• 제목/요약/키워드: boundary resistance

검색결과 468건 처리시간 0.031초

고온에서 미세입자를 가진 석출경화형 Al-0.55 wt% Zr 합금의 Threshold 응력과 전위/입자의 상호 작용에 관한 연구 (Dislocation/Particles Interaction and Threshold Stress in Precipitation-Hardened Al-0.55 wt% Zr Alloy with Fine Particles at High-Temperature)

  • 김병일;나카지마 히데하루
    • 열처리공학회지
    • /
    • 제5권4호
    • /
    • pp.201-208
    • /
    • 1992
  • An experimental study of the constitutive response of precipitation-strengthened Al-0.55wt% Zr alloy, which consists of an Al matrix precipitation-strengthened by coherent particles, ${\beta}^{\prime}(Al_3Zr)$ with $L1_2$ structure has been performed. The deformation response of the materials has been examined by stress relaxation test at 573K, 623K and 673K. It was found that there exist the threshold stress during stress relaxation and threshold stress results from the presense of ${\beta}^{\prime}(Al_3Zr)$ particles. The ratio of threshold stress and Orowan stress decreased gradually with increasing temperature. The resistance to climb-pass of particles was independent of particles size for a fixed volume fraction although the threshold for bowing and particles cutting are sensitive to the particles dimensions. The smaller particles cutted by dislocations. This behavior of dislocations in this alloy was explained in terms of the small value antiphase boundary energy. The dislocation networks wrere more extensive in spesimens subjected to stress relaxation and there were numerous areas that have a high denstiy of jogged dislocation. This experiment results indicate that the rate controlling stress relaxation process is the climb of edge dislocation over particles.

  • PDF

고체산화물 연료전지용 (La,Sr)$MnO_3$-YSZ 복합체 양극의 산소환원 반응기구 및 전극 특성 (Part II: 전극 특성) (Oxygen Reduction Mechanism and Electrode Properties of (La,Sr)$MnO_3$-YSZ Composite Cathode for Solid Oxide Fuel Cell (Part II: Electrode Properties))

  • 김재동;김구대;이기태
    • 한국세라믹학회지
    • /
    • 제38권1호
    • /
    • pp.93-99
    • /
    • 2001
  • (La,Sr)MnO$_3$(LSM)-YSZ 복합체 양극에 있어서 소결온도 및 전극두께와 cathodic potential이 전극 특성에 미치는 영향을 고찰하였다. 양극의 소결은 삼상계면의 양을 결정하는 중요한 변수로 LSM 단미 양극과 YSZ가 40 wt% 포함된 LSM-YSZ 복합체 양극 모두 120$0^{\circ}C$에 소결했을 때 가장 낮은 분극저항을 나타내었다. 또한 양극 후막의 두께가 얇아지면 양극의 in-plane 저항이 증가하여 ohmic 저항이 증가하였는데, LSM-YSZ 복합체 양극의 경우 약 30$mu extrm{m}$ 정도의 전극두께가 가장 효과적인 전극 특성을 나타내었다. 한편, LSM-YSZ 복합체 양극에 -0.5 V의 cathodic potential을 인가함에 따라 양극에서 일어나는 산소환원반응의 활성이 증가하였는데, 1가 산소이온의 표면확산반응의 분극저항은 감소하였으나, 고주파수 영역에서 나타나는 산소이온전달반응의 저항은 거의 변화하지 않았다. 이것은 Mn의 환원에 의한 양극표면에 생성된 산소공공에 기인한다.

  • PDF

Investigation of Li Dopant as a Sintering Aid for ScSZ Electrolyte for IT-SOFC

  • Mori, Masashi;Liu, Yu;Ma, Shuhua;Hashimoto, Shin-ichi;Takei, Katsuhito
    • 한국세라믹학회지
    • /
    • 제45권12호
    • /
    • pp.760-765
    • /
    • 2008
  • In this study, the effects of small amounts (${\leq}3\;mol%$) of Li doping on the sintering characteristics and electrochemical performance of $(ZrO_2)_{0.89}(ScO_{1.5})_{0.1}(CeO_2)_{0.01}$ (ScSZ) were investigated. By adding 3 mol% lithium, the densification temperature of ScSZ was reduced from the conventional temperature of $1400^{\circ}C$ to $1200^{\circ}C$. It was found that Li doping also led to changes in the Zr:Sc ratio at the grain boundaries. Correspondingly, the dispersion of lithium zirconia at the grain boundaries accelerated the growth of ScSZ grains and increased the grain boundary resistance at temperatures below $450^{\circ}C$. At elevated temperatures of $450{\sim}750^{\circ}C$, the electrical conductivity of the ScSZ after doping remained almost unchanged under air and reducing atmospheres. These results suggest that the addition of lithium is promising for use in low temperature co-firing of ScSZ-based components for intermediate temperature solid oxide fuel cells.

Zircaloy-4 합금의 Nodule형 부식에 미치는 열처리 온도의 영향 (Effect of Annealing Temperature on the Nodular Corrosion of Zircaloy-4 Alloy)

  • 정용환;최종술;임갑순
    • 한국표면공학회지
    • /
    • 제24권1호
    • /
    • pp.31-41
    • /
    • 1991
  • The nodular corrosion behavior of Zircaloy-4 alloy was investigated by autoclave test at 50$0^{\circ}C$ under 1500 psi for the specimens quenched into water from $700^{\circ}C$, 80$0^{\circ}C$, 90$0^{\circ}C$, and 105$0^{\circ}C$. It was observed that the corrosion resistance of Zircalloy-4 specimen increased with increase in annealing temperature, and annealing at $\alpha$-region temperatures resulted in nodular corrosion while annealing at the temperature range of $\alpha$+$\beta$ and $\beta$ did not show nodular corrosion. It was also found that the size of nodule formed on the surface of the specimens increased with increase in exposure time in autoclave, but the total number of nodule remained uncha-nged. The corrosion of furnace-cooled specimens progressed mostly in the interior of grains where Fe and Cr alloying elements were largely depleted during the cooling process. However, the grain boundary seemed to act as a barrier to the nodular corrosion. From combining the present results with other works, it is suggested that the nodules nuc-leate in the local region where some of alloying elements are depleted.

  • PDF

좌심실보조장치의 출구 캐뉼라의 삽관 위치에 따른 혈액관류에 대한 시뮬레이션 연구 (Simulation Study of Blood Perfusion according to Outflow Cannulation Site of Left Ventricular Assist Device)

  • 지인혁;김형균;임기무
    • 대한의용생체공학회:의공학회지
    • /
    • 제36권4호
    • /
    • pp.135-142
    • /
    • 2015
  • Outflow cannulation site of left ventricular assist device(LVAD) chosen by considering anatomical structure of thoracic cavity and vascular system. Though outflow cannulation site influences blood perfusion at each branch, there is no standard rule or quantitative data. In this study, we computed the amount of blood perfusion at each arterial branch numerically according to outflow cannulation sites(ascending aorta, aortic arch, descending aorta). We generated computational meshes to the three-dimensionally reconstructed arterial system. Clinically measured arterial pressure were used for inlet boundary condition, porous media were applied to mimic blood flow resistance. Blood perfusion through left common carotid artery was 2.5 times higher than other cases, and that through right common carotid artery was 1.1 times higher than other branches. Although this is simulation study, will be useful reference data for the clinical study of LVAD which considers blood perfusion efficiency.

전기화학적 수소 주입에 의한 Ti-6Al-4V 합금의 미세조직과 수소 취성에 미치는 어닐링 처리의 영향 (Effect of Annealing Treatment on Microstructure and Hydrogen Embrittlement of Ti-6Al-4V Alloys Subject to Electrochemical Hydrogen Charging)

  • 고석우;이지민;권용남;황병철
    • 소성∙가공
    • /
    • 제29권4호
    • /
    • pp.211-217
    • /
    • 2020
  • This paper presents a study on the hydrogen embrittlement of Ti-6Al-4V alloys with different microstructures depending on annealing treatment. They were electrochemically charged with hydrogen and subjected to tensile tests to investigate hydrogen embrittlement behavior. Tensile test results showed that the elongation of Ti-6Al-4V alloy specimens was remarkably decreased with increasing the volume fraction of β phase after hydrogen charging. This is because the β phase with a relatively low diffusivity tends to easily form a hydride at grain boundaries during electrochemical hydrogen charging. After hydrogen charging of the Ti-6Al-4V alloy specimen, it found that silver particles were decorated mostly at the grain boundary, and coarser silver particles were usually formed in the specimen annealed at 950 ℃. Therefore, the specimen having higher β phase fraction shows a poor hydrogen embrittlement resistance because the β phase promotes the formation of coarse hydride during electrochemical hydrogen charging, which leads to a large decrease in ductility.

붐 형상 변화에 따른 컨테이너 크레인 구조 안정성의 실험적 해석 (An Experimental Analysis of the Structural Stability Analysis of a Container Crane according to the change of the Boom Shape)

  • 이성욱;한동섭;심재준;한근조;김태형
    • 한국정밀공학회:학술대회논문집
    • /
    • 한국정밀공학회 2006년도 춘계학술대회 논문집
    • /
    • pp.371-372
    • /
    • 2006
  • This study was carried out to analyze the effect of wind load on the structural stability of a container crane according to the change of the boom shape using wind tunnel test and provide a container crane designer with data which can be used in a wind resistance design of a container crane assuming that a wind load 75m/s wind velocity is applied in a container crane. Data acquisition conditions for this experiment were established in accordance with the similarity. The scale of a container crane dimension, wind velocity and time were chosen as 1/200, 1/13.3 and 1/15. And this experiment was implemented in an Eiffel type atmospheric boundary layer wind tunnel with $11.52m^2$ cross-section area. Each directional drag and overturning moment coefficients of a container crane according to the change of the boom shape were investigated.

  • PDF

북미 법규 강화를 고려한 국내 자동차의 천정강도 시험특성에 관한 연구 (A Study on the Characteristics of Domestic Vehicle on the Roof Crush Test Considering the Enhanced Safety Standard, FMVSS 216)

  • 김은희;이재광;이문구;홍민성
    • 한국생산제조학회지
    • /
    • 제18권4호
    • /
    • pp.348-354
    • /
    • 2009
  • In order to reduce the risk of roll over crash, one of the greatest risk events, National Highway Traffic Safety Administration(NHTSA) issued Notice of Proposed Rulemaking(NPRM) enhancing the safety standard on roof crush resistance, FMVSS No. 216 and changing some part of the test procedure. According to this NPRM, the boundary Gross Vehicle Weight Rating(GVWR) of the vehicles applied by this standard is extended from 2,722kg(6000 lb) to 4,536 kg(10000 lb) and the applied test force is increased from 1.5 times to 2.5 times of Unloaded Vehicle Weight (UVW). Also the current limit on the amount of roof crush, 127mm(5 inch), is replaced with a new requirement of maintaining enough headroom without touching the head of a seated 50% male dummy. In this paper, we carried out the rollover crash test on some domestic cars and investigated their safety due to the KMVSS No. 92 and the enhanced safety standard, FMVSS No. 216, respectively. The result shows that most of them can satisfy the new standards but further tests will be necessary, especially for heavier cars.

  • PDF

AZ31마그네슘합금의 마찰접합특성 (Mechanical Properties of Friction Joint of AZ31Mg Alloy)

  • 공유식;천봉근;강대민
    • 소성∙가공
    • /
    • 제19권5호
    • /
    • pp.277-282
    • /
    • 2010
  • Magnesium alloy has been known as lightweight material in automobile and electronic industry with aluminum alloy, titanium alloy and plastic material. Friction welding is useful to join various metals and nonferrous metals that are difficult to join by such as gas welding, resistance welding and electronic beam welding. In this study, friction joining was performed to investigate mechanical properties of Mg alloy with 20mm diameter solid bar. Also the optimal joining conditions for its application were determined on the basis of tensile test, and hardness survey. The joining parameters were chosen as heating pressure, heating time, upsetting pressure, and upsetting time. Heating and upsetting pressure were executed under the range of 10~40MPa and 20~80MPa, respectively. From the experimental results, optimal joining conditions were determined as follows; rotating speed=2000rpm, heating pressure=35MPa, upsetting pressure=70MPa, heating time=1sec, upsetting time=5sec. Also the hardness of jointed boundary showed as HV50 which was similar to that of base metal at the optimal condition, and it was supposed that zone of HAZ was 8mm. Finally two materials were strongly mixed at interface part to show a well-combined microstructure without particle growth or any defect.

철골보의 정규하중분포에 따른 파손확률 평가 (Evaluation of the Probability of the Steel Beam to Collapse in Accordance with the Normal Distribution Load)

  • 송창영
    • 한국방재안전학회논문집
    • /
    • 제7권1호
    • /
    • pp.43-50
    • /
    • 2014
  • 본 논문은 신뢰성 이론에 기초하여 철골보의 단경간 및 2경간 연속보의 파손확률을 결정하였다. 계산식에서 철골보에 가해지는 하중은 정규 분포로 가정하여 진행되었으며, 파손확률의 변화를 확인하기 위해 보의 중앙범위에 적용하는 하중을 보의 1대 1과 1대 2로 분할된 지점에 배치하였다. 보의 끝부분의 경계 결합조건 역시 연구에 포함되었다. 연구 결과 파손확률이 있는 보에 대한 결합조건 및 파손확률은 2차 분석에 따라 그 중요도가 낮은 것으로 나타났다. 결론적으로 일부의 경우를 제외하고 보의 파손확률은 보 양단의 경계조건에 따라 차이가 있는 것으로 나타났다.