• Title/Summary/Keyword: bonding surface

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Spin-coated ultrathin multilayers and their micropatterning using microfluidic channels

  • Hongseok Jang;Kim, Sangcheol;Jinhan Cho;Kookheon Char
    • Korea-Australia Rheology Journal
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    • v.15 no.1
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    • pp.1-7
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    • 2003
  • A new method is introduced to build up organic/organic multilayer films composed of cationic poly(allylamine hydrochloride) (PAH) and negatively charged poly (sodium 4-styrenesulfonate) (PSS) using the spinning process. The adsorption process is governed by both the viscous force induced by fast solvent elimination and the electrostatic interaction between oppositely charged species. On the other hand, the centrifugal and air shear forces applied by the spinning process significantly enhances desorption of weakly bound polyelectrolyte chains and also induce the planarization of the adsorbed polyelectrolyte layer. The film thickness per bilayer adsorbed by the conventional dipping process and the spinning process was found to be about 4 ${\AA}$ and 24 ${\AA}$, respectively. The surface of the multilayer films prepared with the spinning process is quite homogeneous and smooth. Also, a new approach to create multilayer ultrathin films with well-defined micropatterns in a short process time is Introduced. To achieve such micropatterns with high line resolution in organic multilayer films, microfluidic channels were combined with the convective self-assembly process employing both hydrogen bonding and electrostatic intermolecular interactions. The channels were initially filled with polymer solution by capillary pressure and the residual solution was then removed by the .spinning process.

Effects of Friction Pressure on Bonding Strength and a Characteristic of Fracture in Friction Welding of Cu to Cu-W Sintered Alloy (동-텅스텐 소결합금(Cu-W)과 동(Cu)의 마찰용접에서 마찰압력이 접합강도와 파단특성에 미치는 영향)

  • 강성보;민택기
    • Journal of Welding and Joining
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    • v.15 no.4
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    • pp.90-98
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    • 1997
  • A copper-tungsten sintered alloy(Cu-W) has been friction welded to a tough pitch copper in order to investigate the effect of friction pressure on bonding strength and a charicteristic of fracture. The tensile strength of the friction welded joint was increased up to 90% of the Cu base metal under the condition of friction time 1.2 sec, friction pressure 4.5kgf/$\textrm{mm}^2$ and upset pressure 10kgf/$\textrm{mm}^2$. From the results of fracture surface analysis, the increase of friction pressure could remarkably decrease the force and the time to be normally acted on weld interface. The W particles which were included in the plastic zone of Cu side could induce fracture adjacent to the weld interface because their existance in Cu induces a decrease in available section area and an increase in notch effect. Therefore, the tensile strength was decreased at high friction pressure (6kgf/$\textrm{mm}^2$) because the destruction of W was increased by an increase in mechanical force and crack was formed at weld interface.

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Mechanical Properties of Jute Fiber Reinforced Thermosetting Composites (황마섬유 보강 열경화성 복합재료의 기계적 특성)

  • Lee, C.H.;Song, J.E.;Nam, W.S.;Byun, J.H.;Kim, B.S.;Hwang, B.S.
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.04a
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    • pp.111-115
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    • 2005
  • Recently, natural fibers draw much interests in composite industry due to low cost, light weight, and environment-friendly characteristics compared with glass fibers. In this study, mechanical properties were evaluated for two extreme cases of jute fiber orientations, i.e. the unidirectional yarn composites and the felt fabric composites. Samples of jute fiber composites were fabricated by RTM process using epoxy resin, and tensile, compression, and shear tests were conducted. As can be expected, unidirectional fiber specimens in longitudinal direction showed the highest strength and modulus. Compared with glass/epoxy composites of the similar fabric architecture and fiber volume fraction, the tensile strength and modulus of jute felt/epoxy composites reached only 40% and 50% levels. However, the specific tensile strength and modulus increased to 80% and 90% of the glass/epoxy composites. The main reason for the poor mechanical properties of jute composites is associated with the weak interfacial bonding between fiber and matrix. The effect of surface treatment of jute fibers on the interfacial bonding will be examined in the future work.

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Planar Shock Wave Compaction of Oxidized Copper Nano Powders using High Speed Collision and Its Mechanical Properties (고속 충돌 시 발생하는 평면 충격파를 이용한 산화 나노 분말의 치밀화 및 기계적 특성 평가)

  • Ahn, Dong-Hyun;Kim, Wooyeol;Park, Lee Ju;Kim, Hyoung Seop
    • Journal of Powder Materials
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    • v.21 no.1
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    • pp.39-43
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    • 2014
  • Bulk nanostructured copper was fabricated by a shock compaction method using the planar shock wave generated by a single gas gun system. Nano sized powders, average diameter of 100 nm, were compacted into the capsule and target die, which were designed to eliminate the effect of undesired shock wave, and then impacted with an aluminum alloy target at 400 m/s. Microstructure and mechanical properties of the shock compact specimen were analyzed using an optical microscope (OM), scanning electron microscope (SEM), and micro indentation. Hardness results showed low values (approximately 45~80 Hv) similar or slightly higher than those of conventional coarse grained commercial purity copper. This result indicates the poor quality of bonding between particles. Images from OM and SEM also confirmed that no strong bonding was achieved between them due to the insufficient energy and surface oxygen layer of the powders.

A study on abrasive wear characteristics of side plate of FRP ship (온도변화에 따른 유리섬유/폴리우레탄 복합재료의 충격파괴거동)

  • Kim, Byung-Tak;Koh, Sung-Wi
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.45 no.3
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    • pp.188-193
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    • 2009
  • The present study was undertaken to evaluate the effect of temperature on the results of Charpy impact test for glass fiber reinforced polyurethane(GF/PUR) composites. The Charpy impact test were conducted in the temperature range from -50$^{\circ}$ to 50$^{\circ}$. The impact fracture toughness of GF/PUR composites was considerably affected by temperature and it was shown that the maximum value was appeared at room temperature. It is believed that sensitivity of notch on impact fracture energy were increased with decrease in temperature of specimen. As the GF/PUR composites exposed in low temperature, impact fracture toughness of composites decreased gradually owing to the decrease of interface bonding strength caused by difference of thermal expansion coefficient between the glass fiber/polyurethane resin. And decrease of interface bonding strength of composites with decrease in specimen temperature was ascertained by SEM photographs of Charpy impact fracture surface.

Synthesis of [P(AA-co-PEGMM)] Copolymer Films and its Physicochemical Characteristics ([P(AA-co-PEGMM)] 공중합체 필름의 합성 및 물리화학적 특성)

  • Kim, Joun-Sik;Park, Jeong-Sook;Han, Kun
    • Journal of Pharmaceutical Investigation
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    • v.31 no.3
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    • pp.173-180
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    • 2001
  • The physicochemical characteristics such as glass transition temperature (Tg), surface energy, swelling and FT-IR of [P(AA-co-PEGMM)], a copolymer of acrylic acid (AA) and polyethyleneglycol monoethylether mono methacrylate (PEGMM), were evaluated. The Tg of [P(AA-co-PEGMM)] decreased with increasing PEGMM content. [P(AA-co-PEGMM)] with 18 mole% PEGMM had the Tg of about $40^{\circ}C$, the similar physiological temperature of human. Moreover, [P(AA-co-PEGMM)] with lower PEGMM content had higher hydration and expected lower mucoadhesive strengths. To predict the mucoadhesiveness of [P(AA-co-PEGMM)] films, the contact angle of films were measured. With the increasing content of PEGMM of films, the contact angle was increased and the higher mucoadhesive forces was expected. ATR-FTIR studies revealed that the addition of the PEG moiety in AA increased the potential of hydrogen bonding for [P(AA-co-PEGMM)] as compared to cross linking polyacrylic acid (cr-PAA) because the oxygen in the repeat unit of PEG contributed in the formation of hydrogen bonding in the presence of mucin solution.

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A Stud on the Fabrication and Characteristics of Al-Sn Alloy Strips by Twin-Roll Process (쌍롤법에 의한 Al-Sn합금 Strip의 제조 및 특성에 관한 연구)

  • Lee, Jeong-Keun;Joo, Dae-Heon;Kim, Myung-Ho
    • Journal of Korea Foundry Society
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    • v.22 no.4
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    • pp.174-183
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    • 2002
  • Twin-roll process is a relatively new continuous casting process which can produce high-quality strip products directly, and solidification rate can reach $10^3$ to $10^4$ K/s, leading to fine and uniform microstructures with enhanced mechanical properties. The strip casting condition for producing fine Al-Sn alloy strip was obtained experimentally, and defects appearing on the strip was examined. Crack formation and surface quality of the strip was found to depend mainly on process parameters such as melt temperature, roller gap and rolling speed. Sn structure of network type was observed in Al-20Sn and Al-40Sn alloy strips, and cell spacing of Al-40Sn alloy was smaller than that of Al-20Sn. Banding strength of the heat treated specimens increased with increasing of soaking time and temperature, and bonding strength of Al-20Sn alloy was more superior than that of Al-40Sn alloy. However wear resistance of Al-40Sn alloy contained large amount of soft Sn which possess good anti-friction characteristics was superior than that of Al-20Sn alloy.

Use of modern microscopes in Analyzing fiber and Paper Properties( I )-Use of CLSM in Analyzing Fiber and Paper Properties- (최신 현미경을 이용한 섬유 및 종이의 성질 분석(제1보)-Confocal Laser Scanning Microscope를 이용한 섬유 밑 종이의 성질 분석-)

  • ;Keith Roy Wadhams
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.30 no.1
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    • pp.7-17
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    • 1998
  • With the advent of CLSM in the end of 1980s, it has been applied to the field of pulp and paper science in various ways. This study showed the potentials of CLSM In analyzing a change of pulp fiber and paper properties before and after mechanical treatment. In particular, a quantification of internal fibrillation has been done using cross-sectional images of fibers and image analysis technique, then evaluated the effects of fiber wall delamination on fiber and paper properties. It showed that the delaminated fibers were closely associated to development of the interfiber bonding in a fiber network. The CLSM made it possible to investigate a density profile along the sheet thickness, which was created by some papermaking processes like pressing, drying and calendering. Through the attempt to observe the forming procedure of a fiber network during handsheet making, the CLSM images showed that the pressing stage was considered greatly to contribute to generation of interfiber bonding with removing a free water and partly a bound water between fibers. In addition, the CLSM could be used to illustrate not only a surface profile of paper showing the extent of smoothness or roughness, but also a density profile in a B-direction of the network. Finally it became evident that the CLSM could be used as an excellent tool to predict development in fiber and paper properties before and after mechanical treatment during papermaking processes.

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Bond-slip constitutive model of concrete to cement-asphalt mortar interface for slab track structure

  • Su, Miao;Dai, Gonglian;Peng, Hui
    • Structural Engineering and Mechanics
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    • v.74 no.5
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    • pp.589-600
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    • 2020
  • The bonding interface of the concrete slab track and cement-asphalt mortar layer plays an important role in transferring load and restraining the track slab's deformation for slab track structures without concrete bollards in high-speed railway. However, the interfacial bond-slip behavior is seldom considered in the structural analysis; no credible constitutive model has been presented until now. Elaborating the field tests of concrete to cement-asphalt mortar interface subjected to longitudinal and transverse shear loads, this paper revealed its bond capacity and failure characteristics. Interfacial fractures all happen on the contact surface of the concrete track slab and mortar-layer in the experiments. Aiming at this failure mechanism, an interfacial mechanical model that employed the bilinear local bond-slip law was established. Then, the interfacial shear stresses of different loading stages and the load-displacement response were derived. By ensuring that the theoretical load-displacement curve is consistent with the experiment result, an interfacial bond-slip constitutive model including its the corresponding parameters was proposed in this paper. Additionally, a finite element model was used to validate this constitutive model further. The constitutive model presented in this paper can be used to describe the real interfacial bonding effect of slab track structures with similar materials under shear loads.

Analysis of the DC Resistance of the Butt Joint using the Random Contact Patterns of Strands

  • Lee, Ho-Jin;Lee, Sang-Il;Lee, Bong-Sang
    • Progress in Superconductivity and Cryogenics
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    • v.6 no.4
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    • pp.17-21
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    • 2004
  • The butt joint was verified to satisfy the thermal stability of the ITER magnet system through the ITER CS model coil test. Since the contact area in the butt joint is limited to the cross section of the cable, it is necessary to analyze and control the joining parameters precisely for improving the DC resistance. It is difficult to simulate the cables, which are composed of a lot of strands, as three-dimensional models using the commercial code. The random numbers were used to simulate many kinds of contact patterns of the strands on the bonding surface for calculating the bonding area and the DC resistance of the butt joint. The calculated DC resistance decreases with an increase of cable filling factor in terminal. The calculated DC resistance of a 0.9 cable filling factor is about 0.48 n-Ohm, which is about one-tenth of that in the CS model coil test when not considering the electrical contact resistance. From this difference, the electrical contact resistance between the strands and copper sheet was calculated.