• Journal of the Korea Concrete Institute
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• v.11 no.4
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• pp.129-136
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• 1999

For the prediction of concrete-steel bond ability in reinforced concrete, many countries establish specifications for the pullout test. But these methods hardly to consider many parameters such as strength, shape, diameter and location of steel, concrete restrict condition by loading plate, strength of concrete and cover depth etc, and it is difficult to solve concentration and disturbance of stress. The purpose of this study is to propose a New Ring Test method which can be rational quantity evaluations of bond splitting mechanism. For this purpose, pullout test was carried out to assess the effect of several variables on bond splitting properties between reinforcing bar and concrete. Key variables are concrete compressive strength, concrete cover, bar diameter and rib spacing. Failure mode was examined and maximum bond stress-slip relationships were presented to show the effect of above variables. As the result, it appropriately expressed general characteristics of bond splitting mechanism, and it proved capability for standard test method.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.185-188
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• 2005

Bond between reinforcing bar and surrounding concrete is supposed to transfer load safely in the process of design of reinforced concrete structures. Bond strength of ribbed reinforcing bars tends to split concrete cover, by wedging action, or shear the concrete in front of the ribs. In this study, using a reducing bearing angle theory, bond strengths of beam end specimen are predicted. Values of bond strength obtained using the analytical model are in good agreement with the bond test results. The analytical model provides insight into bond mechanism and the effects of bearing angle on the bond strength of deformed bars to concrete.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.04a
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• pp.750-755
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• 1999

When the RC frame structures subjected to the seismic load, brittle shear failure of vertical members induces brittle collapse of whole structures. Failure mechanism like this is not desirable. So shear strengthening method to avoid this failure mechanism is needed. Recently, strengthening method using continuous fiber sheet is studied and used widely which have high elastic and high strength characteristics. In this study, RC columns which is strengthened by carbon fiber sheet in the form of tape or whole sheet were tested under the cyclic load. The parameter of this test is the amount of strengthening. As the amount of strengthening increase, strength, ductility and energy capacity increase. The failure mode of test results are shear and bond-split failure.

• Journal of the Korean Chemical Society
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• v.18 no.3
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• pp.180-188
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• 1974

Adsorption mechanism of alkyl aldehydes, acetaldehyde, acrolein, and crotonaldehyde on cations supported by layer silicates was studied by means of IR spectroscopy and X-ray. An analysis of four characteristic split bands in the region of $1720∼1580㎝^{-1}$ was made. The carbonyl stretching band which shifted about $130㎝^{-1}$ to lower frequencies was observed only for $Ni^{2+}$ and Al^{3+}$ but slightly with $Ca^{2+}$ at high sample temperature and was attributed to >C=O…M complex formation. A sharp band which appeared as a shoulder at 1722 for acetaldehyde and 1690 for acrolein and crotonaldehyde was responsible for the interaction of carbonyl with surface hydroxyl. The second broad band which appeared at about 1710~1660 was responsible for hydrogen bonding between carbonyl oxygen and cationic hydroxyl group. The third band which appeared at about 1640~1660 was attributed to induced >C=C< double bond due to the strong carbonyl interaction. This was supported by the interlamellar spacings obtained by X-ray diffractometry.

• Journal of the Korean Chemical Society
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• v.32 no.3
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• pp.186-194
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• 1988

The electrochemical reduction of O,O-dimethyl-O-(3-methyl-4-nitrophenyl)-phosphorothioate (Fenitrothion) has been studied in acetonitrile solution containing surfactant micelle by direct current (DC)-differential pulse (DP) polarography, cyclic voltammetry (CV) and controlled potential coulometry (CPC). The partially reversible electron transfer-chemical reaction(EC, EC mechanism) of fenitrothion reduction proceeded by four electron transfer to form O,O-dimethyl-O-(3-methyl-4-hydroxyaminophenyl)-phosphorothioate which undergoes single bond of the phosphorus atom and phenoxy group cleaves to give p-amino-m-cresol and dimethyl thiophosphinic acid as major product by two electron transfer-protonation at higher negative potential. The polarograpic reduction waves shown to suppressed due to inhibitory effect of sodium lauryl sulfate micelle solution and split up on selectivity of anionic micelle effect in two step at the first reduction peak.