• 제목/요약/키워드: boron addition

검색결과 198건 처리시간 0.026초

Application and evaluation of boron nitride-assisted liquid silicon infiltration for preparing Cf/SiC composites

  • Kim, Jin-Hoon;Jeong, Eui-Gyung;Kim, Se-Young;Lee, Young-Seak
    • Carbon letters
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    • 제12권2호
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    • pp.116-119
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    • 2011
  • C/SiC composites were prepared by boron nitride (BN)-assisted liquid silicon infiltration (LSI), and their anti-oxidation and mechanical properties were investigated. The microstructures, bulk densities, and porosities of the C/SiC composites demonstrated that the infiltration of liquid silicon into the composites improved them, because the layered-structure BN worked as a lubricant. Increasing the amount of BN improved the anti-oxidation of the prepared C/SiC composites. This synergistic effect was induced by the assistance of BN in the LSI. More thermally stable SiC was formed in the composite, and fewer pores were formed in the composite, which reduced inward oxygen diffusion. The mechanical strength of the composite increased up to the addition of 3% BN and decreased thereafter due to increased brittleness from the presence of more SiC in the composite. Based on the anti-oxidation and mechanical properties of the prepared composites, we concluded that improved anti-oxidation of C/SiC composites can be achieved through BN-assisted LSI, although there may be some degradation of the mechanical properties. The desired anti-oxidation and mechanical properties of the composite can be achieved by optimizing the BN-assisted LSI conditions.

보론강을 이용한 리어 범퍼 임팩트빔의 경량 설계 및 해석 (Light-weight Design and Simulation of Automotive Rear Bumper Impact Beam Using Boron Steels)

  • 김기주;한창평;임종한;이영숙;원시태;이재웅
    • 한국자동차공학회논문집
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    • 제20권2호
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    • pp.98-102
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    • 2012
  • Increasing the fuel economy has been an inevitable issue for the development of new cars, and one of the important measures to improve the fuel economy is to decrease the vehicle weight. In order to obtain this goal, the researches about lighter, stronger and the well impact absorbing bumper impact beam have been studied without sacrificing bumper safety. In this study, the overall weight reduction possibility of rear bumper impact beam could be examined based on the variation of frontal, offset and corner impact crash capability by substituting a ultra high strength steel material (boron steel ) having tensile strength of 1.5 GPa grade instead of conventional steels. In addition, the section variations (open section, closed section, open section with 5 stays) of the bumper impact beam structure were examined carefully. It could be reached that this analysis could be well established and be contributed for design guide and the optimum design conditions of the automotive rear bumper impact beam development.

Physics study for high-performance and very-low-boron APR1400 core with 24-month cycle length

  • Do, Manseok;Nguyen, Xuan Ha;Jang, Seongdong;Kim, Yonghee
    • Nuclear Engineering and Technology
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    • 제52권5호
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    • pp.869-877
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    • 2020
  • A 24-month Advanced Power Reactor 1400 (APR1400) core with a very-low-boron (VLB) concentration has been investigated for an inherently safe and high-performance PWR in this work. To develop a high-performance APR1400 which is able to do the passive frequency control operation, VLB feature is essential. In this paper, the centrally-shielded burnable absorber (CSBA) is utilized for an efficient VLB operation in the 24-month cycle APR1400 core. This innovative design of the VLB APR1400 core includes the optimization of burnable absorber and loading pattern as well as axial cutback for a 24-month cycle operation. In addition to CSBA, an Er-doped guide thimble is also introduced for partial management of the excess reactivity and local peaking factor. To improve the neutron economy of the core, two alternative radial reflectors are adopted in this study, which are SS-304 and ZrO2. The core reactivity and power distributions for a 2-batch equilibrium cycle are analyzed and compared for each reflector design. Numerical results show that a VLB core can be successfully designed with 24-month cycle and the cycle length is improved significantly with the alternative reflectors. The neutronic analyses are performed using the Monte Carlo Serpent code and 3-D diffusion code COREDAX-2 with the ENDF/B-VII.1.

Three-D core multiphysics for simulating passively autonomous power maneuvering in soluble-boron-free SMR with helical steam generator

  • Abdelhameed, Ahmed Amin E.;Chaudri, Khurrum Saleem;Kim, Yonghee
    • Nuclear Engineering and Technology
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    • 제52권12호
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    • pp.2699-2708
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    • 2020
  • Helical-coil steam generator (HCSG) technology is a major design candidate for small modular reactors due to its compactness and capability to produce superheated steam with high generation efficiency. In this paper, we investigate the feasibility of the passively autonomous power maneuvering by coupling the 3-D transient multi-physics of a soluble-boron-free (SBF) core with a time-dependent HCSG model. The predictor corrector quasi-static method was used to reduce the cost of the transient 3-D neutronic solution. In the numerical system simulations, the feedwater flow rate to the secondary of the HCSGs is adjusted to extract the demanded power from the primary loop. This varies the coolant temperature at the inlet of the SBF core, which governs the passively autonomous power maneuvering due to the strongly negative coolant reactivity feedback. Here, we simulate a 100-50-100 load-follow operation with a 5%/minute power ramping speed to investigate the feasibility of the passively autonomous load-follow in a 450 MWth SBF PWR. In addition, the passively autonomous frequency control operation is investigated. The various system models are coupled, and they are solved by an in-house Fortran-95 code. The results of this work demonstrate constant steam temperature in the secondary side and limited variation of the primary coolant temperature. Meanwhile, the variations of the core axial shape index and the core power peaking are sufficiently small.

Ti-Nb 합금강에서 합금성분의 변화에 따른 석출물거동이 고온연성에 미치는 영향 (Effect of Precipitates on Hot Ductility Behavior of Steel Containing Ti and Nb)

  • 한원배;이종호;김희수;안현환;이승재;김성우;서석종;윤종승
    • 대한금속재료학회지
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    • 제50권4호
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    • pp.285-292
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    • 2012
  • Hot ductility behavior of precipitation-hardened low-carbon iron alloys containing 0.02 wt% Ti and 0.05 wt% Nb was characterized by a hot tensile stress test. Carbon (0.05, 0.1, 0.25 wt%) and boron (0.002 wt%) contents were varied to study the effect of precipitates on the high-temperature embrittlement of the alloys in the temperature range of $600{\sim}800^{\circ}C$. Ductility loss was observed at $700^{\circ}C$ for the tested alloys. The cause of the ductility loss was mainly attributed to the carbides and ferrite films formed at the grain boundaries during deformation. Although the carbon content tended to raise the total fraction of Nb (C, N), the precipitates were formed mostly in the grain interior as the precipitation temperature was raised above the deformation temperature by the high carbon content. Hence, carbon in excess suppressed the hot ductility loss. Meanwhile, boron addition improved the hot ductility of the alloys. The improvement is likely due to the boron atoms capturing carbon atoms and thus retarding the carbide formation.

M2 분말의 진공소결에 관한연구 (A Study on Vacuum Sintering of M2 HSS Powder)

  • 최영택
    • 한국기계연구소 소보
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    • 통권20호
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    • pp.89-104
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    • 1990
  • This study was carried out to obtain the most optimum conition in vacuum sintering of M2 HSS powder, by analysis of sintering characteristics and fracture strength in several conditions. The conclusion deduced from this study are as follows; -Boron was more effective element than graphite; at this time, the optimum amount of addition was 0.05 wt% -The optimum condition of sintering temperature and time were 1190- $1200^{\circ}C$ and 1-1.25hr, respectively -Fracture strength of vacuum sintered and heat-treated specimen in the most optimum condition was 2-2.5KN/ $mm^2$

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Convenient Procedure for the Reduction of Carboxylic Acids via Acyloxyborohydrides

  • Cho, Byung-Tae;Yoon, Nung-Min
    • Bulletin of the Korean Chemical Society
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    • 제3권4호
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    • pp.149-152
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    • 1982
  • A new convenient method for the reduction of carboxylic acids to the corresponding alcohols via acyloxyborohydrides was explored. Acyloxyborohydrides, prepared from the reaction of various carboxylic acids and sodium borohydride, underwent reduction to the corresponding alcohols readily by the addition of dimethyl sulfate or Lewis acids, such as boron trifluoride etherate and triphenyl borate, presumably through acyloxyboranes. By utilizing this procedure, aliphatic and aromatic acids are rapidly and quantitatively reduced to the corresponding alcohols in terahydrofuran either at room temperature (or at $65^{\circ}$). This procedure provides selective reduction of carboxylic acids in the presence of halogen, nitro, and heterocyclic rings such as furan and thiophene.

열-소성 연계 해석을 이용한 자동차 로어암 부품 개발 (Development of Automobile One-piece Lower-Arm Part by Thermo-Mechanical Coupled Analysis)

  • 손현성;김흥기;최병근;조열래
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2008년도 추계학술대회 논문집
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    • pp.218-221
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    • 2008
  • Hot Press Forming (HPF), an advanced sheet forming method in which a high strength part can be produced by forming at high temperature and rapid cooling in dies, is one of the most successful forming process in producing components with complex geometric shape, high strength and a minimum of springback. In order to obtain effectively and accurately numerical finite element simulations of the actual HPF process, the flow stress of a boron steel in the austenitic state at elevated temperatures has been investigated with Gleeble system. To evaluate the formability of the thermo- mechanical material characteristics in the HPF process, the FLDo defined at the lowest point in the forming limit diagrams of a boron steel has been investigated. In addition, the simulation results of thermo-mechanical coupled analysis of an automobile one-piece lower-arm part are compared with the experimental ones to confirm the validity of the proposed simulations.

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Calcium-Boron Interaction in Exopolysaccharide Production by the Cyanobacterium, Nostoc spongiaeforme

  • Singh;Netu;Asthana, R.K.;Singh, S.P.
    • Journal of Microbiology and Biotechnology
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    • 제10권3호
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    • pp.381-385
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    • 2000
  • The effect and interaction of Ca and B on exopolysaccharide (EPS) synthesis in the diazotrophically growing cyanobacterium. Nostoc spongiaeforme, was investigated. The absence of B inhibited EPS synthesis 1.56-fold ($16\mu\textrm{g}$ glucose equivalent/mg dry weight, 16 d) over the control cells ($25\mu\textrm{g}$ glucose equivalent) grown in medium containing 0.5 mM Ca and $8{\mu}{\textrm}{m}$ B. When B concentration was raised to $40{\mu}{\textrm}{m}$, EPS production was stimulated 1.8-fold. Reduction of Ca concentraion to one-half (0.25 mM) resulted in increased B demand (16$\muM$) by the cells for EPS production at par with the normal sets. However, without Ca, EPS production also increased as B increased. Addition of B to a Ca-free medium stimulated cyanobacterial diazotrophic growth as well as synthesis of Chl a and phycocyanin (0-8 d). The data suggest B-dependent diazotrophic growth during Ca-deficiency and point to and important interactive role of Ca and B in regulation of cyanobacterial EPS synthesis.

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