soft magnetic material, and in this study F1 score was used as a performance indicator to better predict Bs above the threshold value of Bs (1.4 T). After obtaining two ANN models optimized for the R2 and F1 score conditions, respectively, their prediction performance was compared for the test data. As a case study to evaluate the prediction performance, new Fe-based BMG datasets that were not included in the training and test datasets were predicted using the two ANN models. The results showed that the model with an excellent F1 score achieved a more accurate prediction for a material with a high saturation magnetic flux density.

Mechanical Properties of a Cu55Zr30Ti10Pd5 Bulk Amorphous Alloy (Cu55Zr30Ti10Pd5 비정질 합금의 기계적 거동)

  • Choi Won Wook;Gato H.;Kim Hyoung Seop;Hong Sun Ig;Inoue A.
    • Korean Journal of Materials Research
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    • v.15 no.4
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    • pp.281-284
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    • 2005
  • Room and high temperature deformation behaviors of Cu-Zr-Ti-Pd bulk metallic glasses produced by copper mold casting were investigated. The addition of Pd was shown to enhance the glass forming ability and thermal stability of Cu-Zr-Ti base bulk metallic glass. The compressive strength of $Cu_{55}Zr_{30}Ti_{10}Pd_5$ bulk metallic glass was 2230 MPa with 1.8 plastic strain. The stress overshoot and yield drop phenomenon were observed below $487^{\circ}C$ and a drastic decrease in the flow stress was observed at $487^{\circ}C$. The stress overshoot is thought to be associated with stress-induced structural relaxation.

Evaluation on Liquid Formability of Bulk Amorphous Alloys (벌크비정질합금의 액상 성형성 평가)

  • Joo, Hye-Sook;Kang, Bok-Hyun;Kim, Ki-Young
    • Journal of Korea Foundry Society
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    • v.26 no.5
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    • pp.227-231
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    • 2006
  • Liquid formability of bulk amorphous alloys is known to be very poor due to their high viscosity comparing with conventional metallic materials. It is important to have the fabricating technology of bulk amorphous alloys in order to make the components with complicated shape. Liquid formability includes the mold cavity filling ability and the hot tear(crack) resistance during solidification. A mold made of a commercial tool steel for the formability test was designed. Melting was performed by the arc melting furnace with melting capacity of 200 g in an argon atmosphere. Liquid formability and glass forming ability of Cu base and Ni base bulk amorphous alloys were measured and evaluated. Mold filling ability of Ni-Zr-Ti-Si-Sn alloy was better than that of Cu-Ni-Zr-Ti alloy, however the reverse is the hot tear resistance. Bulk amorphous alloy is very susceptible to crack if partial crystallization occurs during solidification. Crack resistance was thought to be closely related with the glass forming ability.