• Title/Summary/Keyword: buffer gas

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High-Tc Superconducting Bi-Sr-Ca-Cu-O Thin Films prepared by Sputter Deposition (스퍼터 증착법으로 제작한 Bi-Sr-Ca-Cu-O 고온 초전도 박막)

  • Cheon, Min-Woo;Yang, Sung-Ho;Park, No-Bong;Park, Yong-Pil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.329-330
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    • 2005
  • Bi-Sr-Ca-Cu-O thin films have been fabricated by sputter deposition method. During the deposition, 10 and 90 wt%-ozone/oxygen mixture gas of typical pressure of $1\sim9\times10^{-5}$ Torr are supplied with ultraviolet light irradiation for oxidation. XRD and RHEED investigations reveal out that a buffer layer with some different compositions is formed at the early deposition stage of less than 10 units cell and then Bi-2201 oriented along the c-axis is grown.

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Preparation and validation of Chitosan-phthalocyanine complex - absorber of mutagens and carcinogens -

  • Rhee, Hee-Kyung;Jeon, Hee-Kyung;Ryu, Jae-Chun
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 2003.10a
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    • pp.175-175
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    • 2003
  • Phthalocyanine, a water soluble porphyrin derivative and dye, is known to inhibit the mutagenic and carcinogenic actions of compounds having polycyclic structures, e.g. heterocyclic amines. There is evidence that this adsorbent effect shows by a complex formation between the porphyrin-like structure of phthalocyanine and the planar molecular surfaces of theses compounds. That phthalocyanine can form an insoluble material when mixed with chitosan, a polyglucosamine, and that the solid chitosan-phthalocyanine, named Eco-Blue, thus prepared can efficiently adsorb polycyclic mutagenic compounds. The adsorption was experimented by UV/VIS spectrometry. The adsorbent effects of mutagens and carcinogens was identified by Gas chromatography (GC) and Ames Test. The adsorbed polycyclic mutagens were elutable with buffer, but only to small extents. Chitosan-phthalocyanine may be expected to be useful as an adsorbent against polycyclic mutagens and carcinogens.

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Measurement of Optogalvanic Signal in Hollow Cathode Discharge Tube (Hollow cathode discharge tube에서의 광검류 신호 측정)

  • 이준회;정기주
    • Journal of the Korean Vacuum Society
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    • v.11 no.2
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    • pp.119-126
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    • 2002
  • The optogalvanic signals were measured using hollow cathode discharge tube with argon as buffer gas at change of discharge currents. A change of ionization rate due to electron collision causes an increase or decrease of the electric conductivity, This change in electric conductivity generates the optogalvanic signal. We conclude that optogalvanic signal has close relation with change of the lowest metastable atoms density at low current.

Oxidation of Carbon Monoxide by Pseudomonas carboxydohydrogena (Pseudomonas carboxydohydrogena에 의한 일산화탄소의 산화)

  • ;Hegeman, George
    • Korean Journal of Microbiology
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    • v.21 no.1
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    • pp.27-35
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    • 1983
  • The stoichiometry between the consumption of CO and $O_2$ and the production of $CO_2(2CO+O_2{\rightarrow}2CO_2)$) showed that Pseudomonas carboxydohydrogena grows as a typical aerobic CO oxidizer with CO. The optimal concentration of CO for growth was found to be 30% in gas mixture with air. The initial buffer concentration of the culture medium did not affect the growth of this bacterium. P. carboxydohydrogena is an obligate aerobe and dose not use nitrate as a terminal electron acceptor. The CO dehydrogenase is an inducible and soluble enzyme. The reaction rate and stability were maximal at pH7.5, and the Arrhenius plot revealed an activation energy of 37.7kJ/mol (9.0 Kcal/mol). The crude enzyme used methylene blue, thionin, and toluylene blue as electron acceptors for the oxidation of CO to $Co_2$ under anaerobic conditions. It was found that water must be the source of the second oxygen atom for CO oxidation.

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이온통로에서 음이온 투과성 연구

  • Seo, Bong-Im;Sim, Eun-Ji
    • Proceeding of EDISON Challenge
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    • 2014.03a
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    • pp.287-299
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    • 2014
  • Bicarbonate anion ($HCO_3{^-}$) takes the role of major buffer systems in our body by maintaining the pH at 7.4. Epithelial $HCO_3{^-}$ secretion also hydrolyzes the mucus which protects body from noxious infections. It has been widely known that such infections are closely related to $HCO_3{^-}$ permeability through membrane and, thus, increasing the $HCO_3{^-}$ permeability is essential. To evaluate the $HCO_3{^-}$ permeability through ion channels, the free energy changes relevant to ion pumping are calculated with the Integral Equation Formalism-PCM (IEF-PCM) theory. Molecular structures of various anions including $HCO_3{^-}$ were optimized with the density functional theory at the level of B3LYP/6-311++G(d,p) in gas and solution phase. In addition, the anion permeability is significantly influenced by the relative size of the anion and pore. We introduce a shifted volume factor model that describes the pore size effect when the charged solutes transfer through ion channels. We found excellent agreement between experimental and calculated permeability when our novel model of the size effect was taken into account to.

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Simple Iysine sensing system using $CO_{2}$ electrode and enzyme immobilized to CNBr-activated sepharose 4B

  • Kim, Eun-Jung;Koh, Kwang-Nak;Choi, Myung-Sook
    • Journal of Sensor Science and Technology
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    • v.6 no.6
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    • pp.437-444
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    • 1997
  • A potentiometric L-lysine-selective sensor is described for the direct determination of lysine. The sensor system is based on a carbon dioxide gas sensing electrode and an L-lysine decarboxylase immobilized to CNBr-activated sepharose 4B. A highly selective L-lysine sensor has been prepared with immobilizing enzyme slurry put into reaction buffer solution. The optimum conditions for the measurement were evaluated by various experiments. This sensor exhibits a linear response to L-lysine concentrations from $10^{-4}M$ to $10^{-1}M$. Response time of this lysine sensor is shorter than 30secs and the immobilized enzyme slurry is stable over one year.

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Development of Measurement System of Very Fast Transient Overvoltage (과도급준파전압측정계의 개발에 관한 연구)

  • Lee, B.H.;Kil, G.S.;Chung, S.J.;Kim, J.N.;Lee, J,S.;Lee, H.H.;Kim, J.K.;Lee, K.Y.
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1523-1525
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    • 1994
  • This paper describes a proposed very fast transient overvoltages(VFTO) measurement system suited for established gas insulated switchgear(GIS). The detecting system consists of a shield electrode connected to a buffer amplifier, and the transmission of the detected signal to an oscilloscope is made through an optical fiber. The bandwidth of the measurement system is 5 Hz to 30MHz. When determining the voltage dividing ratio by use of the commercial frequency voltage, the error is less than 0.5 %. Also, the data were obtained by the electric field probe and the high voltage probe, and their deviation for voltage dividing ratio were less than 1 %.

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Study on Characteristics of Plasma in Hollow Cathode Discharge (Hollow Cathode Discharge에서 플라즈마 특성에 관한 연구)

  • Yoon, Man-Young;Shin, Jong-Soon
    • Journal of the Korean Graphic Arts Communication Society
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    • v.23 no.2
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    • pp.93-101
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    • 2005
  • The measured plasma temperature of Ar hollow cathode discharge for several metal cathodes are about $620\;{\sim}\;780K$ at discharge current of $7\;{\sim}\;10mA$. The optogalvanic signals were measured using hollow cathode discharge tube with argon as buffer gas at change of discharge currents. A change of ionization rate due to electron collision causes an increase or decrease of the electric conductivity. This change in electric conductivity generates the optogalvanic signal. We conclude that optogalvanic signal has close relation with the lowest metastable atoms density at low current.

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Studies of Antipyretic Component of the Earthworm (지렁이(지룡)의 해열성분에 관한 연구)

  • 김영은;이왕규;윤희정
    • YAKHAK HOEJI
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    • v.25 no.4
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    • pp.137-143
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    • 1981
  • In order to confirm the exact antipyretic component in the earthworm, etherial extract of American earthworm(Red Worm) was fractionated into five fractions by using silica gel column chromatography and thin layer chromatography. The fraction including free fatty acids was found to possess artipyretic response and standard arachidonic acid showed marked antipyretic response on typhoid vaccinated rabbits. Arachidonic acid was identified from the free fatty acid fraction of the earthworm by using gas liquid chromatography. Thus it was considered that the antipyretic activity of the free fatty acid may be due to the presence of arachidonic acid. Lipid-free earthworm powder was extracted with phosphate buffer (pH, 8.0, 0.1M) and all the proteins was salted out by ammonium sulfate. The crude precipitate was dialyzed and the impure proteins were eliminated at pH 5.4 and 4.6. The remaining protein solution was fractionated with various concentrations of acetone. The acetone fractions were identified by using S.D.S. polyacrylamide gel electrophoresis and disc gel electrophoresis. The precipitate at 85% acetone concentration and the remaining proteins in the supernatant did not exhibit the antipyretic activity.

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Single-phase Gallium Nitride on Sapphire with buffering AlN layer by Laser-induced CVD

  • Hwang Jin-Soo;Lee Sun-Sook;Chong Paul-Joe
    • Bulletin of the Korean Chemical Society
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    • v.15 no.1
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    • pp.28-33
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    • 1994
  • The laser-assisted chemical vapor deposition (LCVD) is described, by which the growth of single-phase GaN epitaxy is achieved at lower temperatures. Trimethylgallium (TMG) and ammonia are used as source gases to deposit the epitaxial films of GaN under the irradiation of ArF excimer laser (193 nm). The as-grown deposits are obtained on c-face sapphire surface near 700$^{\circ}$C, which is substantially reduced, relative to the temperatures in conventional thermolytic processes. To overcome the lattice mismatch between c-face sapphire and GaN ad-layer, aluminum nitride(AlN) is predeposited as buffer layer prior to the deposition of GaN. The gas phase interaction is monitored by means of quadrupole mass analyzer (QMA). The stoichiometric deposition is ascertained by X-ray photoelectron spectroscopy (XPS). The GaN deposits thus obtained are characterized by X-ray diffractometer (XRD), scanning electron microscopy (SEM) and van der Pauw method.