• Title/Summary/Keyword: buffer concentration

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Effect of Green Buffer Zone in Reducing Gaseous Air Pollutants in the Shiwha Industrial Area (시화공단 완충녹지대의 대기오염물질 저감 효과 분석)

  • Song Young-Bae
    • Journal of the Korean Institute of Landscape Architecture
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    • v.33 no.6 s.113
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    • pp.90-97
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    • 2006
  • The effects of a green buffer zone to protect a residential area from air pollution from industrial facilities and traffic was examined by analyzing the case of a green buffer zone in the Shiwha industrial complex. The green buffer zone is 175 m wide. The intent was to assess the dispersion patterns of atmospheric air pollutants and the reduction in concentration around the green buffer zone. To measure atmospheric sulfur dioxide$(SO_2)$ and nitrogen dioxide$(NO_2)$ concentration, badge-type passive samplers were used and set up at 76 locations in order to measure the concentration of air pollutants with respect to the spatial dispersion. The weighted mean values of $SO_2\;and\;NO_2$ concentration were $3\~57 ppb\;and\;18\~62 ppb$ and the differences among the green buffer zone, the industrial area and the residential areas were $0.7\~1.1 ppb$. Mean values of atmospheric concentrations of $NO_2$ were similar in industrial and, residential areas and the green buffer zone. Results of the study show that the effect of the green buffer zone on reducing the dispersion of air pollutants was very low. This study also recommends that micro-climate, i.e., wind direction should be considered as a factor for planning and design of green buffer zones.

Effect of Citrate and Phosphate on the Inhibition of Browning in Minimally Processed Potatoes (최소가공 처리 감자에 대한 Citrate 및 Phosphate의 갈변저해 효과)

  • Jung, Hur
    • Culinary science and hospitality research
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    • v.13 no.2
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    • pp.254-259
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    • 2007
  • The control of enzymic browning in potato slices by the use of citrate and phosphate buffer at different pH values and concentration was investigated. Minimally processed potatoes were stored at $5^{\circ}C$ and $20^{\circ}C$ followed by dipping in distilled water, citrate buffer (pH $3.0{\sim}5.0$) and phosphate buffer (pH $5.0{\sim}7.0$). The color characteristic was measured after storage at $5^{\circ}C$ and $20^{\circ}C$ for 24 hours. Treatment effectiveness was greatly improved by reducing pH and temperature. The citrate buffer was more effective than phosphate buffer in the browning inhibitory capacity. The citrate buffer (pH 3.0) showed the most anti-browning effect in this condition and more effective inhibition of browning by increasing concentration of treatment solution. The phosphate buffer (pH 5.0) treatment showed more effectiveness than concentration of 0.5 M of citrate buffer treatment.

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New Retention Mechanism of Mononucleotides with Buffer Concentrations in Ion-suppressing RP-HPLC

  • Lee, Ju-Weon;Row, Kyung-Ho
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.6 no.1
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    • pp.37-41
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    • 2001
  • HPLC separation of ionic samples tends to be more complicated and difficult to understand than that of non-ionic compounds. On the other hand, band spacing is much more easily manipulated for ionic than for neutral samples. Ion-suppression RP-HPLC method was used with organic modifier and aqueous buffer solution. In this work, five mononucleotides of cytidine-5-monophosphate (5-CMP) disodium salt, uridine-5-monophosphate disodium salt (5-UMP), guanosine-5-monophosphate disodium salt (5-GMP), inosine-5-monophosphate disodium salt (5-IMP), and adenosine-5-monophosphate disodium salt (5-AMP) were examined. Acetic acid and sodium phosphate were used as buffers, and methanol as an organic modifier. A new relationship between the retention factor and the buffer concentration at a fixed modifier content (5% of methanol) could be expressed by following: K = (k(sub)-1 + k(sub)0 (k(sub)B/k(sub)S)/(1 + (k(sub)B/k(sub)S) C(sub)B(sup)a), where C(sub)B was the concentration of buffer. Using this relationship, the calculated values closely matched the experimental data. The derived relationship showed that as the buffer concentration increased, the retention factor approached a certain value, and this was buffer dependent.

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Current-Voltage-Luminance Characteristics of Organic Light-Emitting Diodes with a Variation of PVK Concentration Used as a Buffer Layer (버퍼층으로 사용한 PVK의 농도 변화에 따른 유기 발광 소자의 전압-전류-휘도 특성)

  • Kim, Sang-Keol;Hong, Jin-Woong;Kim, Tae-Wan
    • Journal of the Korean Applied Science and Technology
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    • v.19 no.1
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    • pp.68-72
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    • 2002
  • We have seen the effects of buffer layer in organic light-emitting diodes(OLEDs) using poly(N-vinylcarbazole)(PVK) depending on a concentration of PVK. Polymer PVK buffer layer was made using spin casting technique. Two device structures were fabricated; one is ITO/TPD/$Alq_{3}$/Al as a reference, and the other is ITO/PVK/TPD/$Alq_{3}$/Al to see the effects of buffer layer in organic light-emitting diodes. Current-voltage-luminance characteristics and an external quantum efficiency were measured with a variation of spin-casting rpm speeds and PVK concentration. We have obtained an improvement of external quantum efficiency by a factor of four when the PVK concentration is 0.1wt% is used. The improvement of efficiency is expected due to a function of hole-blocking of PVK in OLEDs.

Reaction Conditions for Laccase Catalyzed Degradation of Bisphenol A

  • Kim, Young-Jin
    • Journal of Environmental Health Sciences
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    • v.30 no.2
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    • pp.79-83
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    • 2004
  • The oxidative degradation of BPA with laccase from Trametes versiclor was conducted in a closed, temperature controlled system containing acetate buffer for pH control. The effects of medium pH, buffer concentration, temperature and mediator on degradation of BPA were investigated. The inactivation of the enzyme by temperature and reaction product was also studied. The optimal pH for BPA degradation showed about 5. Buffer concentration did not affect BPA degradation. On the other hand, the enzyme stability was higher at low concentration buffer(25 mM). Temperature rise increased the degradation rate of BPA up to 45$^{\circ}C$. The valuable mediator of laccase for BPA was ABTS. Elevated temperature and reaction product irreversibly inactivated the enzyme.

Effects of Ionic Strength in the Medium on Sample Preconcentration Utilizing Nano-interstices between Self-Assembled Monolayers of Gold Nanoparticles

  • Nguyen, Ngoc-Viet;Wu, Jian-Sheng;Jen, Chun-Ping
    • BioChip Journal
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    • v.12 no.4
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    • pp.317-325
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    • 2018
  • This paper investigated the effects of ionic strength in the medium on a preconcentrator for a protein sample with low concentration. The preconcentration chip was designed and fabricated using a polydimethylsiloxane replica through standard lithophotography. A glass substrate is silanized prior to functionalizing the nanoparticles for self-assembly at a designed region. Due to the overlap of electrical double layers in a nanofluidic channel, a concentration polarization effect can be achieved using an electric field. A nonlinear electrokinetic flow is induced, resulting in the fast accumulation of proteins in front of the induced ionic depletion zone, so called exclusion-enrichment effect. Thus, the protein sample can be driven by electroosmotic flow and accumulated at a specific location. The chip is used to collect fluorescein isothiocyanate-labeled bovine serum albumin (FITC-BSA) diluted in phosphate-buffered saline (PBS) buffer solution. Different concentrations of the buffer media were studied herein. Fluorescence intensity images show that the buffer concentration of 4 mM is more appropriate than all the other ones. The sample of FITC-BSA with an initial concentration of $10{\mu}M$ in the 4 mM PBS solution increases its concentration at the desired region by up to 50 times within 30 min, demonstrating the results in this investigation.

Estimation of the Pollutant Removal Efficiency in a Buffer Strip Using a SWAT Model

  • Lee, Eun-Jeong;Choi, Kyoung-Sik;Kim, Tae-Geun
    • Environmental Engineering Research
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    • v.16 no.2
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    • pp.61-67
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    • 2011
  • The water quality from nonpoint source run off results from different land use types has been studied. The construction of a buffer strip is one method of nonpoint source pollutant control. The Soil and Water Assessment Tool (SWAT) model has been applied to estimate the pollutant removal through the buffer strip. When the non-business land has been changed into grass to form a buffer-strip, the change of land use effects the results of the model according to measures of the water quality. The data from a water level station within the watershed in the years 2006 and 2007 was used for calibration and validation of the model. Under the rainfall conditions in 2007, the removal rates of SS, BOD, TN, TP were 11.5%, 9.5%, 1.2%, and 4.5%, respectively. During the rainy days, the removal rates at the buffer strip were 92.3% of SS, 91.2% of BOD, 82.4% of TN, and 83.5% of TP. The pollutants from nonpoint sources were effectively removed by over 80% as they passed through the buffer strips. Rainfall resulted in soil erosion, which led to an increase in the SS concentration, therefore, the construction of buffer strips protected the streams from SS inflows. Since TN concentrations are affected by the inflows of ground water and the N concentration of the rainfall, the removal rate of TN was relatively lower than for the other pollutants.

Suppression of Pyrite Oxidation by Formation of Iron Hydroxide and Fe(III)-silicate Complex under Highly Oxidizing Condition

  • Lee, Jin-Soo;Chon, Chul-Min;Kim, Jae-Gon
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.2
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    • pp.297-302
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    • 2011
  • Acid drainage generated by pyrite oxidation has caused the acidification of soil and surface water, the heavy metal contamination and the corrosion of structures in abandoned mine and construction sites. The applicability of Na-acetate (Na-OAc) buffer and/or Na-silicate solution was tested for suppressing pyrite oxidation by reacting pyrite containing rock and treating solution and by analyzing solution chemistry after the reaction. A finely ground Mesozoic andesite containing 10.99% of pyrite and four types of reacting solutions were used in the applicability test: 1) $H_2O_2$, 2) $H_2O_2$ and Na-silicate, 3) $H_2O_2$ and 0.01M Na-OAc buffer at pH 6.0, and 4) $H_2O_2$, Na-silicate and 0.01M Na-OAc buffer at pH 6.0. The pH in the solution after the reaction with the andesite sample and the solutions was decreased with increasing the initial $H_2O_2$ concentration but the concentrations of Fe and $SO_4^{2-}$ were increased 10 - 20 times. However, the pH of the solution after the reaction increased and the concentrations of Fe and $SO_4^{2-}$ decreased in the presence of Na-acetate buffer and with increasing Na-silicate concentration at the same $H_2O_2$ concentration. The solution chemistry indicates that Na-OAc buffer and Na-silicate suppress the oxidation of pyrite due to the formation of Fe-hydroxide and Fe-silicate complex and their coating on the pyrite surface. The effect of Na-OAc buffer and Na-silicate on reduction of pyrite oxidation was also confirmed with the surface examination of pyrite using scanning electron microscopy (SEM). The result of this study implies that the treatment of pyrite containing material with the Na-OAc buffer and Na-silicate solution reduces the generation of acid drainage.

THE RELATIONSHIP BETWEEN BUFFER INDEX CURVE AND FERMENTATION QUALITY OF SILAGE

  • Kim, K.H;Uchida, S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.4 no.1
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    • pp.67-71
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    • 1991
  • The purpose of this study was to investigate the possibility of using the buffer index curve as a criterion of silage quality evaluation. The buffer index (or buffer capacity, $\beta$) value is the amount of 0.1N NaOH consumed in titrating from the beginning to the end of the chosen pH step. This value equals the slope of the titration curve at the chosen pH range (${\beta}={\Delta}NaOH/{\Delta}pH$). There were two patterns of buffer index curve. Poorly preserved silages had a peak at pH 5.0, whereas with well preserved silages the peaks tended to rise to the pH 3.75 or 4.00. Well preserved, wilted silages with high pH also appeared to have peak values at pH 3.75 or 4.00. There was a high positive correlationship between the concentration of lactic acid and peak value of good quality silage (r = 0.994, p < 0.01). Also a high positive correlationship (r = 0.899, p < 0.001) was found between the sums of concentration of acetic and butyric acids and the peak values of poor quality silages. The results of these experiments verified the value of the buffer index method as a criterion of silage quality evaluation.

THE EFFECT OF ACID CONCENTRATION AND pH OF LACTATE BUFFER SOLUTION ON THE PROGRESS OF ARTIFICIAL CARIES LESION IN HUMAN TOOTH ENAMEL (유산완충액을 이용한 인공치아우식의 형성에 미치는 산의 농도와 pH에 관한 연구)

  • Park, Seong-Ho;Lee, Chan-Young;Lee, Chung-Suck
    • Restorative Dentistry and Endodontics
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    • v.18 no.2
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    • pp.277-290
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    • 1993
  • Dental caries is considered to be caused by demineralization by organic acid produced by microorganism. But the formation of subsurface lesion in initial caries make it diffcult to explain by simple demineralization. This study is carried out on the basis of thermodynamic concept proposed by Margolis and Moreno. The purpose of this study is to evaluate the effects of acid concentration and pH of lactate buffer system on the artificial caries lesion progress. 160 teeth without any crack, defect or opaque enamel were used and coated with nail varnish except the window ($2{\times}3$ mm). Under the constant degree of saturation(D.S.). The teeth were divided into 8 groups according to acid concentration(10mM, 25mM, 50mM, 100mM) and pH(4.3, 5.0, 6.0). Each group was immersed in buffer solution for 3, 6, 9, 18 days under controlled temperature($25^{\circ}C$). After cutting through the window and grinding, the specimens, 100-150 um in thickness, were imbibed in water or air and examined using polarilizing microscope. The depth of the surface and subsurface surface lesion were measured. 1. In the constant pH and D. S. value, the subsurface lesion progresses more rapidly as the concentration of lactic acid increases. (0.01, 0.025, 0.05, 0.1) 2. In the constant acid concentration and DS value, the subsurface lesion progresses more slowly as the pH increases. (4.3, 5.0, 5.5, 6.0) 3. The width of surface lesion seems to be constant independant of pH and acid concentration.

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