• Title/Summary/Keyword: bound level

Search Result 351, Processing Time 0.031 seconds

Recovery of Covalently Linked Fatty Acid Monolayer on the Hair Surface Using Biomimetic Lipid (생체모사 지질을 이용한 모발 표면에 공유 결합된 지방산 단분자층의 회복)

  • Kim, Ei-Suk;Son, Seong-Kil;Lee, Cheon-Koo
    • Journal of the Society of Cosmetic Scientists of Korea
    • /
    • v.38 no.2
    • /
    • pp.139-145
    • /
    • 2012
  • There is a unique type of fatty acid in the hair surface. 18-methyleicosanoic acid (18-MEA) is an unusual anteiso fatty acid covalently linked to the outermost surface of hair cuticle. A layer of 18-MEA is located in the upper ${\beta}$-layer of the CMC that is responsible for the low surface energy and low friction resistance of the hair's outer surface. The high mobility of 18-MEA molecule facilitates spreading of extraneous lipid by decreasing interfacial shear strength. In this study, we introduced N-hydroxyl succinimidyl ester functional group to the one end of C10 - 40 isoalkyl acid for regenerating hair surface with covalently bound fatty acid layer. The re-hydrophobicization of hair surface has been investigated by contact angle measurement. The inner moisture content of hair at different levels of humidity (40, 55, 70 %RH) was measured by electric moisture analyzer. Treatment with Hydroxysuccinimidyl C10 - 40 Isoalkyl Acidate (HCIA) was supposed to make hair surface smoother by filling the cracks between cuticles with covalently bound fatty acid monomolecular layer like cuticle glue. This glue effect was also confirmed with line profile of AFM images. Therefore, the moisture and structural components of inner hair were not easily flown out and the optimum moisture content could be kept constantly though the outside humidity level was changed. The lateral force microscopy (LFM) by using atomic force microscope showed that the friction force of hair surface treated with HCIA was decreased. It also showed the constantly sustained friction value even after shampooing repeated 15 times.

Health Risk Assessment of Disinfection By-products by Chlorination in Tap Water Ingestion (수도수중 염소 소독부산물로 인한 건강위해성 평가에 관한 연구 - 서울시 수도수중 Trihalomethanes 및 Haloaceticnitriles을 중심으로 -)

  • Chung, Yong;Shin, Dong-Chun;Yang, Ji-Yeon;Park, Yeon-Shin;Kim, Jun-Sung
    • Environmental Analysis Health and Toxicology
    • /
    • v.12 no.3_4
    • /
    • pp.31-41
    • /
    • 1997
  • Public concerns about hazardous health effect from the exposure to organic by-products of the chlorination have been increased. There are numerous studies reporting that chlorination of drinking water produces numerous chlorinated organic by-products including THMs, HAAs, HANs. Some of these products are known to be animal carcinogens. The purpose of this study was to estimate health risk of DBPs by chlorinated drinking water ingestion in Seoul based on methodologies that have been developed for conducting risk assessment of complex-chemical-mixture. The drinking water sample was collected seperately at six water treatment plant in Seoul at March, April, 1996. In tap water of households in Seoul, DBPs were measured wilfh the mean value of 36.6 $\mu$g/L. Risk assessment processes,. which include processes for the estimation of human cancer potency using animal bioassay data and calculation of human exposure, entail uncertainties. In the exposure assessment process, exposure scenarios with various assumptions could affect the exposure amount and excess cancer risk. The reference dose of haloacetonitriles was estimated to be 0.0023 mg/kg/day by applying dibromoacetonitrile NOAEL and uncertainty factor to the mean concentration. In the first case, human excess cancer risk was estimated by the US EPA method used to set the MCL (maximum contaminant level). In the second and third case, the risk was estimated for multi-route exposure with and without adopting Monte-Carlo simulation, respectively. In the second case, exposure input parameters and cancer potencies used probability distributions, and in the third case, those values used point estimates (mean, and maximum or 95% upper-bound value). As a result, while the excess cancer risk estimated by US EPA method considering only direct ingestion tended to be underestimated, the risk which was estimated by considering multi-route exposure without Monte-Carlo simulation and then using the maximum or 95% upper-bound value as input parameters tended to be overestimated. In risk assessment for Trihalomethanes, considering multi-route exposure with adopting Monte-Carlo analysis seems to provide the most reasonable estimations.

  • PDF

Seismic Evaluation of Steel Moment Frame Buildings based on Different Response Modification Factors and Fundamental Periods (반응수정계수와 주기의 영향에 대한 철골모멘트저항골조 건물의 내진성능평가)

  • Shin, Ji-Wook;Lee, Ki-Hak;Lee, Do-Hyung
    • Journal of the Earthquake Engineering Society of Korea
    • /
    • v.12 no.5
    • /
    • pp.47-56
    • /
    • 2008
  • This study was performed to evaluate the effect of Response modification factors (R-factor) in 3-, 9- and 20- story steel Moment Resisting Frame (MRF) buildings. Each structure was designed using a R-factor of 8, as tabulated in the 2000 International Building Code provision (IBC 2000) and Korea Building Code (KBC) 2008. In order to evaluate the maximum and minimum performance expected for such structures, an upper bound and lower bound design were adopted for each model. Next, each analytical model was designed using different R-factors (8, 9, 10, 11, 12) and four different structural periods with the original fundamental period. For a detailed case study, a total of 150 analytical models were subjected to 20 ground motions representing a hazard level with a 2% probability of being exceeded in 50 years. In order to evaluate the performance of the structures, static push-over and non-linear time history analysis (NTHA) were performed, and displacement ductility demand was investigated to consider the ductility capacity of the structures. The results show that the dynamic behaviors for the 3- and 9-story buildings are relatively stable and conservative, while the 20-story buildings show a large displacement ductility demand due to dynamic instability factors. (e.g. P-delta effect and high mode effect)

Effect of 1-MCP and High $pCO_2$ Treatment on the Firmness and Pectin Changes in Peach(Prunus persica) Fruit During Shelf-life (1-Methylcyclopropene(1-MCP) 및 $CO_2$ 처리가 복숭아(Prunus persica) 과실의 경도와 세포벽 변화에 미치는 영향)

  • Kim, Myun-Surn;Min, Jeong-Ho;Chun, Jong-Pil;Kim, Jin-Guk;Lee, Eun-Mo;Lee, Ji-Yong;Hwang, Yong-Soo
    • Korean Journal of Agricultural Science
    • /
    • v.37 no.2
    • /
    • pp.209-216
    • /
    • 2010
  • In order to understand the effects of a single or combined treatments of 1-MCP($1{\mu}L/L$) and $CO_2$(100%) on the firmness of melting type peach fruit(cv. Chunjungdo), fruit were harvested at commercial maturity and examined physiological changes including flesh firmness during 10 days of shelf-life. Firmness loss of fruit was delayed by both single and combined treatments of 1-MCP and $CO_2$. The treatment of 1-MCP was more effective than $CO_2$ treatment but no additive effective on firmness retention was found in the combined treatment. The upsurge of ethylene evolution occurred 5 days of shelf-life in air treated control but ethylene evolution gradually increased in fruit treated by 1-MCP and 1-MCP+$CO_2$. The suppression of ethylene evolution seemed stronger in $CO_2$ treatment. The respiration of fruit significantly inhibited up to 10 days except control where climacteric increase of respiration was found at 10 days of shelf-life. A molecular shift of pectic polymers(an increase of chelator soluble pectins and decrease of water soluble pectins) was induced by both 1-MCP and $CO_2$ treatments. An increase of water soluble pectins was coincident with firmness loss. The delay of firmness loss seemed to be associated with the migration of calcium to wall matrix, especially pectins, resulting in the increase of wall bound calcium. The polygalacturonase activity was significantly reduced by 1-MCP alone 1 day after treatment and increased to similar level of activity 5 days after treatment compared to other treatment except air treated control whereas pectin methylesterase activity seemed not to be affected by both 1-MCP and $CO_2$ treatments. Thus, the molecular shift of pectic polymers appeared not to be related with pectin methylesterase. Further study is required to clarify the softening mechanism associated with molecular shift of pectic polymers and the inter- or intra-cellular movement of calcium ions induced by postharvest treatments of 1-MCP and $CO_2$.

Tritium Distribution in Some Environmental Samples-Rices, Chinese Cabbages and Pine Needles in Korea (국내 환경시료(쌀, 채소, 솔잎) 중 삼중수소의 분포)

  • Kim, Chang-Kyu;Cho, Yong-Woo;Han, Man-Jung;Pak, Chan-Kirl
    • Journal of Radiation Protection and Research
    • /
    • v.17 no.2
    • /
    • pp.25-35
    • /
    • 1992
  • To evaluate tritium level in some environmental samples, tissue-free water tritium (TFWT) and tissue-bound tritium (TBT) were analyzed in rices, chinese cabbages and pine needles collected at 12 locations in Korea. The TFWT was recovered by freeze-drying of the samples and the TBT was obtained in the form of water by combustion of the dried samples. Tritium was measured by liquid scintillation counter. The concentrations of TFWT were in the range of $0.96{\sim}3.96 Bq/1,\; 0.83{\sim}3.40 Bq/1\;and\;1.02{\sim}3.01 Bq/1$ in rices, chinese cabbages and pine needles, respectively. The mean specific activity ratios (TBT/TFWT) were 0.94, 1.71 and 1.39 in rices, chinese cabbages and pine needles, respectiviely. This excess TBT in the samples may be attributed to the fact that the residence time of TBT in the plant is longer than that of TFWT. The specific activity ratio depends on the plant species, the exposed time to tritiated atmosphere, atmospheric moisture, temperature and diffusion factor.

  • PDF

Proteomic Analysis to Identify Tightly-Bound Cell Wall Protein in Rice Calli

  • Cho, Won Kyong;Hyun, Tae Kyung;Kumar, Dhinesh;Rim, Yeonggil;Chen, Xiong Yan;Jo, Yeonhwa;Kim, Suwha;Lee, Keun Woo;Park, Zee-Yong;Lucas, William J.;Kim, Jae-Yean
    • Molecules and Cells
    • /
    • v.38 no.8
    • /
    • pp.685-696
    • /
    • 2015
  • Rice is a model plant widely used for basic and applied research programs. Plant cell wall proteins play key roles in a broad range of biological processes. However, presently, knowledge on the rice cell wall proteome is rudimentary in nature. In the present study, the tightly-bound cell wall proteome of rice callus cultured cells using sequential extraction protocols was developed using mass spectrometry and bioinformatics methods, leading to the identification of 1568 candidate proteins. Based on bioinformatics analyses, 389 classical rice cell wall proteins, possessing a signal peptide, and 334 putative non-classical cell wall proteins, lacking a signal peptide, were identified. By combining previously established rice cell wall protein databases with current data for the classical rice cell wall proteins, a comprehensive rice cell wall proteome, comprised of 496 proteins, was constructed. A comparative analysis of the rice and Arabidopsis cell wall proteomes revealed a high level of homology, suggesting a predominant conservation between monocot and eudicot cell wall proteins. This study importantly increased information on cell wall proteins, which serves for future functional analyses of these identified rice cell wall proteins.

Relationships between Speciation of Heavy Metals in Soil and Water Dropwort (Oenanthe javanica DC.) Cultivated near Industrial Complex (토양내 중금속 존재형태와 미나리중 함량과의 관계)

  • Jung, Goo-Bok;Kim, Won-Il;Lee, Jong-Sik;Kim, Jin-Ho;Lee, Jeong-Taek
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.40 no.2
    • /
    • pp.164-171
    • /
    • 2007
  • This experiment was conducted to investigate heavy metal speciation and bioavailability from soil to the edible parts of water dropwort near industrial complex. The soils and water dropwort were collected from the paddies cultivating water dropwort(10 sites), stream sediments(5 sites), and background soils(3 sites) near industrial complex. The total concentrations of Cd Cu, and Ni were higher than those of permissible level for soil contamination(Cd 3, Cu 100, Ni $50mg\;kg^{-1}$ in soil) suggested by Kloke(1979). Dominant chemical forms of Cd in paddies cultivating water dropwort and stream sediments were exchangeable form(49.1-56.3%), and those of Cu, Zn, and Ni were Fe and Mn oxide bound and residual forms. The mobility factor of heavy metals in paddies cultivating water dropwort and stream sediments was in the order Cd>Zn>Ni>Cu>Pb, specially, the mobility factor of Cd (62-72%) were relatively higher than that of other metals in soils. The total concentrations of Cd in soils showed significant positive correlation with the ratios of exchangeable and Fe and Mn oxide bound forms, while correlated negatively with residual form. Heavy metal contents in root parts were higher than those in top parts of water dropwort. The bioavailability of water dropwort varied considerably between the different parts and heavy metals. Cd, Cu and Ni contents in water dropwort were correlated with each fractions in soils. Specially, the exchangeable form of Cd and Ni in soils showed significant positive correlation with the those contents of water dropwort.

Nitrogen Retention and Chemical Composition of Urea Treated Wheat Straw Ensiled with Organic Acids or Fermentable Carbohydrates

  • Sarwar, M.;Khan, M. Ajmal;Nisa, Mahr-un
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.16 no.11
    • /
    • pp.1583-1591
    • /
    • 2003
  • The influence of varying levels of urea and additives on nitrogen (N) retention and chemical composition of wheat straw was studied. The wheat straw was treated with 4, 6 and 8% urea and ensiled with 1.5, 2 and 2.5% of acetic or formic acid and 2, 4 and 6% of corn steep liquor (CSL) or acidified molasses for 15 days. The N content of wheat straw was significantly different across all treatments. The N content of urea treated wheat straw was increased with the increasing level of urea. The N content was higher in urea treated wheat straw ensiled with acetic or formic acid as compared to urea treated wheat straw ensiled without these organic acids. The N content of urea treated wheat straw was further enhanced when it was ensiled with CSL or acidified molasses. This effect was significant across all levels of urea used to treat the wheat straw. Nitrogen retention in urea treated wheat straw was decreased linearly as the urea level was increased to treat the wheat straw. The N content was increased linearly when higher levels of CSL or acidified molasses were used to ensile the urea treated wheat straw. Most of the N in urea treated wheat straw was held as neutral detergent insoluble N (NDIN). The NDIN content was increased linearly with the increasing levels of urea and additives. The neutral detergent fiber (NDF) contents were higher in urea treated wheat straw ensiled with acetic or formic acid as compared to urea treated wheat straw ensiled without additive. The NDF content further increased in urea treated wheat straw ensiled with CSL and acidified molasses. The entire increase in NDF content was because of fiber bound N. The hemicellulose content of urea treated wheat straw ensiled with CSL or acidified molasses was higher as compared to urea treated wheat straw ensiled with acetic or formic acid. The acid detergent fiber content of urea treated wheat straw ensiled with or without additives remained statistically non-significant. The cellulose contents of wheat straw was linearly reduced when urea level was increased from 4 to 6 and 8% to treat the wheat straw. This effect was further enhanced when urea treated wheat straw was ensiled with different additives. The results of the present study indicated that fermentable carbohydrates might improve the Nitrogen retention and bring the favorable changes in physiochemical nature of wheat straw. However, biological evaluation of urea treated wheat straw ensiled with fermentable carbohydrates is required.

Influences of Supplemental Plant Phytase (Phytazyme®) on Performances and Phosphorus Excretion in Laying Hens (사료내 식물성 Phytase (Phytazyme®) 첨가가 산란계의 생산성 및 인 이용성에 미치는 영향)

  • Kwon, S.K.;Kim, S.K.;An, B.K.;Yang, U.M.;Nam, K.T.;Kang, C.W.;Kang, S.J.
    • Journal of Animal Science and Technology
    • /
    • v.44 no.1
    • /
    • pp.55-60
    • /
    • 2002
  • Two experiments were conducted to investigate the effect of dietary supplementation of plant phytase (Phytazyme$^{(R)}$) in corn-soybean meal based diets on utilization of phytase-bound phosphorus in laying hens and evaluate nitrogen(N) digestibility and phosphorus(P) availability in breeders. In the experiment one, three levels of the Phytazyme$^{(R)}$(0.05, 0.1, and 0.2% of diet) were added to diets containing a half of control TCP level(0.96%) for 4 wks. Feed consumption, egg production rate, egg weight and eggshell quality were recorded weekly. At the end of experiment, 8 birds per treatment were sacrificed, liver weight were weighed and right tibiae were removed for determination of P content. The second experiment was conducted to evaluate the P availability and nitrogen digestibility in breeders fed same diets for 2 wks. Feed and excreta were collected to determine the P and N contents for the last three days of experiment two. Addition of Phytazyme$^{(R)}$ resulted in no effects on feed intake, egg product rate, egg weight and egg shell quality. P excretion decreased and its availability enhanced as phytase supplementation increased in diets. Dietary supplementation of Phytazyme$^{(R)}$ above 0.1% level in corn-soybean meal based diets did not have an adverse effect on production and decreased level of phosphorus in excreta.

Two Level Bin-Packing Algorithm for Data Allocation on Multiple Broadcast Channels (다중 방송 채널에 데이터 할당을 위한 두 단계 저장소-적재 알고리즘)

  • Kwon, Hyeok-Min
    • Journal of Korea Multimedia Society
    • /
    • v.14 no.9
    • /
    • pp.1165-1174
    • /
    • 2011
  • In data broadcasting systems, servers continuously disseminate data items through broadcast channels, and mobile client only needs to wait for the data of interest to present on a broadcast channel. However, because broadcast channels are shared by a large set of data items, the expected delay of receiving a desired data item may increase. This paper explores the issue of designing proper data allocation on multiple broadcast channels to minimize the average expected delay time of all data items, and proposes a new data allocation scheme named two level bin-packing(TLBP). This paper first introduces the theoretical lower-bound of the average expected delay, and determines the bin capacity based on this value. TLBP partitions all data items into a number of groups using bin-packing algorithm and allocates each group of data items on an individual channel. By employing bin-packing algorithm in two step, TLBP can reflect a variation of access probabilities among data items allocated on the same channel to the broadcast schedule, and thus enhance the performance. Simulation is performed to compare the performance of TLBP with three existing approaches. The simulation results show that TLBP outperforms others in terms of the average expected delay time at a reasonable execution overhead.