• 펄프종이기술
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• 제43권4호
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• pp.49-58
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• 2011

The maximum drying shrinkage velocity was proposed to verify bulk and stiffness improvement mechanism during drying according to papermaking parameters. It was based on the wet-web shrinkage behavior without the restraint of wet-web during drying, so intact drying impact could be measured. Bulking agent reduced the drying shrinkage and the maximum drying shrinkage velocity, so paper bulk increased and paper strength decreased. When adding cationic starch to stock with the bulking agent for strengthening, the bulk was increased further with additional decreasing of the drying shrinkage and the maximum drying shrinkage velocity. Paper strength also increased except tensile stiffness index with decreasing the drying shrinkage and the maximum drying shrinkage velocity. When using additional strength additives for strengthening of fiber interfaces extended by bulking agent and cationic starch, amphoteric strength additive increased paper stiffness without loss of paper bulk. It was considered that the added amphoteric strength additives were cross-linked to the stretched cationic starch and this cross-linking increased elasticity of fiber-polymer-fiber interfaces without changing the drying behavior. Paper bulk could be increased with decreasing the maximum drying shrinkage velocity. The drying shrinkage of paper also could be controlled by fiber-to-fiber bonding interfaces by the bulking agent. In this case, paper strength including stiffness was decreased by reducing fiber-to-fiber bonding but it could be improved by strengthening fiber-to-fiber interfaces with polymer complex without loss of bulk.

• Journal of the Korean Wood Science and Technology
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• 제29권3호
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• pp.27-35
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• 2001

Four different sources of wood-fibers from Eucalyptus, Italian poplar, hemlock, and mixed species fibers were used to study the influence of their fiber characteristics on the performance of medium density fiberboard (MDF) panels bonded with both urea-formaldehyde (UF) and phenol-formaldehyde (PF) adhesives. Included fiber characteristics were fiber length, size distribution, bulk density, and acidity. Physical and mechanical properties of MDF panels manufactured by dry process using these different fibers were determined for the comparison of board performance. Two hardwood species had a large fraction of short fibers resulting in a higher bulk density while very long hemlock fibers had lower bulk density. Fiber acidity was revealed to strongly affect the internal bond (IB) strength of MDF panels bonded with UF resins. MDF panels made from mixed species fibers showed highest IB strength of all panels prepared. UF-bonded MDF panels showed poor dimensional stability. In conclusion, the present study showed that wood-fiber characteristics such as fiber length, bulk density, and acidity affect the performance of MDF boards, and also suggested that fiber characteristics be considered for MDF panel manufacture.

• 펄프종이기술
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• 제45권6호
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• pp.88-95
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• 2013

Effects of beating and water immersion time on fiber swelling and paper properties were elucidated for the fundamental study of producing high bulk paper. Chemical pulps were beaten for various freeness and the beaten pulp was immersed in water up to 24 hours. Fiber swelling was evaluated by measuring water retention value (WRV). It was found that fiber swelling, bulk and paper strength were quickly changed at the initial stage of beating. Immersion in water did not significantly increase WRV, paper density and strength, implying that soaking in water alone could not effectively swell fiber wall. In order to swell further, hydrogen bonds between fibrils in fiber wall and hence fiber wall structure shall be broken by mechanical force during beating.

• Restorative Dentistry and Endodontics
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• 제40권4호
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• pp.262-269
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• 2015

Objectives: The aim of this study was to evaluate the mechanical and physical properties of a newly developed fiber reinforced dental composite. Materials and Methods: Fiber reinforced composite EverX Posterior (EXP, GC EUROPE), and other commercially available bulk fill composites, including Filtek Bulk Fill (FB, 3M ESPE), SonicFill (SF, Kerr Corp.), SureFil (SDR, Dentsply), Venus Bulk Fill (VB, HerausKultzer), Tetric evoceram bulk fill (TECB, Ivoclar Vivadent), and Xtra Base (XB, Voco) were characterized. Composite samples light-cured with a LED device were evaluated in terms of flexural strength, flexural modulus (ISO 4049, n = 6), fracture toughness (n = 6), and Vickers hardness (0, 2, and 4 mm in depth at 24 hr, n = 5). The EXP samples and the fracture surface were observed under a scanning electron microscopy. Data were statistically analyzed using one-way ANOVA and unpaired t-test. Results: EXP, FB, and VB had significantly higher fracture toughness value compared to all the other bulk composite types. SF, EXP, and XB were not statistically different, and had significantly higher flexural strength values compared to other tested composite materials. EXP had the highest flexural modulus, VB had the lowest values. Vickers hardness values revealed SF, EXP, TECB, and XB were not statistically different, and had significantly higher values compared to other tested composite materials. SEM observations show well dispersed fibers working as a reinforcing phase. Conclusions: The addition of fibers to methacrylate-based matrix results in composites with either comparable or superior mechanical properties compared to the other bulk fill materials tested.

• 한국산업보건학회지
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• 제5권2호
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• pp.137-146
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• 1995

Twenty(20) large commercial buildings located in Seoul with friable sprayed-on surface insulation material on ceilings were investigated for asbestos content in bulk material by polarized light microscopy and for airborne fiber concentrations in buildings by phase contrast microscopy. In addition, such building-related variables as building age, numbers of traffic, airflow, surface conditions of the ceiling, temperature, and humidity were studied for any correlation with airborne fiber concentrations. The results were as follows: 1. Chrysotile asbestos was found in two bulk samples with 3-5% content and with <1%in one sample out of total 20 bulk samples collected. Glass fiber and mineral wool were the two major constituents of the bulk samples. 2. The ceiling surfaces were very friable in 16 buildings and were relatively hard in 4 buildings. The friability of the surface material was dependent upon the type and the amount of binder that had been mixed with the sprayed-on surface material. 3. Airborne fiber concentrations were log-normally distributed and the geometric mean(geometric standard deviation) fiber concentrations in the underground parking lots, inside buildings, and outdoor ambient air were 0.0063(1.97)f/cc, 0.0068(2.29)f/cc, and 0.0033(2.36)f/cc, respectively. 4. No significant relationship of airborne fiber concentrations and all building-related variables studied except humidity was found. The results of this study suggest that the sprayed-on surface insulation material found in some commercial buildings may possibly be contaminated with asbestos. Since most of the ceiling surfaces surveyed were very friable and poorly maintained and the airborne fiber concentrations were relatively high, there is a possibility of asbestos fiber contamination in these buildings, particularly at those buildings with asbestos-contaminated surface material. Since poorly maintained surface conditions were thought to be a source of high airborne fiber concentrations, there is a urgent need of a systematic operation and maintenance program. Further study of non-occupational asbestos exposure in general population utilizing advanced analytical technique such as transmission electron microscopy is highly recommended.

• 한국산업보건학회지
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• 제6권2호
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• pp.165-175
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• 1996

Fourteen(14) large commercial buildings located in Seoul with friable sprayed-on surface insulation material on ceiling were investigated for fiber types in bulk material and for airborne fiber concentrations in buildings by transmission electron microscopy (TEM) in order to compare the results with those by polarized light microscopy (PLM) and phase contrast microscopy (PCM). The results were as follows: 1. Chrysotile asbestos was found in one bulk sample out of total 14 bulk samples collected. Glass fiber and mineral wool were the two major constituents of the bulk samples. 2. The Na-Mg-Si-Ca-Fe-Al ratios of the EDX spectra which were normalized with the Si peak were 0-1.0-10-8.3-4.0-4.0 in mineral wool and 0-5-10-21-0-0 in chrysotile asbestos, respectively. 3. Airborne fiber concentrations were log-normalcy distributed and the geometric mean (geometric standard deviation) fiber concentrations by TEM in the underground parking lots and inside buildings were 0.0048 f/cc(1.93) and 0.0040 f/cc(2.27), respectively with no statistical difference. In the outdoor ambient air, statistically significantly lower concentration of 0.0018 f/cc(2.04) was measured. 4. The TEM/PCM ratios of airborne fiber concentrations ranged 0.5 - 2.0 for 80 % of airborne samples analyzed, end the regression equation between TEM and PCM was PCM=-0.2724+1.1355(TEM) with the coefficient of determination $R^2=0.52$. The results of this study confirmed that the sprayed-on surface insulation material found in some commercial buildings may possibly be contaminated with asbestos fiber. Since statistically significant relationship of fiber concentrations measured by PCM and TEM inside buildings and ambient air was found, previous results by PCM in ambient air could be used to estimate the ambient fiber concentrations in knowing the ratio of TEM/PCM.

• Advanced Composite Materials
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• 제16권4호
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• pp.385-394
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• 2007

In this study, the effect of molding condition on the tensile properties for plain woven hemp fiber reinforced green composite was examined. The tensile properties of the composite were compared with those of the plain woven jute fiber composite fabricated by the same process. Emulsion type biodegradable resin or polypropylene sheet was used as matrix. The composites were processed by the compression molding where the molding temperature and its heating time were changed from 160 to $190^{\circ}C$ and from 15 to 25 min, respectively. The following results were obtained from the experiment. The tensile property of hemp fiber reinforced polypropylene is improved in comparison with polypropylene bulk. The strength of composite is about 2.6 times that of the resin bulk specimen. Hemp fiber is more effective than jute fiber as reinforcement for green composite from the viewpoint of strength. The molding temperature and time are suitable below $180^{\circ}C$ and 20 min for hemp fiber reinforced green composite. Hemp fiber green composite has a tendency to decrease its tensile strength when fiber content is over 50 wt%.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
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• pp.423-426
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• 2006

Paper has fibers and fines network structure and it is strongly affected by interface bonding between fibers. Depending on the inter-fiber bonding, paper bulk is determined. Fines play an important roll in Campbell and consolidation effect through wet pressing and drying operations. Refined Sw-BKP, Hw-BKP and BCTMP fines were used to investigate the fines effect. Wet-web strength, breaking length, scattering coefficient, and hydrodynamic specific volume were measured. According to the result of experiments, chemical and morphological compositions of fines do not strongly affect to wet-web forming, but strongly affect to drying operations which form hydrogen bonding among fiber-fines-fiber matrixes. Paper bulk should be controlled by the extent of hydrogen bonding between fibers during drying operations.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 1987년도 제2차학술발표초록집
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• pp.15-15
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• 1987

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 1995년도 추계 학술발표회
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• pp.120-121
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• 1995