• Korean Journal of Materials Research
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• v.28 no.9
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• pp.495-498
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• 2018

Intermetallic compound matrix composites have been expected to be established as high temperature structural components. $Ni_3Al$ is a representative intermetallic alloy, which has excellent ductility even at room temperature by adding certain alloying elements. $Ni_3Al$ matrix composites with aluminum oxide particles, which are formed by the in-situ reaction between the alloy and aluminum borate whiskers, are fabricated by a powder metallurgical method. The addition of aluminum borate whiskers disperses the synthetic aluminum oxide particles during sintering and dramatically increases the strength of the composite. The uniform dispersion of reaction synthesized aluminum oxide particles and the uniform solution of boron in the matrix seem to play an important role in the improvement in strength. There is a dramatic increase in strength with the addition of the whisker, and the maximum value is obtained at a 10 vol% addition of whisker. The $Ni_3Al$ composite with 10 vol% aluminum oxide particles $0.3{\mu}m$ in size and with 0.1 wt% boron powder fabricated by the conventional powder metallurgical process does not have such high strength because of inhomogeneous distribution of aluminum oxide particles and of boron. The tensile strength of the $Ni_3Al$ with a 10 vol% aluminum borate whisker reaches more than twice the value, 930 MPa, of the parent alloy. No third phase is observed between the aluminum oxide and the matrix.

• Korean Journal of Materials Research
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• v.15 no.12
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• pp.791-795
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• 2005

In this study, aluminum borate whisker reinforced Mg-3Al-2Ag-1Zn matrix composites were fabricated by the squeeze infiltration technique. The purpose is to develop materials for elevated temperature applications. Microstructure observation revealed successful fabrication of the metal matrix composites, namely no cast defects such as porosity and matrix/reinforcement interface delamination etc. High temperature hardness and creep rupture properties were improved significantly with addition of Ag to the Al borate whisker reinforced Mg alloy composite. $Mg_3Ag$ phase formed during aging heat treatment could improve creep properties of the Mg matrix composites.

• Journal of Korea Foundry Society
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• v.16 no.6
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• pp.537-549
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• 1996

This study aims at investigating the correlation of microstructure and mechanical properties of the AZ91 Mg/Al borate whisker composites fabricated by squeeze csting technique with a variation of applied pressure. Microstructure observation and in-situ fracture tests were conducted on the composites to identify the microfracture process. Detailed microstructural analyses indicated that the grain refinement could be achieved with applied pressure and the little change in volume fraction on reinforcing whiskers could be carried out. It was also found clearly from in-situ observation of crack initiation and propagation that in the composite processed by the lower applied pressure, microcracks were initiated earily at whisker/matrix interfaces, thereby resulting in the drop in strength. In the composite processed by the higher applied pressure, on the other hand, planar slip lines were well developed in the matrix, and then propagated through whiskers without whisker/matrix decohesion. Thus, the effect of the applied pressure on microstructure and mechanical properties can be explained by grain refinement, increased amounts of reinforcements, and improvement of whisker/matrix interfacial strength as the applied pressure in increased.

• Journal of the Korean Ceramic Society
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• v.40 no.10
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• pp.998-1004
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• 2003

With starting materials of two different powder mixtures, $Al_2$(S $O_4$)$_3$+xNa$_2$B$_4$ $O_{7}$$.$10$H_2O$(㏖ ratio; x=0.1, 0.7) and ${\gamma}$-Al$_2$ $O_3$+xNa$_2$B$_4$ $O_{7}$$.$10$H_2O$(㏖ ratio; x=0.1, 0.7), whisker-type $Al_{18}$B$_4$ $O_{33}$ particles were synthesized by using conventional and microwave heat-treatment. The effects of microwave, amount of flux and temperature on the growth of whisker-type $Al_{18}$B$_4$ $O_{33}$ particles were investigated by using X-Ray Diffractometry (XRD) and Scanning Electron Microscopy (SEM). With increase of heat-treatment temperature and amount of flux, the size of whisker-type $Al_{18}$B$_4$ $O_{33}$ particles increased in both conventional and microwave heat-treated samples. However, compared to the conventional heat-treated samples, whisker-type $Al_{18}$B$_4$ $O_{33}$ particles were well grown for the microwave heat-treated samples.ted samples.

• Transactions of the Korean Society of Automotive Engineers
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• v.9 no.5
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• pp.188-194
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• 2001

Metal matrix composites with whisker reinforcements have significant potential for demanding mechanical applications including defense, aerospace, and automotive industries. Especially, metal matrix composites, which are reinforced with aluminum borate whisker, have been used for the part of piston head in automobile because of good specific strength and wear resistance. Aluminum alloy-based metal matrix composites with whisker reinforcements have been produced using squeeze casting method, which is kind of an infiltration method. In this study, AC4CH-based metal matrix composites with $Al_{18}B$_4$O_{33}$ reinforcement have been produced using squeeze casting method, after T6 heat treatment, we evaluated mechanical properties of matrix and MMC composite were evaluated.

• Journal of Korea Foundry Society
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• v.28 no.6
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• pp.268-272
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• 2008

Interfacial characteristics of aluminum borate whisker reinforced AS52 matrix composite was investigated. Peak hardness of AS52 composite was obtained aging at $170^{\circ}C$ for 15h and the aging process was accelerated by the presence of the aluminium borate whisker. The MgO layer, which was the interfacial reaction product between the reinforcement and the Mg matrix, was produced with 20 nm thickness in as-cast condition. As the aging time increased, the thickness of the interfacial reaction layer increased to 50 nm in peak aged condition. The nano-indentation test results indicated that the strength of interface was improved by the aging but over-aging degraded the reinforcement and decreased the interfacial strength which resulted in the decrease of overall composite strength.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.25 no.10
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• pp.1583-1589
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• 2001

Metal matrix composites with whisker reinforcements have significant potentials for demanding mechanical applications including defense, aerospace, and automotive industries. Especially metal matrix composites, which are reinforced with aluminum borate whisker, have been used leer the part of piston head in automobile because of good specific strength and wear resistance. In this study, AC4CH-based metal matrix composites with $Al_{18}$B$_{4}$ $O_{33}$ reinforcement have been produced using squeeze casting method, after T6 heat treatment, we evaluated fatigue life property of matrix and MMC composite and investigated fracture mechanism.m.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2002.10a
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• pp.373-378
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• 2002

Metal matrix composites have a great interest in recent years because high specific strength, high specific stiffness characteristics, and application ranges of the composites are extend to variety industry. In this paper, an investigation was performed on the plane strain fracture toughness and slinding wear properties of AC4CH alloy(Al-Si-Mg line) reinforced with 20wt% aluminum borate whisker expect one, which contained a inorganic binder($TiO_2$). the binder led to the formation of strengthen the whisker each other. The test of fracture toughness was using CT(half size) specimen of thickness 12.5mm, width 25mm. and test of slinding wear of using tribo a pin-on-disk machine and lubricant is used without paraffine 8.2CST at room temperature. As results, Fracture toughness $K_{IC}$ is $8.7MPa-m^{05}$ for ABOw/AC4CH, $9.28MPa-m^{05}$ for ABOw/AC4CH added $TiO_2$. but AC4CH alloy was violated the critical stipulated by ASTM standard for valid measurement of $K_{IC}$. In case of, it was performed $J_{IC}$ test instead of $K_{IC}$ based on ASTM E 1820.

• Korean Journal of Metals and Materials
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• v.48 no.5
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• pp.469-475
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• 2010

In this study, the interfacial bond strength of a squeeze infiltrated $Al_{18}B_{4}O_{33}$/AS52 Mg composite was investigated by using a finite element method. Three types of Mg composites with volume fractions of 15, 25 and 35% were fabricated. Three-dimensional models of the composite were developed by using a unit cell model in order to determine the effective elastic modulus of the metal matrix composite and the interfacial bond strength between the whisker and magnesium matrix. After modeling, numerical results were compared with the experimental tensile test results of $Al_{18}B_{4}O_{33}$/AS52 Mg composites. The results showed that the effective modulus of the composite strongly depended on the interfacial strength between the matrix and reinforcement. Based on the numerical and experimental findings, it was found that the strong interfacial bond was achieved by the interfacial reaction product of 30 nm thick MgO, which led to an improvement in the mechanical properties of the $Al_{18}B_{4}O_{33}$/AS52 Mg composites.

• Korean Journal of Metals and Materials
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• v.46 no.7
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• pp.412-419
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• 2008

Creep behavior of the squeeze infiltrated AS52 Mg matrix composites reinforced with 15 vol% of aluminum borate whiskers($Al_{18}B_4O_{33}w$) fabricated squeeze infiltration method was investigated. Microstructure of the composites was observed as uniformly distributed reinforcement in the matrix without any particular defects of casting pores etc.. Creep test was carried out at the temperature of 150 and $200^{\circ}C$ under the applied stress range of 60~120 MPa. The creep resistance of the composite was significantly improved comparing with the unreinforced AS52 Mg alloy. The creep behavior of composites might be interpreted with the substructure invariant model successfully for the composite. Threshold stress of the composite exist for the creep deformation of the composite. The analysis of the creep behavior of the composite with threshold stress indicated that creep deformation was controlled by the lattice diffusion process of AS52 Mg matrix at given effective stresses and temperatures. Activation energy was also calculated to check lattice diffusion controlled creep behavior of the composite.