• Bulletin of the Korean Chemical Society
• /
• v.16 no.3
• /
• pp.256-260
• /
• 1995

Laser induced fluorescence spectra of OH produced from photodissociation of $H_2O_2$ at 280-290 nm in the gas phase have been observed. By analyzing the Doppler profiles, the anisotropy parameter($\beta$ =-0.7) and the center of mass translational energy of the fragments have been measured. The measured energy distribution is well described by an impulsive model. The excited state leading to dissociation is found to be of 1Au symmetry. The dissociation from this state is prompt and direct with the fragment OH rotating in the plane perpendicular to the O-O bond axis.

• Journal of the Korean Chemical Society
• /
• v.41 no.1
• /
• pp.22-46
• /
• 1997

Kinetic studies on nucleophilic substitution reaction of phenacyl bromide and phenacyl chloride with pyridines were conducted at 25℃ and 35℃ in methanol-acetonitrile solvents mixtures. It was shown that the reaction proceeds via an SN2 reaction mechanism based on the transition state parameters, ΔH≠ and ΔS≠ and Bro nsted β values. Quantum mechanical model predicted a product-like transition state, where bond-formation is much more progressed than bond breaking, upon changing the leaving group to that with a better leaving ability.

• The Korean Journal of Financial Management
• /
• v.8 no.1
• /
• pp.199-212
• /
• 1991

주식옵션(stock options)에 대한 연구에 비교하여 상품 및 퓨처 옵션(commodity & futures options)에 대한 연구는 선진국에서도 지금 한참 연구를 하고 있는 단계에 있다. 우리나라에서도 이 분야에 대한 이론을 바탕으로 하는 제도를 곧 도입하려는 준비를 하고 있다. 본 연구는 블랙의 '블랙의 컴모디티 옵션의 가격모형(Black commodity option pricing model)'을 이용하여 재무성 장기채권의 퓨처의 균형가격을 예측하는데 있다. 이 블랙모형의 적용가능성을 검증해 본 것이다. 실제퓨처가격(observed futures prices)과는 달리 재무성 장기채권 퓨처 옵션에서의 묵시적 퓨처가격(futures prices implicit)은 시장효율성(market efficiencies)의 전제하에 성립되거나, 아니면 옵션가격모형을 사용하여서는 아니되거나 둘 중의 하나이거나 둘 다 섞이거나 일 것이다. 본 실증적인 연구, 즉 묵시적인 표준편차(implied standard deviations)를 사이멀테니어스(simultaneously)하게 계산한 묵시적인 퓨처가격(implied futures prices)을 사용한 실증적인 연구는 옵션모델에 의하여 퓨처가격을 계산하는 데에 문제가 있음을 발견하였다. 그 이유는 옵션가격결정모형을 이용하여 계산한 재무성 장기채권의 퓨쳐가격은 재무성 장기채권의 미래가격변동의 방향을 제시하는 지표로써 사용할 수 없기 때문일 것이다. 우리나라에서도 이 분야에 대한 이론과 제도를 곧 도입하는 입장에서 선행되는 문헌이 될 것이다.

• Textile Coloration and Finishing
• /
• v.17 no.1
• /
• pp.30-37
• /
• 2005

The tensile properties, acetic acid solubility and degree of swelling in distilled water of cellulose/chitosan and sericin/chitosan film blended by mixing chitosan acetic acid solution with cellulose solution or sericin solution were investigated and the effect of crosslinking agent on solubility and degree of swelling were also considered. From the experimental results, the model of intermolecular bond is proposed. Tensile modulus of 100% cellulose film is high but the tensile strength and elongation are low. The elongation of 100% chitosan film is high but tensile modulus and strength is low. But it is possible to make film having same or higher tensile strength and modulus compared to that of 100% cellulose film by mixing cellulose and chitosan or by mixing sericin and chitosan. Chitosan is solved in 5vol % acetic acid solution but cellulose and sericin are not solved. Degree of swelling of chitosan in distilled water is higher than that of cellulose and sericin. Lower than 40wt% chitosan content, the solubility of cellulose/chitosan film in 5vol % acetic acid solution shows lower expected value but higher in case of sericin/chitosan film.

• Journal of the Korean Vacuum Society
• /
• v.5 no.3
• /
• pp.199-205
• /
• 1996

InGaAs eqitaxial layers have been selectively grown on patterned GaAs(100) substrates by chemical beam epitaxy (CBE) using triethylgallium (TEGa), trimethylindium (TMIn), and unprecracked monoethylarsine (MEAs). Facet growth of InGaAs epilayers has also been investigated at the various growth temperatures and Si4N4 dielectric pattern directions. In [011] jirection of mask, the change from (311), (377) and (111) facets to (311) facet with increasing growth temperature was observed. In [011] direction, however, the change from (011) and (111) facets to (111) facet with increasing growth temperature was observed. These results are attributed to the sidewall growth caused by different surface migration lengths of reactants. The formation of U-shaped (100) top surface is also discussed in terms of dangling bond model.

• Structural Engineering and Mechanics
• /
• v.35 no.2
• /
• pp.241-256
• /
• 2010

The interaction between steel tube and concrete core is the key issue for understanding the behavior of concrete-filled steel tube columns (CFTs). This study investigates the force transfer by natural bond or by mechanical shear connectors and the interaction between the steel tube and the concrete core under three types of loading. Two and three-dimensional nonlinear finite element models are developed to study the force transfer between steel tube and concrete core. The nonlinear finite element program ABAQUS is used. Material and geometric nonlinearities of concrete and steel are considered in the analysis. The damage plasticity model provided by ABAQUS is used to simulate the concrete material behavior. Comparisons between the finite element analyses and own experimental results are made to verify the finite element models. A good agreement is observed between the numerical and experimental results. Parametric studies using the numerical models are performed to investigate the effects of diameterto-thickness ratio, uniaxial compressive strength of concrete, length of shear connectors, and the tensile strength of shear connectors.

• Structural Engineering and Mechanics
• /
• v.35 no.1
• /
• pp.1-18
• /
• 2010

Bonding of carbon fiber reinforced polymer (CFRP) composites has become a popular technique for strengthening concrete structures in recent years. The bond stress between concrete and CFRP is the main factor determining the strength, rigidity, failure mode and behavior of a reinforced concrete member strengthened with CFRP. The accurate evaluation of the strain is required for analytical calculations and design processes. In this study, the strain between concrete and bonded CFRP sheets across the notch is tested. In this paper, indirect axial tension is applied to CFRP bonded test specimen by a four point bending tests. The variables studied in this research are CFRP sheet width, bond length and the concrete compression strength. Furthermore, the effect of a crack- modeled as a notch- on the strain distribution is studied. It is observed that the strain in the CFRP to concrete interface reaches its maximum values near the crack tips. It is also observed that extending the CFRP sheet more than to a certain length does not affect the strength and the strain distribution of the bonding. The stress distribution obtained from experiments are compared to Chen and Teng's (2001) analytical model.

• Journal of the Korean Chemical Society
• /
• v.26 no.5
• /
• pp.296-303
• /
• 1982

The solubilities of 1-phenyl-2-acetamido-3-butanone were measured in $H_2O$ at 20, 30 and 40$^{\circ}$C at pressure from 1 to 4500 kg/$cm^2$. Pressure going up to 4500 kg/$cm^2$, the solubility in $H_2O$decreases consistantly as that of diketopiperazine does. As diketopiperazine is a model compound of peptide bond and 1-phenyl-2-acetamido-3-butanone has only one peptide bond and a pretty large hydrophobic group, the solubility behavior is quite surprising. Volume change and heat capacity change data are reasonable.

• Structural Engineering and Mechanics
• /
• v.9 no.5
• /
• pp.491-504
• /
• 2000

A convenient method for enhancing the strength and stiffness of existing reinforced concrete beams is to bond adhesively steel plates to their tension faces. However, there is a limit to the applicability of tension face plating as the tension face plates are prone to premature debonding and, furthermore, the addition of the plate reduces the ductility of the beam. An alternative approach to tension face plating is to bond adhesively steel plates to the sides of reinforced concrete beams, as side plates are less prone to debonding and can allow the beam to remain ductile. Debonding at the ends of the side plates due to flexural forces, that is flexural peeling, is studied in this paper. A fundamental mathematical model for flexural peeling is developed, which is calibrated experimentally to produce design rules for preventing premature debonding of the plate-ends due to flexural forces. In the companion paper, the effect of shear forces on flexural peeling is quantified to produce design rules that are applied to the strengthening and stiffening of continuous reinforced concrete beams.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.7
• /
• pp.2097-2108
• /
• 2014

Chemical feature based quantitative pharmacophore models were generated using the HypoGen module implemented in DS2.5. The best hypothesis, Hypo1, which was characterized by the highest correlation coefficient (0.96), the highest cost difference (61.60) and the lowest RMSD (0.74), consisted of one hydrogen bond acceptor, one hydrogen bond donor, one hydrophobic and one ring aromatic. The reliability of Hypo1 was validated on the basis of cost analysis, test set, Fischer's randomization method and GH test method. The validated Hypo1 was used as a 3D search query to identify novel inhibitors. The screened molecules were further refined by employing ADMET, docking studies and visual inspection. Three compounds with novel scaffolds were selected as the most promising candidates for the designing of Mcl-1 antagonists. Finally, a 10 ns molecular dynamics simulation was carried out on the complex of receptor and the retrieved ligand to demonstrate that the binding mode was stable during the MD simulation.