• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.5
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• pp.3251-3259
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• 2014

This paper presents experimental and analytical research results to predict nonlinear flexural behavior of corroded reinforced concrete beams. For this purpose, a series of test and an analytical simulation using the Maaddawy's model were carried. Test specimens of total 12 RC beams were placed in accelerated corrosion status using salt water spray test chamber for 5 months and 10 months, after they were preloaded up to 30% and 60% of the maximum load corresponding to nominal flexural strength. The test results showed that flexural strength and ductility decreased to 5.4% and 43% at the most respectively due to breakdown of bond at the steel-concrete interface. Comparative study between the analytical predictions and the experimental results showed that the Maaddawy's model can be applied to predict a real corroded RC flexural members.

• Computers and Concrete
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• v.30 no.5
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• pp.311-321
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• 2022

The interfacial bond strength of partially encased composite (PEC) structure tends to 0, therefore, the cast-in-place concrete theoretically cannot embody better composite effect than the fabricated structure. A total of 12 specimens were designed and experimented to investigate the energy dissipation and damage of fabricated PEC beam through unidirectional cyclic loading test. Because the concrete on both sides of the web was relatively independent, some specimens showed obvious asymmetric concrete damage, which led to specimens bearing torsion effect at the later stage of loading. Based on the concept of the ideal elastoplastic model of uniaxial tensile steel and the principle of equivalent energy dissipation, the energy dissipation ductility coefficient is proposed, which can simultaneously reflect the deformability and bearing capacity. In view of the whole deformation of the beam, the calculation formula of energy dissipation is put forward, and the energy dissipation and its proportion of shear-bending region and pure bending region are calculated respectively. The energy dissipation efficiency of the pure bending region is significantly higher than that of the shear-bending region. The setting of the screw arbors is conducive to improving the energy dissipation capacity of the specimens. Under the condition of setting the screw arbors and meeting the reasonable shear span ratio, reducing the concrete pouring thickness can lighten the deadweight of the component and improve the comprehensive benefit, and will not have an adverse impact on the energy dissipation capacity of the beam. A damage model is proposed to quantify the damage changes of PEC beams under cyclic load, which can accurately reflect the load damage and deformation damage.

• Proceedings of the Korean Society of Crop Science Conference
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• 2022.10a
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• pp.232-232
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• 2022

We reported in our recent studies that the combined treatment of Paenibacillus yonginensis DCY84^T (DCY84^T) and Silicon (Si) promotes initial plant growth and increases resistance to biotic and abiotic stress. To understand the molecular background of these phenotypes, Liquid Chromatography Mass Spectrometry (LC-MS) analysis was performed, and it was confirmed that unsaturated fatty acid metabolites such as oleic acid and linoleic acid decreased in response to the combined treatment of DCY84^T and Si. The stearoyl-acyl carrier protein desaturase (SACPD) introduces the cis double bond into the acyl-ACPs at C9, resulting in the production of unsaturated fatty acid. We identified OsSSI2 encoding SACPD in rice and found that the expression of OsSSI2 was reduced under DCY84^T and Si treatment. Furthermore, qRT-PCR analysis revealed that the expression of OsWRKY45, which is downstream of OsSSI2, was upregulated in response to DCY84^T and Si treatment. These results enable the speculation that activation of the salicylic acid (SA)-responsive gene, OsWRKY45, may contribute to enhancing biological stress resistance. Based on this, we propose a probable model for the rice defense pathway following DCY84^T and Si treatment. This model retains a WRKY45-dependent but NH1(NPR1)-independent SA signaling pathway.

• Journal of the Korea institute for structural maintenance and inspection
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• v.28 no.3
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• pp.19-26
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• 2024

In this study, the compressive behavior of a 1/12.5 scale model of a wind tower support structure connection was experimentally analyzed. A high-performance cementitious grout with a compressive strength of 140 MPa was used to fill the connection, and experiments were conducted with shear key spacing, the shape, and connection length as variables. When the number of shear keys in the connection is the same, the smaller the spacing of the shear keys than the length of the connection, the higher the shear strength, and for the same spacing and connection length, the higher the height of the shear keys, the higher the strength. In addition, it was found that the strength showed a linear behaviour until the connection slip reached 1.0 mm, and it reached the maximum strength at 7.0 mm connection slip showing a non-linear behaviour as the load increased. It was found that the failure mode changed from interfacial shear failure to grout failure as the strength increased according to the shape and spacing of the shear key, and brittle failure did not occur due to steel fibers.

• Journal of the Korea Concrete Institute
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• v.16 no.3 s.81
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• pp.293-302
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• 2004

The transfer of prestress force in pretensioned prestressed concrete (PSC) members is of great concern because it affects directly the distribution of stress around the transfer zone. The design provision of current design code on the transfer length considers only the prestress intensity and the diameter of prestressing steels. However, other factors such as concrete compressive strength and concrete cover may affect greatly the transfer length. The purpose of the present paper is to explore the various factors that affect the transfer length in pretensioned PSC members. The bond stress-slip relation between prestressing steel and concrete was modeled first from experimental data and then this model was incorporated into the interface element. The interface element was used to perform the finite element analysis for pretensioned PSC members. The results indicate that the compressive strength and concrete cover are also very important parameters which affect the transfer length greatly. This means that the current design code, which considers only the effective prestress and diameter of prestressing steel, must be improved to take into account the other important variables of compressive strength and concrete cover. The present study allows more realistic analysis and design of pretensioned PSC members.

• Journal of Distribution Science
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• v.13 no.10
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• pp.73-82
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• 2015

Purpose - This paper aims to investigate whether information asymmetry could explain capital structures in Korean corporations. According to Myers (1984), firms prefer internal funding to external financing due to the costs associated with information asymmetry. When external financing is necessary, firms prefer to issue debt rather than equity by the same reasoning. Since Shyam-Sunder and Myers (1999), numerous studies continue to debate the validity of the theory. In this paper, we show how the theory depends on assumptions and incorporated variables. We hope our investigation can provide helpful implications regarding capital structure, information asymmetry, and other firm characteristics. Specifically, our empirical results are complementary to the analysis of Son and Lee's (2015), a recent study that examines the pecking order theory prediction for Korean retail firms. Research design, data, and methodology - We test empirical models that are some variants of model used in Shyam-Sunder and Myers (1999). The financial and accounting data are provided by WISEfn for the firms listed on the KOSPI during 1990 to 2013. Bond ratings are supplied by the Korea Investor Service (KIS). We take into account the heterogeneity in debt capacity; a firm's debt capacity is measured by using the method of Lemmon and Zender (2010) based on its bond ratings. Finally, we estimate empirical models suggested by Shyam-Sunder and Myers (1999), Frank and Goyal (2003), and Lemmon and Zender (2010). Results - First, we find that Shyam-Sunder and Myers' (1999) prediction fails to explain total debt changes of Korean firms. Second, we find a non-monotonic relationship between total debt changes and financial deficits with respect to debt capacity. This contradicts the prediction of Lemmon and Zender (2010) that argues the pecking order theory survives with a monotonically increasing relationship. Third, we estimate a negative correlation coefficient between financial deficit and current debt changes. The result is the complete opposite of the prediction of Lemmon and Zender (2010). Finally, we also confirm the non-monotonic relationship between non-current debt changes and financial deficits with respect to debt capacity. Yet, the slope of coefficient is smaller than that of total debt change case. Indeed, the results are, to some extent, consistent with the prediction of pecking order theory, if we exclude the mid-debt capacity firms. Conclusions - Our empirical results complementary to the analysis of Son and Lee (2015), a recent study focusing on capital structure in Korean retail firms; their paper suggests interesting topics regarding capital structure, information asymmetry, and other firm characteristics in Korean corporations. Contrary to Son and Lee (2015), our results show that total debt changes and current debt changes are inconsistent with the prediction of Shyam-Sunder and Myers (1999). However, similar to Son and Lee (2015), non-current debt changes are consistent with the pecking order prediction, in the case of excluding the mid-level debt capacity firms. This contrast allows us to infer that industry characteristics significantly affect the validity of the pecking order prediction. Further studies are needed to analyze the economics behind this phenomenon, which is beyond the scope of our paper. In addition, the estimation bias potentially matters regarding the firm-level debt capacity calculation. We also reserve this topic for future research.

• Journal of the Korean Chemical Society
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• v.27 no.5
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• pp.330-339
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• 1983

The CNDO/2 and STO-3G calculations were performed on nitrogen, oxygen, and sulfur compounds in order to examine the effect of interactions between two nonbonding (n) orbitals in the same molecule separated by N intervening $\sigma$ bonds based on the PMO approach. Calculated basis level energies, energy splittings, and interaction energy changes for both chain and cyclic model compounds were qualitatively compared with the corresponding predictions derived from perturbational formalism for n-n orbital interactions and successfully explained in terms of the derived energy expressions. In general, through-space interaction term could be neglected in the N and O systems. And the calculated results were explained simply by through-bond interaction term. As a result, through-bond interaction placed n- below n+ for odd systems and n+ below n- for even systems. Also energy splittings in odd systems were larger than those in even systems. However, in the cases of cis-ethylene diamine and o-phenylene diamine(conformer VI in Table 4), through-space interaction term was found to be substantial and the opposing effects of through-space and through-bonds interactions were observed. Finally it was found that the interactions between two n orbitals on S atoms always had some contribution of the destabilizing through-space interaction term. This result was consistent with the fact that the lone pair lobes of third elements were larger in size than those of the second period elements.

• The Journal of Advanced Prosthodontics
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• v.1 no.2
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• pp.63-67
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• 2009

STATEMENT OF PROBLEM. Use of custom tray and tray adhesive is clinically recommended for elastomeric impression material. However there is not clear mention of drying time of tray adhesive in achieving appropriate bonding strength of tray material and impression material. PURPOSE. This study is to investigate an appropriate drying time of tray adhesives by evaluating tensile bonding strength between two types of polyvinylsiloxane impression materials and resin tray, according to various drying time intervals of tray adhesives, and with different manufacturing company combination of impression material and tray adhesive. MATERIAL AND METHODS. Adhesives used in this study were Silfix (Dentsply Caulk, Milford, Del, USA) and VPS Tray Adhesive (3M ESPE, Seefeld, Germany) and impression materials were Aquasil Ultra (monophase regular set, Dentsply Caulk, Milford, Del, USA) and Imprint II Garant (regular body, 3M ESPE, Seefeld, Germany). They were used combinations from the same manufacture and exchanged combinations of the two. The drying time was designed to air dry, 5 minutes, 10 minutes, 15 minutes, 20 minutes, and 25 minutes. Total 240 of test specimens were prepared by auto-polymerizing tray material(Instant Tray Mix, Lang, Wheeling, Il, USA) with 10 specimens in each group. The specimens were placed in the Universal Testing machine (Instron, model 3366, Instron Corp, University avenue, Nowood, MA, USA) to perform the tensile test (cross head speed 5 mm/min). The statistically efficient drying time was evaluated through ANOVA and Scheffe test. All the tests were performed at 95% confidence level. RESULTS. The results revealed that at least 10 minutes is needed for Silfix-Aquasil, and 15 minutes for VPS Tray Adhesive-Imprint II, to attain an appropriate tensile bonding strength. VPS Tray Adhesive-Imprint II had a superior tensile bonding strength when compared to Silfix-Aquasil over 15 minutes. Silfix-Aquasil had a superior bonding strength to VPS Tray Adhesive-Aquasil, and VPS Tray Adhesive-Imprint II had a superior tensile bonding strength to Silfix-Imprint II at all drying periods. CONCLUSION. Significant increase in tensile bonding strength with Silfix-Aquasil and VPS Tray adhesive-Imprint II combination until 10 and 15 minutes respectively. Tray adhesive-impression material combination from the same company presented higher tensile bonding strength at all drying time intervals than when using tray adhesive-impression material of different manufactures.

• Journal of the Korean Chemical Society
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• v.37 no.12
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• pp.1047-1052
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• 1993

The electronic spectra of enzyme-model organocobalt(Ⅲ) complexes containing completely or partially conjugated macrocyclic ligands were measured in various solvents to investigate the solvent effect on the charge transfer band for the axial cobalt-carbon bond by the extent of conjugation in the equatorial macrocyclic ring; completely conjugated, $CH_3CoL,\;C_6H_5CoL,\;CNCoL,\;CH_3CoL',\;CNCoL'$, partially conjugated $CH_3(py)Co(DH)_2, CH_3CoL＂$, unconjugated dienes, $[CH_3Co(1,4-CT)](ClO_4)_2$, and open ring, $CH_3Co(salen)$. The position of the charge transfer band which corresponds to the cobalt-carbon bond was shifted to a shorter wavelength as the polarity of solvent increased and the transition energy $(E_T)$ had a linear relationship with solvent polarity parameter, Z-value, only in the case of completely conjugated system. However, the linear correlation between $E_T$and Z was not observed for partially conjugated and open ring systems.

• Journal of Cadastre & Land InformatiX
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• v.49 no.1
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• pp.45-63
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• 2019

Until recently, most people have invested in a traditional portfolio consisting of stocks, bonds and real estates based on the three-division method of properties in Korea. However, this study analyzed the impact of the composition of a portfolio combining representative real estate indirect investment products such as Reits and real estate funds on the investment performance. For this purpose, the empirical analysis using the mean variance model, which is the most appropriate method for the portfolio composition, was used. For variables used in this study, mixed asset portfolios were classified into Portfolio A through Portfolio G depending on the composition of assets, and the price indices selected as Kospi, Krx bond, Reits Trus Y7, Hanwha-Lasal fund, and Office (Seoul). The results are as follows; first Portfolio D, which combined bonds, stocks, Reits and Real Estate funds, and Portfolio G, which added the office, the actual real estate, were shown to have the lowest risk. second, Portfolio B composed of bonds, stocks and Reits and Portfolio D with added real estate funds had the lowest risk while Portfolio F composed of bonds, stocks, offices and real estate funds, and Portfolio G with added Reits were the most profitable. As a result, it has been analyzed that it was more effective to compose a portfolio including Reits and real estate funds, which were real estate indirect investment products that eliminated the illiquidity limitation of real estates than real estates, the traditional three-division method of properties. Therefore, it is possible to minimize the risk of investors and reduce the cost of ownership of the real estate by solving the illiquidity problem that is the biggest disadvantage of the direct investment, In addition, it is considered that it is more necessary to reinvigorate the real estate indirect investment market where small amounts can be invested.